Search Documents

By A. W. Fahrenwald

FLOTATION practice in Idaho is now about 13 years old. The advance has been steady during these 13 years. The operators have been alert to take advantage of the newest developments and they have themselves made a constant effort to improve their work. The metallurgical improvements are clue to the development of (1) better equipment, (2) better reagents, and (3) better understanding and control of the process. During the 8 years which the writer has been in this district, there has been continuous experimentation by several companies to improve the ore dressing by flotation methods. Gravity concentration has fought hard to hold its place, and although it is true that gravity processes have been improved during this period, nevertheless, in several of the important mills of the district the few tables that managed to hang on have finally given way. On the straight-lead ores, tables and jigs are still used; and, due to better classification, their hold on this job has been strengthened.

Jan 1, 1927

By Stuart McTavish

"The Brunswick Mining concentrator processes 10,000 D.S. T. per day of a complex sulphide ore. Four separate concentrates- zinc, lead, copper and bulk-are produced by selective flotation. Several major changes have been made to the Brunswick flotation circuit to improve the process and control. This paper will describe the present flotation practices at the Brunswick Concentrator. Special emphasis is given to the conversion of two of the primary circuits to an SO2-aeration flowsheet, and to the addition of a new secondary zinc flotation circuit that produces a zinc concentrate from the plant tailings. IntroductionBrunswick Mining and Smelting Corporation operates a zinclead- copper and silver mine and concentrator near Bathurst, New Brunswick. Since the start-up of operations in 1964, the flotation flowsheet has undergone major modifications to process the increased tonnages and to produce a greater number of concentrates. The flowsheet for the concentrator as it was in 1971 has been described by Neumann and Schnarru) and by Ersklneco. Since then, in 1971, the No.6 concentrator was converted from bulk flotation to selective flotation to produce a copper, lead and zinc concentrate. A separate zinc upgrading circuit was installed in 1972 and a bulk flotation or dezincing circuit, which reduced the zinc in the lead concentrate, was started in 1973. In 1976, the secondary zinc circuit was initiated.In addition to these new circuits, changes have been made to the existing circuits to simplify their operation."

Jan 1, 1980

By Surendra K. Mishra

Metallic and oily components are the major contaminants of industrial wastes. Underground burial and incineration have been the commonly practiced methods of waste management. To provide a relatively more permanent solution, different processes have been developed. In addition to reviewing these processes, potential of using flotation as a process to treat hazardous metal and oil contaminated wastes is discussed in this paper.

Jan 1, 1989

By J Lombardi

OZ Minerals' Prominent Hill copper-gold concentrator is located 130 kilometres south east of the town of Coober Pedy in the Gawler Craton of South Australia. The concentrator was built in 2008 and commenced commercial production in early 2009. The Prominent Hill concentrator is comprised of a conventional grinding and flotation processing plant with a 9.6Mtpa ore throughput capacity. The flotation circuit includes six rougher cells, an IsaMill for regrinding the rougher concentrate and a Jameson cell heading up the three stage conventional cell cleaner circuit. In total there are four level controllers in the rougher train and ten level controllers in the cleaning circuit for eighteen cells.Generic proportional – integral and derivative (PID) control used on the level controllers alone propagated any disturbances downstream in the circuit that were generated from the grinding circuit, hoppers, between cells and interconnected banks of cells, having a negative impact on plant performance. To better control such disturbances, FloatStar level stabiliser was selected for installation on the flotation circuit to account for the interaction between the cells. Multivariable control was also installed on the five concentrate hoppers to maintain consistent feed to the cells and to the IsaMill. An additional area identified for optimisation in the flotation circuit was the mass pull rate from the rougher cells. FloatStar flow optimiser was selected to be installed subsequent to the FloatStar level stabiliser. This allowed for a unified, consistent and optimal approach to running the rougher circuit. This paper describes the improvement in the stabilisation of the circuit achieved by the FloatStar level stabiliser by using the interaction matrix between cell level controllers and the results and benefits of implementing the FloatStar flow optimiser on the rougher train.

Aug 8, 2011

By B Firth, G OÆBrien, B Jenkins

In coal flotation, particles of different components of the coal such as maceral groups and mineral matter and their associations have different hydrophobicities and therefore different flotation responses. By using a new coal grain analysis method for characterising individual grains, more detailed flotation performance analysis and modelling approaches have been developed. The method involves the use of microscopic imaging techniques to obtain estimates of size, compositional and density information on individual grains of fine coal. The density and composition partitioning of coal processed through different flotation systems provides an avenue to pinpoint the actual cause of poor process performance so that corrective action may be initiated. The information on grain size, density and composition is being used as input data to develop more detailed flotation process models to provide better predictions of process performance for both mechanical and column flotation devices. A number of approaches may be taken to flotation modelling such as the probability approach and the kinetic model approach or a combination of the two. In the work reported here, a simple probability approach has been taken, which will be further refined in due course. The use of grain data to map the responses of different types of coal grains through various fine coal cleaning processes provided a more advanced diagnostic capability for fine coal cleaning circuits. This enabled flotation performance curves analogous to partition curves for density separators to be produced for flotation devices.

Jan 1, 2005

Flotation science and technology are related to three major sub- processes which are organized in a hierarchical structure as shown in Fig. 1. The basic sub-process is the chemical process which affects the attachment of air bubbles to mineral particles. In particular, the chem- ical process is related with the adsorption of surface active sub- stances at the gas-liquid, liquid- solid, and gas-liquid-solid inter- faces. This field has been most intensively explored in flotation research. The second domain in flotation research is concerned with the mineral particle to air bubble attachment sub- process in the system. This sub- process represents the dynamics of particle and bubble encounter where the contact angle and the induction time, determined by the surface chem- istry of the system, are among the most significant parameters. This sub-process can be referred to as the micro-process as against the third sub-process, or the macro-process, which corresponds to the integral behaviour of the system. Two other sub-processes are integrated into the macro-process in which they may not reveal themselves explicitly in the details. The third sub-process does not entail surface-chemical or physi- cal events any more, but it represents them all inclusively. To represent this sub-process we use mathematical equations, called models. Only in some simple or simplified cases can the models be solved exactly to find out the behaviour of the flotation system in which we are interested. Digital

Jan 1, 1984

By James C. Conti

A surface charge sensor has been developed that responds to changes in the double layer properties of colloidal silica during the cationic flotation of silica from taconite ores. Sensor design allows for the measurement of two aspects of the electrical double layer surrounding all solids immersed in ionic solutions. One aspect responds to a flow induced change in the double layer properties of a solid. The other is a function of the chemical composition of the aqueous phase. Evaluation of sensor performance during froth flotation experiments has been encouraging. Process monitoring capabilities are indicated.

Jan 1, 1981

By Heikki Laurila, Sirkka-Liisa Jämsä-Jounela, Jarkko Karesvuori

"Artificial Intelligence includes excellent tools for the control and supervision of industrial processes. Several thousand industrial applications have been reported worldwide. Recently, the designers of the A1 systems have begun to hybridize the intelligent techniques, expert systems, fuzzy logic and neural networks, to enhance the capability of the A1 systems. Expert systems have proved to be ideal candidates especially for the control of mineral processes.As successful case projects, an expert system based on on-line classification of the feed type using neural data analysis is described in this paper. The essential feature of this expert system is the classification of different feed types and their distinct control strategies at the plant. In addition to the classification, the expert system has a database containing information about how to handle the determined feed type. This self-leaming database scans historical process data to suggest the best treatment for the ore type under processing. The system has been tested in the Outokumpu Finnmines Oy, Hitura mine. Other projects have been reported to be in progress.INTRODUCTIONIn the past ten years considerable researches have been done in the application of artificial intelligent methods in process industry. The technologies of fuzzy logic, neural networks and expert systems have received several thousand applications worldwide: monitoring and analysis of process operations, fault diagnosis, supervisory control, feedback control and scheduling and planning of operations. Recently, the designers of these systems have begun to hybridize these intelligent techniques to enhance the current capability of expert system. Complex signal processing, neural networks, fuzzy logic and rule-based systems are also implemented to develop new so-called smart or intelligent sensors, actuators or components. Field buses are playing a more and more important role in automation systems and in imbedded systems. The development of field buses has allowed the distribution of smart components over networks."

Jan 1, 2000

By Leming Ou, Qiming Feng, Yiping Lu, Pengyu Zhang, Qing Shi, Kun Liu, Guofan Zhang

"This paper introduces the mineralogical analysis of certain polymetallic copper-zinc ore in China with the aim of improving the flotation process. The main valuable elements, mineral phases and compositions of run-of-mine ore were inspected by the X-ray Fluorescence (XRF) and chemical analysis. For a deep known of the old process defects, Mineral Liberation Analysis system (MLAs) was employed to investigate the minerals liberation degree of selected key slurry points. Analysis results show that the run-of-mine ore belongs to the original copper-zinc polymetallic symbiotic ore at low oxidative level, which mainly contains 0.16% Cu, 4.43% Zn and 0.88% Sn. Gangue minerals are mainly silicate minerals, and zinc mineral is sphalerite. MLAs test illustrates that about 86% sphalerite has been dissociated in zinc flotation feed. In the current flotation process, over grinding of sphalerite monomer and insufficient liberation of intergrowths are the key problems need to be solved imminently. Up to this point, a new process consisted of two steps roughing unit is submitted in this research. It contributes two positive effects on zinc flotation performance: (i) separating sphalerite monomer timely to decrease overgrinding; (ii) improving zinc minerals intergrowths liberation efficiency. Flotation results indicate that the zinc concentrate grade increased 0.90% and the recovery improved 0.96% in the new flotation processINTRODUCTION Mineralogical analysis mainly focusses on solving mineralogy problems in minerals processing, assisting in minerals behaviors prediction and control for separation engineering (Falkovich, et al., 2001; Hillier, et al., 2003; Schouwstra and Smit, 2011). Process defects searching becomes its ordinary work, and flotation optimization appears to be its targets gradually. For example, Lucky Friday mine company (Idaho America) fails to obtain qualified lead concentrate as the change of ore properties (Nadoll, et al., 2011). Mineralogical analysis ascertains that there are too many dissociated sphalerite, pyrite and gangue particles exist in lead concentrate. According to this, more cleaning units are added to solve problems effectively. Kanowna Belle mine (Australia) takes a flash circuit in operation successfully with the aim of optimize flotation process, under the helps of mineralogical analysis and industrial test (Newcombe, et al., 2013). Lotter N.O. (2011) gives a deep description on how mineralogical data assisting mineral processing engineers to design and optimize flowsheet. For decades, quantitative and automated mineralogy techniques (Andersen, et al., 2009; Gu, et al., 2012; Oghazi, et al., 2009; Yu, et al., 2007) get well developed and hugely improve the veracity and repeatability of minerals properties measurement. Among these, MLAs (Gu, 2003) provided by JKMRC (Julius Kruttschnitt Mineral Research Center) is critically acclaimed all over the world. This analysis system can measure mineral phases composition and content, particles size, minerals occurrence and liberation degree directly."

Jan 1, 2018

By M. Mononen, J. Huuskonen, M. Vauhkonen, J. Kourunen, A. Lehikoinen

"A new approach to measure process conditions in flotation cells is presented. Real scale flotation cells in a Zinc circuit are imaged using Outotec LevelSense sensors based on electrical resistance tomography. The latest results from long period plant tests show that the sensors together with FrothControl analysis give new information that correlates well with other process parameters. The sensors can compensate for electrical contact contamination using an automatic calibration technique and they are basically maintenance free. The results indicate that using the LevelSense sensors and FrothControl solution, the process control and optimization can be done automatically, stabilizing and improving the metallurgical performance of the flotation process.INTRODUCTIONThe froth flotation process is widely used in mineral industry for the separation of minerals from low-grade ore slurry. Different property parameters of froth and slurry could be measured to monitor and control the flotation process: air bubble size distribution, flow dynamics, thickness of the froth bed, amount of solids in the froth, etc. Some techniques already exist that can be utilized in studying these important parameters on-line. Examples of the techniques are the high-speed video imaging, simple conductivity probes, ultrasound techniques, floats and pressure transducers (Maldonado et al., 2008). These techniques, however, often suffer from some limitations. For example, the video imaging only gives information from the surface of the froth, simple conductivity probes suffer from contamination and the floats may get stuck and therefore do not give reliable signal for process control and optimization."

Jan 1, 2013

By Manlapig EV, Mackinnon IDR, Laudr DW

Orebodies at Ok Tedi contain a number of different fluorine bearing minerals. Some of these minerals report to concentrate and are responsible for the presence of the penalty element, fluorine, within the concentrate. Previous analytical work has tended to examine geological samples for content, rather than determine the metallurgical behaviour of the different mineralogical species. This investigation utilised X-Ray Diffraction combined with Scanning Electron Microscope / Electron Microprobe to identify the fluorine bearing minerals in flotation test products. Seven fluorine bearing minerals were identified, viz., talc, phlogopite, amphibole (tremolite and actinolite), sphene, apatite, biotite and clay. Talc was found exclusively in the skam ore type. Phlogopite and amphiboles (tremolite and actinolite) were found to occur in both skarn and porphyry ores, while sphene, apatite, biotite and clay were found only in the porphyry ores. Of the fluorine bearing minerals observed, only talc exhibited natural hydrophobicity to any significant degree. Phlogopite and the amphibole minerals were found to be hydrophillic, whilst the remaining minerals occurred in insufficient quantities to determine the flotation behaviour. Ok Tedi copper concentrate fluorine content prior to skarn ore treatment in the mill (typically 350ppm) was previously identified as deriving from phlogopite, while talc was believed to be the source of intermittent high concentrate fluorine contents when skarn ores were treated. This paper provides supporting evidence for this belief, and reports the nature of fluorine bearing mineral flotation behaviour.

Jan 1, 1997

By M. Bryson, G. Marap, M. Ntlhane, M. D. Hlahane

This study investigated flotation of phosphate from a low-medium grade 8-12% P2O5, 65-73% SiO2 sedimentary phosphate ore from Kropz Elandsfontein (herein referred to as Elandsfontein) in South Africa. Quantitative evaluation of minerals by scanning electron microscopy (QEMSCAN) was used to determine apatite grain size distribution, liberation and mineral association in the F2 horizon sample. The mineralogy indicated that apatite was liberated and for the Elandsfontein plant to operate at the design throughput, the flotation feed has to be milled to a coarse grind ranging between 300 μm and 425 μm. Reverse flotation process routes using varying reagent dosages, and flotation feed top sizes that could possibly yield a final product of 31% P2O5,10% SiO2 at a reasonable +70% P2O5 recovery were investigated. Based on the results, a split circuit of coarse (-300+212μm) flotation and fine (-212+20μm) flotation, was mostly preferred as compared to treating the whole ore. A final combined concentrate of 31% P2O5 and 10% SiO2 with P2O5 recovery of 84% could be produced from the reverse split circuit. The robustness of reverse flotation for both coarse and fine fractions was further investigated. Reverse flotation of the fines fraction was found to be robust and produced a final product of 31% P2O5. It was however more challenging to achieve the required product grade and recoveries on the coarser fraction (-425+212μm), suggesting that reverse circuit was not adequately robust at fractions coarser than 300μm. Keywords: Phosphate, sedimentary, reverse flotation, particle size

Jan 1, 2020

By Benjamin Miller

FROM earliest recorded times, limestone has been employed in the industrial life of peoples of all sections of the world where it exists. It is widely distributed and therefore has been available in almost every country and has been employed for a variety of purposes. Its earliest use was for buildings, since it is more easily quarried and dressed than most other kinds of rocks and so could be utilized by early inhabitants, poorly equipped with tools. The next use was in the manufacture of lime, which was employed by the ancients in mortar. These two uses of limestone are still all important, but they have been overshadowed in scores of regions by literally hundreds of new applications for raw lime-stone or products made from it. Anyone familiar with modern manufacturing processes can quickly call to mind many industries in which limestones are essential, and new uses are continually coming to notice. Any enumeration would probably be incomplete and soon out of date.

Jan 1, 1935

By Benjamin Miller

FROM earliest recorded times, limestone has been employed in the industrial life of peoples of all sections of the world where it exists. It is widely distributed and therefore has been available in almost every country and has been employed for a variety of purposes. Its earliest use was for buildings, since it is more easily quarried and dressed than most other kinds of rocks and so could be utilized by early inhabitants, poorly equipped, with tools. The next use was in the manufacture of lime, which was employed by the ancients in mortar. These two uses of limestone are still all important, but they have been overshadowed in scores of regions by literally hundreds of new applications for raw lime-stone or products made from it. Anyone familiar with modern manu-facturing processes can quickly call to mind many industries in which limestones are essential, and new uses are continually coming to notice. Any enumeration would probably be incomplete and soon out of date.

Jan 1, 1935

By S A. Ravishankar, W Perez

Flotation is one of the main concentration processes to purify kaolin clay via the removal of naturally occurring impurity minerals containing Ti and Fe. Currently, there are two types of collector chemistries used in the industry to float coloured impurity minerals. These are traditional tall oil fatty acids (TOFA) and specialty hydroxamate (AHX) based collectors. AHX based collectors have long been known to be the most selective collectors to float Ti and Fe based coloured impurity minerals (CIMs) as compared to TOFA based systems. AHX based collectors provide, not only improved selectivity and simplified process, but also more importantly, make it possible to treat certain kaolin resources that do not respond to standard TOFA systems. However, the relatively higher cost of straight AHX collectors has restricted broader application of these collectors in kaolin clay and other oxide flotation applications for a long time. Recent technological advancements, in both making and formulating AHX products more economically, increased the usage of these collectors in kaolin applications. Modified AHX products offer more economical alternatives and process options to provide high purity kaolin clay products for specialty applications based on cost-performance criteria. In this paper, the flotation performance of a series of newly developed AHX formulations is provided along with the characteristics of AHX flotation in general. In addition, flotation performance of earlier AHX collectors is provided based on published literature as background data.

Jan 1, 2005

By Rongjie Kong, Shiwei Wang, Guomin Wei

Owing to the selective oxidation and uneven combustion that occur on the surface of carbon anode, some carbon particles detach and form carbon residue, which is defined as spent anode slag (SAS). The highly graphitized and toxic impurities such as fluorite ( CaF2), corundum (α-Al2O3), and cryolite ( NaAl11O17) are crucial components of SAS resource but are difficult to separate from graphite. This study developed a method of using water-soluble (emulsified) kerosene to separate the carbon particles from the toxic impurities in the SAS resource. The flotation purification approach of utilizing conventional kerosene was experimentally investigated and compared with that of using water-soluble kerosene. The results showed that with the use of emulsified kerosene, the maximum combustible matter recovery of the carbon particles was 89.86% while that of using traditional kerosene was 80.30%. The emulsified kerosene was comprehensively examined by various instruments to clarify its adsorption mechanism on the carbon particle surfaces. Because of the superior dispersibility of emulsified kerosene, it effectively envelops carbon particles with a smooth surface, oxygen-containing functional groups, and hydrophilic C–F bonds, thereby increasing the surface hydrophobicity and flotation responses of targeted carbon particles.

Feb 6, 2024

By Luis Bergh, Iván Rojas, Juan Yianatos, Luis Vinnett

"At present, flotation rate characterization follows standard measurements to identify the overall flotation performance looking at the feed, tailings and concentrate in flotation cells or banks. This classical approach does not take into account the evolution of the true collection rate down the flotation banks explicitly. The potential for identifying the impact of the mineral characteristics (size and liberation) as well as the effect of different manipulated variables (reagents, froth depth, gas dispersion) on the true flotation process remains hindered. Top-of-froth (TOF) measurements, which consist of sampling the first layer on the froth surface, have been used to characterize the mineral collected by true flotation in rougher banks. The information provided by TOF samples allows evaluating the floatable mineral evolution (grade, particle size, liberation) down the bank. In this work, an indirect approach to estimate the flotation rate along rougher flotation banks is proposed. The new approach is based on the decreasing of collected mineral grades (on top of froth) and the feed characteristics. Flotation rates per liberation classes were used to reconstruct the TOF grades from the feed information. This approach requires a simple froth surface sampling, without constraints typically observed during mass balance surveys and uncertainties on the mineral recovery estimation. The proposed methodology was successfully applied at industrial scale using TOF measurements together with QEMSCAN information."

Jan 1, 2014

By S R. Grano, J Duan, T A, D Fornasiero

We have determined the experimental rate constants for chalcopyrite particles floated from a complex sulfide ore and compared them with those calculated using a recently developed flotation model. The model incorporates contributions from the efficiencies of collision, attachment and stability between particles and bubbles, as well as their frequency of collision. For these calculations, the contact angle of the chalcopyrite particles in the ore was obtained independently using a surface spectroscopic approach. The calculated flotation rate constants were in good agreement with the experimental data and able to reproduce the characteristic maximum in flotation rate constant for particles of intermediate size. The values of bubble velocity and turbulent dissipation energy derived from these calculations are relatively low and may well correspond to mean values of these parameters inside the flotation cell. We have extended this approach through the application of a property based model to an operating plant, with a satisfactory outcome.

Jan 1, 2005

By K. Fair

Using an agitated column 203 mm (8") diameter by 1829 mm (72") tall with independent agitation units for the gas dispersion zone and the collection zones, respectively, permitted the independent evaluation of the attachment and the detachment mechanisms for the chalcopyrite/ silica system. Three particle size fractions were used in this study, i.e. coarse (+75 µ m), intermediate (-75 µ m + 10 µ m) and fines (-10 µ m). The optimum selection of the two agitation zones for the three particle size fractions were determined as a function of grade, recovery, residence time and air superficial gas velocity.

Jan 1, 1990

By Nathaniel Arbiter

THE separation of minerals by flotation can be regarded as a rate process, with the extraction of any one mineral determined by its flotation rate, and the grade of concentrate by the relative rates for all the minerals. So regarded, the significant variables for the process are those that control the rates. These variables are of two types, the first describing the ore and its physical and chemical treatment prior to flotation and the second characterizing the separation process in the cells. This paper will examine the variation in rates for a group of separations, will show that a simple rate law appears to govern, and will consider the relation of the control variables to the rates. The use of rate constants for evaluation of performance and efficiency will be discussed.

Jan 9, 1951