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By W A. Ducker, R-H Yoon, M Mao

Froth flotation relies on an attractive force between a particle and a bubble to selectively extract particles from a mixture. The range and magnitude of this attractive force is an area of ongoing investigation. We describe measurements of the effect of dissolved gases on the long-range attractive surface forces between a silica plate and a glass sphere in aqueous octadecyltrimethylammonium chloride (C18TACl) solutions. The measurements follow on the work of Sakamoto et al (2002) who have concluded that long-range interactions occur in air-equilibrated surfactant solutions but not in degassed solutions. In the present work, we have measured attractive forces that have a much larger in magnitude than the expected van der Waals force in solutions that were degassed by the same procedure used by Sakamoto et al (2002). We find that the forces are most attractive at 5 + 10-6 M C18TACl, which is close to the charge compensation point (ccp) of the glass sphere. At this concentration, the attractive force decays exponentially with distance and the decay length is 34 in air-saturated solution, and 38 nm in degassed solutions. In both air-equilibrated and degassed solution, the force is quite sensitive to the concentration of surfactant. The force is also sensitive to the pH. We note that our degassing procedure increases the pH of the solution from about 5.7 to 6.6 (presumably by removal of dissolved CO2). We find that the forces measured in degassed solution can be reproduced by using a solution that was equilibrated in air, then the pH was increased by addition of NaOH. Therefore, we conclude that the main effect of degassing in our experiments is to raise the pH. We show that the range and magnitude of the attractive force decreases in the presence of salt (NaCl). This suggests an electrostatic mechanism for the attraction. Possible mechanisms for the attractive force are examined, including the mechanisms that rely on a patchy coverage of surfactant on the silica surface.

Jan 1, 2005

By C. E. Beecher

IN the course of the experimental and development work of Henry L. Doherty in an endeavor to obtain an increased yield of oil from oil-bearing sands, it was Mr. Doherty's claim and contention that oil in an undisturbed pool was different in character and behavior than, the same oil when raised to the surface of the earth, and that the gas dissolved in the oil caused a marked reduction in its viscosity and surface tension. Prior to 1924 no information to support this contention could be found in the literature or by a discussion of the subject with technical men in Government and private laboratories. So far as could be ascertained no experimental work had been carried on to indicate that Mr. Doherty's claim was either right or wrong. All parties consulted agreed that the viscosity of the oil would be affected by gas dissolved therein to the extent that natural gasoline was present in the gas, but so far as could be determined any additional effect of the natural gas was unknown. Accordingly, it was necessary to devise equipment and carry on experiments which would either prove or disprove Mr. Doherty's contention or claim. Such apparatus was built under Mr. Doherty's direction and experiments were carried on to determine definitely the viscosity and the surface tension of the crude oils which contain dissolved gases under different pressures. The results of the experimental work carried on have proved that the claim and contention of Mr. Doherty were correct in every particular, as will be seen from the discussion of the subject and the data contained in this paper.

Jan 12, 1926

By S. Acar

The results obtained for the selective flocculation or flotation of natural ores do not usually agree with the corresponding properties of the constituent minerals when present alone. This is mainly due to the presence of dissolved mineral species which can interact in many ways with other components in the system and alter their behavior. In this paper, the effect of dissolved species on the flocculation and electrokinetic properties of sulfide minerals is disscussed. Dissolved Fe, Cu and Ni species are found to affect the properties of chalcopyrite, pentlandite, millerite, pyrrhotite and covellite in certain pH range. These effects are interpreted in terms of species adsorption leading to activation or depression of reagents, surface precipitation and complexation of species, etc.

Jan 1, 1985

By S. Acar, P. Somasundaran

The results obtained for the selective flocculation of natural ores do not usually agree with the corresponding properties of the constituent minerals when present alone. This is mainly due to the presence of dissolved mineral species which can interact in many ways with other components in the system and alter their behavior. In this paper, the effect of dissolved species on the flocculation and electrokinetic properties of sulfide minerals is discussed. Dissolved iron, copper, and nickel (Fe, Cu, and Ni) species are found to affect the properties of natural chalcopyrite and pentlandite in certain pH range. These effects are interpreted in terms of species adsorption leading to activation or depression of reagents, surface precipitation, and complexation of species

Jan 1, 1986

By M. Epiney, A. Ghahreman, R. Kim1and

"Pre-oxidation and cyanide leaching behavior of gold in the presence of sulfide minerals were reviewed, focused on the effects of oxygen injection in the gold leaching process. Generally, pre-oxidation and gold leaching kinetics from iron sulfide refractory minerals, such as pyrite, pyrrhotite, marcasite, pentlandite and arsenopyrite, can be enhanced with higher dissolved oxygen (DO) concentration. However, most of copper sulfide minerals dissolved well both in water and cyanide solutions, and copper from the minerals consumed DO and cyanide to oxidize and leach. Only in the presence of chalcopyrite, gold leaching was effectively occurred with increasing DO. However, chalcocite and covellite severely retarded gold leaching. Stibnite, an antimony mineral, formed a passive film on the gold surface under any DO conditions, and it slowed gold leaching. This impeding effect can be alleviated by leaching at low pH or adding lead salt. Using oxygen and lead together can make synergistic effect in oxidation of sulfide minerals and can enhance gold extraction. Depending on the mineralogical characteristics of the ore, the optimum DO and lead concentrations can be optimized. However, lead can cause environmental problems, and so its dosage should be minimized or eliminated by substituting it with oxygen injection.INTRODUCTIONGold ores containing sulfide minerals are becoming more significant as high grade gold oxide deposits are continuously becoming difficult to find. In light of this situation, to produce more gold, recovery methods from refractory gold ore containing various sulfide minerals should be investigated. Generally, sulfide minerals have impeding effects on gold leaching: formation of a passive film on the gold surface, high consumption of chemicalssuch as cyanide and oxygenduring leaching, reduction of gold cyanide by sulfide ions, etc. (Senanayake, 2008). Therefore, sulfides must be properly treated for better gold recovery. Pre-oxidation of sulfide minerals by injecting pure oxygen can decrease the impeding effects in gold leaching. Prior to cyanidation, sulfide minerals can be oxidized to metal hydroxide and sulfate form, which consume negligible cyanide in the following cyanidation circuit (Bodnaras et al., 1993). Moreover, gold cyanidation can be enhanced by increasing concentration of the dissolved oxygen (DO). In general, the optimum concentration ratio of [CN-]/[O2] is calculated as 6, but it goes higher in the real system (Marsden &House, 2006), which means that the reaction is typically controlled by DO concentration."

Jan 1, 2017

By M. Nduna

Surface properties of metal sulphides have a great significance in various areas of engineering and science, such as acid mine drainage, contaminant sorption, and metal separation. In various attempts at producing metal sulphide particles from synthetic solutions, prodigious quantities of nuclei that grow only to colloidal dimensions have been frequently reported. This copious nucleation is promoted by the high levels of supersaturation that characterize most precipitation reactions. Colloidal particle formation in precipi¬tation-based separation processes results in sub-optimal solid-liquid separation, which is alleviated by the production of more highly crystalline particles or agglomerates. The current work approaches this challenge from an electrochemistry perspective, by measuring surface charge potential of precipitant particles during metal sulphide precipitation with respect to the concentration of metal sulphide lattice ions in solution. Electrophoresis was used to measure the metal sulphide particle zeta potential and the settling properties were obtained by performing settleability measurements using an Imhoff settling cone. A suspension of copper sulphide particles was precipitated from synthetic solutions of copper and sulphide ions at equimolar concentrations. Immediately after precipitation the copper sulphide particles had a zeta potential of -50 mV and a settleability of about 7 ml.l-1. With the addition of copper ions the settleability increased by a factor of nearly three times and the zeta potential also increased to a maximum of -40 mV. A decrease in zeta potential to a minimum of -60 mV was observed after the addition of sulphide ions and this was associated with a settleability of 0 ml.l-1.

Jan 1, 2013

By Rina Kim

There are many factors which affect the gold cyanidation mechanism— mineral composition, free cyanide and dissolved oxygen (DO) concentrations, heavy metal additions, etc. This study combines electrochemistry and surface analysis methods to examine the effectiveness of the above factors on gold cyanidation process. Three gold ore samples were used in this study. Sample 1 was a pyrite concentrate, contained mercury and silver. Sample 2 also contained sulfide minerals, including galena. Sample 3 contained pyrite with sphalerite and galena. In the case of samples 1 and 2, the presence of heavy metals enhanced gold cyanidation kinetics, though the addition of higher DO was not effective on improving the kinetics. Sample 3 showed an opposite behavior: the kinetics was not enhanced by galena, because of its relatively small amount, however, the use of higher DO made improvement in the gold leaching kinetics, likely caused by iron species generated by pyrite oxidation.

By J. Marshall Rounsevell

It is probably not too far from the truth to say that the sulfur content of the steel bath at the first turndown of the basic oxygen furnace is influenced by every factor which varies in the operation of a BOF shop. However, the determination from normal shop operating data of the effect of a given factor on turndown sulfur content requires a means for collecting a large quantity of such data and a significant variation of the factor in question in that data. In this paper, operating data from 4000 heats collected on the computer at Inland's No. 4 BOF Shop is utilized to analyze the effect of four operating parameters -- hot metal sulfur content, hot metal manganese content, percent burnt dolomitic lime (dolomite) in the flux charge, and the presence or absence of transfer ladle slag skimming -- on first turndown sulfur content.

Jan 1, 1972

By John C. Nigro

Bench scale and pilot plant research was conducted using dolomites (CaO,MgO) lime as the basic additive in the preparation of self-fluxed pellets from a typical magnetic taconite concentrate (5.57 S_2). The specific objective of this investigation was to ascertain the viability of the magnesia lime pellets in high temperature oxidizing and reducing atmospheres. Pellet basicity and induration temperature were major parameters affecting fired pellet quality; temperatures ranging from 1,200° to 1,250" C appeared to be the most favorable for production of self-fluxed pellets with basesities (B) above 1.0. Comparison of the mechani¬cal and metallurgical properties of regular (acid) and self-fluxed pellets (B 1.55) produced under similar conditions in a modified grate pelletizing machine showed that the self-fluxed pellets were more resistant to abrasion and to high and low temperature reduction disintegration, an important consideration in commercial application. The Plus 3 mesh Linder index increased from 68 percent (regular pellets) to over 90 percent (self-fluxed pellets). The reducibility and swelling indices of the self-fluxed pellets were found to be comparable to the regular pellets.

Jan 1, 1972

By Charles Prasky, Robert K. Zahl, John C. Nigro

Bench scale and pilot plant research was conducted using dolomitic (CaO - MgO) lime as the basic additive in the preparation of self-fluxed pellets from a typical magnetic taconite concentrate (5.5% SiO2). The specific objective of this investigation was to ascertain the viability of the magnesia lime pellets in high temperature oxidizing and reducing atmospheres. Pellet basicity and induration temperature were major parameters affecting fired pellet quality; temperatures ranging from 1200° to 1250°C appeared to be the most favorable for production of self-fluxed pellets with basicities (B) above 1.0. Comparison of the mechanical and metallurgical properties of regular (acid) and self-fluxed pellets (B = 1.55) produced under similar conditions in a modified grate pelletizing machine showed that the selffluxed pellets were more resistant to abrasion and to high and low temperature reduction disintegration, an important consideration in commercial application. The +3 mesh Linder index increased from 68% (regular pellets) to over 90% (self-fluxed pellets). The reducibility and swelling indices of the self-fluxed pellets were found to be comparable to the regular pellets.

Jan 1, 1974

By T. Belem

In-stope backfill will cure under effective stress, which develops due to a combination of mechanical consolidation (free draining material) and ??chemical consolidation?? (self-desiccation mechanism). A good knowledge of all the drainage and consolidation characteristics of cemented paste backfill is crucial for a better design of underground backfilling sequencing. From many of the existing results and studies done by various authors, as well as the availability of some in-stope backfill pressure data measurements during and after filling, it is possible of developing a procedure of backfilling sequencing. Hence, the objective of this study is to provide a guide for underground backfilling sequencing in the view of preventing the development of excess pore pressure that will affect both the stability of the barricades and the strength development of the backfill. This will be possible by considering the interaction between consolidation/drainage rate, filling rate and binder hydration rate.

Aug 1, 2013

By Trois P

A fully instrumented and bench-mounted diamond drilling machine, purpose designed and built, has been used for investigating the effect of aqueous solutions of various chemical compounds when used as drilling fluids. The rocks investigated were andesite, basalt and granite, the chemical compounds were alkylamines, with various hydrocarbon chain lengths, aluminium chloride and dioxane. Rotation speed seems to be one of the major factors affecting the emergence of mechanochemical effects as the results obtained with aluminium chloride clearly indicate. Penetration rate is either unaf- fected or enhanced by the presence of certain compounds, such as aluminium chloride. On the other hand, penetration rate diminishes when the drilling fluid contains dioxane and exhibits an apparently unpredictable behaviour with alkylamine solutions, although it appears that an increase in hydrocarbon chain length usually equates to an increase in penetration 1. Full Professor, Mining and Mineral Dressing Department University of Cagliari - Italy 2. Associate Professor, Mining and Mineral Ikea- sing Department University of Cagliari û Italy rate. Rock texture seems to have a pronounced effect on test repeatability. With hexadecy- lamine acetate solutions in concentrations ranging from 10-5 to 5 .10-4 molò dm 3 and 41.88 radòs-1 rotation speed, 46 % increments in penetration rate of andesite were observed, with respect to water, whereas penetration rate decreased in basalt by as much as 60¦%o when a dioxane solution was used as drilling fluid. An interpretation of the observed effects is proposed in the light of current knowledge of solid state physics and physical Chemistry.

Jan 1, 1992

By L. J. Leach

Quench and tempered Cr-Mo plate steel was found not to contain a fully martensitic structure as a result of either slow slack quenching or insufficient hardenability at the cooling rates used. The resulting microstructure contains bainite in combination with martensite. It is necessary to examine the implications of bainite for the toughness of the final product. Loss of toughness arises primarily from the inter-lath carbides that typically form in upper bainite. An investigation into the effect of upper bainite in a martensitic matrix of a steel grade containing 0.17% C, 0.1% Cr, 0.54% Mo, and 20 ppm Bindicated lower toughness than in a fully martensitic structure.

Jan 1, 2013

By K Le Bron

Fatalities that occurred because of rock falls in off-reef excavations (excluding shafts) over the last three years range between ten per cent and 20 per cent of the total number of fatalities that have occurred due to rock falls in the South African mining industry. These rock falls, mostly exacerbated by blasting practices, occur because of failure on discontinuities within the rock mass. Among other reasons of their occurrence is insufficient support installation or the incorrect assessment of rock mass conditions. This report presents qualitative analysis intended to outline rock stability conditions in tunnels subjected to dynamic loading. Seismic waves including those created by firing an explosive charge in tunnel rocks are considered. The rock behaviour is monitored using geophones and extensometers variably installed to record the near and far effects of roof bolt support units on a dynamically loaded rock. The paper discusses the results of field investigations.

Jan 1, 1999

By R Ibarra, H Solis, G Teowee, B E. Papillon

The authors have previously described a piezoelectric-based system to measure the dynamic pressure during actual detonation in the field. This technique is used in a water hammer test set-up where a donor detonator is fired first, with the pressure sensor and an acceptor electronic detonator placed underwater in a water tank, and maintained at a fixed distance away from the donor detonator. The functioning and timing of the acceptor detonator are captured using a customised microcontroller board called the water hammer timer. Using such water hammer testing, the effect of dynamic pressure was studied as a function of the magnitude of pressure during the electronic timing countdown. Data obtained indicate there is no significant impact in the timing of the electronic detonators in contrast to what has been reported in non-electric detonators.CITATION:Teowee, G, Solis, H, Papillon, B E and Ibarra, R, 2015. Effect of dynamic pressure on electronic detonator timing, in Proceedings 11th International Symposium on Rock Fragmentation by Blasting, pp 575–578 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 24, 2015

By H. Doostmohammadi

During the tapping of liquid steel from Electric Arc Furnace (EAF), some slag is carried over into the ladle. High levels of FeO and MnO in slag carryover increase the oxygen activity in steel melt leading to oxide inclusion formation during the ladle treatment. The demand on cleaner steels requires minimization of carryover slag. In this work, the effect of EAF slag carryover on ladle slag-steel equilibrium calculations for a hot working tool steel was studied. Steel and slag sampling were done in Uddeholm Tooling AB in Sweden. XRF and OES techniques were used to determine chemical composition of samples. The quantity of slag carryover was calculated based on a mass balance followed by thermodynamic calculations on metal-slag equilibrium using Thermo-Calc software. The agreement between predictions and experimentally determined compositions was good. This leads to the development of a prediction method for optimizing the production of other tool steel grades.

Jan 1, 2009

By Julian Johnson

The effect of changing redox potential (Eh) on the high temperature sulfuric acid leaching of Western Australian dry-land nickel laterite ores has been investigated. In particular, the effect of added reductant (sulfur, sodium sulfite) or oxidant (potassium chromate) on Eh, leaching kinetics, metal extractions, acid utilisation and leach residues has been determined. Three separate ores - nonhonitic ores from Murrin Mumn and Bulong, and limonitic ore from Cawse - were used in the study. Sulfur addition varied from 0 to 7.8 kg/t ore. The total acid loading was kept constant at 430 kg/t (Murrin Murrin ore) and 330 kglt (Cawse ore), whilst acid loading for Bulong ore was varied according to the presence of either reductant or oxidant. The extraction of both nickel and cobalt from limonite ore remained unaffected when small amounts of sulfkr were added, but addition of even small amounts of reductant to nontronitic ore decreased both nickel and cobalt extraction. Increased manganese and iron dissolution were observed as the levels of reductant increased, accompanied by a decrease in chromium dissolution. As the iron dissolution increased, free acidity decreased, with a subsequent decrease in nickel extraction. In contrast, addition of oxidant lead to reduced iron and manganese dissolution and slower extraction of nickel and cobalt. Keywords: Limonite, Nonhonite, Eh, Nickel Extraction

Jan 1, 2004

By L. G. Wang

The stability of foams and froth plays an important role in flotation, in which small amounts of relatively weak non-ionic surfactants (frothers) are used to produce air bubbles and foams. In the present work, factors affecting the stability of the foams produced in the presence of common frothers, such as n-pentanol, n-octanol, methyl isobutyl carbinol (MIBC), and polypropylene glycol (PPG), have been studied. We used the thin film pressure balance (TFPB) technique of Schelud-ko-Exerowa type to measure the equilibrium film thicknesses. The results were used to determine the contributions from the various surface forces to the disjoining pressures in the thin lamellae (foam) films formed between air bubbles. In addition, we used a model developed by Wang and Yoon (Colloids and Surfaces A: Physicochem. Eng. Aspects, 2006) to calculate the elasticities of the lamellae films at the critical thicknesses at which films rupture. The surface forces and elasticity da-ta were then compared with the foam stabilities in the presence of the various flotation frothers. It was found that foam stabilities are controlled by both film elasticity and surface forces, the relative contributions of which change with frother type and concentration. In general, surface forces play a more important role at relatively low frother concentrations, while elasticity plays a more important role at higher concentrations. At the frother additions usually employed in the mining industry, MIBC relies on surface forces while PPG-400 relies on film elasticity in producing stable foams. The former is capable of dampening the hydrophobic force, which is a major attractive force destabilizing lamellae films, while the latter is capable of reducing surface tensions at low concentrations.

Jan 1, 2014

By Andrzej Warczok

Liquid slags produced in smelting of copper concentrates contain copper in a dissolved form as well as mechanically entrained inclusions of copper matte. Coalescence and sedimentation of inclusions during slag cleaning plays a key role in copper recovery. Liquid matte inclusion in a molten slag presents a system of metallic conductor in an ionic solution. Constant electric field induces migration of the matte droplet along the current lines. Additional phenomena occur in a system under crossed electric and magnetic fields. Electromagnetic buoyancy force acting on the inclusion affects its settling rate. Electromagnetic buoyancy force of insulating and metal spheres has been measured in a liquid synthetic slag. It was found that depolarisation of the metal sphere, related to the electrode reactions occurring in the surface, plays an important role in the determination of the direction and magnitude of the electromagnetic force. On the basis of the existing theories and results of measurements a mathematical model describing the behaviour of metallic inclusions in the liquid slag under the influence of crossed electric and magnetic fields was developed. Simulation of behaviour of copper matte inclusions under crossed fields showed trajectory of motion in a liquid slag as a function of the slag properties and the inclusion size.

Jan 1, 2003

By C. Peña, C. A. Zaror, M. Bustamante, M. Vega

The goal of this paper is to present the carbon footprint of Chilean cathodic copper, as a function of the electricity generation mix, ore grade, and process efficiency. Ore grades and acid leach-solvent extraction-electrowinning (LX-SX-EW) yields in the range 0.5-1.0% and 60-80%, respectively, were considered here. Additionally, electricity supply from two Chilean suppliers, SING (1.0 ton CO2/MWh) and SIC (0.4 ton CO2/MWh) was assessed. Simulation results show that oxide plants located in northern Chile, served by the SING network, feature carbon footprint within 4.3 - 11.4 MWh I ton cathodic copper, as compared with 3.5 - 9.3 MWh I ton copper in plants served by SIC. The footprint was found to increase as ore wade and process yields decrease.

Jan 1, 2011