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Mr. P. F. THOMPSON said this matter was one of very great importance to producers of lead. His association with the matter was that he happened to be the Institute representative on the Committee of the Standards Association of Australia charged with formulating a standard for chemical lead, that is, lead used in technical chemistry for acid chambers and the like. The British standard had this test incorporated in it, but those on the committee felt that it should not be included in the specification. The main objection was that in an accelerated corrosion test one was endeavouring to do in a few seconds what in natural conditions would take years; and it was now being recognised that such tests were of little value in assessing the corrosive properties of a metal.The flash point test was carried out with boiling hot strong sulphuric acid; but no chemical manufacturer would be likely to use such in contact with lead. There were many factors such as the formation of steam, the chemical reduction of sulphuric acid, the evolution of hydrogen, the catalytic effect of the surface lead, affecting this test, other than the presence of the segregated impurities upon which this test throws the onus of the whole imperfection of the lead. Mr. Russell had shown that lead which had stood the test of time often gave a low flash point. They were endeavouring to find rapid methods of estimating minute amounts of the more important impurities, which would eliminate the labour and expense of a full analysis.Mr. H. St. J. SOMERSET thanked Mr. Thompson for his remarks. He supposed some of those present knew that the Broken Hill Associated Smelters was responsible for Mr. Russell's investigations at the University, and he could only agree with Mr. Thompson that the flash point test, which had been accepted at the present time...

Jan 1, 1930

By Yousef Mohassab, Hong Yong Sohn, Mohamed Elzohiery

As part of the development of a novel flash ironmaking process at the University of Utah, a labscale flash reactor was used to produce iron directly from iron oxide concentrate. This work tested the feasibility of the novel flash ironmaking process using the partial combustion of hydrogen as fuel and reductant. In this flash reactor, the energy required to reduce concentrate particles was obtained from the internal combustion of hydrogen and oxygen with complementary energy from electrical resistance heating to compensate for the heat loss. After the reaction shaft was electrically pre-heated, hydrogen and oxygen streams produced a non-premixed flame inside the reaction shaft. Various conditions such as flame configuration, flame power, positions of concentrate feeding ports, excess hydrogen amount and residence time were tested. More than 90% reduction of magnetite or hematite was achieved at temperatures as low as 1175 oC with < 100% excess hydrogen in <10 s of residence time.

Jan 1, 2016

By F. R. Milliken

EXPERIMENTS, in what has come to be known as flash roasting began some ten years ago. The principle underlying the operation was not a new one, but the experimental work started at that time was the first that was carried through to a logical conclusion, followed by construction and operation of a pilot plant, and then full-scale production. For a short working definition, flash roasting may he considered the instantaneous and complete oxidation of finely ground sulphide particles, partially suspended in air or gas, the oxidation reaction evolving enough heat to make the reaction self-sustaining, or nearly so.

Jan 1, 1937

By George Beavers

FLASH roasting of iron concentrate is in the experimental stage at Copperhill. The problem is peculiar in that the iron concentrate is predominantly pyrrhotite; the ratio of that mineral to pyrite being 5 to 1. Results so far indicate that the heat, generated in roasting a material containing 52.0 per cent iron and 38.0 per cent sulfur, requires special handling and for this reason the installation costs per ton of roaster feed may be too great to compete with hearth roasting. Interesting features of flash roasting at Copperhill are: 1. The sulfur dioxide content of the roaster exit gas can be varied between wide limits. Eight per cent sulfur dioxide gas, with 1.30 per cent sulfur in the calcine, has been common practice and gas up to 13.0 per cent sulfur dioxide has been possible. 2. Temperatures of the exit gases are very high. When roasting 60 tons or more of iron concentrate per 24 hr. in a modified Wedge roaster, the temperature in the roaster rises to 2000° F. and the calcine is lowered to 0.20 per cent sulfur. If the entire roaster system could be constructed to withstand such temperatures, ideal roasting conditions would obtain as regards sulfur elimination and tonnage roasted.

Jan 1, 1934

By W. E. Lindquist

Roasting of refractory gold ores has the primary goal of oxidizing sulfides and organics to improve gold recoveries prior to leaching. Commercial installations currently utilize bubbling and circulating fluidized beds. The principle of flash roasting is aimed at a more cost effective method of whole ore roasting for large throughput applications. Results of pilot plant testing and scale up to commercial design will be discussed in further detail in this paper.

Jan 1, 1993

By Brian T. Field

Development of cost effective technology for whole ore roasting of refractory gold ores is an important requirement to increase recovery rates as ore grades become more carbonaceous and sulfidic in nature. It is important that the industry focus on the further development of cost effective, environmentally sound technologies to roast this ore. Traditional technologies have centered around bubbling and circulating fluidized beds with and without oxygen enrichment. Fuller Company has developed a process to flash roast refractory ores in its pilot plant with the R&D results, commercial scale up issues, and indicative economics discussed herein.

Jan 1, 1993

By C. E. Dodson

Conventionally hydrometallurgical recovery processes from sulphide concentrates include roasting, leaching, precipitation, impurity removal and zinc electrowinning. The use of the novel (yet commercially proven in other mineral and metallurgical industries) TORBED process reactor for the flash roasting of sulphides will be proposed. The potential advantages in its application will be discussed including very fine particle processing capability, lower cost smaller roasters, waste minimization, improved leaching efficiency and overall process simplification.

Jan 1, 1999

By David Green

Outokumpu introduced Flash Flotation in the early l 980's for the recovery of floatable material from grinding circuits. The devel­opment came as a result of surveys made in the company's own concentrators, initiated to find ways of improving recoveries with increasingly complex and lower grade feeds. Hydrocyclones make a separation on the basis of particle size and mass, resulting in the "over collection" of fine grained, high S.G. particles. Minerals such as pentlandite, galena and gold are easily caught in the circulating load around the mill until they are overground and rendered more difficult to collect. In the case of downstream flotation this may simply involve a reduction in the rate coefficient due to the finer sizes or, as is commonly experienced in gold operations, the mate­rial is slimed and coated onto non-floating gangue and is eventual­ly lost to tails. At the time of Outokumpu's plant surveys, it was a relatively common practice, particularly in Pb operations, to have a flotation section fed directly from the secondaiy mill discharge. This is called unit flotation and certainly provided an improvement but very high wear rates and frequent sanding out of the cells was com­mon. The development of the SkimAir® Flash Flotation cell by Outokumpu provided a subtle but quite dramatic departure from the unit cell approach. Now it was possible to feed cyclone under­flow into a special purpose-built flotation machine and recover a final grade concentrate from the grinding circuit (see Figure I). The cell was designed to handle the coarse circulating load, per­mitting the coarsest fractions to be short-circuited back to the mill and retain the floatable sizes for a nominal time of 30 seconds to several minutes. The short retention time was possible largely due to the relatively clean content of the cyclone underflow stream. This means that the fine gangue is not present except in small quan­tities and most of the fine to mid-size paiiicles are higher S.G. and more likely represent valuable mineral. This condition provides for very high rate coefficients. Typical operations would recover 40-60% of the valuable mineral in this fashion and improvements in recovery were typically from 2-5% for sulphide minerals to the 5-20% range for gold and silver.

Jan 1, 1998

By W. G. Davenport

Flash smelting is used. mainly for making molten Cu-rich matte* from fine Cu-Fe-S** flotation concentrates. It blows dried concentrate particles into a hot fumace, surrounds them with 01-rich gas and allows them to react. The results are: (a) partial oxidation of Fe and S from the concentrate (b) generation of heat (c) melting of the oxidized particles to form molten Cu-rich matte, ~65% Cu and Cu-barren slag, ~1 % Cu. The melted particles fall to the hearth of the flash furnace where they fonn matte and slag layers, The matte is tapped from the furnace and oxidation-converted to metallic copper. The slag is skimmed, treated for Cu recovery then stockpiled or sold. Figures 1.1 and 1.2 show industrial flash furnaces and the position of flash smelting in the coppermaking flowsheet. ,Fig. 1.3 shows the locations of flash furnaces around the world.

Jan 1, 2001

By Tom Gonzales

At San Manuel, AZ, Magma Metals Co. operates an Outokumpu flash furnace, four Peirce-Smith converters and two anode casting wheels that are supported by six anode vessels. Process gasses from the flash furnace and converters are treated in a two-train/ double-contact sulfuric acid plant. The plant captures 98% of the sulfur. A new flash furnace was commissioned in July 1988. It has since processed more than 2.7 Mt (3 million st) of sulfide concentrate without a major rebuild. The company has gained unique experience in the operation of the flash furnace at high oxygen enrichments with low off-gas dust loadings. New procedures have been developed to maintain secondary material generation at equilibrium and for maintaining metallurgical control of operating parameters. Process flow description At Magma&apos;s San Manuel plant, concentrates and other copper-bearing material are blended and conveyed from two separate areas of the plant to three 420 t (465 st) capacity wet charge bins located above the rotary dryer. Flash furnace silica flux is conveyed to a 227-t (250-st) capacity fine flux bin located adjacent to the wet charge bins. The concentrate and flux are blended in controlled amounts and fed into a 168-t/ h (185-stph) gas-fired rotary dryer. The wet charge enters the dryer at 8% moisture and is dried to 0.2% moisture. The dried charge is pneumatically conveyed to a 580-t/h (640-stph) dry charge bin located above the flash furnace. Flash furnace charge is drawn from the bin by two drag conveyors at a concentrate feed rate of 145 t/h (160 stph). The charge is mixed with enriched combustion air and injected into the furnace reaction shaft. In the reaction shaft, the charge is oxidized to form matte, slag and a rich SO, off-gas.

Jan 1, 1992

By T. Gonzales

Magma Metals Company operates an Outokumpu Flash Furnace, four Peirce-Smith Converters and two Anode Casting Wheels supported by six Anode Vessels. Process gasses from the Flash Furnace and Converters are treated in a two train/double contact sulfuric acid plant. Sulfur capture for the smelter is +98%. The new flash furnace was commissioned on July 7, 1988 and has processed over three million tons of sulfide concentrate without a major rebuild. Magma has gained unique experience in the operation of the flash furnace at high oxygen enrichments with low off-gas dust loadings. New procedures have been developed to maintain secondary material generation at equilibrium and for maintaining metallurgical control of operating parameters. This paper describes all the procedures, operation control parameters and operating philosophy that has allowed Magma to achieve superior performance.

Jan 1, 1992

By Tom W. Gonzales

Magma Metals Company commissioned a 3000 tpd Outokumpu flash smelting furnace in July 1988. Through September 1992 the PSP has smelted a first campaign record 4.1 million tons of concentrate. This paper discusses modifications made to the original process equipment to overcome design flaws as well as future design changes currently under consideration.

Jan 1, 1993

By Nobumasa Kemori

Six kinds of copper &apos;90ncentrates. were treated individually in a ,pilot scale. Outokumpu flsah smelting furnace ~n order to study their ?flash smelting behavior with respect to oxygen efficiency and dust generation. The copper concentrates tested were selected from the more than twenty sources which are treated at the Sumitomo Toyo copper smelter, so as to provide a wide range of chemical composition in terms .of Cu, S,Fe, Pb + Zn + As, and Si~ content. Oxygen efficiency &apos;and dust generation rates obtained in &apos;the experiments ranged from 80% ,to 108% and 11% to 20%, respectively. Relationships between these results and experhnental conditions such as chemical and mineral composition of the copper concentrates, flux ratio, fuel consumption and so on are also discussed quantitatively in this paper.

Jan 1, 1998

By Petri Bryk, John Ryselin, Rolf Malmstrom, Jorma Honkasalo

THE theoretical possibilities for the realization of flash smelting have been known for a long time. Calculations concerning the same can be found in previously published literature,1 and suggestions for its accomplishment in practice are described in patents on the subject. Likewise a smaller number of practical test results are known. Autogenous smelting is closely connected with flash smelting, since in flash smelting techniques it is possible to use the heat evolved by oxidation of the sulfides for the smelting process to such an extent that under certain conditions smelting can proceed without additional fuel. However, in the event that insufficient heat is available from the oxidation of the sulfide concentrates, then additional heat may be supplied by preheating the air, using oxygen enriched air, on burning additional fuel with the concentrate.

Jan 6, 1958

By Z. Gostynski

The paper is a historical cross-section through a 28-year period of operation of the direct-to-blister Flash Smelting Furnace in the KGHM Glogów Copper Plant. It presents the origin of the furnace as well as the path of numerous changes and modifications both in technology and process introduced in the furnace in response to the production and cost-reduction challenges. The authors provide justification of the statement that continuous improvement of the "Polish" Flash Smelting Furnace has ranked it among the most modem smelting units in the world.

Jan 1, 2007

By Esko O. Nermes

Outokumpu flash smelting of copper concentrates was introduced in 1949 and flash smelting of nickel concentrates in 1959, both at Harjavalta in southwest Finland. The first flash smelter outside Finland was started up in 1956 in Ashio, Japan. Between 1956 and the present about 25 flash smelters for copper, and nickel concentrates have been put into operation in different parts of the world. Outokumpu"s research organization has been highly involved in the development of flash smelting. For example, a direct blister flash smelting process was developed in 1975 and introduced in Glogów, Poland, in 1978, and another has been designed for Zaire. This straight metal process is based on low iron content of the concentrate, which reduces the amount of recycling slag copper. Additionally, the concentrates are rather low in impurities.

Jan 1, 1982

By Kohra A, Shoji S

The amount of copper production by flash smelting process occupies about 17% (equivalent to 1.4 million t/year) of total free world production. In Japan, 650,000 tons of copper is produced annually by flash smelting. This is 65% of the gross copper production of Japan. To reinforce pollution control, promote energy saving, and enhance production efficiency by increasing the size of furnaces, conventional blast furnaces and reverberatory furnaces are being replaced with the flash smelters worldwide. The Ashio Smelter started copper production in 1884 and developed in association with the Ashio mine. In those days, the Ashio smelter produced copper by using the blast furnace process designed for the high-grade ore from the copper mine. At that time, this process was specialized in Japan. In 1956, for the first time in Japan, the Ashio Smelter introduced the flash smelting process developed by Outokumpu Oy of Finland (it is suitable for treating the copper concentrate, producing sulfuric acid and improving production efficiency). The flash furnace in Ashio, the first ever in Japan, had a capacity of 230 t/day for copper concentrate and was operated up to 1962. During this period, various operational troubles were solved, and further improvements were made; and, in 1962, a Furukawa-type flash smelting furnace was completed in Ashio. This improved version of a flash furnace had a capacity of 450 t/day. There was one flash furnace and one waste heat boiler, which were arranged in a unique pattern for that time. This furnace may be said to be the prototype of the present flash smelting process in the world.

Jan 1, 1987

By B. E. Penrod

The main constituents of flat glass are the eight commonest elements of the earth&apos;s crust. Five of these, silicon, sodium, calcium, magnesium and oxygen are essential. Two more, Aluminum and potassium have beneficial properties. For colorless glasses iron is undesirable, in standard clear glasses a small amount of iron is tolerable, while for most tinted glasses iron is essential. These elements are present in glass as oxides and because they are so common there is no foreseeable resource shortage. The availability of supplies of materials at particular sites at prices which enable a glass manufacturer to be competitive may be another matter. In this paper it is intended to provide a historical perspective to the current situation, to contrast some of the traditional North American and European practices, and to progressively review some of the driving forces for future change and to attempt to assess their effects upon both raw material supplier and consumer.

Jan 1, 1994

By N. S. Dalal, Xianglin Shi

"The mechanism of vanadium(V) V ) toxicity is still not fully understood in spite of extensive current effort (1-3). The presence of a vanadium(V) V ) -dependent NAD ( P )H oxidase in cell membranes suggests that at least one of the pathways involves oxidation of NAD(P)H (1-3). Considerable effort has therefore been devoted to finding the mechanism of NAD ( P ) H-oxidation by va¬nadium( V ) (1-19). Recently Liochev and Fridovich (4, 16) provided a critical review of vanadium( V) -stimulated NAD (P )H oxidation by plasma membranes. They out¬lined a mechanism in which vanadium(V) V )-stimulated oxidation of NAD ( P )H by biomembranes involves an O2 - initiated free radical chain reaction (4 ). While the above may be the major pathway for the vanadium-me¬diated NAD (P )H oxidation in membrane-related sys¬tems, some recent results suggest that in the presence of NADPH the flavoenzyme glutathione reductase can function as a vanadium(V) V ) reductase (18). Because of the significance of this result in relationship to the mech¬anism of vanadium( V) metabolism and the novelty of the metal-reductase behavior of a flavoenzyme, we have car¬ried out additional studies on one-electron reduction of vanadium( V) by two other, related flavoenzymes: lipoyl dehydrogenase and ferredoxin-NADPH oxidoreductase. These two enzymes were selected because they are known to catalyze a one-electron reduction of Cr ( VI ) (19-21 ), which is isoelectronic with vanadium( V ).The present study also reports on the generation of hydroxyl ( • OH) radicals in the vanadium( V) -flavoen-zyme redox system without exogenous H2O2. The • OH study was undertaken because • OH radicals are known to be generated in reactions of vanadium( IV) with H2O2 (17,18,22-27). For example, Piette and co-workers (17, 22) have studied effects of vanadium(IV) IV ) on lipid per-oxidation and NADPH oxidation and suggested that va-nadium( IV) -induced • OH radical formation may play an important role in vanadium( V) toxicity. Carmichael (25, 26) investigated the reaction between a RNA /VO 2' complex and H2O2 with a view to probe the possible re-lationship between vanadium( IV) -mediated • OH radical generation and DNA damage. He has suggested that in this reaction the • OH radical adds to the C (5) carbon of uracil, causing nucleotide damage, similar to what occurs in the nucleotide /Fe2+ / H2O2 reaction (28) and in y-irradiated aqueous solutions of nucleic acids (29 ). To our knowledge, however, there is as yet no report on ·OH radical generation in any reaction involving the reduction of vanadium ( V) by a well-characterized enzyme, without exogenous H20 2 • The present study provides evidence that ·OH radicals can form in a flavoenzyme-mediated reduction of vanadium( V) to vanadium( IV) and that this process involves also the reduction of molecular oxygen ( 0 2 ) to H20 2 • The H20 2 thus generated reacts with vanadium( IV) to produce ·OH radical, in analogy with the Fenton reaction ( Fe2 + + H20 2 - Fe3 + + OH- + ·OH)."

Mar 1, 1992

By Dennis N. Poffenroth

One concern of the Mine Safety and Health Administration is the structural integrity of steel wire ropes used on mine personnel hoists and elevators. Failure of such ropes has resulted in loss of life and property. Although thorough and regular visual examinations are performed, hoist ropes may still fail from undetected internal wear, corrosion, and broken wires. To complement visual examinations, nondestructive rope inspection techniques have been developed to determine deterioration and removal criteria. The techniques use electromagnetic and permanent-magnet test instruments designed by a Canadian firm. This paper describes the operating principles, field and laboratory testing of these nondestructive testing instruments, and discusses the feasibility of using this type of testing as a supplement to visual examination and destructive tests.

Jan 1, 1982