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Factors of importance in the ntilization of coal fines are mentioned, and the results of flotation tests on coal fines from three important coal seams in New South Wales are presented.INTRODUCTIONEconomic utilization of fine coal is an important problem in the Australian coal industry, particularly as the proportion of fines mined is increasing with progressive mechanization.While the use of uncleaned coal fines may be economic, it may be preferable to beneficiate them, but the most economic process must be selected.For beneficiating coal finer than about 28 mesh, froth flotation can be applied, but mining engineers should avoid practices that may be detrimental to flotation. Such practices include the indiscriminate use of water, particularly that containing a wetting' agent, for dust suppression. In addition, clay stemming in wet conditions may produce slimes which could adsorb on coal surfaces, while the use of oils and greases as well as the application of stone dust and chlorides in roadway consolidation may influence adversely fine coal beneficiation.This paper deals with the application of flotation to samples of fine coal from the Bulli, Greta, and Victoria Tunnel seams. In addition a discussion is given of the mineralogical constitution, size analysis, and degree of liberation of ash constituents of the various samples.COAL SAMPLESRepresentative samples of coal from the Bulli, Greta, and Victoria Tunnel seams were obtained for testing.

Jan 1, 1961

By R. W. M. Lai

INTRODUCTION Manganese nodules were first discovered by the H.M.S. CHALLENGER expedition of 1873-76 and have engaged the interest of oceanographers and natural resources engineers ever since (1-4). Manganese nodules, some of them as large as grapefruit, cover vast stretches of the ocean floor throughout many parts of the world. In some areas the ocean floor is literally paved with nodules. The Pacific Ocean alone is estimated to contain 1.5 trillion tons of nodules which are forming at the rate of about 10 million tons per year (2). An analysis of the principal metal values for Pacific Ocean nodules is shown in Table I (5). [ ] The principal ingredients of the nodules are manganese and iron, but they also contain other important associated metal values such as copper, nickel, cobalt, and molybdenum. These associated metal values,

Jan 1, 1980

By H. R. Manouchehri

"It is well understood that, apart from particle hydrophobicity, the flotation process is strongly influenced by the cell hydrodynamics. Once the chemical conditions were optimized and fixed, the flotation rate is essentially determined by impeller speed and the air flow rate.The collection efficiency in flotation is a product of collision, attachment and stability/detachment efficiencies. The collision efficiency for a given particle diameter is increased by decreasing the bubble size and bubble velocity as well as increasing the power input to the cell. The attachment efficiency, however, is defined by bubble size and its velocity. The detachment/stability depends on the relative magnitudes of the attachment force between the bubble and particles and the detachment force acting on the bubble-particle aggregates. For the particles having specific contact angle, the stability decreases as the energy input increases. Therefore, there must be an optimum energy dissipation to maximize recover of defined size fraction.A comprehensive laboratory study was devoted to determine the effect of power input in recovery of finely grind Cu-Ni bearing ore. Several flotation tests were conducted to define the hydrodynamic parameters for a laboratory scale Runge cell under different impeller speeds. An increase in flotation recovery of finely ground ore was observed when the impeller speed was increased from 450 to 1,200 rpm. The experimental results have shown increasing in water recovery and improving in flotation kinetics of fines by increasing the power input to the flotation cell. Implementation of the Wark flotation model to the experimental data revealed a good correlation between the experimental data and the model. For the particles having enough hydrophobicity the flotation rate increases by increasing the impeller speed due to a higher value for collision efficiency within the cell."

Jan 1, 2016

By P. E. Sarquis, R. Lenzo

The concentration of barite by gravity separation generates substantial quantities of fine particle wastes, and it is estimated that =40% of the contained barite is lost to these waste streams. In this study, froth flotation was examined as a potential method for the recovery of fine-barite particles. The study included the use of kinetic equations to estimate the variables affecting flotation, batch-scale rougher flotation tests to study the flotation variables and an examination of alternatives for the cleaning of the rougher concentrate. Results indicated that a concentrate grade of 96.5% could be achieved with a recovery of 77.5%. Although barite flotation from industrial wastes is more difficult than direct barite flotation, the process has considerable economic potential.

Jan 1, 1996

By M. Z. Dogan, M. S. Celik, G. Onal, O. Ozcan, I. Yildirim

A fluorite ore (51.85 % CaF2) containing high contents of calcite, quartz and iron oxides was upgraded by flotation using a new reagent, oleoyl sarcosine (OS). In addition, quebracho and sodium silicate were used as depressants for calcite and quartz, respectively. The effect of pH, collector and depressants concentrations on grade and recovery was determined with the aim of optimizing the flotation conditions. Application of the two-stage cleaning achieved a concentrate assaying 92.17 % CaF2 with 80.1 % recovery. The Si02 content (0.76 %) was below the required level of 1 % SiO2. The mechanism of interaction between OS and fluorite, as compared to oleic acid, is also elucidated based on the zeta potential measurements.

Jan 1, 1993

By K. D’Elia, L. D. Ogrel, O. A. Malyshev, T. I. Yushina, I. M. Petrov

"The purpose of this research is to develop enhancements in the mineral processing by flotation methods of nonferrous ores. Currently, 180-190 million tons of ore are processed by flotation in Russia. The annual processing volume of copper-nickel and copper-zinc ores exceeds 20 million tons. In the total volume of processed ores by flotation, non-ferrous ores account for roughly 35% and ores of precious metals for another 15%. The total demand of flotation reagents in Russia in 2016 was estimated at 170,000 tons. Sulfur-based collectors used in the flotation of non-ferrous sulfide ores (typically, xanthates) do not always offer sufficiently high recovery of valuable components.It has been found that reagents like DMIPEC and DK-80 improve the recovery of metals into concentrates. To identify the reasons of that higher recovery, quantum chemical calculations of the mechanism and interaction forces of DMIPEC with non-ferrous sulfides were undertaken by determining the stabilization energy of the resulting chemical complexes. It has been shown that, in the interaction of DMIPEC and DK-80 with the surfaces of sulfide minerals, ethylene and acetylene bonds act as the reaction centers, and the formation of molecular p-complexes is the result of metal-cation interactions with the surface and the flotation reagents.In the flotation of non-ferrous ores, DMIPEC and DK-80 act as selective supplementary collectors with foaming properties, and at a flow rate of 3-35 g/ton, they reduce the flotation time, and increase copper recovery by up to 3.5%, zinc recovery by up to 12%, gold recovery by up to 8-10%, allowing to increase the recovery of valuable components by 1.5-12.0%, basically this kind of reagents nearly double the flotation rate, improve the grade of the concentrate, improve the stability of the flotation process parameters, and reduce the environmental impact of flotation plants."

Jan 1, 2018

By Mi Chung

T HE ore-dressing problem at Tul Mi Chung is complicated by the unusually complex nature of the ores. These come from replacement ore- bodies in limestone at the contact with a granite batholith, and contain copper, gold, silver, bismuth, molybdenum, iron, arsenic, zinc, and lead, the first two metals constituting the principal sources of profit. Iron is present as pyrite, magnetite, and hematite. Arsenic occurs both as mispickel and lollingite (FelAsa), the latter carrying a certain amount of finely divided gold. The gangue minerals are those typical of limestone con- tact-metamorphism and include a large percentage of garnet, together with diopside, serpentine, calcite, epidote, zoisite, actinolite, 'mica and other minerals. A part of the gold occurs in a free state; some is combined with chalcopyrite and lollingite, and a consider- able proportion is contained in the pyrite. Researches towards the improvement of recovery have been energetically conducted since 1915. Amalgamation, gravity concentrating tables, vanners, can- vas plants, etc., have all been tried and discarded in favor of flotation. It was very quickly established that fine grinding was essential for satisfactory recovery. This was and is still accomplished in Hardinge ball and pebble mills. A comparative test showed that when the ore was crushed to the point at which it contained 20 to 26 per cent. coarser than 100 mesh, the gold recovery was only 55.9 per cent., whereas when crushed so that only 11 to 15 per cent. was coarser than 100 mesh, the gold recovery was increased to 82.5 per cent. No particular difficulty was ever experienced in making a satisfactory recovery of copper but the losses in gold were considered serious and led to the investigation described in this paper.

Jan 1, 1924

The homologous series of saturated fatty acids investigated in this study generally show a steady gradation of properties with chain length. The solution pKa values were assumed constant at 4.9, however reported pKa values could be lower or higher. Hematite flotation response and surface pressure for aqueous solutions of these fatty acids were measured as a function of pH. For the shorter chain fatty acids, the undissociated acid was shown to be the predominant surface active species with flotation, supplemented by the physical adsorption of acid anions as the chain length increased. The reduced solubility of the longer fatty acid carbon chains made these reagents ineffective as flotation agents. The maximum flotation response of hematite using tetradecanoic acid corresponded with the precipitation edge of the reagent. The results show that the values of surface pressure of the surfactants are not always a good indication of their effectiveness as flotation collectors.

Jan 1, 2005

Flotation testing has been done at laboratory scale on hematite mineral and ore samples using stage additions of various hydroxamates. Chemisorption of hydroxamate species onto the hematite surface was inferred from the results, possibly involving both the undissociated hydroxamic acid and hydroxamate ion as maximum recovery occurred close to the pKa of the hydroxamic acid. Flotation testing on a specular hematite ore containing 40 per cent Fe and 42.5 per cent silica gave highest iron grades in concentrate at pH 6, in contrast to published data which suggested pH 9 as the optimum value for ore processing. Using octyl hydroxamate, a rougher concentrate assaying 67 per cent Fe at 51 per cent recovery was obtained using four stage additions of 50 g/t at pH 6. For lower grade concentrates still meeting the chemical analysis for pigment grade micaceous hematite (minimum Fe assay 60 per cent) iron recoveries of 80 per cent were possible for stage additions of 50 g/t octyl hydroxamate in the pH range 6-8.

Jan 1, 1999

Laboratory scale flotation tests were done on mineral hematite and aspecular hematite ore using oleic acid and sodium oleate as collectors. The mineral hematite floated strongly in the neutral pH region, with an increased pH range of flotation at higher oleate additions. Concentrates with sufficient hematite grade to meet the paint pigment specification were produced using oleic acid and sodium oleate as hematite collectors on the specular hematite ore. Hematite recoveries of 70 per cent at 60 per cent Fe grade were obtained using stagewise roughing. The interaction between hematite and oleate was confirmed as chemisorption but the exact mechanism could not be determined, as two independent phenomena can be used to explain the fact that the pH of maximum grade increased with increasing oleate addition.

Jan 1, 1999

By M. S. Celik

Salt-type minerals are usually floated with anionic and cationic collectors. Flotation of a number of systems has been reported to remarkably increase above the concentrations where surface precipitation of collector-metal salt is initiated. Some studies attribute this phenomenon to heterocoagulation of oppositely charged collector colloid and mineral particles. In this study, examples are given on boron minerals to demonstrate that the high flotation region occurs when particles, colloidal precipitates and bubbles acquire a similar charge which induces Van der Waals interactions resulting in hydrophobic bonding.

Jan 1, 1995

By Steven J. Van Kauwenbergh, Talaat A. B. Lawendy

Batch laboratory-scale beneficiation tests were conducted on four high-iron phosphate samples. These samples included sedimentary ores (Tilemsi Valley, Mali and Tahoua, Niger), a sample from an igneous phosphate deposit (Matongo, Burundi), and a fine-grained phosphatic iron ore processing residue from Chile. The Matongo phosphate deposit occurs as a thick (up to 80 m) residual blanket of P205-enriched soil over solid parent rock (carbonatite and associated rock types). Although the Matongo deposit is an igneous deposit, ore from the deposit can be subjected to beneficiation treatments commonly used to treat sedimentary rocks. The beneficiation flowsheets designed to process these diverse ore types involve attrition scrubbing, size classification, and flotation. At the best flotation conditions tested, phosphate concentrates assaying 32.0%-39.0% P205 and 1.0%-1.5% Fe2O3, were obtained at 64.2%-82.2% overall P2O5 recoveries from run-of-mine (ROM) ores containing 9.2%-28.6% P205 and 5.9%-16.1% F,20,. A cleaner phosphate concentrate assaying 33.1% P205, 1.8% A1203, and 3.3% Fe2O3 at 53.4% overall P205 recovery was obtained from the phosphatic iron ore residue that originally contained 4.5% P205, 8.0% A1203, and 17.6% Fe2O3.

Jan 1, 1993

Application of flotation for the removal of hydrophobic compounds from soils was studied. Bench scale flotation tests were conducted on artificially contaminated soil, using both conventional mechanically agitated machine and flotation column. Flotation parameters tested include surfactant collector type, conditioning time, flotation time, surfactant dosage, pulp pH, solid/liquid ratio in conditioning and pulp temperature. It is found that with conventional flotation 74% removal of the contaminant was achieved from soil particles in the range of 75-830 µm; with column flotation up to 80% of oil could be removed from the 250-830 µm soil fraction, and 65% from the 75-830 µm fraction. Flotation was found to have considerable potential for cleaning up contaminated soils.

Jan 1, 1998

By L. Cui

A new flotation collector, benzyl arsonic acid, was used for the flotation of ilmenite. ESCA, Auger spectroscopy, and chemical analysis were used to investigate the correlation between the variation in surface constituents and the flotation recovery of ilmenite. Experiments indicated that, as the ratio of surface Ti ions/surface Fe ions increases, flotation recovery increases. pH regulation with an inorganic acid was found to be effective in changing the ratio of surface ions, and, hence, the flotation recovery.

Jan 1, 1986

By X. Tong

Flotation researches of indium-beard marmatite from the Dulong multi-metallic ore in the Yunnan Province of China has been studied in order to improve the grades and recoveries of zinc and indium of the zinc concentrate in the Dulong concentration plant. The experimental results have shown that copper sulfate mixed with a chemical reagent X-1 as the activator in the marmatite flotation produced a much better beneficiation than copper sulfate alone, increasing the zinc and indium recoveries of 10% and 6%, respectively, while the concentrate grades were unchanged. Also, the new activator acted well around pH 10, allowing large savings on lime consumption in the marmatite flotation. In addition, it has been found that a sufficient activated time of activator with ore slur-ry in the flotation is needed to achieve good beneficiation of the marmatite ore.

Jan 1, 2014

By Y. A. Attia, D. K. Sengupta, H. A. Hamza

Increased recycling of waste paper has been emphasized in recent years in both the United States and Canada for environmental and economic reasons. Removal of ink particles from waste paper pulp is therefore necessary. One of the most promising methods for ink removal is froth flotation. This study investigated the feasibility of a simplified flotation scheme and found that about 90% to 92% ink removal can be achieved. Also, a 95% to 97% ink removal is achievable if a hydrophobic polymer is used ahead of the flotation stage. Clean paper pulp recovery was over 90%. The effects of pulping pH, flotation pH and concentrations of flotation and polymeric reagents are discussed in the paper.

Jan 1, 1995

By D. K. Sengupta

Increased recycling of waste paper has been emphasized in recent years in both the USA and Canada for environmental and economic reasons. Removal of ink particles from the waste paper pulp is therefore necessary. One of the most promising methods for ink removal is froth flotation. Our study investigated the feasibility of a simplified flotation scheme which showed that about 90-92% ink removal can be achieved while 95-97% ink removal is achievable if a hydrophobic polymer is used ahead of flotation. The clean paper pulp recovery was over 90%. The effects of pulping pH, flotation pH, and concentrations of flotation and polymeric reagents are discussed in the paper.

Jan 1, 1993

Laboratory testing by the Federal Bureau of Mines has shown that the removal of insoluble slimes using selective flocculation and flotation is a viable method for treating low-grade potash ores which have a high content of water-insoluble impurities. Results indicated that up to 85 percent of the insoluble slimes could be removed from sylvinite ore containing 5 percent water insolubles and 13 percent K20 using nonionic or cationic polyacrylamide flocculants and cationic, anionic, and/or nonionic collectors. Subsequent potash flotation recovered up to 88 percent of the potash in rougher concentrates containing 47 to 57 percent K20. Sizing and cleaner flotation of the rougher concentrates upgraded the products to 60 percent K20. Filtration of the insoluble slimes flotation concentrates recovered 87 to 0 percent of the brine. Flotation concentrate filtration rates were 7 times faster than the filtration rates of mechanically deslimed products.

Jan 1, 1977

By Herbert H. Kellogg

DEPOSITS of high-silica kaolinite clays occur at many places in central Pennsylvania. These white clays were formed apparently by weathering of argillaceous quartzite and limestone. Their geology, distribution and use have been reported by Leighton.1 The larger deposits have been mined from time to time, and the clay, after washing to remove coarse sand, has found use as rubber filler, foundry clay, and in white cements. In general, the clay from these deposits contains too much grit (quartz) to be useful as paper filler, and the silica content is too high to make it useful as china clay for ceramic ware. Gravity methods for the separation of quartz from these clays have failed because of the extremely fine size of the quartz grains, but by the methods of froth flotation described in this paper these sandy kaolins can be made to yield a purified kaolinite that has a chemical composition close to that of good-grade Georgia kaolins, and is free enough from grit to be used as a paper filler. As by-products of the separation, a fine (-325-mesh) sand assaying 95.5 per cent Si02, and a very fine (-3-micron) clay are produced. The possible ceramic uses of these products are being investigated at The Pennsylvania State College. EXPERIMENTAL PROCEDURE The Sample.-The clay sample used in these tests was obtained from a small mine near Tyrone, Pa. It had already been washed to remove coarse sand, and represented the finished product of this small mine and washery. Microscopic examination showed that the clay was composed almost entirely of the minerals quartz and kaolinite, and that the quartz was present mostly in particles larger than one micron, while the kaolinite particles generally were less than 20 microns in size. The kaolinite and quartz particles were physically separable by blunging the clay in water with a suitable dispersant. Preparation of Flotation Feed.-By the addition of NaOH in an amount equal to 3 lb. per ton of solids, the clay was completely dispersed in water. Flotation feed was prepared by allowing a dispersed suspension (10 per cent solids) of the clay to stand for the period of time required for a 2.5-micron particle of quartz to settle from the top of the container to the bottom. After this settling period the suspension was decanted from the settled solids. The settled solids were redispersed in water and the separation was repeated once. The two fine fractions were then combined. Thus the clay was divided into a fine and a coarse fraction by size separation at approximately 2.5 microns.* The fine fraction was found to have a considerably lower sand content than the raw clay (Table I), and was not treated further. The coarse fraction formed the flotation feed for all the tests described in this paper.

Jan 1, 1945

By Qinbo Cao, Qianshan Peng, Heng Zou, Xingcai Yu

Rutile ore is an important resource for the production of titanium products, and flotation is an efficient method to enrich rutile from its deposits. Motivated by strong commercial demand for titanium metal and alloys, substantial efforts have been made to improve the flotation efficiency of rutile. Styryl phosphonic acid (SPA) and salicyl hydroxamic acid (SHA) are commonly used as collectors for rutile flotation, and lead (Pb) ions can be used as activators for rutile flotation with SPA or SHA. Xanthates have a price advantage over SPA and SHA for the flotation of sulfides as SPA and SHA prices are higher than xanthate prices. In this work, we found that when rutile is activated by lead ions, amyl xanthate is an efficient collector for rutile flotation at pH 8. A slightly basic slurry can be readily obtained. Moreover, the price of amyl xanthate is lower than that of SPA or SHA. In this regard, this flotation strategy has the potential to be used in industry. Furthermore, the adsorption features of amyl xanthate on the Pb-activated rutile surface was investigated by experimental methods, which provides insight into the role of lead ions in rutile flotation.