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By H. A. Schlesinger

Various studies have estimated that for the next few decades, about half of all new power plants will be nuclear. The other half will be fueled with coal. Pending legislation on air pollution control would require all new coal-fueled power plants to install stack gas scrubbers or other technology to reduce sulfur oxide (SO,) emissions. These regulations would require flue gas desulfurization (FGD) or other technology for SO, reduction even on lower sulfur western coals. Among the options for FGD are single or dual alkali throw away processes using lime or limestone as the major reagent. These processes are currently more economically attractive than recovery processes, such as magnesium oxide and Wellman- Lord, that produce a salable product such as sulfur or sulfuric acid. One of the major problem areas with the throw away processes is disposal of the thrown away solid wastes, primarily calcium sulfite (CaSO3) and calcium sulfate (CaS04). Coal ash also must be disposed of, even if SOx reduction is not required. This paper addresses the alternatives for handling and disposal of throw away lime, limestone, and dual alkali process solid wastes. Advantages, disadvantages, and the economics of various methods are discussed. Both large central station power plants (500-1000 MW capacity) and smaller industrial power plants (up to 100 MW capacity) are considered. High sulfur eastern coals (53% S) and lower sulfur (3 1% S) western coals are considered.

Jan 1, 1981

By H. Yoon

Several processes involving injection of sorbent and humidification water downstream of the air preheater in a coal-fired boiler unit, are being developed as low capital cost retrofit S02 control options. Extensive laboratory work, pilot plant programs and larger scale programs have developed performance data and design information. Many of these programs were supported by the U. S. Department of Energy (DOE) as "proofs-of-concept" of three different processes proposed by Dravo, Bechtel and General Electric. Based on these project results, DOE formulated a comprehensive in-duct sorbent injection development program to fully commercialize the technology by 1992. Also, EPRI will conduct a 4 MWe pilot program to develop its HYPAS process. The Consol Coolside process is scheduled for utility demonstration in 1989 on a 104 MWe unit at the Ohio Edison Edgewater Station under partial sponsorship of the DOE Clean Coal Technology Program.

Jan 1, 1989

By R. Bokotko, J. D. Miller, J. Hupka

Laboratory results from an initial study on the removal of SO2 from gas mixtures are reported using air-sparged hydrocyclone (ASH) technology. Tap water and alkaline solutions were used for absorption and the influence of gas flow rate, water flow rate and length of the ASH unit were investigated. Complete removal of SO2 was possible with very favorable kinetics. The efficiency of sulfur dioxide absorption from air using the ASH is compared with the efficiency of conventional technology.

Jan 1, 2002

By Forsythe DJ, Sun S-S Andrew AS

Paragenetic, fluid inclusion, stable isotope, and 87Sr/86Sr and 143Nd/144Nd isotope studies of the Mt Carbine tungsten deposit in North Queensland provide information on the sources of the mineralising components and record the history of fluid-rock interaction during the hydrothermal process. The ore minerals , wolframite and scheelite , are contained in quartz veins which post-date the major deformations in the Siluro-Devonian Hodgkinson Formation . Mineralisation was immediately preceded by the emplacement of the Mossman Batholith (280 ¦ 7 Ma). Two major stages of mineralisation are present and separated by a brittle fracturing episode . The stable isotope and Sr and Nd isotope data suggest that the ore fluids during stage I and most of stage II mineralisation were a mixture of magmatic water and non-magmatic water (connate or metamorphic) which had experienced a long residence time and had extensively exchanged with the sediments at high temperature. Subsequent mineralisation events were dominated by fluids of meteoric derivation with a short residence time. The data imply that other solutes, such as W, were probably derived in minor part from local country rock sources with the major contribution coming from a magmatic source related to the granite batholith.

Jan 1, 1987

By A. Kale

A chlorination pilot plant having capacity to produce 5?10 kg/hr of titanium tetrachloride is in operation at the chlorination facility in Mintek. The bubbling fluid bed chlorination plant can be operated in batch and/or continuous process to study the chlorination kinetics of various feedstocks. The chlorination of titaniferrous ores to produce titanium tetrachloride (TiCl4) was carried out during the commissioning of the pilot plant and also as part of the titanium programme carried out at Mintek. TiCl4 is a basic raw material for producing commercial titanium dioxide pigment and titanium metal. This paper discusses the challenges faced during the commissioning and operation of the chlorination pilot plant. It also discusses the effect on the auxiliary facilities and instrumentation as a result of the harsh operating conditions of +1000°C and use of corrosive gases like chlorine and titanium tetrachloride. It discusses the effect of physico-chemical properties of the titanium tetrachloride and iron chlorides. The effect on the chlorinator refractory lining due to heating and cooling of the chlorinator is also discussed. Besides the special provisions made during the design of the chlorinator, this paper also discusses the operational experience and possible solutions to be implemented in future. Keywords Fluid bed chlorination, titanium ore chlorination, titanium tetrachloride (TiCl4) production using fluid bed technology.

Jan 1, 2011

By Casley G. E, Pritchard J

A single slurry fed fluosolids roaster was chosen to replace six multiple hearth roasters in the Copper Smelter at Mount Isa as part of the overall program to increase production from 100 000 to 155 000 tonnes blister copper per annum. The paper describes factors influencing the choice of the unit, problems encountered during the commissioning and details of the present roaster operation.

Jan 1, 1974

By K. H. Heino

Two 200 T/da Lurgi Turbulent Layer fluid-bed roasters have been in operation at Canadian Electrolytic Zinc Limited since 1966. Zinc concentrate containing 52-54% Zn, 9-11% Fe,31-33% S is treated to produce calcine containing 60-62% Zn,10-12% Fe, .l-.3% S as sulphide and .8-1.2% S as sulphate. Each roaster train comprises a waste heat boiler, two cyclones in parallel and a two-field electrostatic precipitator. Distribution of calcine collected is 10-15 percent from bed overflow, 55-65 percent from boilers, 20-25 percent from cyclones and 2-6 percent from precipitators. A Monsanto designed contact plant produces acid at a rated capacity of 365 T/da (100% H2304 basis) from roaster gases diluted to 7.0-7.5% S02. The process steps are gas cleaning and cooling by weak acid scrubbing, acid mist removal in electrostatic precipitators, gas drying in 93.5-96.5% H2304, conversion of sulphur dioxide to sulphur trioxide in a four-pass converter containing vanadium pentoxide catalyst, and absorption of the sulphur trioxide in 98.1-98.3% H2S04. Product acid is 93.2% H2S04. Conversion efficiency is 97-98 percent and overall sulphur recovery from concentrate is 87-90 percent. The adjacent fertilizer plant has a capacity of 135 T/da of P205. The products are 54 percent phosphoric acid, run-of-pile triple superphosphate, and diammonium phosphate. The plant is of Ugine-Kuhlman design and consists of an air-cooled multiple tank reactor, a tilting pan filter, and a forced circultation vacuum evaporator. Triple superphosphate is made on a continuous belt and partially cured in a rotary dryer. Diammonium phosphate is produced by ammoniating phosphoric acid in a single stage reactor. The slurry of ammonium phosphate is granulated in a blunger and dried.

Jan 1, 1970

Roasting of zinc concentrate at the Risdon Works of the Electrolytic Zinc Company of Australasia Limited, (E.Z.), is carried out in two fluid bed roasters capable of treating 450000 tonne/yr, or sufficient for the output of 220000 tonne of salable zinc. The furnaces were constructed by Lurgi, Australia, to the basic design developed by Vieille Montagne Company of Balen, Belgium. The advantages of fluid bed roasting include a higher metallurgical efficiency in sulphur oxidation from a feed which does not require any pre-grinding, mechanical reliabil- ity through the absence of any moving parts within the furnace and the capability of being scaled up to a large unit.

Jan 1, 1977

By K. P. Wright

THREE OF the gold mines in the Red Lake Camp operates fluid bed roasters in their milling circuits. The mines are Campbell Red Lake, Cochenour Willans, and Dickenson. The roasters are used for the autogenous roasting of a flotation concentrate for subsequent gold recovery by cyanidation. Cochenour and Dickenson operate single stage reactors, whilst Campbell use a two-stage system. Ore treated by the mines is similar in that the major part of the gold is associated with arsenopyrite. Other sulphides present are pyrite, pyrrhotite, stibnite and sphalerite. Gangue minerals are mainly quartz, with carbonates and talc. Mineralization is, for the most part, extremely fine, and there is intimate association between sulphides and quartz, so much so, th at a picked specimen of apparently massive arsenopyrite will frequently contain as much as 80 per cent gangue. Gold recovery by straight cyanidation on this type of ore would not be higher than 80 per cent and

Jan 1, 1961

By R. Parkins

This paper will discuss a method used to refine the fill level, and orifice size for a dual motor conveyor drive with extended delay chamber fluid couplings. The subject conveyor is located on the surface at the Mountain Coal Company West Elk Mine, located near Somerset, co.

Jan 1, 1996

By F. F. Peng, Y. Xia

In modeling of hindered-settling bed separators, the published separation mechanisms are based on differences of particle density and size distributions, without the details of complexity of particles-liquid interactions. A fluid dynamic model for the separator is developed using Euler-Lagrange approach of Computational Fluid Dynamics (CFD). Fluid motion is obtained from solving the movement of liquid governing equations. The damping effect on flow pat-terns caused by the movement of particles resulted in liquid-particle coupling is included in the model. Effects of particle size, and particle density compositions, feed rate, feed water flow rate, upward fluidizing water flow rate, etc., are simulated in the 2-D separation model. Flow pattern effects on the separation of fine particles in the separators with center downward-flow and side cross-flow feed systems are investigated.

Jan 1, 2004

By P. Reyes

The Codelco Chile El Teniente Division Caletones Smelter has an objective to smelt 1,250,000 tonnes per year of copper concentrate. This is a great challenge for the smelter facilities and particularly for the acid plants. The analysis ensuring that there are no obstacles to achieve the production capacity was of great importance. Therefore a series of activities were undertaken as well as studies dedicated to reach the target. This paper presents work focused on a fluid dynamic study, translated in an operation methodology of integrated handling of the smelting and converting gases with the objective to optimize the gas flow and S02 concentration. The optimization should be done employing the current installations, equipment and instrumentation and/or minor modifications. In the first part of the work the condition of the instrumentation involved in the gas handling was checked, improvements determined and the corresponding corrective actions were carried out. The proposed operation method consists of operation of the Cleaning Gas Plant 2 (TC' s gases) and operation of Gas Cleaning Plant 1 (the remaining gas plus the gases from CPS). The implementation of the operation method involves the modification of the valve of the gas into the duct to plant 1 from On to Off to modulate flow. After modification a three days test was carried out. To evaluate the tests, a "Sulphur Capture" indicator was used. During the test the behaviour of the effluent treatment plants was closely examined. No problems or unusual operating conditions were observed. The reduced flow of gas to Gas Cleaning Plant No. 1 permitted the start up of the 2nd test day treating most of the gas received by Gas Cleaning Plant No. 2. The operation was carried out with the limitation not to increase the effluent pond level, which was maintained constant.

Jan 1, 2007

By Kent D. Peaslee

When supersonic oxygen jetting is used in electric furnace steelmaking, the lance jet axis is typically inclined at larger angles to the vertical than is used in basic oxygen steelmaking. The supersonic jet is important not only for refining the steel, but for sustaining the foamy slag in the electric furnace. Physical modeling was carried out using a room temperature, two-dimensional slice apparatus in which mercury represented the metal and water-glycerol the slag. High speed video photography with image analysis was used to study the effects of the angle of inclination on the slag/metal bath. Mathematical modeling using FLUENT provided a method of predicting flow patterns and the trajectories of drops injected at various points in the flowfield. A one-half scale water model of the system, in which lance heights, angles, and flowrates simulated those encountered in steelmaking operations, was used to provide a better understanding of some aspects of the oxygen blowing process in electric furnace steelmaking.

Jan 1, 1994

By Z. X. Cui, X. D. Ma, L. Contreras, X. Jiang

The bath smelting process is one of the key techniques applied in the current copper smelting production, which includes bottom-blown and side-blown furnaces differently from the direction of gas injection. Liquid matte and slag form the bath in the smelting furnace. To better understand the fluid dynamic of the bath and further optimise the operational efficiencies in the smelting furnace, physical simulation of the bath in the horizontal cylindrical reactor was investigated. The mixing behaviour and wave motion of the bath in the bottom-blown and side-blown furnaces have been studied systematically. The mixing time is reduced with increasing gas flowrate and height of the lower layer, while it increases significantly with increasing the height of the upper layer. The wave motion in the furnaces can be suppressed with the presence of the upper layer, but the bath with a lower density generates higher wave amplitude. Overall, in comparison to bottom-blown mixing, side-blown mixing shows better mixing efficiency and lower wave amplitude. In addition, the plume eye and splash phenomena occurred in the bottom-blown furnace have also been studied. INTRODUCTION The bath smelting process is one of the principal techniques used in the current copper making industry. The bath smelting techniques have some advantages of high smelting efficiencies, low capital costs, low energy consumptions and reduced dust generations. From the direction of gas injection, the bath smelting techniques can be classified into five general types: (1) top-submerged blown, e.g. Ausmelt and Isasmelt; (2) top-suspended blown, such as Mitsubishi smelting; (3) top direct-to-copper smelting, such as Outokumpu smelting; (4) submerged side-blown, such as Noranda and Teniente smelting; (5) bottom-blown, such as Dongying Fangyuan bottom-blown copper smelting furnace (Schlesinger et al., 2002; Zhao, Cui, & Wang, 2013; Perez-Tello et al., 2018). In many metallurgical processes involving bath smelting situations, the objectives of agitation are to accelerate the bath homogenization inside the bath which makes a significant contribution to process efficiency and product quality. Extensive mixing studies have been performed for ladle refining and tundish associated to steelmaking processes through water physical models. Mixing time is the parameter used to quantify the efficiency of mixing in the liquid bath and the first empirical equation predicting mixing time was proposed by Nakanishi, Fujii and Szekely (1975). Later on, more systematic studies have been carried out on ladle mixing and researchers realized that the geometry of the vessel could also have a significant impact on mixing (Khajaviand & Barati, 2010). However, the investigations using ladles which are vertical cylindrical vessels, cannot be directly used in the study of mixing behaviour in horizontal cylindrical reactors. Understanding the fluid dynamics inside horizontal cylindrical bath smelter is useful from the industrial perspective. Recently fluid dynamics of horizontal cylindrical smelter related to copper smelting have been studied by the authors’ group (Shui et al., 2015a, 2015b, 2018a; 2018b; Xu et al., 2018, 2019).

Jan 1, 2019

By James F. Albus, Vincent C. Grimshaw

High pressure fluid energy grinding, or jet milling, is a versatile method of continuously fracturing solids into fine particles to gain substantial increases in exposed surface area Applications in industrial minerals grinding include calcium carbonate, talc, barytes, mica, diatomaceous earth, bauxite, rutile, coal, kaolin, sepiolite, diamonds, etc The basic principles can be extended to provide continuous drying and delivery of discrete par¬ticles from a wet process slurry The main design and operational features of jet mills and dryers are described, relating energy consumption for both air and steam milling and hot air drying techniques Mean particle sizes in the order of 1 micron are achievable from pre-milled feeds, or maintained from similar slurries in the drying mode Aspects of feed preparation and multi-stage processing are discussed

Jan 1, 1983

By Vincent C. Grimshaw

High pressure fluid energy grinding, or jet milling, is a versatile method of continuously fracturing solids into fine particles to gain substantial increases in exposed surface area. Applications in the minerals industries include calcium carbonate, talc, barytes, mica, diatamaceous earth, bauxite, rutile, coal, kaolin, sepiolite, diamonds, etc. The basic principles can be extended to provide continuous drying and delivery of discrete particles from a wet process slurry. The main design and operational features of jet mills and dryers are described, relating energy consumption for both air and steam milling and hot air drying techniques. Mean particle sizes in the order of 1 micron are achieveable from pre-milled feeds, or maintained from similar slurries in the drying mode. Aspects of feed preparation and multi-stage processing are discussed.

Jan 1, 1983

By A. N. Khayyat, R. G. Temple, R. Skelton

The fluid energy mill has been in use since the 1930's when an early patent was granted to N.H. Andrews in the USA. The microniser design has been basically unaltered since that date and current designs such as the Airfilco "Micronizer" have been progressively developed from results based on wide experience. The authors have been engaged in a research programme to establish optimum design and operational parameters for the Micronizer so as to provide a more quantitative basis for scale-up prediction of results. An introductory section will first trace the development of fluid energy milling including reference to other designs which have developed alongside the micronizer (especially the “Jet-o-miser"). With regard to design features the number of fluid injection nozzles and their size was investigated to establish the optimum range. Injection angle and, the consequent diameter of the internal "tangential circle" was carefully studied to determine the effect of this parameter on product size. The research was carried out using fine limestone as the test material with air as the grinding medium. Feed size fractions of 0-120µm, 0-250µm, 0-500µm, and 300-600µm were milled and product size analyses were carried out using the Coulter Counter technique.

Jan 1, 1980

By H. Boyd

Fluid energy grinding, or jet pulverization, refers to the process of entraining solid particles in high velocity gaseous or vaporous streams and reducing their size by impact and attrition against other particles or some sort of target. Since all desired size reduction is not achieved in one pass through the zone where energy is applied, some form of classification is necessary to return oversize particles to the grinding zone for further size reduction. Applications Fluid energy mills have normally been used to produce products where the particle size is basically finer than 325 mesh. Products having particle size distributions with a maximum size of 4 or 5 µm, and with a high percentage finer than I µm, can be produced using fluid energy mills. More recently, some fluid energy grinding units have been applied economically to produce ground products with 1 or 2% coarser than 200 mesh. It is also possible to consider usage of a jet-pulverizing zone, without the usual integrated air classi¬fier, operated either in open circuit or in conjunction with a screen. Feed sizes to be delivered to the fluid energy mill depend on the material involved, the type of jet pulverizer used, the finished product size requirement, and the upstream process. In some units feed sizes up to l in. or larger can be accepted, but practical economics usually require the starting material to be -4 mesh or smaller and some pulverizers are typically fed at 20 mesh top size. It is not unusual to find feed materials at essentially -325 mesh when extremely fine products are needed, since capacities are improved with finer feeds. Conventionally the fluid energy grinding process has been used for relatively soft and nonabrasive materials. This includes very low¬melting-point and temperature-sensitive materials or coatings, since there is no measurable temperature rise during fluid energy milling. More recently, however, jet pulverizers are being used on highly abra¬sive materials such as silica, feldspar, glass, zircon, calcined alumina, coke, boron carbide, and similar materials. Since the primary energy application is by impact of particles against themselves, there is a low rate of wear resulting in a small amount of product contamination and in low maintenance costs. Usually the fluid energy pulverizer produces a more narrow particle size distribution than other mills provide, and this is useful where such a requirement exists. It is possible, within limits, to adjust classifi¬cation and other functions of the overall fluid energy system to vary the particle size distribution curve and thereby approach the broader distribution obtained from other grinding methods. By controlling the temperature, composition, and humidity of the fluid used, it is possible to incorporate other functions with the size-reduction process. These include drying or adding moisture, coating, mixing and blend¬ing, and even oxidation or reduction and other chemical reactions or their inhibition. The finished product is discharged in the fluid stream and is conveyed pneumatically to the desired point, where a suitable dust collector must be provided. Operation and Mechanical Features One of the earliest fluid energy mills is the Micronizer now manu¬factured by the Sturtevant Mill Co. Similar units are also manufac¬tured by Jet Pulverizer Co. and others. As shown in Fig. 81, the micronizer consists of a shallow circular grinding chamber with noz¬zles arranged at the outer periphery to discharge tangentially inward. Fluid (usually compressed air or superheated steam) is provided to the nozzles from a manifold at pressures normally in the range of 100-150 psig and at temperatures up to 800°F or higher, depending on the raw material, required results, and economic factors. The com¬pressible fluid expands to high velocity through the nozzles and gener¬ates a spiral flow pattern in the grinding chamber, and discharges

Jan 1, 1985

By G. G. Gold

A leach pad’s fluid flow characteristics greatly affect the recovery of metals from heap leaching. However, because there are other factors such as particle size distribution, application rate and method, and chemical reactions to consider, mining companies often overlook potential problems associated with fluid flow until it is too late. In an effort to better understand the dynamics of fluid flow in leach pads, a series of experiments were preformed using temperature probes. A model leach pad was set up using a particle size distribution, fluid application rate, and application method common to modern leaching methods. Variable water temperatures were applied in succession and data gathered from the three dimensional grid of temperature probes built in to the model. Current work is analyzing these data along with visual observations of the model, computer simulations, past mining experiences, and other related research, in an attempt to develop a low cost test that could be performed prior to large scale leaching to determine the fluid flow characteristics of a particular ore. This paper will summarize the work and findings to this point as well as suggest areas of additional related research.

Jan 1, 2004

By Y. Y. Liu, H. M. Domanus, W. T. Sha

"Casting is fundamental to manufacturing of many types of equipment and products. Although casting is a very old technology that has been in existence for hundreds of years, it remains a highly empirical technology, and production of new castings requires an expensive and time-consuming trial-and-error approach.In recent years, mathematical modeling of casting has received increasing attention; however, a majority of the modeling work has been in the area of heat transfer and solidification. Very little work has been done in modeling fluid flow of the liquid melt. This paper presents a model of fluid flow coupled with heat transfer of a liquid melt for casting processes. The model to be described in this paper is an extension of the COMMIX code and is capable of handling castings with any shape, size, and material. A feature of this model is the ability to track the liquid/gas interface and liquid/solid interface. The flow of liquid melt through the sprue and runners and into the mold cavity is calculated as well as three-dimensional temperature and velocity distributions of the liquid melt throughout the casting process.IntroductionBower et al. (1), in their 1969 review of the evolution of some of the casting techniques, stated that:""The evolution of technology requires alternatives to be available so that choices can be made that lead to changes. The role of solidification science and other disciplines related to casting technology is to develop a better understanding of process and product, so that a wider range of alternatives is possible.Alternatives, whether from science or from invention, must lead to improvements in casting ""utility."" Utility, or economic advantage, must include consideration of total system costs, and final product value. The cost of materials, melt processing and finishing should be optimized with casting costs, since all are part of the production system. It is the favorable relationship between total processing costs and product value that makes a change in casting technology viable, but the best change is not possible unless technology has provided an understanding."""

Jan 1, 1986