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By Fathi Habashi

CRYSTALLIZATION from aqueous solution is a simple and old method for the recovery of metal values from leach solution. Practically all the methods for the recovery of aluminum from clay are based on the crystallization of an aluminum salt from the leach solution. Differences in solubilities may be used to advantage for separating two metals from the same leach solution. The classical method of Marignac (1866), which makes use of the difference in solubilities of K2TaF7 and K2NbOF5 to separate niobium from tantalum, has been used successfully in the manufacture of these metals (Fig. 10-1). The slurry containing the metal oxides is dissolved in 70 % hydrofluoric acid, diluted, and heated near boiling. A potassium salt is added in sufficient quantity to form the complex fluorides of the niobium and tantalum present. The solution is filtered and allowed to cool. At room temperature most of the tantalum salt crystallizes out while the niobium remains in solution.

Jan 1, 1970

By Luben Xie, Lin Hu, Qiang Wang, Min Gan, Tao Jiang, Wenqi Li, Xiaohui Fan, Zhiyuan Yu

"Crystal precipitation behavior of calcium ferrite (CF) during iron ore sintering process along with the effect of cooling rate, SiO2 and Al2O3 on crystalline condensation were studied. The results show that CF, has strong ability of precipitation. The precipitation is barely affected by extenal factors. It begins to precipitate when the liquid phase cools down to about 1200oC. CF could crystallize rapidly at the cooling speed of 150 °C /min. Furthermore, decreasing of the cooling rate favors the development of crystal. Binder phase transformed from CF system to silicate system when SiO2 content was increased to 5~6%, with a constant basicity (R) 2.0. Increasing Al2O3 content could promote the precipitation of CF and the development of crystal.IntroductionCrystalline condensation is the last stage of sinter mineralization. It includes the processes that crystalline substance and amorphous substance precipitate from high temperature solution phase and the consolidation of material when melt cools down. During the crystallization process, minerals precipitate following the order from high to low melting point coupled with the decreases of free energy. Most of binder phase minerals and part of iron oxides crystallize in this process, which have an important influence on mineral composition and microstructure of sinter. They finally determine the sinter strength and metallurgical properties."

Jan 1, 2011

By Hu Meilong, Liu Lu, Bai Chenguang

Extracting perovskite from high titanium-bearing blast furnace (BF) slag is a green and potential method to recover the second titanium resource. The non-isothermal crystallization process of perovskite in synthesized high titanium-bearing slag was studied in situ by confocal scanning laser microscope (CSLM) with cooling rate of 20 K/min. The results showed that perovskite was the primary phase formed during cooling process in the titanium-bearing synthesized slag (TiO2=23%). Perovskite started to precipitate at 1719 K and finally presented an orthogonal straight lines morphology.

Jan 1, 2014

By Takashi Nakamura, Atsushi Iizuka, Yong Fan, Etsuro Shibata

The level of iron in typical copper slag reaches nearly 40% by mass, in the form of iron silicate. We designed a method to oxidize the nonmagnetic iron silicate to magnetite, permitting the selective recovery of the slag’s iron content by magnetic separation. This would effectively decrease the volume of dumped slag; the reclaimed iron could be used for iron and steel making. The crystallization behaviors of magnetite and hematite were studied as reaction products of the molten oxidation of copper slag. A gas atmosphere of 1% by volume of oxygen was found to effectively precipitate the slag’s iron content as magnetite.

Jan 1, 2015

By Edward Peters

Scandium (Sc) has unique properties and is one of the more valuable elements in the periodic table. Scandium can be used in solid oxide fuel cells and to produce high strength aluminium alloys of value, for example, in the aerospace industry. Scandium is often grouped together with the rare earth elements (REE). Amongst others, scandium can be found in bauxite residues, so called red mud. It is possible to extract and enrich scandium from red mud by leaching and solvent extraction. Scandium can then be recovered from the pregnant strip liquor by crystallization. The strip liquor will however still contain certain impurity elements. In the present work, a method for obtaining a pure scandium solid phase by direct crystallization from the strip liquor is evaluated. It was found that Fe and Ti co-precipitate with Sc under the conditions employed.

By L. Becze, B. Pierre, S. Di Carlo, G. P. Demopoulos

From January to June 2007, the autoclave production at the Kidd Metallurgical Site was severely affected as a result of plugged discharge lines and extensive precipitation/crystallization of sulphates that caused massive scaling in different autoclave compartments. Work was performed at McGill University to understand the root causes. The crystallization of zinc and ferrous sulphate salts was investigated in terms of solubility measurements. Scale samples were characterized using chemical and mineralogical-spectroscopic analysis. In this paper, following a description of the Kidd zinc pressure leach operation, highlights from this investigation are presented and solutions used to overcome the problem are outlined.

Jan 1, 2008

By S. S. B Wang

Zirconia-based ceramic materials have potential applications in high temperature furnace insulation, hot extrusion and casting dies, pressure nozzles, cutting tools, engine parts and electronic materials. High purity and superfine powders of zirconium oxide (baddelyte) were synthesized from a solution containing zirconium oxychloride and urea under hydrothermal conditions. crystallization of the metastable tetragonal zirconia using magnesium oxide or yttrium oxide as stabilizing agents was successfully achieved. The mechanism of hydrothermal reaction to produce these powders are discussed.

Jan 1, 1989

By Lynton S. Land

Representative collections of recent dolomites, and of samples concentrated by leaching-out of coexisting magnesian calcites, provide grounds for appraisal of the compositions and cation ordering in recent dolomitized sediments. Unit cell volumes for near-stoichiometric compositions exceed those of ordered dolomite and increase as the departures from regular cation order became more pronounced. Infrared absorption maxima of disordered examples occur at perceptibly lower frequencies. Stable isotope ratios indicate that best ordered examples formed in highly saline environments. Present observations are qualitatively reconciled with data from synthetic products described by other authors.

Jan 1, 1972

By Alden B. Greninger

THE study of mosaic structure of crystals1 has been confined until recently to the field of theoretical physics Crystallographers, in general, have neglected the subject, although X-ray crystallographers constantly make use of formulas for intensities of X-ray reflection as modified by mosaic structure Work on mosaic structure has centered chiefly on the task of proving or disproving the secondary-structure theory of Zwicky,2 and very little attention has been paid to the visible imperfections of crystals A Goetz has been responsible for most of the supposed experimental confirmations of Zwicky's theory 3 On the other hand, Smekal,4 and Orowan,5 among others, maintain that these is neither theoretical nor experimental evidence to substantiate Zwicky's secondary structure

Jan 1, 1935

By Alden Greninger

METALLURGISTS have long believed that martensite in steel forms as plates along the octahedral {111} planes of austenite. Much has been written about mechanisms whereby units of the austenite lattice are pictured as transforming to martensite by shearing movements initiated along the octahedral planes of austenite, supposedly resulting in plates of martensite lying parallel to these planes of shear. A critical inspection of two or three photomicrographs of quenched hypereutectoid steel led us to the conclusion that the orientation habit of martensite, at least in hypereutectoid austenite, could not possibly be octahedral. Inasmuch as recent studies30,31 of the martensite-type reaction in nonferrous alloy systems have established the irrational orientation habit as characteristic of this type of lattice transformation, the need for a thorough restudy of the crystallography of martensite formation in steel was evident. The present paper reports the results of such a study, extended to include both cementite and some of the products of constant-temperature decomposition of austenite. Also reported are a few of the results obtained from a microscopic and X-ray study of the austempering process in very high-carbon steel.

Jan 1, 1940

Controlled Source Audio Magnetotelluric (CSAMT) surveys were carried out by Glass Earth (New Zealand) Limited (Glass Earth) in 2006 - 2007 to investigate epithermal gold targets in the central North Island of New Zealand. The surveys were conducted using a Zonge GDP 32 8-channels receiver and a Zonge XMT 32 transmitter powered by a 16 KW generator. The electric field dipole was maintained at 20 m length (five dipoles per 100 m spread) and the frequency ranged from 4 KHz to 4 Hz. Only scalar (TM mode) signals were recorded, using one magnetic coil per spread. The transmitter bipoles were 1 - 4 km in length and located about 5 to 10 km from each survey area.   Sixteen individual target areas were surveyed by June 2007. The CSAMT survey lines (100 - 400 m spacing) were determined mainly on results from previous ultra-detailed airborne magnetic and gravity surveys conducted by Glass Earth in 2005. The data from each CSAMT line was carefully examined to remove any spurious signals and processed using Zonge SCS2D software, which can produce smooth 2D resistivity inversions of the field data. The results were presented as resistivity sections and maps to help the identification of exploratory drilling targets, mainly from the existence of subsurface high resistivity zones (resistors) that can be interpreted as caused by silicification associated with epithermal mineralization.   An example of processing and interpretation of the CSAMT data is presented in this paper on results from Glass EarthÆs Tahunaatara target, where CSAMT surveys have identified zones of epithermal mineralization confirmed by exploratory drilling.

Jan 1, 2007

By James Ludwiczak

This paper consists of the conduct of a forensic criminal investigation of the components, construction, use, and functioning of two suicide bombs. As the title states, the task was to form professional opinions as to whether the bombs would work, would cause property damage, and would injure or kill. The bombs were created and installed by a defendant in a Federal death penalty case where the defendant’s daughter was killed in a shootout with the West Virginia State Police. The two black powder bombs were placed under the front seats of the defendant’s automobile and were designed to function by the use of a toggle switch connected to the automobile’s cigarette lighter. The forensic work first consisted of an inspection of the remains of the wiring system and bombs at the Bureau of Alcohol, Tobacco, and Firearms Laboratory, in Ammendale, MD. This was necessary to determine and detail the wire diameter and lengths, the lengths and size of the wire used, the type of toggle switch used, the type of containers, the type of rocket motors used to initiate the black powder, the manufacturer and amount of black powder used in each bomb, and the type, wraps, and amount of duct tape used for the construction of each bomb. Using this data, tests were conducted by duplicating the wiring system and the two bombs to insure that the system functioned properly. Each bomb was duplicated and initiated to observe the violence produced when initiated in the open air. Duplicate bombs were placed under the seats of a similar type of automobile and initiated. The purposes of the tests were to duplicate the bombs, to observe the violence of the initiation, and to observe the damages to the automobile produced by the initiation.

Jan 1, 2007

By L Alem

In the field of mineral extraction, complex technologies are being introduced in mines, operators/technicians rely on assistance from an expert (or more) in order to keep their machines functioning. Personnel with such expertise, however, are not always physically on-site. There is a growing need for innovative technological solutions to support effective delivery, just in time, of remote guidance between an offsite expert and an on-site maintenance operator. To meet this need, we have, as part of our Human System Integration project within the CSIRO’s Minerals Down Under (MDU), Transforming the Future Mine theme, explored the usefulness of a number of emerging technologies including: augmented reality, wearable systems and touch table interfaces. This paper presents ReMoTe, an augmented realty system for remote guiding using a touch table interface for the expert station and a combination of augmented reality and a wearable system at the operator end. In designing this system we were interested in exploring the extent to which it can increase the productivity and safety of maintenance personnel. This paper also presents Mobile ReMote, our recent development of a fully mobile remote guiding system. In Mobile ReMote, both the expert and the operator are using a near eye display and wearing a light computer in a back pack. The expert is able to guide the operator using his/her hands on the virtual display, while the operator is able to see the instructions on the rear eye display. Workers in the mining industry are highly mobile, a mobile expert and operator station will meet this need.

Nov 22, 2011

Australia's iron ore industry is entering a challenging period with the development of new orebodies, the introduction of new products and the push for further downstream processing. In addition, the recent price reductions for iron ore exports have intensified the focus on reducing capital and operating costs. To assist in these areas, CSIRO is expanding its research capabilities, including the incorporation into CSIRO of the Mineral Processing Laboratories in Perth, which were previously managed by the WA Department of Minerals and Energy. In addition, a large part of the $24.4 million expansion of CSIRO's Pinjarra Hills laboratories in Brisbane will be devoted to enhancing iron ore processing research, providing purpose built laboratories and large process bays.

Jan 1, 1999

By E. Stoetzer

In all known deep mixing processes the existing soil is mixed with self hardening slurry by mixing tools that rotate about a vertical axis (augers, mixing paddles). Wall panels are constructed using sets of multiple mixing tools combined into a single unit. These techniques have been developed on the principle of the rotary drilling technology. In contrast, the new Cutter Soil Mixing or CSM technique is derived from the cutter technology. The soil is loosened and broken down by cutter wheels, then mixed in-situ by the rotating cutter wheels with the self-hardening slurry - introduced into the ground between the two wheels - to form a soil-slurry mortar. The main area of application lies in the construction of cut-off and retaining walls.

Jan 1, 2006

By Levent Ozdemir, Robert J. Evans, Russell J. Miller, William Sharp

This paper describes the specifications and capabilities of a 6 ft (1.83 m) diameter laboratory rotary cutting machine which was designed and fabricated under a Bureau of Mines (USBM) contract awarded to the Colorado School of Mines (CSM). The machine will be used for carrying out research and development programs aimed toward improving the design and operation of mechanical tunnel, raise and shaft boring equipment.

Jan 1, 1983

By Fabrice Mathieu

The Cutter Soil Mixing (CSM) provides a cost effective solution for the rapid construction of retaining and cut-off walls using new equipment developed from diaphragm wall cutter technology. CSM consists of cutting and mixing drums mounted on compact hydraulic motors. Soletanche Bachy CSM has been designed to leave the space above the tool free, thereby mixing the soil efficiently during all the phases of the wall construction, with high penetration rates. The precise positioning and verticality of the wall is achieved using a kelly bar and full monitoring. Soletanche Bachy CSM is a versatile equipment which can be mounted on various carriers: pile rigs, hydraulic crane, carrier equipped with telescopic mast. The major phases of Soletanche Bachy CSM development are presented, including the results of an extensive trial carried out in Le Havre (France). The soil consists of hydraulic fill with soft soil lenses overlying sandy deposits. 20m deep panels were constructed to support a rectangular shaft. During the construction, and after its completion, the shaft was subjected to an extensive series of tests followed by a partial excavation. The paper discusses also the future development of the technique and its potential applications.

Jan 1, 2006

By Wern-ping Chen

To mitigate and control the combined sewer over-flows from 17 outfalls in Detroit, MI, three outfalls in Dearborn Heights, MI and eight outfalls in Redford Township MI, the Detroit Water and Sewerage Department (DWSD) completed the preliminary design of a storage tunnel in 2005. In 2006, a final design revised the alignments and the inside diameter (ID) of the tunnel. The revised tunnel system includes an 11.28-km (7-mile) 9.14-m (30-ft) ID tunnel, a 24.4-m (80-ft) ID pump station, two work shafts about 15.2-m (50-ft) ID each and 14 drop shafts with various IDs. A small portion of combined sanitary and storm sewers serve the majority of the Rouge Valley water-shed. This includes Detroit, MI and most of the western suburbs. The Northwest Interceptor (NWI), that extends between Eight Mile Road and Ford Road and roughly parallel to the Rouge River, intercepts sanitary sewage and some wet weather flows from trunk sewers in the tributary areas for transport to the wastewater treatment plant (WWTP) for treatment. During extreme storm events, when the capacity of the NWI is exceeded, the excess combined sewer and overflow (CSO) over-flows into the Rouge River through 17 outfalls to local rivers. The purpose of the Upper Rouge Tunnel system (URT) is to capture and significantly reduce the uncontrolled CSO from these 17 outfalls in Detroit, three outfalls in Dearborn Heights and eight outfalls in Redford Township. When implemented, the

Jan 1, 2007

By Miguel Araújo Vasconcelos Filho, Ulisses Tetti

In order to determine the influence of the number of increments of the sinter sample on the variability of the chemical composition obtained in Sinter Plant production, a variographic study was carried out. It was performed with two series of samples. The first series was composed of 40 samples with a 6-second interval, with the objective of obtaining the so-called minimum practical error, resulting from the extraction processes of the sample of the conveyor belt and preparation and analysis in the laboratory and the second series composed of 60 samples with a range of 4 minutes, which points to the sample selection error. The results obtained showed that the minimization of the sample selection error occurs for increments spaced in 15 minutes, being in agreement with ISO 3082, but with significantly better results than those currently practiced for intervals between 1hour increments. It was then decided on the suitability of the sampler to allow hourly increments to be collected and on a second opportunity to install a sampling tower with primary and secondary samplers to collect increments every 15 minutes including sample size reduction.

Oct 1, 2019

By Luis Acainas Caballero, Karl Hoen, Stephan Krämer, Christoph Klein

The situation of the steel industry is still challenging. Worldwide overcapacities have an impact on profitability. More than ever, the point at SMS group is to provide the steel industry with flexible and profitable technologies and systems over the whole process chain. One example for that is the thin slab casting and rolling technology and, in particular the CSP® technology (Compact Strip Production), being well established for hot coil production. From its introduction in 1989, CSP® technology has been continuously further developed. Today, on a CSP® plant, the full range of high-quality steel grades can be produced with tightest geometrical and metallurgical tolerances under optimal economic conditions. With the introduction of semi-endless rolling and, as a further step, the endless rolling process, the product range for thin and ultra-thin products has been further enlarged, allowing for the production of hot rolled coils with a thickness of 0.8 mm for low carbon steel grades. Also high-strength steel grades may be produced with gauges below the minimum product thickness that can be achieved in a conventional-type hot rolling mill. Another step in the further development of CSP® technology is digitalization. In December 2016, the CSP® plant of Big River Steel (BRS), located in Arkansas, USA was put into operation. It is the first learning steel mill in the world. The CSP® plant of BRS comes with innovative technologies, providing impressive operational results right from the beginning.

Oct 1, 2019