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By Chu E. Ho

Key variables that govern the jet cutting process are examined based on fundamental theories of jet hydrodynamics and soil mechanics. Under normal conditions of jet grouting operations, lift speed and rotation speed are found to be of less importance than the depth of jetting, nozzle pressure, nozzle diameter, and the soil bearing resistance, with regards to their influence on jet cutting distance. An analytical equation linking the governing variables is proposed, which allows for the possibility of evaluating column diameters achievable in different ground conditions based on theoretical calculations. When used in conjunction with shallow jet grouting field trials, the equation can provide a means for extrapolating trial results to conditions at actual depths for production jet grouting.

Jan 1, 2006

By F. Allen Meek

The Upshur Complex of Island Creek Coal Corp. consists of approximatly 35.000 acres of both surface and deep mine researves located in Upshur County West Virginia. The principle seams on the researve are the Middle and Lower Kittanning. Other mining in the area during the late 1960's and early 1970's produced surface mines that exhibited severely acidic drainage characteristics both during the mining phase, and after reclamation was completed. The Buckhannon River, the principal drainage for the area, is a high quality, lightly buffered stream, that is periodically stocked with trout. Because past mining had caused post mining acidic discharges and the Buckhannon River was a valuable recreational resource, mining permits for the area were put on hold by regulatory authorities, until solutions to the acid mine drainage questions could be addressed. In 1978, the director of the West Virginia Department of Natural Resources appointed a Task Force consisting of Industry, Regulatory. and Academlc participants. This Task Force was charged with gathering information and evaluating field procedures used during mining to prevent acidic mine drainage. In 1979, the group published a document titled "Suggested Guidelines for Mining in Potentially Acid Producing Overburdens" which summarized material handling and mining procedures that could be employed to help prevent the occurrence of post mining acid mine drainage. In 1982, a Technical Advisory Committee was appointed consisting of well known researchers in the field of acid mine drainage prediction and prevention. The group was charged with the task of conducting research in the field of acid mine drainage prevention. Mining conducted at the Upshur Complex between 1979 and 1986 employed various acid mine drainage preventative techniques recommended in the suggested guidelines manual and techniques concurrently being researched by the Technical Advisory Committee. Costs for the various techniques were documented and the resulting post-mining water monitored. The results of these evaluations are used by Island Creek in the planning of future mining operations in potentially acid prodcuing environments

Jan 1, 1991

By C. G. Bastos Andrade, V. F. Justo, F. R. Valenzuela-Diaz, M. G. S. Valenzuela, C. M. Matos, C. Volzone

For industrial use, the smectite clays are usually treated with inorganic acid of high concentration at temperatures under boiling point, which provide the bentonite´s bleaching power. In the present paper, a sample of brown smectite from Paraiba, Brazil, was submitted to treatment under moderate conditions (90°C, reaction times of 1, 6, 12, 18 and 24hours in close reactor, concentration of the aqueous solution of hydrochloric acid 1.5M, clay/acid solution ratio of 1g/10mL), aiming to reduce impurities, responsible for the color of the clay, without causing significant changes in their structure. The samples were characterized by scanning electron microscopy (SEM), energy dispersive X-ray detector (EDS), stereomicroscopy, Cation Exchange Capacity (CEC), Thermal Analysis (TG/DTA), and X-ray diffraction (XRD). It was observed a bleaching in samples with time of 12h to 18h. With the DRX was possible to monitor the peak intensity of the clay structure and the sample with 12 hours of treatment was not significantly altered its crystalline structure, maintaining the peak clay at d(001). The most pronounced changes in the bleaching occurred within the first 12 hours of acid treatment. Thus, clay can be used in products with high added value.

Jan 1, 2015

By Lawrence Mirabelli, AngloGold Ashanti, Greg Gibson

Cripple Creek & Victor Gold Mining Company (CC&V) operates the largest surface gold mine operation in Colorado and is located west of Colorado Springs in Teller County between the towns of Cripple Creek and Victor. Gold was first discovered in the Cripple Creek mining district in the 1890s. CC&V has been conducting gold mining and precious metal extraction operations in the Cripple Creek Mining District since 1976. Current reserves are only amiable to surface mining since previous underground mining has depleted near surface ore rich veins.

Jan 1, 2014

By J. Wild, M. Ounpuu, G. Chevalier

"The requirements for a finer grind at Heath Steele have resulted in the investigation of agitated milling as a cost effective alternative to conventional tumbling ball mills.The grinding unit is a vertically agitated, or stirred ball mill. Grinding occurs as the result of the motion of a single vertical rotor equipped with protruding pins which impart a stirring action to the ball charge. A comparative evaluation of a 30 kW SALA Agitated Mill (SAM), and a 1.5 m x 2.5 m copper-lead regrind ball mill has been conducted at Heath Steele.An overview of agitated milling as it applies to the reduction of sulphide ore will be the primary topic for discussion. Specific parameters including energy efficiency, media consumption, operating costs, and the mechanical aspects of the SAM operation will be presented.Evaluation of the agitated mill has shown that improved grinding performance at much lower work indices than those of the conventional ball mill is possible. Media consumption has proven to be comparable on an average g/kWh basis, but the mechanical availability of the mill has been low.INTRODUCTIONConventional tumbling ball mill grinding has proven to be an energy inefficient process. Energy losses occurring within the ball mill itself can be attributed to particle friction without breakage, kinetic and potential energy losses, plastic and elastic deformation and the production of heat and sound (Lynch, 1977). It can be generally stated that a certain amount of the input energy will be converted to another form as a necessary by-product of particle breakage. Theoretical interpretation of experimental results indicate that the energy required for breaking the ore particles in a ball mill varies between I% and 25% of the total energy input (SME, 1985)."

Jan 1, 1993

By Matthew S. Sanchez, Richard J. Lee, Matthew D. Zock, Drew R. Van Orden, Yumi Kamiya, Edward B. Ilgren

In many developing countries, asbestos is still used for friction products, insulation, and asbestoscement products. However, there is very limited modern data evaluating the airborne concentrations of asbestos fibers in operating asbestos plants. We have conducted an Industrial Hygiene survey, using state of the art PCM and TEM analysis, of a Bolivian asbestos cement plant that uses crocidolite during the production of roofing shingles and water tanks. The study is the first to use modern analytical measurements in an uncontrolled asbestos environment. Thus, this study offers insight into the historical airborne exposures at asbestos plants operating before modern dust control measures were introduced or airborne fiber levels regulated. The results suggest that fiber concentrations are far in excess of those for which current models would predict the onset of asbestos disease and mesothelioma. Significantly, the plant and community do not have an elevated incidence of asbestos disease or mesothelioma. Airborne fiber levels during comminution and fiber sizing ranged from 100 to as much as 1,000 f/cc. Fiber levels in the mixing, forming and finishing areas ranged from 0.5 to 9 f/cc. Based on the number of overloaded samples and estimates of their concentration, historical estimates of exposure may be underestimated by an order of magnitude. Also, an excellent correlation (1:1) between the PCM and TEM fiber concentrations (for fibers _0.25 um diameter) were obtained, raising questions about the conventional wisdom that the PCM systematically undercounts fibers. The results of this study further indicate that current models may overestimate the risk of asbestos disease and mesothelioma.

Jan 1, 2012

By L. Naude, J. Cloete, S. Engelbrecht

The results of an investigation evaluating whether an industrial plant, currently operating using sodium isobutyl xanthate (SIBX) as primary collector for sulphide minerals (mainly chalocopyrite), could adapt to operate using an alternate primary thiol collector without compromising plant and metallurgical performance. Initial laboratory scale flotation tests identified commercial dithiophosphate (DTP)-based and thionocarbamate (TC)-based collectors, that when blended, showed potential to replace the incumbent SIBX primary PGM collector. Industrial plant trail results show that there was no deterioration in recovery of 4E PGMs, even at a lower concentrate grade when operating the plant on the identified (DTP + TC)-based collector blend compared to SIBX. The effect on Cr2O3 content in the final concentrate was also found to be negligible. The (DTP + DTC)-based collector blend also showed promise in terms of plant adaptability in accommodating a new primary specialty collector blend. These observations highlighted the potential of replacing xanthate primary collectors with alternate thiol collector blends for PGM flotation. Keywords: PGM, xanthate replacement, specialty collector, sodium iso-butyl xanthate (SIBX), dithiophosphates (DTP), dithiocarbamates (DTC)

Jan 1, 2020

By Yuting Xue, Todd Minoski, Daniel Su, Mark Van Dyke, Mark Mazzella, Steve Hicks, Zoheir Khademian, Nicole Evanek

Design of chain pillars in a longwall mine setting is one of the main engineering controls on the global and local stability of the mine. Challenges with roof instabilities, floor heaves, and pillar failures can be alleviated, to some extent, by careful design of gateroad configurations and chain pillars. This work investigates three different alternative designs in a three-entry-system gateroad configuration with an inter-panel barrier in a longwall mine in Virginia. Starting with the current design, which has faced challenges such as excessive floor heave, a geomechanical model developed in 3DEC software is validated by monitoring in-situ pillar stress in the yield, abutment, and barrier pillars in the mine. Next, three different chain pillar designs are evaluated in the model with a focus on roof sagging, floor heave, and pillar average stress. Results show the relationships among the alternative designs and instabilities associated with roof, pillar, and floor in the study mine, providing insights for optimizing longwall mining designs in deep-cover settings.

Feb 1, 2025

By J. A. Herbst

Fine coal cleaning by froth flotation has become common practice in the U.S. with more than 80,000 tons treated in this way per day. In spite of this large tonnage, developments in the automatic control of coal flotation circuits have lagged significantly behind those for mineral systems. One reason such developments have been limited is that instruments have not been available for the on-line measurement of carbon or ash and another critical variables in coal slurries. A second reason is that the influence of the operating variables on coal flotation has not been completely understood. During the last few years some of the required instrumentation has been developed and an improved knowledge of the flotation process itself has occurred through mathematical modeling; as a result certain control strategies for coal flotation are beginning to emerge. This paper attempts to evaluate several control strategies using a detailed flotation dynamic simulator, DYNAFLOAT. After constructing a process matrix for the system of interest, promising alternatives for linking manipulated and controlled variables have been analyzed. In order to develop combined grade and recovery control strategies, the authors found it necessary to construct a grade/recovery map with the aid of the simulator to drive the system to known final, feasible grade/recovery operating conditions. Finally, an advanced strategy which uses an on-line model to identify disturbances and take control actions is proposed.

Jan 1, 1983

By C. R. Stephan, N. B. Greninger, W. A. Slivensky

The U.S. Bureau of Mines and the U.S. Mine Safety and Health Administration (MSHA) are participating jointly in a research program to evaluate strength characteristics and air-leakage resistance of various proposed seal designs for use in underground coal mines. Over 20 full-scale seals were constructed in the Bureau's experimental mine at the Lake Lynn Laboratory, air-leakage tested, then subjected to pressure pulses of 0.14 MPa or greater. A discussion on the experimental procedure, construction techniques, and the explosion and air-leakage test results is presented. Four types of construction material were used during this seal testing program: solid-concrete-blocks, low-density foam blocks, cementitious foam, and wood blocks. Only one of the solid-concrete block designs using a mortared thick wall survived the explosion and air-leakage tests. Most of the low-density foam block and cementitious foam seal designs were judged to meet the requirements to be considered a coal mine seal. One of the wood block convergence seal designs failed explosion testing. Based, in part, on these research findings, several alternative seal design constructions using low-density foam blocks, cementitious foam, or wood have been approved by MSHA for use in coal mines.

Jan 1, 1993

By Stephen Phillips, Luigi P. Gonano

Vertical circular shafts have been proposed for multiple access to high level nuclear waste deep geologic repositories. Shaft construction is a critical path item in the commissioning of a repository. Other constraints on the shaft design and construction criteria include the lack of design precedence for long term performance and the importance of minimizing rock and groundwater disturbance. A comparative evaluation of conventional and mechanized shaft sinking techniques is presented in the context of the particular geologic and design constraints. Technical and non-technical factors for blind drilling, blind boring, raise-reaming, drill-and-blast and ream-and slash methods are reviewed for typically "hard rock" and "salt" type repository sites. Appropriate shaft designs are developed, the suitability of each method to the particular requirements evaluated and construction costs and schedules determined. The explicit appraisal of the significant design factors for each method serves as a rational basis for the preliminary selection of the most suitable sinking technique for a particular set of site/design conditions.

Jan 1, 1983

By Jeroen van Eldert, Daniel Johansson, Henrik Ittner, Håkan Schunnesson

"Numerous aspects of underground construction, from structural stability to construction costs, depended on the tunnel quality, including blast damage and the Excavation Damage Zone. Accurately quantifying the extent and severity of damaged rock is a problem. Recent technical developments in the field of Measurement While Drilling (MWD), including software for on-board logging and on-site analysis, have shown potential for rock-mass characterization. Ground Penetrating Radar (GPR) and P-wave velocity measurement have also improved and show similar potential. This paper explores the use of MWD, GPR and P-wave velocity measurements and uses them in techniques for excavation damage characterization and prediction. The paper is based on data collected from a small underground waste-collection site in central Stockholm, Sweden. The data is correlated against rock-mass characteristics and their responses are evaluated. Results indicate potential for excavation damage characterization for all tested techniques, which could minimize blasting damage and improve the over-all tunnel quality. 1 INTRODUCTION During underground excavation the rock mass is influenced in many ways. The Excavation Damage Zone (EDZ) is a result of these influences. The EDZ can be defined by an irreversible change in rock mass properties, for example increased permeability. EDZ is influenced by the excavation method, the rock mass properties and the in-situ stresses in the area of the tunneling. Since the 1990s research has been done on the EDZ by Emsley et al. (1997), Christiansson et al. (2005), Olsson et al. (2009), Ouchterlony et al. (2009), Ittner et al. (2014), and Siren et al. (2015). Based on past literature the EDZ have in this paper been separated in the following subzones: 1. Failure Zone or over-break is the area outside the planned tunnel profile, including the Look-Out and hole deviation. This zone consists of fracture networks (both natural and blasting-induced), that caused rock fall-outs. The extent of the over-break can be determined by volumetric scanning and photogrammetry and the half cast factor can be used as a damage indicator. 2. The Damaged Zone is split into three parts and but the quantity and depth of damage is difficult to measure. Although it can be visualized by sawing of rock slices in the tunnel wall (Olsson et al. 2009), diamond coring (DC) or P-wave velocity reduction (Jern 2001): a. Inner Damage Zone (Crush Zone): It is located directly around the drill hole, and is caused by the shock-wave energy of the detonation. The micro fractures in the Crush Zone produce a white-wash (rock dust) in the half cast. b. Transition Zone: This zone consists of micro fractures that connect and form macro fractures, both radially and parallel to the tunnel wall. The macro fractures are caused by the gas expansion during the detonation of the explosive; it increases the pressure in the (micro) fractures and creates the macro fractures. Seismic reflection, rock slicing and core drilling can be used for the examination. c. Progressing Zone: In this zone the existing radial fractures propagate due to the increase gas pressure inside these macro fractures. Examination methods are seismic reflection, rock slicing and core drilling. In addition, the Peak Particle Velocity (vibrations) could be used to estimate the depth (Tesarik et al. 2011)."

Jan 1, 2016

By Doxford CI, Perry AJ

Mining Lease 908, situated on Gorge Creek near its confluence with the present Cape River system, has been subjected to intensive recent exploration for alluvial gold.The gold is hosted by a buried palaeochannel, the Gorge Creek Lead and by an overlying remnant meander of the Cape River. The principal, if not sole, sources of gold within the Gorge Creek Lead are the northwest trending Great Australian Reef and Green's Specimen Reef systems which are situated on adjacent high ground. Lower grade gold bearing eluvial ground separates the reefs from the Gorge Creek Lead. The sources for gold within the old Cape River system channel (Canton Lead) are thought to be situated some distance upstream, one source perhaps being the Lolworth Diggings located 30 kilometres to the northwest.Exploration of previously "heavily dug" ground on both leads consisted of detailed geological mapping followed by the collection and treatment of bulk samples from eight costeans. The wash samples varied in size from 120 to 396 cubic metres. Treatment was undertaken through a commercial sized conventional wet screen and jig plant.

Jan 1, 1986

By Philip Morey

Large scale surface coal mining will be required to fill future energy demand in the United States. In realization of this long-term commitment to coal resources, the U.S. Energy Re-search and Development Administration sponsored a study to determine the costs and problems of large-scale surface coal mining. As a result of this study a series of computer models were developed that can be used by government and industry to: 1) facilitate mine design and equipment selection, 2) provide detailed analyses of mining and processing costs. Two types of models were developed: detailed simulation models, which provide detailed information on mining systems and equipment to assist in mine design and equipment selection1 and broad models, which provide a first-order evaluation of deposits and new ventures for an entire mining complex. The complete model series permits examination of surface coal mining under a variety of terrain conditions. Six different mining methods were analyzed and documented during the overall project: 1) Area stripping with draglines, 2) Area stripping with draglines, extended bench, 3) Contour stripping with draglines, 4) Area stripping with shovels (loaders) and trucks, 5) Mountain top removal with shovels (loaders) and trucks, 6) Multiple dipping seam mining with shovels (loaders) and trucks. Each major operation in the coal mining pro-cess is represented in these models so that the best methods and equipment may be selected and 50 that the impact of such selection will be reflected in estimates of capital investment, operating costs, and coal price. Individual models allow the user to separately analyze overburden removal, overburden drilling and blasting, coal drilling and blasting, coal loading and hauling, coal preparation and handling, land reclamation, and premining, facilities, and administrative expenses. Because it is impossible to cover all the models in this paper, only the detailed simulation models representative of the technique "area stripping with draglines," are described. The Fort Union Strippable Coal Resource Region, one of eight test cases, is used as an example to describe the models.

Jan 1, 1978

"A commercially available through-the-earth (TTE) communications system was evaluated at an active underground longwall mine in West Virginia. This TTE system uses electricfield (E-field) sensing to send text-based communications through two separate antenna arrays connected in parallel. Each antenna array is composed of interconnected, grounded metallic rods or other such structures. Two-way communication between subsurface locations was investigated in this study using various antenna configurations. This field study was conducted as a part of a larger multisite evaluation of available TTE systems in an effort to determine their operational sensitivities. IntroductionWireless, through-the-earth (TTE) communication technology is designed to achieve point-to-point communication through solid strata using very low frequency (VLF) and ultra-low frequency (ULF) electromagnetic waves. Using this approach, communications are established without the need for intermediary communications infrastructure. As a result, TTE systems have the potential to provide reliable, robust communications between surface and underground personnel. Exploration into the use of TTE technology for this purpose dates back to the 1920s (Jakosky and Zellers, 1924; Pittman, Church and McLendon, 1985), but U.S. permissibility requirements slowed the development of TTE equipment for widespread implementation (Durkin 1980; Pittman, Church and McLendon, 1985). One of the primary challenges in producing wireless TTE communications is the counteraction of signal attenuation when propagating through solid strata (Barkand, Damiano and Shumaker, 2006; Wadley, 1949). The long wavelengths of TTE transmissions make them well-suited for reducing the rate of attenuation. However, even when operating within the VLF to ULF range, the performance of TTE systems is still affected by geologic and anthropogenic factors (Geyer, 1973; Geyer and Keller, 1976; Geyer, Keller and Ohya, 1974; Jakosky and Zellers, 1924; Large, Ball and Farstad, 1973). Although commercially developed TTE systems have demonstrated the ability to communicate in a variety of conditions, their range and performance have been highly varied (Barkand, Damiano and Shumaker, 2006; Geyer and Keller, 1976; Geyer, Keller and Ohya, 1974; Ilsley, Freeman and Zellers, 1928; Jakosky and Zellers, 1924; Yenchek et al., 2012)."

Sep 1, 2016

By M. K. Mohanty

One of the main objectives of this study was to evaluate a fine-coal cleaning circuit using an enhanced gravity separator specifically for a high sulfur coal application. The evaluation not only included testing of individual unit operations used for fine-coal classification, cleaning and dewatering, but also included testing of the complete circuit simultaneously. At a scale of nearly 2 t/h, two alternative circuits were evaluated to clean a minus 0.6-mm coal stream utilizing a 150-mm-diameter classifying cyclone, a linear screen having a projected surface area of 0.5 m2, an enhanced gravity separator having a bowl diameter of 250 mm and a screen-bowl centrifuge having a bowl diameter of 500 mm. The cleaning and dewatering components of both circuits were the same; however, one circuit used a classifying cyclone whereas the other used a linear screen as the classification device. An industrial size coal spiral was used to clean the 2- x 0.6-mm coal size fraction for each circuit to estimate the performance of a complete fine-coal circuit cleaning a minus 2-mm particle size coal stream. The ?linear screen + enhanced gravity separator + screen-bowl circuit? provided superior sulfur and ash-cleaning performance to the alternative circuit that used a classifying cyclone in place of the linear screen. Based on these test data, it was estimated that the use of the recommended circuit to treat 50 t/h of minus 2-mm size coal having feed ash and sulfur contents of 33.9% and 3.28%, respectively, may produce nearly 28.3 t/h of clean coal with product ash and sulfur contents of 9.15% and 1.61%, respectively.

Jan 1, 2008

By L. M. Cathles, L. E. Murr

Results of two years of leaching of 160 metric tons of low grade industrial copper sulfide waste in a large (40` high 10` diameter) thermally insulated tank at the New Mexico Institute of Mining and Technology are analyzed in the light of a previously developed model of the waste leaching process. It is shown that the model is verified in all major aspects and that the parameters in the model that characterize the leaching of a particular sulfide waste are usefully constrained by the results of the tank leaching experiment. The similarity between waste leaching parameters determined from the tank experiment and from interpretation of the leach behavior of test dumps constructed of similar waste encourages optimism it may be possible to predict the leach behavior of field dumps from suitably interpreted column experiments using the computer model developed.

Jan 1, 1980

By W. C. Smith

Over the past several years, the Bureau of Mines has conducted studies on the performance of fully grouted resin bolts In underground mines. The effectiveness of resin-grouted bolts in maintaining a competent roof, even in weak rock, has been well documented in the literature. Recent Bureau studies have evaluated the affects of shortened grout columns on bolt behavior in a variety of rock types (1, 2, 3). The application of partial grout columns to primary roof support systems has been introduced as a viable alternative to fully grouted bolt systems in some mines. The point-anchored resin bolt and combination bolt represent such alternatives. While both systems usually employ some mechanical interlocking system, their primary difference lies in the length of resin column used. Point- anchor systems rely on an anchoring device that is a short length of resin column of 2 feet or leas. Combination bolts, on the other hand, often require 3 feat or more of resin column. Resin migration into voids and fractures intersecting the borebole wall is a major problem when installing fully grouted bolts in weak roof rock and can result in a reduced column length that provides reduced anchorage. The relationship between column length and anchorage integrity deserves closer study. The Denver Research Center of the Bureau of Mines has examined the load- carrying capabilities of resin-grouted bolts in weak strata. Pull tests were performed on about 900 resin-grouted, 4- foot-long bolts with column lengths ranging from 6 to 48 inches. The practical performances of 8 different column lengths were evaluated for 10 mines under in sit" conditions using data obtained from standard pull tests. In addition criteria are discussed, including engineering properties of the host rock for designing safer and more effective grouted bolt installations.

Jan 1, 1987

By John Skelton, E. J. Harvey

Seepage runs (stream flow measurements in a short time at many points in a basin,) and stream flow records are used to locate losing areas in stream basins in the Missouri Ozarks. The terrane consists of dolomitic limestone and sandstone of Ordovician and Cambrian age. Side-looking radar imagery emphasizes variations in topography and reveals two types of drainage basin topography, rough and smooth (deeply dissected and slightly dissected basins). In the deeply dissected basins (rough ones), main streams and tributaries generally gain. In the slightly dissected basins (smooth ones), the streams lose a part or all of their flow. Logan Creek, a tributary of Black River in the southeastern Ozarks, loses much of its storm runoff and all of its dry weather flow. East and West Forks of the Black River, north of Logan Creek, gain water through most of their main stems. On radar imagery Logan Creek basin has a light uniform tone and smooth texture in contrast to the darker tone and rough texture of the East and West Forks. The contrast is due to the difference in degree of dissection. Therefore, radar imagery may be useful in suggesting gaining or losing streams (or reaches of streams).

Jan 1, 1973

By G. Chisakuta, P. Bwando, G. Mitshabu

By the end of 2022, the south-eastern Copper Belt region of the Democratic Republic of Congo was host to more than 40 small, medium, and relatively large sized copper solvent extraction sites. To date, solvent extraction reagents supplied in this region have never exceeded 50% of ketoxime content. We generated laboratory extraction and strip isotherms and used these with the BASF IsocalcTM modelling software to assess the benefit of using higher ketoxime blends on the main metallurgical performance indicators such as copper recovery and net transfer. Pure ketoxime extractants combine a relatively low strip point and a decent loading capacity, which are most effective as the pH of the pregnant leach solution gets closer to 2.

Jan 1, 2023