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By Marcel Sturzenegger

Though the extraction of copper is well established, generation of sulfur dioxide (S02) is still a troublesome issue. Conventional processes are further challenged by the increasing amount of impurities in the concentrates. Direct decomposition of the metal sulfides into the metal(s) and elemental sulfur under concentrated solar radiation offers a promising path to solve both problems. Thermogravimetric measurements under inert atmospheres have shown that synthetic chalcocite or chalcopyrite yield copper at temperatures as low as 1773 K. Even though optimum reaction temperatures might be somewhat higher, such temperatures are straightforwardly accessible in solar chemical reactors. The absence of oxygen will reduce the extent of slag forming reactions and thereby alter the evaporation characteristics of volatile impurities such as arsenic or antimony. Chemical equilibrium calculations for a chalcopyrite-enargite feed, e.g., have shown that under inert atmospheres arsenic compounds are completely evaporated at temperatures above 1000 K and an effective separation of arsenic from the matte is expected. An important step towards a solar production of copper is the design and testing of prototype solar chemical reactors for this reaction. Numerical modeling is a key tool supporting a rational design but it requires data of the high-temperature properties that prevail in these processes. Development of techniques for determining the essential quantities such as decomposition rates or radiative properties at temperatures up to 2000 K is therefore a main activity in our laboratory in order to control and optimize the process. Though developed in the frame of high-temperature solar technology, the experimental techniques are also suited to advance the understanding of conventional high-temperature processes. Keywords: Solar technology, Sulfur dioxide, Solar Radiation, Thermogravimetry, Chalcocite, Chalcopyrite, Numerical modeling.

Jan 1, 2003

By Abdel Rahman, M. Khaled, Abo Makarem

There are four large limestone quarries, located nearby Cairo metropolitan. Drilling and blasting operations are used to extract limestone for the cement industries. In these quarries, the blast vibration should be kept below a certain limit. One of these quarries is Tourah Portland Cement Company (TPCC) limestone quarry which, lies near important and historical large caves, within Tourah Mountain. Therefore, control of blast vibration level becomes very critical.

Jan 1, 2007

By Fiseha Tesfaye, Pekka Taskinen

"A thermodynamic study of the equilibrium phase assemblage AgBi3S5-Bi2S3-S was made by an EMF-technique, using the RbAg4l5 solid electrolyte. The ternary phase was synthesized from the pure Ag2S and Bi2S3 in an evacuated silica ampoule and grinded into powder and mixed with appropriate compositions of B12S3 and S, in a series of experiments, for pressing in to pellets. The pellets were assembled to form the galvanic cells Pt (-) | Ag ] RbAg4ls | AgBi3S5+ Bi2S3 + S + (C) I Pt (+). The EMF-measurements were made in the temperature range 299 - 460 K.In this paper, thermodynamic functions of the ternary phase AgBi3S5 (pavonite) have been determined. The agreement between the obtained results and the literature values were established.IntroductionThe complex group of ore minerals constitutes from trace amounts to a major proportions of sulfosalts. Although the sulfosalts rarely form massive ore bodies, they are commonly associated with rich sulfide ore minerals for the base and precious metals and widely distributed in a metal poor sulfide minerals [1]. For instance, Ag-bearing sulfosalts are encountered in ore minerals for the production of the base metals and are common sources of silver. Nevertheless, thermodynamic properties of the sulfosalts are poorly known.Reliable thermochemical data are essential for quantitative modeling of the chemical behavior of the sulfosalts in equilibrium with sulfides, which in turn would promote the optimization of complex minerals treatment and extractive metallurgy of the valuable metals."

Jan 1, 2012

By Markus Aspiala, Fiseha Tesfaye, Pekka Taskinen

In this paper, the standard thermodynamic properties of Ag3Sb and Ag6Sb intermetallic compounds have been studied by the solid state EMF-method, using Ag+ ion conducting β- alumina and AgI. The intermetallic compounds were synthesized from pure substances in evacuated silica ampoules and their formation were confirmed by the SEM-EDS analyses. The EMF measurements were made on electrochemical cells of the type [Ag | β-alumina | Ag-Sb] and [Ag | AgI | Ag-Sb]. The usage of β-alumina electrolyte, in this study, enabled thermodynamic measurements of the Ag-Sb-intermetallic compounds above 710 K, hitherto unreported. Based on the new experimental data, thermodynamic properties of the Ag-Sb-intermetallic compounds have been determined. The obtained experimental values have been compared with the available literature data.

Jan 1, 2015

Experimental Validation of a Flotation Cell Model

Sep 13, 2010

By T. Moodleya, I. Govender

Despite the widespread use of DEM to simulate particle processes, comparatively little work has been done to evaluate its accuracy. One of the reasons is a lack of available measurement techniques that can capture dynamic information at the momentum transfer timescale which is lower than 10-6 s - typical of the kinetics occurring within the drum. This work makes use of Positron Emission Particle Tracking (PEPT), an in-situ method capable of measuring 3D kinematic data at 1000 frames per second. PEPT measurements are performed using 3 mm and 5 mm mono-size glass beads in a 300 mm diameter rotating drum at critical speeds that are relevant to industry. We undertake systematic ‘tuning’ of DEM with a view to optimising the agreement between experiment and simulation. To ensure an equitable comparison scale, both the DEM and PEPT data are coarse grained within representative volume elements. This work seeks to validate DEM predictions against experimentally derived PEPT kinematic measurements. Keywords: PEPT, nuclear imaging, DEM, Tumbling Mills

Jan 1, 2020

By W Wu

The prospect of discrete element modelling (DEM) being used as an everyday design tool for transfer chutes in the iron ore mining industry is becoming more and more probable. However, much care needs to be taken to ensure accurate results are obtained. Whilst there are many publications in industry portraying the potential of DEM, there is little evidence of where it has been validated against a real set of experimental results. The purpose of this investigation was to gauge whether the incorporation of the physical properties of a specific bulk material at the DEM pre-processing stage can yield visually and numerically accurate simulations for a simple flow case. Effects such as irregular particle shapes, varying frictional properties and coefficients of restitution, all found through experimentation were investigated. Video analysis was used to compare simulations to real flow cases. It was found the most critical attributes in determining the accuracy of the simulations were particle shape and wall friction. Keeping the particle-to-wall friction factor constant was not sufficient to describe the flow accurately. But by introducing the varying effects of wall friction with consolidation stress, the correct results were simulated.

Jan 1, 2007

By Manfred K. Walther

"Tests were conducted on instrumented plates cast in the Abex Experimental Foundry to compare recorded solidification histories with results computed for corresponding models simulated with the C.A.S.T. program. The first plate was cast of low alloy steel and the second of carbon steel with a graphite chill at one end. Both were cast in molds of bonded silica sand. Temperature histories were recorded in the castings, molds and chill. Exceptionally good agreement was achieved between computed and experimental data. Other investigators will find the results useful as a benchmark against which they can compare the results of their own calculations.IntroductionSince the early 1970's our foundry engineers have used both two- and three-dimensional versions of the G.A.S.T. program to gain knowledge of the solidification process [1,2,3]. Study of the computed data gave insight as to how the rigging and risering of specific castings might be changed or adjusted to improve quality and yield. New schemes based on such analyses were then recommended for implementation on the foundry floor. The degree of success of the new practice was subsequently evaluated after the part had been poured, shaken out and examined. Similar conditions were noted in the sectioned castings whenever porosity and voids had been predicted by the computations. Appropriate modifications, when found successful in the model, were applied to the process. This led to a reduction, if not complete elimination, of the defects. Such results gave credence to the use of these programs as an aid in the production of better castings.Earlier investigations on simple shapes revealed excellent correlation between output derived with the G.A.S.T. program and exact solutions. Results also compared favorably with data calculated using other codes as reported in the literature [4] and summarized in the Appendix. However, since the computer program had not been verified by direct experiment, it was decided to run instrumented tests to check the theoretical predictions with actual measurements."

Jan 1, 1986

The disadvantages of the present zinc producing methods, RLE and ISP, are high energy consumption and environmental problems. Therefore, efforts have been directed in Outokumpu Zinc towards the development of alternate routes. One interesting pyrometallurgical process to produce zinc is to inject zinc calcine together with a solid reductant into molten iron, saturated with carbon. This process has been studied by thermodynamic calculations, laboratory tests and mini-pilot test runs at Outokumpu Research Oy, Pori, Finland. The results of these tests are presented and discussed in this paper. The mini-pilot tests demonstrated that over 97 per cent evaporation of the zinc was possible using a reactive coal dust as the reducing agent. The recovery of zinc in the metal phase was at best 88 per cent of input zinc, but only part reported in molten lead in the splash condenser. The final metallic zinc contained at best 98 per cent Zn, the main impurities being dissolved lead and coal carried along with the flue dusts.

Jan 1, 1993

By R. W. Charles

The Los Alamos National Laboratory, under the sponsorship of the U.S. Department of Energy; is involved with laboratory and field experiments to assist in development of the Hot Dry Rock concept of geothermal energy. The field program consists of experiments in which hot rock of low permeability is hydraulically fractured between two wellbores. Water is circulated from one well to the other through the fractured hot rock. Our field experiments are designed to test reservoir engineering parameters such as heat-extraction rates, water-loss rates, flow characteristics including impedance and buoyancy, seismic activity, and fluid chemistry. Laboratory experiments were designed to provide information on the mineral-water reactivity encountered during the field program. Two experimental circulation systems tested the rates of dissolution and alteration during dynamic flow. SOlubil ity of rock in agitated systems was studied. Moreover, pure minerals, samples of the granodiorite from the actual reservoir, and Tijeras Canyon granite have been reacted with distilled water and various solutions of NaCl, NaOH, and Na.CO.. The results of these experimental systems are compared to the observations made in field experiments done within the hot dry rock reservoir at a depth of approxi-mately 3 km where the initial rock temperature was 150 to 200°C.

Jan 1, 1981

By Patrik Fredriksson

Thermodynamic data concerning FeO-containing slags is of importance in ladle refining of steel. With a view to generate a set of reliable and self-consistent thermodynamic data for these slags, experimental determination of the activities of FeO in binary and ternary slags was carried out using the gas equilibration method involving CO-C02-Ar gas mixtures at steelmaking temperatures. The slag samples in Pt crucibles were quenched after the equilibration and subjected to chemical analysis. The thermodynamic activities of "FeO" in the slags were calculated from the experimental data. The results are incorporated into a thermodynamic description of silicate melts in the present laboratory. The model is based on a Temkin-Lumsden approach and is able to compute the thermodynamics of higher order systems from the lower order ones.

Jan 1, 2003

By David A. Summers

In May 1975 the U. S. Bureau of Mines contracted with the University of Missouri-Rolla, Rock Mechanics and Explosives Research Center to develop a Hydrominer modification to a long-wall shearer unit, wherein the rotating pick-laced drums and connecting gear drives are replaced by a water jet cutting head.1 The concept of the water jet cutting head is based on using the high localized energy of the water jets to isolate a slice of coal by cutting a slot under, at the back of, and at the top of the web. The plow blade of the head then advances into the cut and wedges the pillar over onto the conveyor (Figure 1). There were several potential advantages foreseen for the system of which perhaps the most significant were the elimination of coal dust from the working area2 and the ability, with a variation in nozzle geometry, to cut webs of greater depth with a small increase in equipment horsepower. The University initially designed the head, based on experiments carried out in the laboratory, under an earlier Bureau of mines contract. The experiments showed that it was more advantageous to work at a pressure of 10,000 psi with an estimated flow rate of 50 gpm than go to the higher pressures and lower flow rates which have been advocated elsewhere.

Jan 1, 1977

"En 1953, se habilita la nueva planta de flotación de cobre en Paragsha, donde el funcionamiento de las soleras tipo Lorain y la producción del mineral pirita lograron buenos resultados. Empero las nuevas condiciones de proceso, limitaron su funcionamiento y costo. Por tal motivo, el objetivo del trabajo se basa en la construcción de una solera de mayor rendimiento y menor costo, modificando su diseño al de una honda contínua. El primer juego de este diseño fue instalado en el molino de cobre Nº 1, sin aún obtener el dato final sobre su rendimiento. Posteriormente se consideró la solera AMSCO, dado que el diseño fue más eficiente y el costo final por tonelada fue menor. Sin embargo, se encontró que el contorno del valle era muy cerrado y las bolas N°4 se alojaban de modo ajustado, formando una solera muy gruesa. En consecuencia, se construyó otro diseño denominada ""Solera de onda abierta contínua"", el cual fue instalado en el molino de cobre N°7, donde la capacidad de molienda es igual de óptima y los costos son menores. Así, se pensó que la solera de una sola honda, es mejor que la de onda contínua puesto que este diseño tiene una sola honda en el centro de cada plancha de la solera. Luego, se diseño un tercer diseño, donde el promedio de vida era mejor. Por ello, de los tres diseños a seleccionar -la solera Lorain con 10 hondas, la solera de una honda con 20 hondas y la solera de honda continua de 30 hondas -, la última demostró ser la más eficiente. De otro lado, se probaron otros diseños de honda contínua con distintas aleaciones como el ""Nihard"", cuyo promedio de vida es entre 14 y15 meses aproximadamente, con el tonelaje actual de aproximadamente 270 000. Concluyendo que la experiencia anterior con solerasNihard en molinos a rodillos de 4 pies de diámetro, el impacto es mayor, obteniéndose en quebrantamiento de soleras a 3/4 grosor, pero que pese a esto, resulta ser superior a cualquier otra solera usada actualmente y en eñ que Paragsha esté 100% con soleras de molinos Nihard, a excepción de las rejillas dada su fragilidad. "

Jul 20, 1957

La influencia de los estudios de adsorción para el beneficio de los minerales, se relaciona con la flotabilidad de las especies minerales, y la perspectiva que se ofrece para el progreso de la metalurgia de concentración. Por ello, el objeto de la investigación se basa en la realización de tales experimentos como búsqueda del dominio de la clase de fenómenos fisico-químicos. Dentro de los métodos usuales de determinación de xantatos por yodo, se buscó hallar la concentración por medio del descenso de la adsorción, para determinar la máxima cantidad de reactivo y encontrar el más adecuado para el mineral. Empero, se reparó que a mayor concentración de colector, se genera mayor adsorción. Asímismo cuando se añade el xantato sobre el mineral con poca agua, la cantidad de reactivo adsorbida es superior, justificándose la ventaja que en procesos industriales significaría acondicionar después del espesamiento. En cuanto a la adsorción de galena oxidada, se observa que mezclando este mineral con un sulfuro de zinc, disminuye la adsorción. Posteriormente se ve cómo la superficie oxidada de la galena, puede alterarse por medio de reactivos, variando el grado de adsorción para los diferentes reactivos colectores de flotación. Finalmente se infiere que la realización de las pruebas pretenden determinar principalmente cuál es el reactivo más adecuado más adecuado para una galena determinada.

Jul 20, 1957

By E. C. Pechin

THE Lucy furnace, owned by Messrs. Carnegie, Kloman & Co., and located on the Alleghany River, on the outskirts of Pittsburgh, is a splendid modern furnace, 75 feet high, and 20 feet bosh. She had been working well on low grade ores of about 50 per cent., producing daily 68 to 75 tons. There was on stock 500 tons of Republic ore, one of the purest and best of the Lake Superior ores, averaging over 68 per cent. of iron, which had been procured for the purpose of making a trial for Bessemer iron. This was charged by itself, and Mr. Skelding, the founder, reports that he did not succeed in getting a single cast when it came down, before the furnace chilled from the hearth to the top of the boshes, some 25 feet. Every effort was made to save her, without avail, and the disagree-

Jan 1, 1874

By T. L. Joseph

LARGE deposits of manganiferous iron ores, representing several million tons of metallic manganese, occur in the United States. The Minnesota deposits of such ore-are of outstanding importance because of their size, state of development, ease of mining and proximity to the Great Lakes, which permits water transportation to steel centers. In' view of the fact that our steel industry requires large quantities of manganese, for which no satisfactory substitute-has been found, and because our reserves of ferro-grade ore are comparatively small, the development of methods that will make our large deposits of manganiferous iron ores available as a source of ferromanganese is an important problem. Realizing the importance of this problem, some years ago the North Central Station of the U. S. Bureau of Mines and the Minnesota School of Mines Experiment Station undertook jointly the development of methods for recovering the manganese content of manganiferous iron ores in a: form suitable for the production of ferromanganese, the 80 per cent. alloy indispensable in producing steel. Two types of manganiferous iron ores have been described in previous reports. I The brown ores are higher in iron and lower in manganese than the black ores; the black ores are more siliceous but contain less phosphorus. The utilization of the iron content of the brown ores in the production of steel appears to furnish the best basis for their treat-ment. The method of attack has been to work out modifications in iron and steel practice so as to recover manganese in the form of slag comparable to ferro-grade ores. The greater part of the experimental work has been conducted with a 6-ton blast furnace and a Y2-ton basic open hearth. This paper is devoted mainly to open-hearth tests in which high-phosphorus spiegel

Jan 1, 1930

By D. W. Frommer, M. M. Fine

Early in 1957 St. Joseph Lead Co. announced discovery of three new centers of iron ore deposition in east central Missouri.1 The discovery resulted from exploratory drilling in the vicinity of a magnetic anomaly or high. A deep hole, drilled into the Pre-Cambrian porphyry to determine the cause of anomaly, penetrated a magnetite-rich deposit.2 The magnetic surveys that revealed the anomalies were begun by the Missouri Geological Survey in 1929 and were continued into the 1930's 3. At that time an area in Crawford County known as the Bourbon magnetic high was located. A second anomaly, similar in size and intensity, was discovered about six miles to the northeast in Franklin County in the vicinity of Sullivan. This area was not studied in detail until the early 1940's.

Jan 3, 1959

By Frank Wartman

RECENTLY Horace Freeman1 obtained a patent on a successful method of conducting a roasting procedure described as to general features by Carl Schnabel2 almost forty years ago. Essentially, the Freeman process of roasting consists in introducing the finely powdered sulfide mineral, suspended in air or any other suitable gaseous medium, into the upper portion of a heated chamber. The stream of suspended particles is directed vertically downward. A counter-current stream of gas introduced at the bottom of the chamber flows upward. The mineral particles are oxidized as they fall through the heated atmosphere of the chamber. All air required for the oxidation may be admitted either at the top or the bottom of the chamber, or may be divided between the top and bottom inlets in any desired proportion. Heat may be recovered by passing the gases leaving the furnace through a waste-heat boiler or other form of interchanger. In speaking of the results obtained in roasting pyrite, Freeman says:3 Steam yield from the boiler exceeds 1 pound of steam per pound of pyrite con-sumed, which pays the cost of operation of the burner. The oxide produced is in the form of fused particles or hollow shells of magnetite, containing about 65 per cent of iron. It contains the gangue material ordinarily produced in flotation concentrate, of course, but it is being found that most of this can be eliminated by magnetic separa-tion, and that the sulfur content, as consistently produced, is below 0.2 percent. This material is especially interesting as a high-grade iron ore, free from phosphorus and low in sulfur. It may be sintered or briquetted. It is even more interesting as a raw material for sponge-iron production, to be directly smelted in electric furnaces without the usual cooling of the iron powder and magnetic separation between the reducing kiln and the electric furnace.

Jan 1, 1933

By Scott Dupont

Due to the scarcity of miners, and the necessity of decreasing the cost of mining, the Phelps-Dodge Corporation, Stag Canon Branch, at Dawson, [ ] New Mexico, decided to try, by various methods of mining, to increase the tonnage of coal mined per man, per day. With this in view, they first tried mining on a 250-foot face, maintaining the track at the face and using six to eight men shovel- [ ] ling. These men were able to aver age from ten to twelve tons each per, day when they were loading, but with

Jan 1, 1926

By Robert G. Van Nostrand, John H. Henkel

TRANSIENT potentials obtained in resistivity prospecting can be separated into two classes. The first is electromagnetic, has a comparatively short time constant, and increases in relative amplitude as the electrode separation is increased. These electromagnetic transient potentials, of which an excellent theoretical treatment is given by Yost,1 are the result of changes in the current and can be classed as differentiated signals. The second class is electrochemical, has a comparatively long time constant, and decreases in relative amplitude as the electrode separation is increased. The electrochemical signals are generated by the current flow itself and can be classed as integrated signals. The transient potentials due to electrochemical factors are the subject of this article. The phenomenon is referred to as induced polarization. Schlumberger2 was the first worker to observe induced polarization, but he was unsuccessful in attempts to apply the principles of induced polarization in electrochemical prospecting. Other workers, notably Bleil3 have studied polarization and in some cases pointed out its possibilities, but no theory has been presented that describes polarization and its time dependence adequately. It is the purpose of this discussion to present the essence of a theory to geo- physicists and to show that it leads to results consistent with experimental evidence. The theory on which this analysis is based has existed in electro- chemical circles since 1910.4

Jan 3, 1957