Search Documents

By J. J. Kellar, W. M. Cross, J. D. Miller

Infrared spectroscopy has been one of the most useful experimental techniques for the analysis of surface reactions in flotation systems, including surface alteration and surfactant adsorption reactions. With the advent of Fourier transform infrared (FTIR) spectrometers, many low-energy throughput IR experimental techniques previously unused by flotation researchers have come into greater use. In particular, internal reflection spectroscopy (IRS) is the most often used technique for in-situ studies. To date, three IRS methods have been used for in-situ measurements. These techniques are evaluated for use in characterization of surface reactions in flotation systems. The method using mineral crystals as reactive internal reflection elements (IRE) is of particular interest because it allows surfactant adsorption densities to be calculated directly from in-situ spectral data in real time. Application of in-situ FTIR/IRS with reactive internal reflection elements will be demonstrated for collector adsorption reactions in each of the major flotation systems. The alumina (A1203)/sodium dodecylsulfate system is used as an example for insoluble oxide/silicate flotation, while the fluorite (CaF2)/oleate system serves as a paradigm for semisoluble salt flotation. For sulfide flotation, sphalerite (ZnS) is used as the reactive IRE with potassium amylxanthate and potassium ethylxanthate as collectors. In the case of soluble salt flotation, sylvite (KC1) is used as the IRE with n-octylamine as collector. Finally, the use of reactive IREs in the near-IR spectral region and in spectroelectrochemical research is discussed.

Jan 1, 1989

By Alan S. Peck

Chemisorbed oleate films on the surfaces of fluorite, barite, and calcite were studied by means of infrared spectrophotometry. Evidence is presented which indicates the mineral anions, i.e., fluoride, sulfate, and carbonate, are displaced from the mineral surfaces as a result of the adsorption from aqueous solutions. Also, chemisorption reactions between oleic acid and fluorite or calcite occurred spontaneously in the absence of water. Carbon dioxide was identified as a reaction product when dry calcite was contacted with oleic acid. There was no evidence of reaction between oleic acid and barite in the absence of water.

Jan 1, 1964

By J. O. Leppinen

FTIR measurements using a special ATR cell were carried out to investigate the adsorption of two thiol collectors, potassium ethyl xanthate (KEX) and sodium diethyl dithlophoshate (NaDTP), on an unoxidized lead sulfide surface. Both qualitative and quantitative determinations of the collectors were made at the coverages from two monolayers down to 2% of the monolayer. The experiments revealed that the thiol collector species coordinate to the lead atoms at the surface of lead sulfide but the surface products distinctly differ from the precipitated bulk lead compounds. There exists a linear relationship between the coverage and the signal intensity of the IR spectra within the coverage range studied.

Jan 1, 1987

By M. T. Ansari

"This article explains the ways in which investment on mining infrastructure is a geopolitical issue. It discusses the effect of installing sufficient infra structure to get the product to the world market, and argues that there is a risk involved in depending on traditional suppliers who wish to invest in the infrastructure. It explains how to make a distinction between dedicated purpose infrastructure and general use infrastructure by examining the positions of the main actors in mining projects. It argues that these positions can not be understood as analogous to projects in developed countries. To conclude, infrastructure is a crucial link in the supply chain to market but the relative size of such projects in relation to the economy means that investors decisions in developing countries have quite different implications from those in developed countries."

Jan 1, 2011

By Charles A. Maliszewski, James M. Galvin, Gerhard Urschitz

With obvious signs of deterioration, the double track, historically registered Bergen Tunnels as part of the commuter rail system in New Jersey waited for rehabilitation for a long time. Serious water in filtration not only caused operational and safety hazards for the electrified rail line but also deteriorated and structurally compromised the tunnel lining. An innovative rehabilitation program was developed to enlarge the tunnel and to provide a new waterproofing system and final lining. For the rock excavation and support New Austrian Tunneling Method (NATM) principles were utilized, while water tightness was achieved by installing a PVC membrane waterproofing system followed by a reinforced cast-in-place final lining. Experienced on-site supervision generated additional savings during construction by streamlining support elements based on geologic conditions encountered.

Jan 1, 2003

By R. Berton, M. Walden, S. Melberg, N. Rocco

Recent tailings dam failures around the globe have influenced many mining industry regulators to reassess their requirements for the numerical modelling of tailings dam failures. This type or forward modelling is associated with overarching uncertainties as the model cannot be calibrated against a physical result. Dam breach analyses that meet the requirements of current industry standards and guidance typically begin with identification of credible failure modes and selection of appropriate topographic data set to represent the study area. The breach parameters and the volume of tailings released are then determined using available methodologies and empirical relationships. Subsequently, when the breach hydrograph is developed and the hydrology of stream networks are complete, the runout simulation is implemented. Due to the uncertainty involved in the process, sensitivity analyses are recommended to quantify variations in model inputs on the inundation extent and the flow characteristics. This paper outlines some common methodologies utilized for development of dam breach models, summarizes associated uncertainties with these methodologies and inputs, and provides guidance on how sensitivity analyses can address a wide array of uncertainties inherent in tailings breach analyses. This paper provides an understanding of how selecting appropriate breach parameters can result in reasonably conservative inundation extents consistent with the identified credible failure modes.

Mar 2, 2022

By Donald G. Rogich

The concept of initiating a large action-oriented contract, directed toward inherently safe mining systems, was conceived by the U. S. Bureau of Mines in January 1970. At that time we were in the process of establishing research contracts and grants, about 100 of which were let in FY 71 to deal individually with fairly specific technological areas. These projects in the aggregate covered a wide spectrum of health and safety problems. What appeared to be necessary was the creation of a project or program that would provide a focal point for the demonstration of many of the results of this research and also in the action sense culminate with working hardware and systems that could be tested and demonstrated over a fairly long teen. The concept of working demonstrable systems, rather than just a conceptual study, was, felt to be necessary for two significant reasons. In the development of any new system, the translation from concept to working hardware is usually a costly and time consuming process which acts as a deterrent to implementation. Secondly, many decisions in the mining community to change equipment or systems ,are based on first hand observation of the new system, in operational practice, an attitude which is certainly understandable in view of the high capital costs of equipment. The decision was made to procure a single R&D contract which would be aimed at developing underground coal mining systems which

Jan 1, 1972

By V. Castranova, L. Wu, K. Van Dyke, J. Gutierrez, V. Vallayathan

Since it has been demonstrated that silica caused phagocytic cells to activate lipoxygenase metabolism of unsaturated fatty acids we thought selective inhibition of this metabolic pathway might be helpful in treatment of silicosis. It is known that lipoxygenase metabolism plays a role in the pathogenesis of a variety of inflammatory and hypersensitivity conditions. Further, it is believed that the alveolar phagocytic cells which engulf silica begin the inflammatory cycle which produces the metabolic products, cytokines and growth factors which causes fibrosis in the lung. There have been indications that drugs which inhibit lipoxygenase can inhibit fibrosis from other causes. Previously, we developed a method which detects the activity of lipoxygenase metabolism by measuring free radical oxidation via light production or chemiluminescence (CL). We decided to apply this method to phagocytic cells that would be found in the lung in the presence of silica with and without newly developed inhibitors of the lipoxygenase reaction. We used drugs which inhibit lipoxygenase directly including AA861 (TAKEDA), A63162 (Abbott), and an inhibitor that scavenges free radicals produced from the lipoxygenase reaction, nordihydroguairetic acid. In addition we used an indirect inhibitor, tetrandrine. We found drug inhibition of silica activated CL from alveolar macrophages, neutrophils and human leukemia (HL-60) cells differentiated with DMSO. Nordihydroguairetic acid 2x10-5M produced almost complete inhibition in all three cell types. In human leukemia cells (HL-60) A63162 and tetrandrine were equally inhibitory at 42% while in human neutrophils A63162 and tetrandrine were less active 22 and 10% respectively. In macrophages A63162 and AA861 were less than 50% inhibitory to cellular CL at 2xl0-5M. Direct assay of tetrandrine (2x10-5M) with sodium arachidonate and soybean lipoxygenase reveals no inhibition. All antilipoxygenase drugs regardless of mechanism were inhibitory to cellular chemiluminescence from all three types of phagocytic cells. These drugs alone or in mixtures could prove useful in treatment of silicosis.

Jan 1, 1991

The results of studies to ameliorate acid mine drainage by retarding the rate of oxidation of pyrite at source are discussed. In the transpassive region, pyrite oxidizes by reactive dissolution, mass transfer through the product layer and diffusion in the bulk solution. One can decrease the rate of pyrite oxidation by inhibiting either oxidation reactions or cathodic reactions. It is demonstrated in this study that some surface active reagents extend the passive region by affecting both the anodic and cathodic processes. The extension to higher potentials occurs by inhibition of the anodic dissolution process whereas to lower cathodic potentials through decrease in the rate of reduction of molecular oxygen and/or ferric ions. To retard the oxidation of pyrite by ferric ions, which is considered to be the dominant oxidant under conditions of acid mine drainage, it would be necessary to restrict mass transfer or promote complexation of ferric ions at the surface. Imidazoline based reagents were found to be most effective in meeting this goal.

Jan 1, 1994

By Eric Sitorus, Septian Prahastudhi, Roy William, Wieda Azani

In July 2020, massive slope failure occurred in the southeast corner Grasberg open pit. This was the final episode in the breakthrough of Production Block 2 South (PB2S) of the Grasberg Block Cave to connect to the surface. This breakthrough had been rapidly evolving during the first half of 2020 and occurred as expected with no adverse impacts to safety or operations. To manage and safeguard the exposure to the workforce and operations, numerous hazards were identified and anticipated. The failure of the sill pillar between the open pit and PB2S cave was identified as the main area of interest and was closely watched during the failure process. This paper reviews the systematic approach developed to convert monitoring data into information around the collapse of the GBC PB2S cave sill pillar. The data that was interpreted consisted of micro-seismic, piezometric, ground-based radar and observational inspections. Geological structures on the boundary of the PB2S cave were clearly involved in the breakthrough process. As the cave propagation reached these structures and triggered instability, the resulting acceleration and breakdown were clearly shown by IBIS radar units associated with high movement in the slope. The focus of this paper is on the evolution of changes seen in the micro-seismic data and how it was used to understand the rapidly changing conditions of the sill pillar. The seismic parameters evaluated were event distribution, Es/Ep value, and the seismic moment tensor inversion. The changes of breakthrough indication seen in these parameters were substantiated by Shear Wave Splitting (SWS) analysis that showed a close correlation with the fractured zone above the PB2S cave as indicated by the increasing anisotropy.

Jan 1, 2022

By Rakesh Sehgal, Pushkar Verma, Mohit Sharma

"SJVN Limited successfully commissioned its Rampur HEP (412 MW) in 2014. The project has been planned to operate in tandem by directly utilizing the Tail Water of SJVN’s prestigious Nathpa Jhakri Hydro Power Station 1500 MW located upstream. The initial filling of voluminous water conductor system of RHEP with 10.50 m diameter, 15 Kilometer long Head Race Tunnel, involved more than 1.5 million m3 of water. The filling operation of such a large diameter tunnel constructed in young folded Himalayas which always offer less ideal sites for tunnelling and their subsequent operations under pressurized conditions is worth sharing with tunnelling fraternity. The paper covers meticulous planning, execution, precautions taken, and performance monitoring during filling process keeping in view the fragile geology, low rock cover zones, shear zones in close vicinity of thickly inhabited areas, squeezing zones, hot water zones encountered during excavation.1.0 RAMPUR HYDRO POWER STATION IN BRIEFRampur Hydroelectric Project (412 MW), is located in Himachal Pradesh (India). This project is a downstream development of Nathpa Jhakri Hydro Power Station (1500 MW) constructed on river Satluj and commissioned during 2003. Both the projects today are now successfully working in tandem. The upstream NJHPS has been constructed on the left bank of the river while the downstream Rampur HPS is located on right bank of the river (Figure-1).The major length of HRT of Rampur project lies on right bank of river before it crosses under the river in its initial reach (Figure-2). The main features of the project are as below:• 10.50 m diameter 15 km long HRT ending in a 155.75 m deep, 38.00 m diameter surge shaft.• 3 steel lined pressure shafts, 5.4 m dia, 211-220m long.• Surface valve house 69 m long x 10.50 m wide x 23 m high housing 3 No. butterfly valves• 3 No. surface penstocks 5.4m dia 368-382m long, bifurcating into six penstocks, each of 3.80 mdia. to feed six generating units of surface power house 158 m long x 24.50 m wide x 48 m high, with Francis turbines each of 68.67 MW capacity."

Jan 1, 2016

By A. B. Cortes

This research work discusses the development of a two-dimensional model that represents the flow that occurs in the inlet section of hydrocyclones. The governing equations are the two-dimensional, unsteady, incompressible Navier-Stokes equations in cylindrical polar coordinates with primitive variable formulations. In this approach, no assumptions have been made other than independence in the axial direction. The full two-dimensional Navier-Stokes equation in the r-a plane is used. The commonly used simplifying assumption of axisymmetry is not used. A numerical technique based on a newly developed spectral-difference method is used to solve the equations. The spectral-difference method is a multi-domain, and multi-dimensional extension of the Jacobi polynomial collocation technique. The computational grid for the inlet section is composed of 25 sub-domains which result from five partitions in the angular direction and five partitions in the radial direction. Several test cases are used to validate the appropriateness of the numerical model.

Jan 1, 1995

By Robert L. Gamble

The world's largest fluidized bed steam generator located at Rivesville, West Virginia is currently undergoing initial operation. This unit is designed to generate 3708 kg/s (300,000 Ib/hr) equivalent to 30 MWe of superheated steam while firing coal in a fluidized bed of limestone. Coal was first fired in this unit in December, 1976 and start up operation is progressing.

Jan 1, 1977

By L. L. Lien

In this economic age of high interest rates and softening mineral commodity markets, the mining industry is taking a hard look at how it conducts its business and where economies can be effected. The capital investment to build a new metallurgical facility or open a new property has traditionally attracted substantial investigation, analysis and management attention. The areas of mineral exploitation, financial feasibility, engineering and construction have been studied extensively and their management, although still difficult, have become refined disciplines.

Jan 1, 1982

By M. J. Shulman

An algorithm used by the US Coast Guard to find lost objects is utilized to optimally allocate exploration efforts during initial stages of an exploration program. Based on classical search theory, the algorithm assumes a target probability distribution function, a detection func¬tion, and a cost function. The three Junctions are analogous to delineating areas of possible mineralization, choice of exploration methods, and exploration budget. Application of the algorithm is shown for a hypothetical target distribution. Using the maximum number of field days available as the cost function, the optimal allocation of effort is shown for different exploration methods, e.g. electromagnetic survey and induced polarization. The adaption of the algorithm for the exploration process is discussed.

Jan 3, 1984

By Irwan S. Halim

For tunnels in horizontally bedded rock, geologic factors affect the selection and design of the initial supports, including the rock propensity toward parting along bedding and the resulting high potential for rock slabbing during excavation. To evaluate this ground behavior, numerical analyses and results with Mohr-Coulomb, Hoek-Brown, and Ubiquitous Joint constitutive models were used, using the Upper Rouge CSO tunnel in Detroit, Michigan as an example. The different rock models and other geologic considerations are shown to impact the selection of the tunnel initial support and design. This paper emphasizes the appropriate selection of an analytical model based on the site specific geology to achieve an optimum initial support design.

Jan 1, 2008

By J. P. Baur

The sensitivity of radiochemical techniques makes possible the study of the initial stage sulfuric acid leaching kinetics of chalcopyrite and other copper sulfide minerals. High-grade Transvaal chalcopyrite was neutron irradiated in a TRIGA reactor to produce radioisotopes copper-64, iron-59, and sulfur-35. Dissolution rates were measured in the time interval zero to 60 minutes during which time significant anomalies were observed. First, an initial period of rapid dissolution lasting a few minutes; second, an arrest or "plateau" region usually lasting from 6 to 10 minutes; third, a second period of dissolution of lesser rate than the first. The effect of solution variables such as pH, oxygen partial pressure, and ferric ion concentration at different temperatures were measured. The initial rate data were correlated by considering the rapid reaction to be due to the dissolution of surface oxidation products or the formation of an iron depleted surface layer. The data for the second slower reaction have been explained to be due

Jan 1, 1972

By Duport. P. J.

INTRODUCTION In February 1981, the Canadian Institute for Radiation Safety (CAIRS) initiated a routine Personal Alpha Dosimetry service for personnel of the Canadian uranium mining industry. This service is based on the use of the [Personal Alpha Dosimeter] developed by the French Atomic Energy Commission (CEA). The origins of personal alpha dosimetry and its rational are briefly described. Technical and organizational aspects of a routine personal alpha dosimetry service are outlined in this paper. HISTORICAL BACKGROUND International recommendations (1) and Canadian regulations have established Maximum Permissible Exposures (MPE) for each source of radiation exposure. Uranium workers in mines and mills are exposed to external radiation ( [y] rays) and to internal radiations ( [B] and [a] particles) which are delivered to the respiratory track by airborne alpha emitters (Rn and Th daughters and Long Lived Dust). To date, dosimetry for uranium workers has been performed by area monitoring/collective dosimetry. In North America the concentration of radon daughters is routinely measured by grab samples taken at the work place and by on-site gross alpha counting. The concentration of potential alpha energy is then calculated (usually by Kusnetz method) and expressed in Working Levels (WL). The time spent by each worker at a given work place is determined from his time sheets and used to calculate the individual monthly exposures to airborne alpha emitters, which is then expressed in Working Level Months (WLM). The uncertainties attached to such a procedure are obvious even in the case of frequent grab samplings and can be expected to lead to an underestimation of individual doses. Among fifteen possible sources identified in a mine situation, (2) four may stretch the standard deviation of the measurements' distribution, nine may lead to an underestimation and two may lead to either an underestimation or to an overestimation. To improve this situation, in 1971 the Atomic Energy Commission began studying the use of personal alpha dosimeters to determine individual exposures from the airborne alpha emitters encountered in the uranium industry environments. Criteria for a Personal Alpha Dosimeter In order to minimize the difficulties encountered in determining exposures received by uranium workers, the CEA in co-operation with the Atomic Energy Control Board of Canada (AECB), has developed a set of criteria for personal alpha dosimeters. Exposures may be determined easily and accurately using this criteria. Autonomy The dosimeter must operate for at least 10 to 12 hours. Excess time spent in the mine or in the facility may possibly be related to an accidental situation causing unusual levels of radioactivity. Since the dosimeter may be needed in non-underground settings where a cap lamp is not used, full autonomy is desirable. Maintenance, Periodicity of Reading In order to complement other dosimetry systems, the personal alpha dosimeter should be read monthly when the filter should also be changed. Routine air flow checks can be made according to local conditions (e.g. diesel loading). Radioisotopes Identification Since the exposure unit (WLM) is based on the concentration of potential alpha energy in the air, the personal alpha dosimeter should be capable of identifying each short lived alpha emitter included in the calculation of the WI, and WLM. Permanent Exposure Record Three points may be considered here: 1. In many countries, lung cancer in uranium workers is a compensable occupational disease. In some instances, compensation is awarded when it can be proven that the worker has received an exposure above a certain limit. The present uncertainty of the individual exposure makes the compensation procedure difficult. 2. By design, a personal alpha dosimeter must representatively sample all airborne particles, ranging in size from the unattached fraction to the upper limit of respirable aerosols (0.001 to 5 µm). The dosimeter must offer minimal resistance to the penetration of these aerosols. While the mining/ milling environment presents harsh conditions which may accidentally contaminate the dosimeter, it is important to be able to distinguish these cases of contamination and still obtain accurate readings. 3. A dependable dose register is most valuable for further epidimiological studies. The dependability of such a data base increases with the possibility of a second assessment of the dosimeters' reading (filter, film).

Jan 1, 1981

By John Bley

White Pine Copper Company operates a mine in the Upper Peninsula of Michigan using a modified room-and-pillar system for extracting ore.1 Mine production averages 15, 500 tons per day. The terrain is predominantly level and the depth of cover varies from 500 to 800 feet over the present workings with depth increasing as mining progresses down the dip. The deposit is situated on a low angle plunging, anticlinal structure composed of sedimentary beds. Local terminology for the stratigraphic units which contain the ore horizons, named in ascending order, is as follows: lower sandstone, parting shale, upper sandstone and upper shale. The ore zones of copper enrichment are, contained in the parting and upper shales. The parting shale will vary; from 6. 5 to 9.0 feet thick; the upper sandstone from 2 to 10 feet; and the upper shale from 1. 5 to 6. 5 feet. Two variation of the room-and-pillar system are used to extract the ore depending on grade and local ground conditions. One system is called the parting shale method and recovers the parting shale only. This system requires a mining height of 8 1/2 feet to accommodate large-scale, high-capacity equipment and this working height is obtained by removing approximately 1 to 2 feet of the barren lower sandstone with the ore. Under the second system, locally termed full column, the mining height is about 14-1/2 feet and this system removes the parting shale, the upper sandstone and the lower mineralized zone, approximately 1-1/2 feet, of the upper shale at which point it is possible to maintain a competent back (Fig. 1).1

Jan 1, 1964

By Eric C. Schwamberge, Clem A. Pelletier, Deborah L. Muggli, George W. Poling

The Pit Lake at Island Copper has evolved into a 3-layered meromictic system. Acid Rock Drainage (ARD) is collected and injected into the lake at 220 m depth via 2 diffuser systems. In situ dye studies were conducted during 2 differing hydrological regimes in order to determine the behavior of the ARD plume within the Pit Lake. Results indicated that when runoff from the waste dumps was low, the injected ARD remained within the bottom half of the intermediate layer of the Pit Lake, initially below depths of 90 m. However, when runoff from the waste dumps was high, the injected ARD at -220 m depth rose through the intermediate water column layer rapidly, but did not breach the top pycnocline at -10 m depth. Overall, the system is currently performing as a mixing bowl with a strong boundary or cap at the upper pycnocline. maintaining mixing below the 10 m depth water level.

Jan 1, 2000