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By Dorsey Lyon

I. INTRODUCTION THE utilization of hydro-electric power in electro-metallurgical indus¬tries, aside from purely mechanical operations, may he of two kinds. The electric energy may be used to supply the heat necessary for the per¬formance of the chemical reactions of a metallurgical process, or the elec¬trolytic action of a direct current may be employed for extraction of metals, either in a reduction process or a refining process. In discussing this subject, it is well to distinguish between established industries, which are producing metals and alloys at a profit by use of the electric current, and the many processes which are either still in the experimental stage or have not even passed the paper stage of development of a patent. That is, we consider electro-metallurgical industries as commercial operations which are now consuming large blocks of electric energy, while processes which are not in commercial operation are only prospective consumers. Also, owing to the difficulty and risk of any attempt to foresee the effect of the European war upon electro-metallurgical industries, we have felt obliged to disregard the war entirely, and state our opinions regardless of its existence.

Jan 8, 1915

By Ying-Chu Hoh

The extraction of cerium(IV) by valence change with two-phase electrolysis was studied experimentally. The results show that the electro-oxidation extraction depends mainly on the distribution of the solute between the two phases, the reaction on the electrode surface and the diffusion of the reactant and product between the electrode and aqueous interphases. The effects of various parameters on cerium extraction were also studied. The selected parameters were background current, catholyte acidity, agitation speed, operation current and voltage and surfactant addition. The electro-oxidation extraction mechanism can be divided into eight steps. In addition, Wee the rate of extraction is quite fast, the percentage extraction Ce+4 can be taken as an index to show the conversion rate of Ce+3 J to Ce+4.

Jan 1, 1989

By Zhang. L.

Ordered intermetallic PtSb had been synthesized by arc-melted and then sintering treatment. The electro-oxidation of formic acid on PtSb was investigated at room temperature by cyclic voltammetry and chronoamperometry. The results are compared to those at a polycrystalline platinum electrode surface. It was found that PtSb intermetallic was catalytically more active than pure platinum according to the onset potential and current density. XRD and XPS technologies had been used to investigate the crystal structure and electron effect. We think formic acid decomposition on PtSb favors the reactive intermediate route and is not very much affected by the CO intermediate as compared to Pt.

Jan 1, 2005

By Yunhua Gan, Xiaowen Chen, Yang Tong

Experimental studies of electro-spraying were carried out using ethanol as fuel in a microcombustor under combined electric field. And the effects of different electro-spraying modes on the combustion efficiency were analyzed. Results showed that when ring electrode potential was invariant, there were four different electro-spraying modes with the variations of nozzle potentials, which were varying with the flow of ethanol. The cone-jet mode was the stablest one during the whole experimental process. The atomized ethanol was ignited and combusted stably near the steel mesh, the combustion efficiency increased firstly and then decreased along with the increasing of the equivalent ratios, reached the maximum values when the equivalent ratio equal to 1.0. And the maximum values were the highest at the cone-jet mode, and the lowest at the pulsed-jet mode.

Jan 1, 2016

By Abhakumari

Effect of applied DC potentials on the bioleaching of a chalcopyrite concentrate in the presence of Acidithiobacillus ferrooxidans is discussed. Copper dissolution was the highest at an applied potential of +600mV (SCE), while all the dissolved copper got cathodically deposited at a negative potential of -600mV (SCE). Electrobioleaching at an applied potential of +600mV (SCE) was established at different pulp densities as a function of time. Effect of the magnitude of electrolytic currents on the activity and growth of bacterial cells was studied. Preadaptation of bacterial cells to the concentrate slurry and electrolytic growth conditions significantly enhanced copper dissolution. Electrochemical and biochemical mechanisms involved in electrobioleaching are illustrated with respect to oxidative dissolution and bio catalysis of anodic oxidation.

Sep 1, 2012

By Orson Shepard

THE term "electrocapillary amalgamation" is used in this paper to designate amalgamation processes that depend upon electrocapillary phenomenon; i.e., the action of an electric current upon the surface tension of mercury at the contact with aqueous solutions. Electro-capillary amalgamation is selected as a name for these processes because the electrocapillary phenomenon has been found to be the effective agent in the use of sodium amalgam, as well as in the various processes using an electric current from a source outside of the amalgam. Amalgamation processes that depend upon supplying an electric current to the amalgam from an outside source, such as batteries and generators, have previously been called electrical amalgamation processes. There has been a tremendous amount of experimental work done on amalgamation processes involving the use of an electric current, as shown by the large number of patents issued on these processes: the earliest in 1885 and the latest in 19341. Regardless of all the experimental work, the fundamental principles causing the operation of electrocapillary amalgamation processes have not been described. The explanation usually given is that an electric current keeps the amalgam bright and clean. Patent No. 328532 states: It is well known that when amalgam plates are used for collecting gold and silver from their ores the surfaces of these plates are liable to become tarnished or sickened by certain substances contained in the ores or in the current of water which is employed to carry the ore over the plates, and that in this condition they are unfitted for amalgamating the particles of gold and silver. To prevent this and to keep the surfaces of the amalgamation plates always bright and in a better condition for catching and amalgamating the particles of gold and silver I employ electricity in the following manner:. . . A similar explanation is given 49 years later, in patent No. 1953364: The sodium (Na) ions lose their charge at the cathode becoming sodium atoms, which do not react with the electrolyte, but follow the grounded electrical current through the mercury body producing in their passage sodium amalgam and liberate themselves in the amalgamation compartment when brought in contact with the fed

Jan 1, 1936

By Kotaro Ogura

"The electrolysis process in which CO2 is selectively reduced to C2H4 at a three-phase(gas/solution/metal) interface on a copper-mesh electrode has been developed in a concentrated solution of potassium halide. At open-circuit potential, CO2 is captured on the electrode by being inserted into the double-layer consisting of halide anions specifically adsorbed and potassium cations which are located in the Helmholtz inner and outer layers, respectively. CO2 thus activated is subjected to the electrochemical reduction. In the early stage of reduction, CO2 is converted to formate radicals that are adsorbed on the electrode by taking the place of halide anions. The reductive coupling of these radicals results in the formation of intermediates such as -CH2C(O)- and CH2=CH-, and C2H4 is finally produced. The catalytic activity of the electrode process involving the insertion of CO2 into the double layer is not deteriorated at all during the electrolysis, and the continuous reduction of CO2 to C2H4 is possible with the addition of inorganic acid under the assistance of natural energy.Carbon dioxide is a serious pollutant released from fossil fuel power station, internal combustion and many industrial operations. The easy release of CO2 to the air has caused the global warming, and the technique which intends to curtail CO2 by pushing it back into the ground has been suggested. However, this problem should be greatly mitigated if CO2 can be converted to innocuous substances. Especially, the reuse of CO2 as fuels and chemicals is extremely effective not only for the mitigation of the global warming but also against the depletion of the fossil fuel reserves. Several processes for converting CO2 to valuable compounds have been proposed including hydrogenation over heterogeneous catalyst at high temperature and electrochemical and photochemical reduction. In the conversion and cutback processes of CO2, however, it is of importance that the process is feasible under mild conditions, because the secondary generation of CO2 is feared if high energy is required and supplied with a fossil fuel. In this meaning, the electrochemical reduction of CO2 taking place at room temperature, which is similar to photosynthesis, is promising. From the practical point of view, it is further necessary that the conversion rate is high enough and the product is satisfactorily valuable."

Jan 1, 2008

By K. L. Hardee

A recent development has emerged which produces a retrofittable, low cost anode by attaching disposable, electrocatalytically active titanium mesh over the existing lead anodes. The coated titanium mesh anode operates at potentials of several hundred millivolts lower than the lead anode, providing significant power savings. The exposed lead surfaces are stabilized since most of the current flows through the titanium mesh. With the minimal lead corrosion, the sludge formation is virtually eliminated and the purity of the plated copper is greatly enhanced. Further savings may be realized by the elimination of non-essential chemicals such as cobalt. Since the combination anode is stable and uniform, the plated copper is also more uniform with minimal formation of dendrites, reducing the shorting. Full-size anodes have been tested for over 6 months in commercial copper electrowinning cells. The laboratory and field performance of the stabilized lead anode will be reviewed, including the voltage characteristics, the lead stability and the copper cathode purity.

Jan 1, 1999

By Garrett R. Hyde, Aleksandar Stojsic

Introduction Economic pressures in the international marketplace have spurred advances in almost every facet of flotation. New developments have occurred in flotation chemicals, flotation machines, and in the application of automated process control technology to grinding and flotation. Many of these advances are the results of concerted efforts to apply the knowledge obtained from basic flotation research over the past 15 to 20 years, to develop industrial technology for the more efficient separation of sulfide minerals in real ores. Mining company executives and equipment manufacturers are being called on to make decisions for incorporating some of this technology into present operations. This discussion is limited to two developments now at the stage of being engineered into industrial scale operations. They are control of the electrochemical environment or redox potential of the slurry, and control of bubble size in column flotation. Potential economic impacts are noted. Froth flotation Froth flotation makes use of differences in the surface properties of finely ground minerals to obtain separation. If the mineral surface is water repellent, the mineral particle will stick at the air-water interface of a bubble and float. If a mineral surface is not naturally water repellent, a chemical collector is added to the slurry to make it so. The collector must adsorb on, and make water repellent only the mineral to be recovered, not the gangue minerals. To achieve this degree of selective adsorption, chemical modifiers may have to be added to the slurry. Modifiers include pH regulators, activators, and depressants. Electrochemical control One of the most significant developments in recent years in the area of mineral processing technology is the recognition that collector adsorption of sulfide minerals is an electrochemical process. Consequently, flotation of these minerals depends on the electrochemical or redox potential of the system. Many of the modifiers used to control various flotation processes are actually potential controlling reagents. For example, the role of well known depressants, such as cyanide, sodium hydrosulfide, and sulfur dioxide, is essentially to

Jan 7, 1987

By K. Prashant Sarswat

Isotopes are critical to a variety of applications including physical science analyses, biology, medicine, pharmaceuticals, and national security. In most cases isotopes must be relatively pure or highly enriched before they become useful. Current isotope separation technologies are relatively inefficient, capital and labor intensive, and often produced by a limited number of suppliers. In the category of isotopes, lithium is among other important candidates. Lithium is found naturally in two isotopes, 6Li which accounts for 7.5% of all lithium, and 7Li which makes up the balance of 92.5%. Each of these isotopes is important to the nuclear industry. 7Li is often used in the form of lithium hydroxide which is used to control pH in pressurized water reactors. The current supply of 7Li is based mostly outside of the United States, and its long-term supply is uncertain. Apart from supply issues, the use of mercury for 7Li separation is also a concern in commercial processing using the most common and efficient approach [1–3]. Hence, a reliable, environmentally friendly, and efficient technique is needed to produce 7Li. In this line of investigations, the authors used a two-compartment system and significant separation was achieved. In this piece of research, some preliminary results are presented including cell design and actual isotope ratio after enrichment. Applying an electro-potential across two electrodes can be used to drive electromigration of Li isotopes. The electromigration is in addition to normal diffusion. Note that 6Li diffuses faster and hence there will be a lowering of the 6Li concentration near the positively charged electrode and an enhancement in 6Li near the negative electrode during the separation process. Similarly, 7Li will be more prevalent near the positive electrode and less prevalent near the negative electrode during the initial separation stage [1].

By M. Hodgson

The redox reactions that occur on pyrrhotite and pentlandite in contact with oxygenated deionized water were examined using voltammetry. Reactions were put forward in which both minerals were progressively hydroxylated to form thermodynamically metastable surface intermediate products. These intermediates were modelled as metal deficient sulphides where a sulphurous layer was coordinated onto the remaining metal sites via polysulphides. Prior to hydroxylation pentlandite exhibited changes in the surface stoichiometry which were not related to pH effects. The formation of polysuiphide-sulphur intermediates were believed to promote collectorless; flotability for the two minerals. Microflotation tests (0.3 g samples) verified that the surface potential and particle size affected the flotation response, excessive oxidation inhibiting the minerals' flotability. Larger scale tests using ore samples (30 g) confirmed that the extent of pulp oxidation, particle size distribution and the presence of frothers affected the flotation response, the findings being in accordance with the postulated model for the hydrophobic species generated on the pentlandite and pyrrhotite surfaces.

Jan 1, 1985

By I. Iwasaki, P. L. De Bruyn

Electrical double-layer properties of the silver sulfide-solution interface in different electrolytes and the influence the properties exert on the adsorption of dodecylammonium acetate (DAA) were studied using an electrochemical titration technique. The flotation behavior of silver sulfide was observed using DAA as collector and the results were correlated with adsorption measurements. Silver and sulfide ions were identified as the potential determining ions and their adsorption densities were measured as functions of the pAg and of the ionic strength at two different pH values. The point-of-zero-charge (PZC) was observed to be at pAg 10.2, the value being independent of pH and of the nature and concentration of the electrolyte used. The surface charge of silver sulfide in these electrolytes was positive for pAg values less than 10.2 and was negative for pAg values greater than 10.2. The adsorption of amine on silver sulfide surfaces at pH 4.7 was found to be strongly dependent on the pAg. A shift in the PZC towards a lower pAg due to the adsorption of amine indicated a specific affinity of dodecylammonium ion towards silver sulfide surfaces. At pH 9.2 a strong adsorption of the undissociated amine molecule was indicated. The PZC shift towards a higher pAg and the adsorption of the amine was virtually independent of the interfacial electrical conditions.

Jan 1, 1972

By J. J. Pavlica

Grinding in steel mills adversely affects the flotation removal of pyrrhotite from magnetite ores. To elucidate the effect of grinding media on the floatability of pyrrhotite, rest potential and short-circuit current measurements were made on electrode combinations of pyrrhotite-mild steel and pyrrhotite-stainless steel. Galvanic contact of pyrrhotite with mild steel increased the rate of surface reactions on pyrrhotite in air-exposed and oxygenated solutions. It was postulated that the formation of ' an iron hydroxide coating on the pyrrhotite adversely affected its floatability. Its formation was minimal when pyrrhotite was contacted with stainless steel. Fine magnetite particles caused slime coating on pyrrhotite surfaces by magnetic interaction and impaired the flotation of pyrrhotite.

Jan 1, 1982

By J. J. Pavlica, I. Iwasaki

Grinding in steel milk adversely affects the flotation removal of pyrrhotite from magnetite ores. To elucidate the effect of grinding media on the floatability of pyrrhotite, rest potential and galmic current measurements were made on electrode combinations of pyrrhotite-mild steel and pvhotite- stainless steel. Galvanic contact of pyrrhotite with mild steel increased the rate of surface reactions on pyrrhotite in air-exposed and oxygenated solutions. It was postulated that the formation of an iron hydroxide coating on the pyrrhotite adversely affected its floatability. Its formation was minimal when pyrrhotite was contacted with stainless steel. Fine magnetite particles cawed slime coating on pyrrhotite surfaces by magnetic interaction and impaired the flotation of pyrrhotite.

Jan 1, 1983

By W. K. Choi

Using electrochemical techniques it was demonstrated that bioleaching of gold from refractory pyritic ores is a complex phenomenon. Many intermediate electrochemical reactions were found to be involved in the oxidation of pyrite, using cyclic voltammetry and carbon paste-pyrite containing electrode. Furthermore, the oxidation process was controlled by solid-state diffusion as suggested by chronoamperometric and chronopotentiometric measurements. Using the Sand's approach, the activation energy of solid-state diffusion was found to be = 22.4 kJ. After bioleaching, 96% gold was extracted from the leach resi¬due with a thiourea solution in 1 hour. A generalized model for the mechanism of pyrite oxidation has been presented.

Jan 1, 1990

By Natarajan K. A.

During sulphide ore grinding, electrochemical interactions between grinding medium and the minerals play a significant role in bringing out enhanced ball wear on the one hand and alter the surface property of the ground minerals on the other. The role of the flotation reagents added simultaneously during grinding with respect to ball wear as well as flotation is yet to be established. Electrochemical measurements such as rest potential, combination potential and galvanic current between sulphide mineral and ball material couples have been carried out in the presence and absence of flotation reagents to understand the nature of electrochemical interactions between ball material and sulphide mineral. Electrochemical mechanisms and models have been proposed to explain the role played by the flotation reagents during different binary, ternary and quaternary interactions with respect to ball wear during grinding.

Jan 1, 1992

By K. A. Natarajan

This paper deals with the various electro- and biochemical mechanisms involved in the bioleaching of multisulfide minerals such as those containing copper-lead-zinc and copper-nickel-iron. Galvanic series for sulfide minerals consisting of pyrite, chalcopyrite, galena, sphalerite, pentlundite, and pyrrhotite in an acid bacterial leaching system is illustrated, and the role of relative electrochemical activity on selective dissolution is discussed. Typical leaching results are shown to illustrate the practical applicability of galvanic effects in bioleaching of multisulfides. Attachment of Thiobacillus fewooxidans onto chalcopyrite and sphalerite mineral substrates is illustrated through scanning electron micrographs. The role of high-metal-tolerant, specially adapted strains in the leaching of multimetal concentrates is also outlined.

Jan 1, 1987

By G. P. Brahmaprakash, K. A. Natarajan, N. Jyothi, K. N. Sudha

Some important electrochemical aspects involved in the bioleaching of mixed sulfides have been discussed with reference to selective sphalerite dissolution from different binary mineral combinations. Combination potentials and galvanic currents were measured in different binary combinations of sphalerite with other minerals such as galena, chalcopyrite and pyrite in order to under- stand the electrochemical dissolution behaviour of sphalerite when coupled with other minerals. The effect of applied DC potential was also studied with reference to selective sphalerite dissolution from a binary mineral mixture. An application of a potential of -500 mV (vs SCE) was found to enhance bacterial growth as well as selective sphalerite dissolution. Factors influencing bioleaching of sphalerite under a negative applied potential are discussed.

Jan 1, 1989

By Xiangwen Wang

Electrochemical measurements associated with the electrowinning of lead metal from concentrated brine (NaCI) - lead chloride (PbCI,) electrolytes at temperatures in the range 328 to 353°K (55 - 80°C) were conducted. The electrodeposition of lead metal onto a lead rotating-disk electrode may be described by the electrodic reaction: {PbCl 4 2 + 2e- = Pb° + 4Cl-} The deposition-overpotential requirements are low (approximately 41mV per decade of current density - Am+), with a corresponding high exchange current (approximately 0.018 A.cm2). The diffusion coefficient of the electroactive PbC142- species in a 3.5 NaCl electrolyte at 353°K was insensitive to the total PbCI, concentration (0.01 to 0.1M), and its value was found to be (1.21*0.1)~10-5 cm2Is with a temperature-sensitivity coefficient (E,/R) of approximately 1.98x103K-1 (328OK(T<353OK).

Jan 1, 1993

By K. A. Natarajan, M. K. Yelloji Rao

The electrochemistry of sphalerite and chalcopyrite was investigated under both open-circuit and applied potential conditions. Emphasis was placed on the selective dissolution of sphalerite from a mixture of sphalerite-chalcopyrite flotation concentrates as a function of applied potential, acid concentration, pulp density, and time. Morphological studies using a scanning electron microscope (SEM) were also carried out with chemically leached, galvanically leached, and unleached surfaces of sphalerite and chalcopyrite. Selective dissoulution of sphalerite could be achieved if the mixed chalcopyrite-sphalerite concentrate slurry was maintained at a negative applied potential of -0.4V (SCE). Probable mechanisms involved in the selective dissolution of zinc are disscussed.

Jan 1, 1990