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By Andrea Koschinsky, Sophie Paul

"INTRODUCTIONOnce again deep-sea mining has been receiving a lot of attention in recent years. Industrial and political advancements also call for environmental baseline studies and analyses to aid the development of standards and monitoring protocols. As part of the EU research project “JPI Oceans: Ecological Aspects of Deep-Sea Mining”, the RV Sonne cruise SO242 to the Peru Basin revisited the DISCOL area that had been artificially disturbed in 1989. This offered the unique opportunity to study a deep-sea site 26 years after a disturbance similar to manganese nodule mining had been carried out (Figure 1). A comparison of a variety of undisturbed and disturbed sites shed light on the re-establishment of a geochemical equilibrium and a range of baseline values. This information can help to inform standard development for monitoring and mining purposes.Heavy metal data and its applicationResearch findingsDuring the cruise, disturbed and undisturbed surface sediment was sampled. The pore water analyses show that the 26 years old disturbance is not visible in the metal profiles and that the pore water reaches equilibrium through diffusive fluxes relatively quickly. The sediment, however, shows some differences between disturbed and undisturbed sites in the upper 20 cm, even after 26 years. Lower concentrations in the usually manganese-oxide rich top layer, variations and “unnatural” peaks in the manganese profiles, for example, suggest removal or mixing of the top layer (Figure 2)."

Jan 1, 2017

By I Swane, R Rait, A Robertson

Geochemical assessment of mine waste materials prior to commencement of a proposed mining operation is a fundamental component of mine feasibility studies and the regulatory approvals process. Static and kinetic geochemical test methodologies are widely used to predict the geochemical nature of mine waste materials and to develop strategies for managing potentially æhostileÆ materials. These data can also be integrated with data from other fundamental studies such as hydrogeology to predict specific environmental outcomes and potential impacts at mine closure and post-closure.A case study is presented for a proposed open pit gold mine in Mongolia, which illustrates how geochemical, hydrogeological and groundwater quality data can be used as part of a geochemical modelling process to predict the final pit lake water quality over time. A series of static and kinetic test geochemical test programs were completed and acquired data integrated with hydrogeological and groundwater quality data provided by the proponent. A widely used geochemical modelling program (PHREEQC) was used to develop the geochemical model and predict water chemistry in the pit void after mine closure. Sensitivity analyses were completed to explore the effects on the model output of groundwater to leachate water ratio, pit wall rock type and climate.Modelling has indicated that pit void water should be pH circum-neutral at mine closure and should remain within Mongolian and World Bank water quality guideline limits under the modelled simulation most likely to occur in the field. Final void water salinity is expected to increase eight fold over 14 years after end of mine life due to a continuous flux of salts (particularly sulfate salts) into the pit lake whilst the pit lake volume will remain relatively constant due to evaporation and a slow recharge rate. Dissolved metal and sulfate salt concentrations in pit water are also predicted to increase over time and could be moderately elevated compared to applied water quality guideline values. Some of the metal concentrations, however, may be lower as these would be expected to precipitate at circum-neutral pH and greater. Recommended additional assessment work on the project when mining commences includes determining the magnitude of adsorption and co-precipitation of metals occurring in the pit void water/sludge system.CITATION:Robertson, A, Rait, R and Swane, I, 2013. Geochemical assessment of mine waste materials and prediction of final pit lake water quality at a proposed gold mine in Mongolia, in Proceedings The Second AusIMM International Geometallurgy Conference (GeoMet) 2013 , pp 165-170 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 29, 2013

By Roman Pyrih, Jim V. Rouse

Because cyanide is a naturally-occurring chemical, geochemical and biogeochemical mechanisms exist to retard or attenuate the movement of cyanide and its compounds in the subsurface and to degrade such compounds into low-hazard reaction products. The attenuation capacity of subsurface earth materials can be measured, predicted, and enhanced by simple and inexpensive procedures. The paper describes methods of testing the geochemical and biogeochemical attenuation capacity of the subsurface and offers general suggestions for methods of enhancing such capacity. It also presents examples of data which documents such attenuation.

Jan 1, 1991

By C. Ptacek, D. Hiller, J. L. Janbor, H. Mccreadie

Between 1991 and 1994, metallurgical residues from a pressure-oxidation autoclave at the Campbell Au-quartz mine at Red Lake, northern Ontario, were neutralized with dolomite-rich flotation tailings and were deposited in a polyethylene-lined disposal area. Mineralogical analysis indicates that most of the As occurs as a crystalline ferric sulfarsenate, and some is associated with Fe oxides and with K-H3O jarosite. Field pore-water geochemical data from 1994 and 1995 showed increases in Fe(II) and As(III) concentrations, suggesting that the sulfarsenate and jarosite are dissolving; none of the discrete As phases included in a thermodynamic database limit dissolved-As concentrations, and these concentrations may continue to increase. These results demonstrate the potential for Fe and As loading through groundwater systems.

Jan 1, 1998

By R. Argane

In this work we assessed the geochemical behavior of concentrator tailings deposited at the abandoned mines of Zeida and Mibladen (Upper Moulouya, Morocco), using physico-chemical analyses, mineralogical characterization, acid base accounting and weathering cell tests. The aim of the study was to evaluate mine drainage quality and to assess metal mobility from these concentrator tailings. Chemical analyses show that the Upper-Moulouya abandoned tailings contain relatively high quantities of lead (0.261 to 0.594 % wt). Mineralogical analyses reveal the abundance of neutralizing minerals (calcite, dolomite, ankerite, and aluminosilicates) which influence mine drainage and metal mobility in mine tailings. Leachate analyses from weathering cell tests show alkaline conditions, small conductivity values, and low solubility of Pb-mineral phases. According to these results, abandoned mine tailings in the Upper-Moulouya district have very low potential for generation of contaminated mine drainage and for leaching of heavy metals. However, the inhalation of tailings exposed to winds generate dust problem facing the local population and may cause health consequences.

Aug 1, 2013

By Daryl R. Tweeton, William H. Engelmann, Orin M. Peterson, Jon K. Ahlness, Gregory R. Anderson

The Bureau of Mines measured the geochemical changes as H2SO4 was used for in situ uranium leaching by Rocky Mountain Energy Company near Casper, Wyoming. Cores and ground water were analyzed before leaching. Water samples were taken from observation wells located between injection and production wells as the leach solution was brought up to full strength in several steps. Measurements were made of pH, Eh, temperature, conductivity, total dissolved solids, dissolved oxygen,HC03, U. V, Na, K, Ca, Mg,S04, CI, Mo, Mn, Fe, AI, Si, F, P, As, and Se. The data were gathered to assist in geochemical modeling of leaching and to study the potential environmental effects of acid leaching. Environmental considerations appear favorable. For example, the concentration of Se, a toxic element often found in uranium deposits, stayed below the EPA standard for drinking water.

Jan 1, 1979

By Daryl R. Tweeton

The Bureau of Mines measured the geochemical changes as H2S04 was used for in situ uranium leaching by Rocky Mountain Energy Company near Casper, Wyoming. Cores and ground water were analyzed before leaching. Water samples were taken from observation wells located between injection and production wells as the leach solution was brought up to full strength in several steps. Measurements were made of pH, Eh, temperature, conductivity, total dissolved solids, dissolved oxygen, HC03, U, V, Na, K, Ca, Mg, SO4, C1, Mo, Mn, Fe, Al, Si, F, P, As, and Se. The data were gathered to assist in geochemical modeling of leaching and to study the potential environmental effects of acid leaching. Environmental considerations appear favorable. For example, the concentration of Se, a toxic element often found in uranium deposits, stayed below the EPA standard for drinking water.

Jan 1, 1979

By G D. McDonald

Flinders Mines is an ASX300 iron ore explorer and developer with a tenement package located in the Hamersley Ranges region of Western Australia, approximately 70 km north of Tom Price. Exploration over the past three years has identified a Global Resource in excess of 740 Mt at a grade of 55.4 per cent Fe (+50 per cent Fe cut-off). This resource is spread across multiple deposits and has been divided into a number of mineralisation type domains based on geometallurgical and geochemical boundaries. These domains are comprised of transported haematite rich detrital iron deposits (DID) and goethite dominant Channel iron deposits (CID) as well as in situ bedded Brockman iron deposits (BID). On the basis of differences in physical and chemical characteristics, the DID have been divided into four discrete units. The four DID units form a stratigraphic sequence with the iron grade increasing and the contaminant concentrations decreasing with depth. The upper DID unit is lower grade and currently unlikely to provide a marketable product, without signifi cant beneficiation. The lower three DID units, together with the CID and BID, are of a higher quality and have the potential to yield marketable ore. The ability to define and recognise these different units has resulted in a more reliable and robust geological interpretation and hence greater confidence in the resulting resource model. This has been evident in the excellent conversion of inferred to indicated resources.

Jul 11, 2011

By Sung-Hyun Park

Core sediment samples collected from the KODOS area of the Clarion-Clipperton Fracture Zone in the NE Equatorial Pacific were analyzed for chemical and mineralogical compositions to investigate the depth- and time-related variation of paleoenvironmental and paleoceanographic conditions during their deposition. These core sediments are divided into three layers from top to bottom by its color; 1) brown layer (Unit I), 2) pale brown layer (Unit II), and 3) black brown layer (Unit III). Geochronology of 10Be indicated the depositional age of Quaternary for Units I and II and of late Pliocene for Unit III with a potential short hiatus between them. Analyses of interelemental correlation identified three major groups of elemental groups that show moderate-to-strong correlations: 1) Al, Ti, K, and Fe representing for terrestrial alumino-silicate fraction of sediments, 2) Ca, P, REEs, Cu, and Zn for biogenic apatite, and 3) Mn, Ni, and Co for hydrogenous Mn-oxide. With an exception, Fe content was very high and showed fair correlations with Mn, Ni, and Co in Unit III. Unit III shows high smectite but low quartz and illite contents compared to the overlying two units, indicative of reduced supply of terrestrial materials. In a meanwhile, major elements (Fe2O3, CaO, P2O5), minor elements (Cu, Zn) and REEs are highly enriched in Unit III compared to the upper two units. All these elements other than Fe reflect the fraction of biogenic apatite, which indicates higher fraction of biogenic components in Unit III. This is also supported by higher amount of smectite formed by the consumption of siliceous biogenic components. The reduced supply of terrestrial material and/or increased productivity of surface water at the time of Unit III deposition are attributed to Pliocene warming preceding Northern-pole glaciation during Quaternary. Unit III also includes clinoptilolite and unidentified 8Å mineral, likely amphibole, that are absent in Units I and II, suggestive of the possibility of different source region and/or materials during Pliocene. Higher contents of Mn and Fe in Unit III are likely due to the high fraction of Mn-oxide that was formed by diagenetic process after deposition.

Jan 1, 2003

By R M. Briggs, I E. Smith, P M. Black, A B, R L. Brathwaite, J L. Mauk

The Hauraki Volcanic Region of the North Island developed between 18 and 1.9 Ma. Initial andesitic volcanism from 18 to 12 Ma was followed by 12 to 1.9 Ma volcanic activity that included rhyolitic, dacitic, andesitic, and basaltic compositions, with a gradual migration of activity to the SSE. Early andesitic volcanism evolved over the course of 8 m.y. to more silicic compositions; this trend was reset and repeated by post-10 Ma andesitic volcanism. Early and later andesites are otherwise remarkably similar in trace element composition. Rhyolites have the most diverse compositions, suggesting a major role for crustal input in their formation.

Jan 1, 2007

By H Kundapen, B R. Bolton, H Davies

The Ok Tedi porphyry copper-gold mine is located in the Star Mountains of Western Province, Papua New Guinea. Open-cut mine commenced in 1984 and is due to cease around 2010. The mine produces a total of 88 Mt of waste annually including 58 Mt overburden and 30 Mt tailings, which are discharged directly in to the Ok Tedi River. Mine derived wastes are transported downstream and deposited within the river channel in a variety of bar forms. The prevailing hydrogeological conditions including, velocity, competency, capacity, gradient, grain size and specific gravity, control the deposition and segregation of these sediments. Periodic exposure of the reactive sulfides to oxygen during fluctuations in the river discharge may result in oxidation, localised acid generation and liberation of metals into solution. To evaluate the significance of this issue, Ok Tedi Mining Limited initiated an investigation of the sediments deposited in the upper Ok Tedi River as part of its overall ARD Management Program. The specific objectives were to: evaluate the acid-forming characteristics of identified high sulfide river deposited sediments; characterise geochemically the waters in contact with sulfide-bearing river deposited sediments; map and monitor exposure areas and oxidation depth of deposited potentially acid forming (PAF) sediments; determine the depositional processes controlling sulfide distribution; and assess lag period, oxidation and metal release rates for the sediments. This work included the analysis of sediment and water samples collected on a 50 + 50 metre grid at six gravel/sand bars. The sediment samples were analysed for total sulfur, ANC, NAG, total sulfur and total copper. Water samples were tested for general water quality parameters, sulfate and a suite of dissolved metals including; Al, Ca, Cd, Cu, Fe-sol, K, Mg, Mn, Na, S and Zn. This paper presents the results of these investigations with particular emphasis on the geochemistry of the river sediments and associated contact waters.

Jan 1, 2003

By T Mizuta, T Nakano, D Ishiyama

The Tamagawa Hot Spring, from which Ra-Pb-Sr-bearing barite precipitates, is a representative hot spring in a volcanic gas-bearing hydrothermal system associated with Quaternary andesitic to dacitic magmatic activity beneath the Yakeyama Volcano. Thermal water in the Tamagawa Hot Spring is divided into three types: Cl-SO4-type (Ohbuki hot spring: pH 1.2); SO4-type (pH 1.8 to 2.9); and neutral-type (pH 6.1). The concentrations of dissolved components in the Ohbuki Cl-SO4-type thermal water are about ten times higher than in the SO4-type thermal water. The 87Sr/86Sr isotopic signatures of the Ohbuki Cl-SO4-type thermal waters (0.703992 ¦ 0.000004 to 0.704032 ¦ 0.000006) are different from those of SO4-type thermal waters (0.704245 ¦ 0.000003) formed by the interaction of andesitic volcanic rocks (0.704065 ¦ 0.000007 to 0.704093 ¦ 0.000009) and groundwater derived from river water (0.704314 ¦ 0.000012 to 0.704519 ¦ 0.000013) in a shallower part of the hot spring area. The possible origins of Sr in the Ohbuki Cl-SO4-type thermal water and in the SO4-type thermal water are different. The Sr isotopic ratios (0.704130 ¦ 0.000012 to 0.707556 ¦ 0.000014) of Aniai Formation andPreYakeyama Lake deposits occurring below the hot spring area are distinctly higher than those of the Cl-SO4-type thermal water. However, it is expected that a solidifying andesitic or dacitic magma which has similar Sr isotopic ratios of the Ohbuki Cl-SO4-type thermal water, occur in the deep portion of the Tamagawa Hot Spring. The Cl-SO4-type thermal waters having low Sr isotopic ratios do not acquire their Sr isotopic signatures by interaction with strata below the hot spring area, but they are likely to reflect water interaction with a solidifying magma with low Sr isotopic ratios. Components including rare metals in Cl-SO4 type thermal water could be transported from a deeper part. An EXTENDED ABSTRACT is available for download. A full-length paper was not prepared for this presentation.

Jan 1, 2008

By L. C. Hsu, H. F. Jr. Bonham, M. O. Desilets, P. J. Lechler, J. G. Price, L. J. Garside

Abstract-Geochemical background levels have been established for unmineralized sedimentary rocks that are elsewhere the hosts of Carlin-type gold deposits in the Getchell Trend. The Paleozoic rocks in the Winnemucca Quadrangle consist predominantly of the lower Paleozoic siliceous and clastic sequences that were carried eastward along the Roberts Mountains thrust during the Late Devonian and Early Mississippian Antler Orogeny and the late Paleozoic Havallah and Pumpernickel sequences brought along the Golconda thrust eastward during early Mesozoic Sonoma Orogeny. Over 260 rock samples were collected from the Paleozoic sequences. Major and trace elements were determined by instrumental methods best suited for the specific elements. The general geochemical features of the Paleozoic sedimentary rocks are discussed in detail with reference to the data of average abundances of elements in sedimentary rocks. The background and threshold values of certain trace elements in sandstone, shale, and carbonate rock of one formation, as well as back- ground levels for the entire sequence were obtained. The characteristic geochemical features of the Paleozoic rocks in this area include: consistently high Ba and low Au contents (1.1 ppb, 1.5 ppb, 1.1 ppb Au for average sandstone, shale and carbonate, respectively); generally low contents of those elements which may be of environmental concern such as As, Cd, Hg and Pb. Plots of major and trace elements suggest that the majority of the Paleozoic clastic rocks are related to a passive- margin tectonic setting. Samples with gold values higher than threshold are considered to have been affected by hydrothermal alteration related to gold mineralization. Most of these samples generally also have higher values of Sb, Hg, V and/or As. These observations support the use of such elements as pathfinders for gold, although V has not been identified as such before. Ba is not effective for gold exploration in this area due to the generally high background value of Ba, even though it may be an important pathfinder elsewhere.

Jan 1, 1995

By L. C. Hsu, M. O. Desilets, P. J. Lechler, Jr. Bonham, J. G. Price, L. J. Garside

Geochemical background levels have been established for unmineralized sedimentary rocks that are elsewhere the hosts of Carlin-type gold deposits in the Getchell Trend. The Paleozoic rocks in the Winnemucca Quadrangle consist predominantly of the lower Paleozoicsiliceous and clastic sequences that were carried eastward along the Roberts Mountains thrust during the Late Devonian and Early Mississippian Antler Orogeny and the late Paleozoic Havallah and Pumpernickel sequences brought along the Golconda thrust eastward during early Mesozoic Sonoma Orogeny. Over 260 rock samples were collected from the Paleozoic sequences. Major and trace elements were determined by instrumental methods best suited for the specific elements. The general geochemical features of the Paleozoic sedimentary rocks are discussed in detail with reference to the data of average abundances of elements in sedimentary rocks. The background and threshold values of certain trace elements in sandstone, shale, and carbonate rock of one formation, as well as back-ground levels for the entire sequence were obtained. The characteristic geochemical features of the Paleozoic rocks in this area include: consistently high Ba and low Au contents (1.1 ppb, 1.5 ppb, 1.1ppb Au for average sandstone, shale and carbonate, respectively); generally low contents of those elements which may be of environmental concern such as As, Cd, Hg and Pb. Plots of major and trace elements suggest that the majority of the Paleozoic clastic rocks are related to a passive-margin tectonic setting. Samples with gold values higher than threshold are considered to have been affected by hydrothermal alteration related to gold mineralization. Most of these samples generally also have higher values of Sb, Hg, V and/or As. These observations support the use of such elements as pathfinders for gold, although V has not been identified as such before. Ba is not effective for gold exploration in this area due to the generally high background value of Ba, even though it may be an important pathfinder elsewhere.

Jan 1, 1995

By Eli Curiel, Ingar F. Walder, Patrizia P. Schuster, Walt Keyes

Mansfield Canyon, of the Wrightson Mining District, Santa Cruz County, Coronado National Forest, Arizona, was actively mined in the late 1800's and early 19001s, with minor activity until 1953. The main products were lead, silver, copper, zinc, and gold occurring in polymetallic quartz veins. The canyon contains numerous adits and waste dumps, some of which generate metal-loaded acid. Samples of seeps, waste dumps and bedrock have been collected for various analyses: metal concentrations, acid base accounting (ABA), and water quality to evaluate the extent of oxidation and metal release from the start of mining until present, the potential impact, and reclamation options. Although the waste-rock piles within the canyon are small (2,000-10,000 tons), they have a high sulfide content with little or no neutralizing capacity. It is planned, therefore, to move the waste piles either to a constructed repository site within the canyon or to a copper leach facility to be used as an acid generator.

Jan 1, 2000

By Maurizio Violo, Arjan Beqiraj, Umberto Masi

"Abstract - Four main podiform occurrences of chromite have been distinguished in the ultramafic Bulqiza massif, Albania; they are associated from the bottom to the top with: i) basal harzburgites (lower tectonite sequence), ii) dunitic lens-bearing harzbugites (middle-upper tectonite sequence), iii) layered chromitite-bearing dunites of transitional zone, and, iiii) the stratigraphically lowermost part of the magmatic section. However, only the occurrences hosted by rocks ii) and iii) are economically important.Chromite compositions similar to those of other podiform chromites are bimodal. Thus, chromites from occurrences ii) and iii) are richer in Cr than chromites from the other two occurrences. Accessory chromite disseminated throughout the massif is richer in Fe than orebody chromite, displaying similar range of the Cr/Cr+Al ratios, with accessory residue chromite matching the characteristic (Cr/Cr+Al >0.6) range of type-III Alpine peridotites. Both orebody and accessory chromites show compositional ranges correlating with host-rock compositions, i.e., the Cr-rich chromites are hosted by the most refractory ultramafic rocks. Therefore, the Cr/Cr+Al and Mg/Fetot (Cr/Fetot) ratios of chromite are useful for exploration of high-grade, metallurgical chromite ore at Bulqiza and in other massifs of similar geodynamic setting."

Jan 1, 2000

By Ken Pill, Jennifer Nyman, Liz Moran, Keaton Belli, Chelsea Bokman

The Moab Uranium Mill Tailings Remedial Action (UMTRA) Project Site (Site) is a former uranium-ore processing facility near Moab, Utah, where production ended in 1984. The United States Department of Energy Office of Environmental Management (DOE-EM) is responsible for remediating the site to meet 40 Code of Federal Regulations (CFR) 192 standards promulgated by the United States Environmental Protection Agency under the authority of the Nuclear Regulatory Commission (NRC). Tailings from the former mill were stored in an unlined impoundment (tailings pile), totaling 16 million tons of waste material. Surface cleanup has been ongoing since 2009 and consists of removal and transport of tailings via rail to an off-site disposal facility in Crescent Junction, Utah, with an estimated completion date around 2029. Gravity-driven migration of tailings fluids and recharge through the tailings pile and former on-site ore storage areas in the northeastern part of the site led to contamination of site soil and groundwater. The primary contaminant of concern is ammonia, which was present in fluids used in the milling process (DOE 2003). Uranium is a contaminant of potential concern. An interim groundwater remedy is currently in place that utilizes a system of extraction and injection wells to limit discharge of contaminated groundwater into the nearby Colorado River. Exceedance of surface water standards for ammonia are a principal concern due to potential endangered species fish habitat areas along the Colorado River adjacent to the Site. When necessary, surface water diversion is used to lower surface water ammonia concentrations when suitable habitats develop for endangered young-of-year fish. Once surface cleanup concludes and the tailings pile is removed, a formal groundwater remedy must be selected and documented in a Groundwater Compliance Action Plan (GCAP). Under Title 1 of the Uranium Mill Tailings Radiation Control Act, natural flushing (i.e., monitored natural attenuation), may be selected as the groundwater remedy if it can be demonstrated that the remedy will achieve groundwater standards within 100 years. The 40 CFR 192 groundwater standard for uranium is 44 micrograms per liter (μg/L), and the target groundwater concentration of ammonia based on adverse effects on local fish species is 3 milligrams per liter (mg/L). A collaboration with Geosyntec Consultants, Inc. (Geosyntec), the Moab UMTRA Project team, the DOE Office of Legacy Management, the DOE-EM, and the Network of National Laboratories for Environmental Management and Stewardship was held in 2022 with the goal to generate actionable recommendations to develop a GCAP for the Site. The primary recommendation was development of a groundwater fate and transport model to predict the remedial timeframe under various groundwater remedies. This paper presents the results of soil and groundwater sampling, geochemical modelling, and laboratory column and batch reactor testing that will be used to parameterize a numerical model for estimating the remedial timeframe under various scenarios, including natural flushing.

Feb 1, 2025

By H. D. B. Wilson

"IntroductionRECENT ADVANCES in geo-chemistry and in •our knowledge •of crystal structure provide a key which enables us to create a systematic picture of the genesis of many ore deposits. This genetic scheme may be used with confidence in assessing certain types of orebodies and may be of some aid in actual exploration, since it affords a rational explanation of the dependence of the composition •of the ore minerals on that of the rock type in which they occur with which they -are •associated. For purposes of the present paper, .the elements chosen are •chromium, vanadium, iron, and titanium. The oxides of all these metals occur in deposits of similar or related type, and it is proposed to show that, for each, the composition of the •ore mineral is related to •the composition of the enclosing :rock, and that one of the principal factors controlling the composition of the ore is the ionic size of its constituent elements.Geochemical PrinciplesThe crystals of the rock-forming silicates and of the magmatic oxide minerals are essentially ionic types. This means that they are composed •of oppositely charged ions such as Mg²+ and 0²-, which are held together by electrostatic attraction. The ions of each element are spherical, with characteristic size known as the ionic radius. Crystals are built up by the packing of these spheres in the most stable arrangement compatible with the size and the size and valence of the ions• involved.Many of the principles governing the formation of ionic crystals are •simple ,and logical."

Jan 1, 1953

By B Manda, K L. Sandvik, K Musiwa

Mining and processing of pyrite ore at Iron Duke Mine, north east of Zimbabwe, generates large quantities of acidic mine water as a result of the oxidation of iron sulfides on exposure to air and water used in the drilling and blasting operations. The acid mine drainage (AMD) contains elevated levels of dissolved Fe, Al, Mn and sulfate and has characteristic pH values ranging from about 0.50 to 3.00. Handling and disposal of such a drainage places significant impacts on the economics of the mining operation due to the corrosive nature of the drainage on infrastructure, the limitations placed on water reuse and discharge to the environment under a new law governing effluent discharge. Treated sludge at Iron Duke is chemically unstable, changing pH from ~7 to ~3 within four days after deposition in the evaporation ponds. The effluent does not meet the permitted level of neutral pH, 500 mg/l sulfate and less than 2000 mg/l total dissolved solids. Excessive acid seepage from the evaporation ponds has resulted in contamination of the ground water below the ponds area, which shows high mean annual levels of iron (368.67 mg/l), sulfate (1702.89 mg/l) and low pH (2.86) in addition to other pollutants. This poor quality seepage infiltrates into the nearby Yellow Jacket River, contaminating the public water source. Furthermore, a deterioration of the land area and vegetation adjacent to the tailings dump is also observed. Understanding the controls on the neutralisation of acidic drainage and long-term sludge stability after placement in evaporation ponds is essential to minimise costs of closure requirements and for the protection of environment and human health. This study examined the effects of the master variables pH, redox potential, acidity and alkalinity on acid neutralisation. The results indicate that ferrous hydroxides are not as stable as ferric hydroxides and that proper oxidation of iron also leads to better sludge stability, higher treatment efficiency and a manageable sludge viscosity. Metal hydrolysis and secondary mineral formation at the evaporation ponds under a wide range of pH and redox conditions is responsible for equilibrium shifts in metal reactions, resulting in high potential for metal leaching and mobility. Mechanisms of metal attenuation are also discussed.

Jan 1, 2006

By F. P. Agterberg

It can be useful to model the mean grade values for a metal in mineral deposits containing that metal as representing the extreme value tail of a lognormal frequency distribution for the concentration values of the metal in common rocks of all types. Results for copper and zinc in the Abitibi area of the Canadian Shield are compared to results previously obtained for the Canadian Appalachian region. The lognormal model is also applied to a set of 162 large gold deposits in the Abitibi area. In the second part of the paper, 1311 large and small gold deposits in the Abitibi area are modeled as discrete events. By means of a newly developed spatial clustering model it is possible to predict the variances of random variables for frequencies of deposits in cells of different sizes.

Jan 1, 1981