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By Miroslav Cervenka

The Coal, characterized by coal quality parameters as for example, ash content (Ad), moisture (Wrt), heat content (Qr1), sulphur content (Sd) and other parameters is still in many countries the basic source of energy. Energy is life, especially in modern society, where the demand for ecologically clean energy is very high; and therefore, there is great importance in effective coal utilization Direct utilization - burning of coal for energy generation, is still one of the most effective methods. In most cases, it is one of the cheapest energy transformation methods in spite of the fact that this energy transformation is connected with the deterioration of our surroundings. Deterioration can be substantially reduced if the burning of coal at power stations, heat power stations and other coal consumers is optimized. That means the burning is done in steam boilers, the technical state of which is very good; the coal has minimimum .variations with respect to the projected values; and the burning process is controlled and checked not only from a regulation point-of-view but also from an ecological point-of-view. The instrumentation capable of measuring the characteristic coal quality parameters in real time exists and it forms the basic assumption for the work our research team has made. The proper application of this instrumentation is able to provide information for burning process optimalization. It is the main topic of this paper, which is the compilation of the information on our work -made during the last five years. The whole information is based on practical experience and applied systems in Czechoslovakia in the mines and power engineering industry. See [Cervenka, 1989]

Jan 1, 1992

By E. V. Zelinskaya, A. E. Burdonov

"In the raw aluminum production processon electrolyzers with self-baking anodes, during technological operations, flow-regulated treatment and adjustment of the electrolyte chemical composition produced by diesel and floor-rail technology, alumina and fluoride salts are spilled through the ventilation grilles of the electrolysis body aeration channels, leakage in the equipment, machinery and motorized machinery construction elements. As a result of this, a part of the bus station and the level of ± 0 (the basement room with supporting curbstones and columns, on which electrolyzers are installed) are covered with technological raw material. This leads to an increase in the conductor (bus) resistance, contact connections deterioration, cell insulation failure and raw materials loss. For example, at the enterprise ""Rusal-Bratsk"", as a result of the activity, up to 420 tons per month of alumina-containing wastes that are unfit for use in the electrolysis process are formed due to the alumina substantial contamination with salts of iron and silicon, which significantly reduces the technical and economic parameters of the electrolysis process. The main scientific problem is the processing (cleaning) of alumina-containing waste having a complex mineralogical composition of the material, its contrast and structure, from oxides of iron and silicon, using ""dry"" separation methods. In the performing the work process, qualitative indicators of the influence of external factors (air humidity, precipitation, sunlight, temperature difference) on the physicochemical processes components interaction during the raw materials storage are established. On the basis of laboratory tests, it is established that alumina-containing raw materials can be separated and photometric and gravitational separation methods used. A mathematical model of the motion of particles of primary and prepared alumina-containing raw materials in a cascade-gravity classifier was developed. The criteria and factors characterizing the alumina-containing material, as well as influencing and determining the maximum material enrichment, are established."

Jan 1, 2018

By F. Sekula

Tetrahedrite and siderite are two main valuable minerals present in the silver Mária Bana deposit. The tetrahedrite concentrate prepared from it by flotation has certain specific properties from the metallurgical point of view. Siderite is concentrated in the flotation tailings. The paper presents results of the laboratory and pilot-plant testing of the combined hydrometallurgical and pyrometallurgical methods proposed for treatment of the tetrahedrite concentrate and siderite waste. The testing conditions were based on thermodynamic analysis of the reactions that proceed in the process. The proposed technology makes it possible to separate copper from sulphur, mercury and iron in a straightforward way. Copper, after its refining, can be subsequently treated in the finishing operations. At the same time it is a valuable source of precious and noble metals. The siderite-containing flotation tailings can be converted to iron of the technical purity and slag. The proposed method is a good starting point for the development of the closed-cycle technology.

Jan 1, 2006

By V. A. Chanturiya

In Pt- and Au-keeping complex ores processing, about 10% ~ 15% of noble metals are lost with true tailings that are due to low floatability of Pt- and Au-keeping minerals by the conventional collectors. With the aim to achieve the effective recovery of noble metals at flotation of Pt-Cu-Ni and Au-keeping ores organic complex reagents keeping electron-donating atoms of nitrogen, oxygen, sulfur or phosphorus may be offered as selective collectors for the indicated minerals. These rea-gents tend to form complex compounds with PGM. Besides this, Cu-Ni-Pt and complex Pt and Au carbonated mica ores are characterized by finely disseminated (up to nanometer size) mineral forms of Pt in multivalent states. In this connection, the use of a combination of the strong ionic collectors with nonionic reactants that are capable to derivate complex compounds with multivalent PGM seems to be expedient for this type of ores. In the research new complex reactants were tested such as cyclic alkylene-trithiocarbonates, oxyalkyl butylxanthogen acid ethers, a combination of the collectors ? mercaptobenzothiazole (MBT) and dialkyldithiophosphates (DTP). Sorption and flotation tests were made with monomine-ralic samples of chalcopyrite, pentlandite, pyrrhotite, pyrite, and Pt-Cu-Ni sulfide ore samples. Sorption properties were examined by the extractive UV spectrophotometric method and potentiometric measurements. To indicate a structure of modified xanthate solutions the method of a thin-layer chromatography (TLC) was applied. The chromatographic behavior of the basic components of modified xanthate solution ? ButX, cyclic propylene-trithiocarbonate (PTTC), diethyl-dithiocarbamate (DEDC) and the product of its modification ? oxypropyl-S-ether of dithiocarbamatic acid was studied on plates ?Silufol UV ? 254?. The composition of organic solvents and its ratio in a mobile phase was deter-mined for simultaneous chromatography of the main components of a reaction mixture. It was found that operating selectivity of MBT, DTP and cyclic alkylene-trithiocarbonates incorporated in modified xanthate in relation to Pt-Cu-Ni and Au-containing sulfide minerals might be explained by an electoral sorption of this nonionic collector on a surface of the minerals studied. It was demonstrated that the application new reagent modes with the use of a combination of designed complex reactants helped to increase the extraction index of Pt- and Au-keeping minerals from complicated ores.

Jan 1, 2014

By R. J. Lipp, I. Iwasaki, R. H. Heerema

The presence of calcium ion in iron ore pulps that are upgraded by selective desliming can result in indiscriminate flocculation of both iron oxide and siliceous gangue slimes. In order to overcome this adverse effect, deflocculation by three complexing agents, namely ethylenediaminetetzaacetate (EDTA), sodium tripolyphosphate (STPP), and sodium hexametaphosphate (SHMP), was investigated. The precipitates and complexes of these agents with calcium ion were characterized by potentiometric and conductometric titrations, and the surface properties of quartz and goethite were studied in the presence of calcium ion and of the complexing agents by means of streaming potential measurements and flotation tests. The results were then correlated with selective flocculation tests on an artificial mixture of quartz and goethite. EDTA markedly improved the selectivity of flocculation when added in near stoichiometric amounts, whereas STPP was less effective and SHMP was totally ineffective due to strong, indiscriminate dispersion. Remanent calcium polyphosphates on the goethite surface interfered with the adsorption of starch flocculant.

Jan 1, 1983

By Charles D. Litton

This Bureau of Mines paper describes a novel fire detector that can be used to discriminate between smoke produced by a fire and smoke produced by a diesel engine. The detector uses a pyrolysis technique whereby a sample of smoke- laden gas passes through a short, heated tube within which fire smoke particles pyrolyze and increase their number concentration and decrease their average size, while diesel smoke particles are unaffected. The detector is designed for use in mines that use diesel-powered equipment where the detection of fires is complicated because of the diesel emissions background levels of smoke and other products of combustion.

Jan 1, 1989

By S. J. Zagula

Improved desulfurization of Illinois coals is a widely Shared research goal. The development of a physical cleaning strategy and the results of a project to demonstrate technical and economic feasibility of producing a low sulfur compliance coal from the Illinois Basin are reported. Processing flowsheets to extend or retrofit existing preparation plants are considered. Comminution, conventional and micro-bubble flotation, and selective agglomeration technologies were investigated to maximize pyrite rejection while maintaining high product yield. Batch bench scale testing was followed by continuous pilot plant studies. Parameters included grind size, flow rates, pulp density, aeration, agitation, and reagent dose. An economic evaluation of targeted processes is included.

Jan 1, 1987

By Gary E. Slagel

The federal Office of Surface Mining (OSW) has undertaken an effort to revise many of their permanent program regulations. Numerous procedures for compliance are being rewritten to allow for greater flexibility while meeting the requirements of the Surface Mining Control and Reclamation Act. This study investigates, for certain select provisions, the cost differential between complying with the original OSM standards and the more flexible, state-specific standards being allowed in many of the revised regulations. Estimated cost savings that could be realized under a few of the revised regulations are substantial and should provide a basis for seeking revisions to the state regulatory programs.

Jan 1, 1982

By J. Glazewski

The mining industry in South Africa has developed its own environmental guidelines in the form of an Aide-Mémoire1,which is an extension of the previous rehabilitation provisions to include all aspects of the environment and all phases of a mining operation. This development, at the time, recognized an international trend towards the formalization of environmental management in mining practice, which resulted from the realization of the large environmental liabilities that mines could face, particularly on closure. Over the past decade the international environmental focus in the mining industry has moved from operational management, to the reduction of liability on mine closure. Mine closure guidelines are being developed internationally by nations (for example, SRK, 19982) and by large mining groups (for example, Rio Tinto, 19983). In South Africa the Department of Minerals and Energy (DME) is presently reviewing the Aide-Mémoire to bring it in line with international and local developments and a separate mine closure plan is being considered.

Jan 1, 2000

By Scott Jones

New Mexico Coal Operations ?San Juan, La Plata, And Navajo Mines ?Three Sites 100% Owned By BHP Billiton ?San Juan And La Plata Mines Owned/Operated By San Juan Coal Co. Supplies Coal To San Juan Generating Station ?Navajo Mine Located On Navajo Nation Lands Supplies Coal To Four Corners Power Station

Jan 1, 2008

By NORMAN D. FitzGkrald

IN 1942 the outstanding characteristic of the petroleum industry was the multiplicity of war-induced distortions in virtually every segment of the business. So devastating was the success of the Nazi submarine campaign along the shores of the western Atlantic and on transoceanic routes that within six months after our entry into the war petroleum rationing was necessary in the East Coast area. The conquest of the Netherlands Indies by the Japanese three months after the opening of the war in the Pacific cut off our normal sources of rubber, and in our first year of war nationwide rationing of gasoline had to be invoked to conserve rubber-borne transportation facilities. Meanwhile the oil industry faced the imperative necessity for rapid expansion in the output of aviation gasoline and later accepted the vast responsibility for developing a new industry. synthetic rubber manufacture. Probably no other essentially peacetime industry has been forced to make so many complicated adjustments, yet its response to its wartime obligations has been nothing short of dramatic.

Jan 1, 1943

By Douglas R. Burns

Complying with SARA-Title III and the Emergency Planning and Community Right-To-Know Act as a Non-Manufacturing Facility. As of August 23, 1988 non-manufacturing facilities storing end using chemicals which require MSDS (Materia1 Safety Data Sheets) must fi1e with SERC (State Emergency Response Commission), the LEPC (Loca1 Emergency Planning Commission), and the loca1 Fire Department a list or copies of all MSDS sheets with the Tier I and Tier II forms completed.

Jan 1, 1989

By Osvaldo A. Bascur

Intelligent systems (IS) technologies have received much attention in a wide range of process engineering applications including process operations. With the revolutionary progress in information and computer technologies applying the latest technologies in metallurgical complexes has become a serious challenge to both management and technical teams. Objects and components are changing the way everyone relates to their computer and networks. Goals of real time performance monitoring includes maximizing the profitability by maximizing production, improving efficiency, attending product quality, costs, maintenance, environmental and safety regulations. Designers must consider the greatly expanded desktop computing, Microsoft object technology, Internet and how to build these systems. This paper discusses some opportunities and challenges using objects, components in designing applications and integrating intelligent systems tools. Two examples using performance equations and IS technologies applied to mineral processing are presented.

Jan 1, 1997

By R. H. T. Garnett

N.B. This paper provoked much (positive!) discussion in later issues, with responses from the author (and thanks also for the many private contributions he had received) - see under Garnett R.H.T. Expanded version of a paper originally presented at the Alluvial mining conference, London, 11-13 November 1991 and published in Alluvial mining, Barking: Elsevier Applied Science for IMM, 1991, p.115-156. The usual measure of performance in gold and tin dredging is the R/E factor. It compares actual production or recovered grade for a given period with that estimated from the original sampling. The factor is a multiple of four component factors, each ideally approaching 1.00. The factors are concerned with estimation, selection, excavation and treatment. The estimation factor reflects the errors involved in determining the grade and depth of single drill-holes or pits. An optimum selection factor is achieved by a higher drilling density. The excavation factor is affected by failure of the dredge to excavate the total volume contained within its course. The required dredge throughput rate influences not only the success in digging recovery but also the treatment factor. No two alluvial deposits are the same, but, in general, the greatest divergence from 1.00 is invariably demonstrated by the estimation factor. A major divergence in one of the other factors may also be the cause of the R/E factor being significantly different from 1.00. The component factors are examined in detail and historical trends in R/E factors are discussed

Sep 1, 1991

By C H. Dowding, P W. Linehan

Many of the technical and non-technical or human problems associated with blasting can be minimized through a proper preconstruction test-blast program.

Jan 1, 1986

By Jheison Lopes dos Santos

Sistemas de blindagens multicamada têm sido estudadas pela sua ótima capacidade de proteção, devido à combinação de diferentes materiais que constituem seus componentes. A primeira camada é constituída por um componente cerâmico, cujo objetivo principal é fragmentar o projétil, dissipando grande parte de sua energia. A camada intermediária compreende tecido de aramida ou matriz polimérica com fibras naturais, que também dissipa energia tanto do projétil quanto do cerâmico e opera retendo os fragmentos cerâmicos. Neste trabalho, pela primeira vez, o sistema cerâmico Al2O3-Nb2O5-LiF tem seu comportamento dinâmico avaliado balisticamente. Este composto cerâmico foi submetido a impactos balísticos de projéteis 7,62 mm, para testar este cerâmico do primeiro componente de um sistema de blindagens multicamadas. Os resultados obtidos mostraram que a adição de LiF ao composto cerâmico Al2O3-4%p. Nb2O5, sinterizado a 1.300 ºC, obteve desempenho comparável ao obtido por Al2O3-4%p. Nb2O5 sem LiF, sinterizado a 1.400 ºC. Os resultados revelaram que, ao serem submetidos a esses impactos balísticos, apresentaram valores comparáveis aos esperados de pressão e de velocidade de partícula na interface de impacto projétil-cerâmico. Dessa forma, a adição de fluoreto de lítio ao composto cerâmico alumina-nióbia possibilitou a redução em 100 ºC na temperatura de sinterização, sem comprometer o desempenho balístico e exibindo parâmetros de choque comparáveis, e redução de custo.

Oct 30, 2017

By Tobias Bertoldi Agostini

O estudo de biomateriais degradáveis é um dos tópicos de pesquisa mais interessantes dos biomateriais nos dias atuais. Magnésio e suas ligas estão sendo estudados para serem usados como materiais de implantes bioabsorvíveis, para uso em dispositivos cardiovasculares ou ortopédicos. A dificuldade que se encontra em utilizar implantes à base de magnésio é a sua alta taxa de corrosão. Este trabalho tem por objetivo estudar o comportamento corrosivo de ligas de magnésio bioabsorvíveis (ZK30 e ZK60) em eletrólito que simula o fluido corpóreo (SBF Kokubo) através de técnicas de perda de massa por imersão e curvas de polarização. Os resultados indicaram uma menor resistência à corrosão da liga ZK60 no eletrólito analisado comparada com a liga ZK30.

Oct 30, 2017

By Gusttavo Reis Leite Matos

Neste trabalho, a resistência à corrosão das ligas Ti-35Nb(0,0;0,5;1,0;1,5) Si e os metais puros, foram investigados em meio à saliva artificial fluoretada. Para tal, curvas de polarização, impedância eletroquímica, microscopia eletrônica de varredura (MEV), microscopia óptica (MO) e difração de raios-X (DRX) foram realizadas. O MEV e MO indicam que as amostras que contém Si apresentam maior ataque comparado aos metais puros. Esse fato foi confirmado através dos ensaios eletroquímicos onde foi possível observar que as ligas com a presença do Si apresentam menor resistência de polarização (Rp) e não passivam a superfície do material.

Oct 30, 2017

By Leiliane Alves de Oliveira

O aço EUROFER (9Cr – 1W), pode ser utilizado em turbinas para geração de energia, vasos de pressão, reatores nuclear ou aplicações, onde o material é submetido a temperaturas de serviço entre 250°C e 450°C. Uma forma de melhorar as propriedades do aço, para que ele trabalhe a temperaturas mais altas ou que se torne mais estável é adicionar partículas de segunda fase na sua matriz. Estas partículas podem estar na forma de óxidos, carbetos, nitretos ou até mesmo em solução sólida quando alguns elementos químicos são adicionados ao material. Neste contexto, este trabalho objetiva estudar o efeito da adição de 3% de carbeto de tântalo na matriz metálica do aço ferrítico/martensítico. Para isto a metalurgia do pó foi a rota empregada para a produção deste compósito de matriz metálica (CMM). Duas moagens distintas foram realizadas. A primeira com o aço EUROFER e a segunda com o aço EUROFER com adição de 3% de carbeto de tântalo (TaC). A moagem de alta energia foi realizada durante 5 horas. Em seguida, os dois pós produzidos foram sinterizados em um forno a vácuo (10-4torr) a temperatura de 1.250°C durante 60 minutos. O produto final foi caracterizado por microscopia óptica, microscopia eletrônica de varredura (EDS) e ensaio de microdureza. Os estudos iniciais dos sinterizados obteve uma resposta positiva nas propriedades mecânicas independente do processamento. Com valores de microdureza maior que 100% do valor de 333,2 HV obtidos para o aço puro como recebido(barra).

Aug 8, 2018

By Antonio Adel dos Santos

Visando elucidar o comportamento da carepa terciária durante a laminação de tiras a quente, em um aço produzido como laminado a quente e com rigorosa exigência de qualidade superficial, foi realizada uma parada forçada do laminador, impondo-se, imediatamente, um resfriamento rápido da superfície da tira. Amostras coletadas na região do arco de contato mostraram que a carepa possui espessura na faixa de 10 ?m a 14 ?m na entrada das cadeiras, sendo reduzida para 7 ?m com a deformação, sem ocorrência de ruptura. Tais características indicam que, do ponto de vista do comportamento no trem acabador, a carepa apresenta espessura e plasticidade adequadas para evitar defeitos nos produtos laminados. A carepa foi constituída predominantemente por Fe3O4, óxido plástico na temperatura de laminação. Foi desenvolvido e aplicado um modelo de crescimento da carepa, que forneceu valores de espessura muito próximos dos medidos, se tornando uma ferramenta útil para análise da influência de condições de processo na carepa.

Oct 30, 2017