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By Rafaela Pacheco Malvão dos Santos

O enxofre no aço é, normalmente, um residual indesejável, afetando negativamente propriedades como ductilidade tenacidade, conformabilidade, soldabilidade e resistência à corrosão. Desde os anos 1970 a prática mais comum é dessulfurar o gusa fora dos altos-fornos, evitando, sempre que possível, a dessulfuração do aço em forno panela. Isto permite vazamento de gusa com teores de enxofre mais elevados do alto-forno, reduzindo os custos de produção desde reator. Termodinamicamente, a dessulfuração do gusa é favorável, devido as condições redutoras e a interação do enxofre com o carbono. Operacionalmente, o gusa pode ser dessulfurado em carros torpedos ou em panelas de transferência, através da adição de diversos reagentes. Para controlar o processo de dessulfuração é necessário conhecer a cinética do processo. Este trabalho descreve estudos iniciais para a melhoria do modelo de controle da dessulfuração em carro torpedo na CSN através da injeção de carbureto de cálcio em pó.

Aug 16, 2017

By Fulton Flick

THE micrography and macrography of aluminum and its alloys present certain difficulties. Many of the difficulties attendant on the micrography have been removed by methods developed during the past few years, notably those of E. H. Dix, Jr.1 The development of grain size in aluminum and its alloys may be equally troublesome, yet comparatively little detailed attention appears to have been given to it. Satisfactory reagents. are available for the development of such structures in ferrous and most non-ferrous metals, but those applied to aluminum and its alloys, i. e., alcoholic or aqueous solutions of sodium hydroxide or hydrofluoric acid are not entirely satisfactory. Hanson and Archbutt,2 in speaking of these two reagents, state that "These two reagents give fairly satisfactory results, but they sometimes produce badly tarnished surfaces from which the surface deposit is difficult to remove." It has been our experience that neither of these reagents is to be entirely relied on for developing structures suitable for study or photography. This means that when the etch fails to produce satisfactory results the, specimen must be repolished, through the 000-paper at least, and then etched with another reagent. This procedure entails a con¬siderable loss of time, and the final results may not be all that might be desired. However, the reagent to be described, although not a panacea for all etching troubles, has improved results so markedly that it is felt that it is worth offering as a grain-size etch generally applicable to aluminum and aluminum alloys. Czochralski3 in 1915 mentioned the application of a solution of 10 to 20 c. c. concentrated hydrofluoric acid in 100 c.c. absolute alcohol, etching in this reagent being followed by dipping in concentrated hydrochloric-acid solution.

Jan 2, 1925

By Alexander Filotti, Richard Kalson

"In the last decade, the construction industry has witnessed significant changes in the project delivery systems and contractual relationships between the general contractors (GC) and Deep Foundation Specialty Contractors. The Deep Foundation industry, especially including industry specialty subcontractors, have experienced a significant increase in requests that project risks be transferred through contract documents to subcontractors and suppliers with a decrease in margins for the industry. GCs regularly revise their form subcontracts to take into account recent experiences/contractual trends and newly issued judicial precedent, an exercise that is less frequently undertaken by subcontractors and suppliers. These contradictory trends are at the base of the ethical analysis of subcontracts that comprises the subject matter of this paper. Using contracts as a risk management tool in order to mitigate the general contractor’s risks in the context of dynamic changes in the legislative environment will also be addressed. Furthermore, another possibility for risk mitigation for the industry is to actively promote the introduction of the latest technical developments into the contract documents.CONTRACTS’ ETHICSFor thousands of years, ethics have been a constant presence in our lives and have been debated by different branches of philosophy. In modern times, ethics in business started to be an imperative for the success of a globalized economy.“Ethics are standards by which one should act based on values. Values are code beliefs such as duty, honor, and integrity that motivate attitudes and actions.” (Rumbaugh 2004). Some of these values and actions have been carved in legislation in general and in business legislation in particular. More and more, unethical business practices (e.g., corruption) are identified as the root cause of poverty, underdevelopment, and war around the world. In the context of contract ethics, three aspects are of interest:•,Ethics of contract construction•,Ethics of contracting processes•,Ethics of risk allocation in contracts"

Jan 1, 2016

By L Brodie-Hally

In the early-1990s, Tad Golosinski, the former the head of mining department at WASM participated in a review mining engineering courses in Australia. The review team asked various industry executives what subjects they thought graduates needed to be taught. Tad made the comment to me that the more senior executives thought that history and ethics were very important. The outcome was that the mining engineering courses were required to contain at least five per cent content dealing in ethics. The course was to be modified to reflect this. Tad thought at the time the students would think that subjects dealing in history and ethics came from retirees and professionals that were over the hill. So let me talk to you today about ethics.

Jan 1, 2002

By J. T. M. Amphlett, C. A. Sharrad, M. D. Ogden, R. I. Foster

"A renewed interest in nuclear power around the world in order to reduce greenhouse gas emissions is going to increase demand for uranium as fuel. This will result in more uranium being mined, which will in turn increase associated environmental pressures, such as fresh water use. A move to lower quality waters containing impurities such as chloride would help alleviate these pressures. In this work, we determined the uptake characteristics of weakly basic anion exchange resin Ps-EDA towards uranium from saline solutions in a dynamic flow column. Breakthrough curves were produced, with suppression of uptake being observed for chloride concentrations above 5 g L-1. Calculated resin saturation capacities at zero and 5 g L-1 chloride are comparable with literature values for strong-base anion exchange resins, and exceed those published for weak-base resins up to 20 g L-1 chloride. Data has been fitted to multiple breakthrough models, with the modified dose-response model most effectively predicting uranium recovery. The results show that the ethylenediamine functionality could be suitable for use in future uranium processing flow sheets where a high-saline lixiviant is used. IntroductionIon exchange (IX) is a key technology in the uranium mining industry and is well established for the extraction of uranium from both acidic and alkaline leach liquors (Edwards and Oliver, 2000). It was first employed in 1952 at the West Rand mine in South Africa (Ford, 1993; Taylor, 2016). H2SO4 and Na2CO3 are the most commonly employed lixiviants used to solubilize uranium in acidic and alkaline leach conditions respectively. The chemistry of these systems causes uranium to form anionic sulphate or carbonate complexes, which can be taken advantage of by anion exchange resins.Another major technology for the extraction and purification of uranium from leach liquors is solvent extraction (SX). This technique involves the extraction of uranium from the aqueous phase into an immiscible organic layer. Although this is a commonly used method, there are major drawbacks to it, including the use of large volumes of flammable solvents, solvent loss, phase disengagement, third phase formation, and the production of problematic degradation products (Veliscek-Carolan, 2016). These problems can be circumvented through the use of IX resins."

Dec 1, 2018

By Welington Bermudes Merelles

A ArcelorMittal Tubarão, unidade de produção integrada de aços Planos, faz parte do Grupo ArcelorMittal, maior produtora de aço do mundo. A empresa localizada na Região metropolitana de Vitória (ES), tem como principais produtos bobinas a quente e placas de aço. Como resposta ao cenário econômico do País, que atualmente se posiciona com baixa atividade econômica e em busca de manter a perenidade de seus negócios, lançou um Programa para identificar e eliminar “desperdícios”, baseado na metodologia Lean Thinking/ Manufacturing. Uma das iniciativas, apontadas como oportunidade de aumento de produtividade foi a etiquetagem das Placas de aço em substituição ao processo tradicional de Marcação e Pintura das placas. Esta mudança no processo de identificação de placas, proporciona maior produtividade na área de Condicionamento de Placas e a possibilidade de aumentar a produção com menos recursos e custo operacional.

Oct 30, 2017

By F. P. Hassani, J. F. Boily, A. M. O. Mohamed, M. Hossein

The optimal geochemical parameters required to form ellringite in a lime-remediated site have been investigated with the use of thermodynamic modelling. The speciation of sulphate and 10 metals analyzed in samples of a mine tailing from northern Quebec was calculated with a computer model. The model also includes calcium, which would result from the addition of lime to the system. Two speciation calculations were done. The first one is a hypothetical speciation before the onset of precipitation and was used to devise the stability fields of minerals susceptible of forming in high pHs. The stability fields were determined by building activity ratio diagrams with sulphate, aluminum and calcium species concentrations for pHs ranging from 4 to 14. The investigation was carried out for a 25°C solution with an ionic strength less than 0.12. Thermodynamics predict that an optimal stability field for ettringite in the mine tailing samples containing 10-3 mol/L SO4-2,10-2 mol/L of AI(OH)4 requires at least 10-2mol/L of Ca+2 and a pH larger than 11.6. The sulphate contents of the mine tailing samples, however, limit the precipitation of ettringite and monosulphate could be an end-precipitate. The second speciation is in equilibrium with precipitates and provides information on the speciation of the residual metals. If ellringite could be precipitated as a stable form, it could serve as a sorptive agent for residual metals, and, due to its binding properties, consolidate tailings.

Jan 1, 1995

By R. Bryce, T. J. Doughty, K. Stoll

Sulfate-impacted mine waters are under regulatory scrutiny to reduce total dissolved solids (TDS). There are several options to reduce TDS. One option is transforming the soluble sulfate into insoluble ettringite. The Water Company LLC (TWC) patented a process for sulfate removal through ettringite formation by reacting directly with metallic aluminum. Freeport-McMoRan (FMI) and TWC have collaborated to design, build and operate a 10-gallon-per-minute (gpm) ettringite pilot plant to establish reagent consumption, plant availability and full-scale design criteria. Using metallic aluminum as the primary aluminum source for ettringite precipitation eliminates the addition of other ions, resulting in significant demineralization. The pilot plant achieved greater than 98% water recovery, greater than 90% reagent efficiencies and maintained reactor sulfate levels below 250ppm. BACKGROUND Ettringite is a hydrated calcium, aluminum, sulfate mineral with the following formula: Sulfate-impacted mine waters are under regulatory scrutiny to reduce total dissolved solids (TDS). There are several options to reduce TDS. One option is transforming the soluble sulfate into insoluble ettringite. The Water Company LLC (TWC) patented a process for sulfate removal through ettringite formation by reacting directly with metallic aluminum. Freeport-McMoRan (FMI) and TWC have collaborated to design, build and operate a 10-gallon-per-minute (gpm) ettringite pilot plant to establish reagent consumption, plant availability and full-scale design criteria. Using metallic aluminum as the primary aluminum source for ettringite precipitation eliminates the addition of other ions, resulting in significant demineralization. The pilot plant achieved greater than 98% water recovery, greater than 90% reagent efficiencies and maintained reactor sulfate levels below 250ppm. BACKGROUND Ettringite is a hydrated calcium, aluminum, sulfate mineral with the following formula: Ca6Al2(SO4)3(OH)12•26H2O Ettringite readily precipitates in high pH water and by doing so, removes sulfate from impacted waters. The SAVMIN process, piloted in South Africa, is one method to produce ettringite. In this process, aluminum hydroxide is the aluminum source. The Cost Effective Sulfate Removal (CESR) process is similar to SAVMIN, but uses a proprietary aluminum source instead of aluminum hydroxide. Outotec and Veolia also have their own versions of the process using their specialized process equipment. TWC patented a version of ettringite precipitation using metallic aluminum as the aluminum source for ettringite formation. The benefit of using aluminum metal is that no additional ions are added to the process. At high pH, the raw aluminum corrodes in water causing hydrogen gas generation as the water is chemically reduced. This reaction is shown below:

Jan 1, 2019

By A. Liard, H. Sommelet, G. Sauriol

"Description des études qui ant conduit à la conception spécifique du système de drainage de la mine à ciel ouvert. Les approches différentes sont examinées ainsi que la valeur du système recommande.IntroductionLa Division Mines Gaspé de Mines Noranda Ltée exploite un gisement de cuivre par mine souterraine et mine à ciel ouvert à Murdochville, Québec. L'exploitation par mine aciel ouvert a commencé en 1965 avec une operation à flanc de montagne. Elle se poursuit actuellement sous Ie niveau de la vallée dans une fosse dont Ie diamètre est de I'ordre de 800 m (2,600 pi), et la profondeur de 150 m (500 pi) sou s Ie fond de la vallee. Elle doit atteindre une profondeur de 360 m (l, 180 pi) sous Ie fond de la vallee , avec des murs hauts de 360 à 490 m et des pentes moyenne de 44°. Le rythrne d'extraction est actuellement de 85,000 tonnes par jour.Dans Ie cadre des etudes entreprises par les Services Techniques de la Division Mines Gaspé, la compagnie Géomines Ltée a été consultée pour étudier les conditions hydrogéologiques et hydrologiques locales et participer a la conception d'un système de drainage superficiel et souterr ain. Un tel systerne de drainage visait: a éviter les importantes venues d'eau qu i affectent I'exploitation en periode de crue; amaintenir les pressions hydrostatiques au sein des parois de la fosse dans les limites imposees par les etudes de stabilite des pentes réalisees par la Mine.Les principales étapes de cette etude ont porté sur: la collecte et la compilation des données sur la géologie, l'hydrologie et l'hydrogeologie du site; . la détermination des caractéristiques hydrauliques du milieu rocheux à partir d'études structurales et de test s de perméabilité;"

Jan 1, 1981

By André Gobell

"La distribution des éléments majeurs dans une séquence de roches volcaniques felsiques, la formation de Waconichi, au sud de Chibougamau, indique que les roches pyroclastiques du secteur ouest de ce segment sont chimiquement anormales si on les compare à la composition moyenne des roches volcaniques de Chibougamau: elles sont caractérisées par une teneur anormalement élevée en f er, en magnésium et en potassium et une teneur anormalement basse en sodium et en calcium; ce chimisme caractérise les encaissants des dépôts de sulfures massifs d 'origine volcanique.Les coulées rhyolitiques massives sous-jacentes au gite de cuivre-zinc avec or et argent de Lemoine ne montrent pas ou très peu d’altération de ce genre. Le schéma de mise en place des dépôts de sulfures massifs d'origine volcanique et la nature des roches en présence permettent de croire que la zone d'altération mise en évidence à l'ouest de la mine Lemoine puisse être reliée à la mise en place de ce gisement d'ou l'im portance de tenir compte des caractères texturaux des roches lors de l'interprétation de données litho géochimiques."

Jan 1, 1980

By J. C. Marchand, M. A. Berube

"L'objectif principal recherché lors du broyage d 'un minerai est de libérer adéquatement ses valeurs utiles en vue de leur concentration ultérieure. La pratique courante consiste à tenter d'obtenir un produit de broyage d'une granulométrie constante. Malheureusement, les propriétés texturales des minéraux utiles varient naturellement dans un gisement et une telle stratégie n'entraine pas toujours pour ces minéraux un degré de libération constant. Pour un rendement optimal du procédé de concentration, cette variable très importante doit donc être périodiquement vérifiée.Jusqu'à maintenant, la plupart des études de libération des minerais se font en examinant des sections polies de particules du minerai broyé. Le GRAAIM a récemment assemblé un système modulaire d'analyse d'images qui servira en grande partie à des mesures automatiques du degré de libération des minéraux. Le système s'avère relativement peu coûteux comparativement à la plupart des analyseurs de texture conventionnels si l'on considère que plusieurs de ses composantes, par exemple le miniordinateur, sont utilisées à une foule d'autres applications, et il permet de plus une grande souplesse d'utilisation puisque l'on a qu'à construire des algorithmes de mesure et de calcul en fonction de l'objectif recherché. Des programmes particuliers permettant des études automatiques de libération sur des sections polies de particules ont ainsi été élaborés. Ils permettent également des mesures de teneurs et de distributions granulométriques apparentes des particules. Des résultats obtenus dans le cas de minerais de fer sont brièvement présentés afin d'illustrer la technique."

Jan 1, 1983

By Matthew Clay, Colin Chambers, Susan Hookham

Opencast (quarries) and underground mines around the world use blasting methods to mine valuable ore. Traditional blasting systems use technologies such as electric delay detonator systems (developed in the 1950s) and non-electric detonator systems (developed in the 1970s) to initiate a detonation train to blast rock more effectively, and so retrieve valuable product more efficiently. However, the lack of precise control over blast timings with these approaches can result in undesirable outcomes such as significant flyrock, excessive ground vibration, uneven grade of rock and misfires (in which sections of the blast can remain unfired). The development of Electronic Initiation Systems (EIS), first used in the 1990s, introduced a higher level of control over the blast. These systems greatly reduce the negative issues associated with blasting. However, this precision introduces complexity, and with this complexity comes difficulty in demonstrating the predictability, safety and reliability of such systems.

Jan 1, 2017

By Roberto Folchi, Hans Wallin, Mara Battocchio

An understanding of explosives science and technology, and the competence to harness it is central to maintaining Explosives capability, national security, and in sustaining a competitive industry. A consequence of eroding this competence is the increased likelihood of explosives accidents. These are often catastrophic as demonstrated by accidents in Nigeria, Russia, Toulouse and Enschede. In addition to the serious loss of life there was the very significant damage to houses, domestic and industrial infrastructure and to the environment at a cost of many millions of Euros.

Jan 1, 2013

By AIME AIME

WHEN a local man has attained high position in business and civic affairs at home, his fellow citizens feel elated if his attainments are given recognition in the form of election to office in an organization of national scope. Eugene Ainsworth White, a new Director of the Institute, is one of the must prominent citizens of Tacoma, where for the past thirteen years he has managed the Tacoma Smelter of the American Smelting and Refining Co. A list of the civic duties he has carried with distinction would be a long one; for recent years it would show that he has been chairman of the Community Chest, vice-president of the Chamber of Commerce. and a member of the Pierce County Taxation Bureau.

Jan 1, 1945

By AIME AIME

TO attempt to say anything adequate about Eugene McAuliffe as a human being, engineer, or executive in this brief space is ridiculous, for one could extol his virtues at length in all three catagories. Too, one might dwell on his good humor, and also his modesty, for lie did not wish even these few words to be said, "having no illusions regarding either ability or achievement, not even blessed with good looks." Mr. McAuliffe was born in England just seventy years ago. Twenty years later he started at the bottom with the Northern Pacific, gradually being promoted to locomotive fireman, engineer, and so

Jan 1, 1936

By AIME AIME

EUGENE McAULIFFE will be the fifty-ninth man elected President of the Institute. Looking back to the first President, David Thomas, and reading Dr. Raymond eulogy of him, written eleven years after lie had served his term, we cannot help but feel that Mr. McAuliffe is much the same type of man. Like Mr. Thomas. Mr. McAuliffe takes office in his middle seventies the first President was 76 and our new chief will be 75. Dr. Raymond said A Mr. Thomas: " .. those of us who attended the first few meetings of the Institute ... will bear witness that his indomitable agility, activity and

Jan 1, 1941

By P Simpson, P Bundo

The Eureka Mine is situated in the Guruve district of Zimbabwe, some 150 km north of Harare. The mine was first worked in 1895 and until recently was operated as a typical Zimbabwean "smallworking" with a single owner­operator and small labour force mining at up to 50m depth and processing 50 tonnes per day of ore via grind, gravity recovery and CIP. The gravity circuit comprised a Knelson 12" Centre discharge Concentrator from which a significant but variable portion of production was recovered. In 1996 exploration was commenced by Delta Gold Zimbabwe (Pvt) Ltd (DGZ), a wholly owned subsidiary of Delta Gold NL of Australia, with the aim of testing mineralisation and establishing a large-scale open pit operation. A feasibility study was completed in April 1998. Construction began in August 1998 and first gold was poured in June 1999. The mine is designed to produce 65 000 oz/annum of gold from 1.5 million tonnes of opencast ore grading 2 git Au.

Jan 1, 2000

By James M. Lockwood

"Eureka Technology has developed and patented a technology for the recycling of EAFD. Through this process all constituents of the material become salable commodities or are returned to the steel making process. In transforming the EAFD ""waste"" stream into a ""process"" stream the Steelmaker eliminates potential liabilities and the uncertain future of current processes while further reinforcing its role as a recycler. This is a cost-effective and energy efficient technology that combines hydrometallurgic and electrolytic processes resulting in the recovery of salable metals. For instance, unlike pyrometallurgic processes, zinc is recovered in metallic form and no elements are volatilized. This on-site operation also eliminates expensive transportation costs. In summary this technology reduces the cost of dealing with EAFD by recycling material currently being landfilled.IntroductionWorld crude steel production reached a new record level in 2007 - 1.34 billion tons of which 31% was produced by EAF steel makers [1]. This resulted in the generation of over 6 million tons of EAFD. This steel byproduct contains significant amounts of lead, cadmium and other hazardous metals. In the United States the Environmental Protection Agency (EPA) has designated EAFD a hazardous waste (EPA waste code K061). With over 50% of steel production in the US coming from EAF steel making this byproduct represents the single largest source of solid hazardous waste generated."

Jan 1, 2008

By Ingvar Janelid

13.7-1. General. Iron ore mining in western Europe is mostly carried out underground and only a minor part is mined by open pit methods. Actual open pits of importance in this connection are, among others, Svappavaara in Sweden, Mo i Rana and Sydvaranger in Norway, Corby Mines, Colsterworth, and Scunthorpe in Great Britain, and in western Africa, Nimba and Bong Range in Liberia, and Kedia d’Idjil in Mauritania. The open pit mines of western Africa are of great interest in this connection as they are designed according to European practice and have accepted the same techniques, methods, equipment, etc. as the European mines. In the surface mining of limestone, granite, shale, etc., the technical conditions generally are similar with those in the iron ore mines. Some information will therefore be submitted from typical quarries. The geological conditions at the various iron ore mines and limestone and other quarries vary extensively. In Scandinavia the iron ores occur exclusively in Precambrian rocks. The ore is hard, mostly magnetite or hematite, folded and steep dipping, and hence accessible to surface mining only in the shallow sections. In the mines referred to, open pit mining will last for another 10 to 30 years, whereupon mining has to be continued by underground methods. In France the Minette iron ore has previously been mined in open pits but, because of increased overburden, mining underground with room and pillar methods now dominates. The iron ores are Jurassic, flatlying strata of oolitic type, containing chamosite, siderite, and brown hematite. The British iron ores are mostly of the same origin and appearance as the French deposits, but despite heavy overburden they are preferably mined from the surface. In western Africa, the iron ores are of the same type as in Brazil, i.e., itabirites with high-grade portions resulting from silica-leaching and weathering. The ore contains mostly brown and blue hematite and magnetite. Nimba and Kedia d’Idjil are very similar regarding ore quality and geology. Bong Range is a deposit of low-grade ore which has to be concentrated.

Jan 1, 1968

By George Bárdossy

Most of the bauxite deposits in Europe belong to the karst type. They are located mainly ill Southern Europe along the Mediterranean Sea and in the Ural Mountains. Lateritic bauxite deposits occur on the Russian Platform, in Poland, Northern Ireland and in Turkey. Tikhvin-type deposits arc found on the Russian Platform. Bauxite formation in Europe started in the Middle Devonian. The main bauxite forming period was the Upper Cretaceous. Very few bauxites are younger than Eocene. Most deposits are covered by overburden of up to 1000 m. Prospecting is carried out by drilling. Several geophysical methods are used to detect the hidden deposits. Geostatistical methods were introduced in several countries for evaluation of the reserves and the geometry of the deposits. Data on bauxite production are given for 1982 and since the beginning of mining in Europe.

Jan 1, 1984