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By A. Warczok

Metal losses in discard slag are the main factor determining overall recovery. The metals are present both in dissolved form and as matte or metallic inclusions, varying in size from 2 to 1000 µm. Pyrometallurgical slag cleaning usually consists of heating the slag, reduction of oxides and settling of matte/metal droplets. Heating the slag decreases viscosity and accelerates reactions. Reduction of magnetite liberates inclusions and facilitates co-reduction of dissolved metal oxides. A significant amount of the matte and metal is present as very fine metallic inclusions, too small for settling. The coalescence of these matte or metal inclusions is required to remove them from the slag. The developed new concept of slag cleaning combines DC furnace technology with an extra magnetic field for vigorous slag stirring, enhancing mass transfer to the reductant surface, accelerating the rate of reduction, and destabilizing the emulsion of matte or metal inclusions. Intensive slag stirring increases the probability of collision of inclusions, will accelerate their growth and will therefore improve settling. The process is carried out in a patented DC channel furnace, where the liquid metal or matte layer acts as a cathode and the floating coke bed on the slag surface is the anode. In the first part of the furnace, a superimposed magnetic field induces a Lorentz's force causing the slag to start an intensive circular motion. The next furnace zone does not experience any stirring and is dedicated for quiet sedimentation of the inclusions. A mathematical model of gravitational coalescence combined with forced slag motion showed the possibilities of effective removal of copper matte inclusions. The results of laboratory pilot scale tests of continuous slag cleaning showed fast slag reduction and confirmed the improved matte removal from the slag. Conceptual analysis shows the potential use of the technology in various other non-ferrous industries, like for example nickel plants. It is also possible to use this technique batch wise.

Jan 1, 2007

By A. J. Rigby

Anode vessels are often relined with refractory every one to two years and a typical reline time can take between 16-20 days. Modem refractory designs using dense, corrosion resistant brick applied directly to the vessel shell in the high wear areas around and above the tuyeres and at the slagline can yield a lining life of up to 4-5 years before a complete reline is necessary. Installation methods using brick delivery on roller conveyors through an endwall access port and complete anchoring of the brick to allow for lining self-support can take days off the installation time. It is possible, therefore, to reduce the refractory relining period by 50% and increase lining life by 100% compared to typical anode repair schemes. Cu2007

Jan 1, 2007

By Z. Manafi

Bioleaching of a copper sulfide ore containing "activated pyrite", using a mixed culture of mesophilic bacteria, was studied. This type of copper ore had been found unsuitable for flotation because it produces a concentrate containing relatively high iron concentrations and, therefore, a low copper grade. Microscopic observations showed that pyrite particles had been activated by the formation of a thin film of chalcocite. Hence, a bioleaching process was considered as an alternative to treat this ore. Following shake flask and acid consumption tests, column tests of the crushed ore (75% -12.5 mm) were initiated and the effects of culture medium, agglomeration, and irrigation type on copper recovery were studied. The results showed that all the columns containing bacteria had copper recoveries around 90% compared to the abiotic control column with a recovery of 50%. It was concluded that bioleaching could be successfully utilized to process copper ores containing activated pyrite.

Jan 1, 2007

By L. J. Friedman

The recovery of sulfur dioxide from metallurgical gases for the production of sulfuric acid has been the primary means of reducing sulfur dioxide emissions from nonferrous smelters. Sulfuric acid has been produced from gas originating from fluid bed roasters, electric furnaces, reverberatory furnaces, flash smelting furnaces, Pierce Smith and flash converters, sinter machines, etc. The gas from each of these sources has a unique set of variables that affect the design and operation of the sulfuric acid plant. In addition, the sulfuric acid plant itself has been evolving, with new equipment designs and materials. This paper will review each of the unit operations in the gas cleaning and contact sections of the metallurgical sulfuric acid plant, discussing various equipment designs, materials and the handling of gas stream variables and impurities. The paper updates to 2007 previous works on metallurgical sulfuric acid plants by the authors, and analyzes new equipment and systems, including: FRP or alloy quench systems, alloy converters, towers and pump tanks, heat recovery systems, high efficiency mist eliminators, tower packing, etc.

Jan 1, 2007

By D. D. Tannant, H. Ozturk

Thin spray-on liners are increasingly being used as rock support in underground mines. The adhesive strength between the liner and the rock surface is an important design parameter. Adhesion tests were conducted to assess the impact on adhesion of the presence of oil, water, and dust on a substrate, and the roughness and grain size of different substrates. Other factors such as curing time, loading rate, and liner thickness were also considered. Adhesion was measured using a pull test of a 33 mm diameter elevator bolt attached to an over-cored section of liner with strong epoxy. Most tests were performed using Tekflex liner material, although five other liner products were also tested. Adhesive strengths of about 2 MPa can be achieved with Tekflex under optimal conditions. Long-term creep tests showed that the adhesive strength could drop by at least 50% when the liner carries load for about a month. Where the rock surface is contaminated with dust or the rock is weak in tension, it may be difficult to reach adhesion strengths of 1 to 1.5 MPa. As the thickness of the liner increases, the adhesive strength to a substrate appears to decrease.

Jan 1, 2007

By V. Ushakov, P. Bogdan

Daily production scheduling in a highly dynamic smelter environment has always been a great challenge for the operation management due to a significant amount of uncertainties. Planned and unexpected equipment failures, various energy outages, inaccuracies in flow and mass balancing, manpower availability conflicts and other constraints make the job of daily production planning exceptionally difficult. This paper discusses a general scheduling approach utilized by the production management of the Phelps Dodge Miami Smelter (the Smelter). It also describes logical assumptions and some practical software solutions that have been exploited by the Smelter managers to assist the front line supervisors in dealing with daily planning activities for several years.

Jan 1, 2007

By R. Bonifaz

The Chagres Smelter, part of the Anglo American plc group situated 80 Km north of Santiago in Chile, completed a series of operational improvement in 2005 resulting in an optimum capacity in its operational units. At present the Chagres Smelter has developed an operational strategy which seeks to reduce bottle-necks in the production process. In this way we have managed to lower operational cost, decrease energy consumption and maximize the capacity of the Acid, Oxygen, and Smelting, Converting, Refining and Casting units. A constant application of international benchmarks together with continuous staff improvement and the latest smelter technology have combined to place Chagres among the finest smelting works in the world. In response to environmental challenges, we have studying various options for investment suitable for a profitable business of benefits to both Anglo American and Chile as a whole. The most relevant technical indicators are the figures : Energy consumption less than 6,3 GJ/ton fine copper, Intensity of smelting rate in Flash Smelting unit of 6900 ton of copper concentrate/m2 settler of furnace area and be one of the top five smelter in direct cash cost .

Jan 1, 2007

By S. Dessureault, M. Yildirim

More mining companies are now investing in IT, including updating one of the traditional IT process control tools used in the mining industry: real time in-pit truck allocation control and monitoring systems, or fleet management systems (FMS). These systems have been used to maximize the overall mine production by improving equipment utilization and reducing production costs. Most modern operations monitor the in-pit operations using GPS and wireless communications to produce data. Improvements in bandwidth, sensors, and computing power are causing modern systems to become more complex and generate more data. However, human analysis by simple regression or table generation in spreadsheets of the data is becoming impossible. Data mining solves this data management problem. Data mining finds patterns and relationships in very large data sets. This paper describes the application of modern data mining techniques on truck dispatching systems in a real open pit hard-rock copper mine. The analyses conducted included determining how the trucks performed under particular conditions and allocation systems. The long-term benefits of this work are to identify strengths and improvement opportunities in truck assignment systems and establish the skill sets and IT infrastructure needed in undertaking more complex datadriven technology such as a truck dispatcher trainer.

Jan 1, 2007

By K. G. Markkola

Since 2005, Compafifa Contractual Minera Candelaria (CCMC) has defined various strategies which aim to optimize the usage of the available energy in each of the SAG grinding circuit modules (SABC-A configuration). For this purpose, the use of larger size balls along with operating with an optimum balls/load ratio has been implemented. Additionally, in the ball mills, the amount of balls in relation to the equipment's usable diameter has been optimized. In the pebble crushing circuit, the percentage of material passing 12 mm (112 in) product has been increased by 15% by: (1) modifying the crusher mantle profile, (2) implementing a strategy for maximizing the power in each crusher, (3) using continuous improvement tools (Lean - Six Sigma), (4) redesigning SAG mills discharge grates, and (5) changing discharge grates in order to control the crusher feed size distribution profile. All these activities have improved plant throughput by 1,000 t/d with no significant capital investment. As part of the energy consumption optimization study, we have considered determining the optimum operational rate of each SAG mill, in relation to the mill liner life and also the improving the control strategy in conventional grinding.

Jan 1, 2007

By P. J. Williams, A. R. Foster

Petrographic studies, assay records, and laser ablation-inductively coupled plasma-mass spectrometer (LA-ICP-MS) analyses of major sulfides suggest nearly all of the gold at the Ernest Henry Cu-Au deposit occurs in the form of native gold or electrum (95-65 wt.% Au); sylvanite and dissolved gold in cobaltite, chalcopyrite, and pyrite make only minor contributions. LA-ICP-MS analyses of the gold contents of chalcopyrite gave from 8 to 139 ppb (mean = 56 ppb), more than an order of magnitude lower than those experimentally determined in chalcopyrite in equilibrium with native gold at the estimated mineralization temperatures (350°-450°C). Gold content is more variable in pyrite (1-400 ppb, mean = 77 ppb) and highest in narrow growth zones of a subordinate type of complexly zoned pyrite wherein it is associated with elevated As, Ag, Sn, Sb, Te, and Bi. Deposition of gold-electrum was closely associated with, but preceded some of the chalcopyrite deposition, as indicated by microtextures and lower bulk Au:Cu ratios in late-stage chalcopyrite-rich veins. Gold grains have maximum dimensions from <1 to 50 micrometers, and are heterogeneously distributed with most occurring in microscale clusters. Fifty-five out of 76 grains recorded in polished sections are in contact with both chalcopyrite and pyrite, and many of the rest are in sites where such a relationship could exist in the third dimension. The dominant textural sites are intergrowths with chalcopyrite in microveinlets cutting pyrite, and on faces of pyrite grains in contact with chalcopyrite. Scanning electron microscopy, electron microprobe analysis, and proton induced X-ray emission studies show that pyrite associated with gold includes complexly zoned, weakly zoned, arsenian, and arsenic-poor types. The textures are compatible with the possibility that most gold was deposited electrochemically as native metal on pyrite surfaces. The textural distribution of gold has important metallurgical implications given that the ore processing circuits at Ernest Henry and most other sulfide copper mines are designed to exclude pyrite (and arsenic) from concentrates.

Jan 1, 2007

By J. A. Muñoz

In this work, short and long-term tests were performed using different massive mineral sulfide specimens (chalcopyrite, pyrite, sphalerite, galena, covellite and chalcocite) of museum grade and quartz of analytical grade in an acid medium containing silver ions. After attack, the samples were observed by SEM and products characterized by EDS. Parallel, massive specimens of pyrite (FeS2) and chalcopyrite (CuFeS2) were embedded in an epoxy resin, either electrically isolated or in electrical contact, and treated with silver ions in the presence of bacteria. Finally, massive chalcopyrite and pyrite electrodes were subjected to electrochemical measurements in an acid medium under different experimental conditions (addition of silver ions and inoculation). The results showed that silver deposition takes place preferentially on specific mineral surfaces: chalcopyrite, galena, covellite and chalcocite. The chemical reaction of silver ions with pyrite and sphalerite was negligible at low silver concentration (8 ppm). But sphalerite reacted with silver ions at higher silver concentration (100 ppm). In a mixture of chalcopyrite and pyrite, silver was deposited on the former surface creating new cathodic sites which sped up the electrochemical reactions of chalcopyrite dissolution.

Jan 1, 2007

By S. Demetrio

China has a traditional segment of Copper Smelters with its own Chinese technology, typically small in size from 20.000 to 50.000 tCu/a, and they are responsible for the processing and production of more than 600,000 tonnes of blister copper per year. For occidental experts, like one of the authors, it is not so easy to believe that they are profitable, because the size and the use of old Blast Furnaces, but they are with simple and effective production lines. The authors are convinced that China has a good alternative to improve theses old copper production lines with small innovative changes in its process arrangement, jumping to higher level technology, more efficient in production, productivity and cost, assuring copper as a raw material for the country and its high speed development. The key to improve that the traditional Chinese Copper Smelter is white metal as an extra raw material as a first step doubling the copper production from raw materials and the complete replacement of concentrates by white metal (WM) in a second step increasing it four times or more as the final goal. It is not so difficult nor expensive to make it happen, but there are a couple of questions for implementing this innovation in the copper smelter industry: 1 - Will the old fashioned mentality be open to this new direction for China being the biggest copper consumer on one side, and the biggest copper Primary Producers on the other hand? and 2 - Will they be open to follow this "win-win" strategic way for both ends of the copper market? We don&apos;t know if anybody will take up the challenge to improve it but our responsibility as a consulting expert and a university professor is to put the alternative on table for others to decide whether to implement it.

Jan 1, 2007

By F. Romero

In the last four years, Compañia Minera Doña Ines de Collahuasi has been working in the application of advanced multivariate statistical techniques for the improvement of the metallurgical processes. In this paper the main conclusions for the application of multivariable analysis to the EW process are presented; including the identification of (target) process patterns according to throughput and quality criteria. Based on the process patterns, process variables hierarchies were identified by selecting the most influential ones, as well as to identify and isolate the root causes of pattern deviations and sub-standard operating conditions, cause-effect relationships were established, leading to the definition of process policies and controls to give early corrections to potential failures. The analysis was focused on cathode quality, specifically in its sulfur content, using an empirical model based on those variables that from a phenomenological and statistical stand point appeared to be the most influencing ones.

Jan 1, 2007

By T. Stergiou

An extensive research is being carried out on the shaft furnace operation in order to minimize down-times and reduce operational cost. The need to increase the scrap percentage on the charging mix, together with the need of cheaper spare parts has led to the investigation of alternative materials for the burner system on the shaft furnace. This system consists of a burner block and a flame holder. Traditionally these items are constructed either from SiC ? oxide bonded or SiC-nitride bonded. A lot of problems have been confronted over the past 8 years of operation. Usually, large cracks are formed on both flame holders and burner blocks. This resulted in leakage of combustion gases to the back of the lining and a quick erosion of it. Additionally, the burner blocks suffer from chemical erosion, due to the increased amount of scrap used in the charging mix and the presence of slag inside the furnace. Alternative materials such as stainless steel for the flame holder and alumina-chromia refractory for the burner block have been tested in terms of life-time and resistance on chemical erosion. Furthermore, additional changes have been made on the burner block design in order to alter the flame shape and improve the scrap melting operation.

Jan 1, 2007

By Sanjeeva Latchireddi

"Deteriorating ore grade and high demand of metals has tremendously influenced the unit capacity of SAG mills. Pebble circuits have been added to the existing SAG circuits to increase their unit capacity. To make the pebble circuits justifiable, the grate openings are increased almost to 4.5 inches to draw large quantity of pebbles. The inherent transportation problems associated with SAG mills in closed circuit with pebble fraction are more complicated than the single stage SAG mill operation, because the coarse pebbles behave significantly different to that of slurry in pulp lifters. In addition, operation of mills at higher speed, to take advantage of precise design of high release angled shell lifters significantly reduces the discharge efficiency of the conventional pulp dischargers. The presence of a sizable quantity of pebbles in the pulp lifter limits the space available and reduces the flow gradient through the grate thus increases the load inside the mill and hence the mill power-draw. This paper analyses all the problems associated in discharge of slurry and pebbles in SAG mills with pebble circuits. The Outokumpu patented Turbo Pulp Lifter (TPLTM) aims at eliminating the inherent material transport problems to ensure good grinding conditions. Recent installation of TPLTM in a 26-ft SAG mill has proven these claims by reducing the specific power consumption while increasing the mill capacity.INTRODUCTIONThe conventional wisdom is to look at the semi-autogenous grinding (SAG) mill as just another grinding mill in which ball charge, mill filling, and mill speed are varied to attain maximum throughput. Liner design for the SAG was also approached more from a wear perspective rather than a metallurgical and hydraulic-flow perspective. The extensive research work carried out by Latchireddi and Morrell (1997,2003a and 2003b) has demonstrated to think of the SAG as more of a pump in which the grates and pulp discharger end (“impeller”) were designed to efficiently discharge the product sized particles smaller than the grate size with minimal recirculation out of the mill.The rock load in the mill is essentially depends on ore characteristics and the discharge rate of broken particles. The discharge rate of the product material depends on how efficiently the discharge pump (grate and pulp lifters) is operating. Similar to the impeller design affecting the pump capacity, the pulp lifter design affects the discharge capacity (or mill throughput) of the SAG/AG grinding mills. The general arrangement of AG/SAG mills discharge system is shown in Figure 1."

Jan 1, 2007

By R. W. Lawrence

"In the past year, BioteQ Environmental Technologies Inc. have initiated design and construction of new plants to add to an existing list of plants that utilize the BioSulphide® and ChemSulphide™ process technologies for metal recovery and water treatment. In these plants, low cost biogenic sulfide or, in some cases, chemical sulfide reagent is used to selectively remove metals from contaminated water. The process produces high grade, marketable, metal sulfide products even from low grade feed solutions. The revenues generated from the sale of products can allow for water treatment at a profit in some cases, offset treatment costs in others, and generally reduce sludge disposal and management costs. The effluents produced from the process can meet stringent environmental standards. Current plants in operation and under construction range in sulphide demand from 50 kg/day to 3.7 tonnes/day, with the feasibility of larger plants with sulfide demands ranging from 6 to 43 tonnes/day under review.Biogenic sulfide reagent can also be considered for other applications in hydrometallurgy and mineral processing. Uses under consideration by a number of mining companies include: (1) replacement of sodium hydrosulphide in the SART process for cyanide regeneration and copper recovery in the processing of gold-copper ores, and (2) replacement of sodium hydrosulphide for use in the separation of copper and molybdenum in flotation. Biogenic sulphide, produced on demand at site, offers significant cost savings and provides the additional benefit of improved safety due to the elimination of the transportation, handling and storage required for chemical sulphide reagents.This paper reviews the applications of the BioSulphide® and ChemSulphide™ technologies for water treatment and metal recovery, and introduces projects where biogenic sulfide can be applied in hydrometallurgy and mineral processing."

Jan 1, 2007

By Renaud Adams, Vladimir Salatic

"The El Mochito Mine located in Honduras, Central America, has produced lead, zinc and silver in concentrates since the 1950s. The paper discusses changes made in both lead and zinc circuits to reduce costs while maintaining production during the recent period of low metal prices.The intent of this paper is to show that sometimes thinking “outside the box” is beneficial for progress. Also, in striving for better metallurgical results we should not forget the basics of flotation. Sometimes the latest trends may not be applicable to the ore we are treating and may not meet the operating cost constraints.A major beneficial impact on El Mochito metallurgy was achieved when the overall grind was coarsened, eliminating the significant percentage of slimes. Switching from two parallel twostage grinding circuits to one circuit with three-stage series grinding has resulted in a significant reduction in power and steel consumption. With minor layout/reagent modifications, both lead and zinc circuits gained not only in retention time but as well in producing better grade products.Of course, the challenges are still there; they exist and only with the full support of operational data collection and metallurgical laboratory investigation success can come. That is why, we as professionals, can never stop in trying to make the most of what we have.INTRODUCTIONThe El Mochito Mine is owned by American Pacific Honduras S.A. de C.V. (AMPAC) a subsidiary of Breakwater Resources Ltd. Of Toronto, Canada. The mine is located in western Honduras, approximately 220 kilometers northwest of the capital city, Tegucigalpa and 90 kilometers south of the country’s second largest city, San Pedro Sula. The mine began operating in 1948 and to date has produced more than 19 million tonnes grading 240 g/t Ag, 3.5% Pb and 7.4% Zn. Production in 2005 was 700,190 tonnes grading 87 g/t Ag, 1.85% Pb and 6.61% Zn.Decreasing metal content in the ore followed by the lowest zinc price on the market in the last 15 years (see Figure 1) has reduced the cash flow and endangered to stop the operation."

Jan 1, 2007

By H. Kuboyama

The synergistic effects of polymer additives such as gelatin and polyethylene glycol) (PEG) and Cl- on Cu electrodeposition have been investigated by measuring the polarization curves for Cu deposition, by rotating ring-disk electrode technique and by AC impedance measurements. The cathode potential for Cu deposition was greatly polarized in solutions containing both Cl- and gelatin or PEG, showing evident synergistic effect of polymer additives and Cl- on Cu deposition. The cathode potential was shifted to the less noble direction with increasing the concentration of Cl- in solutions containing polymer additives and showed the maximum polarization at Cl- concentration range between 0.1 and 1 mmol/L. The rotating ring-disk electrode technique revealed that Cu deposition in solutions containing small amounts of Cl- proceeded with initial formation of adsorbed intermediate CuClad. The Cole-Cole plots obtained by AC impedance techniques suggest that the reduction of CuClad is suppressed by polymer additives. The morphology of Cu deposited from solutions containing both PEG and Cl- showed the compacted surface composed of smaller grains due to an increase in the overpotential for Cu deposition.

Jan 1, 2007

By F. Parada, R. Parra

"The neutralization process of SO2 from coal burning plants is a well-defined technology using limestone to form CaSO4 according to the following reaction: CaCO3 + SO2(g) + 1/2O2(g) = CaSO4 This paper presents the results of a study carried out to validate the option of capturing SO2 using gases from a non-ferrous smelter; SO2 content was up to 12% using a three-stage fluidized bed reactor. The difference in SO2 content affects equilibrium conditions and kinetics, rendering a direct extrapolation of the high efficiency achieved for low SO2 content impossible. The R&D program consisted of a laboratory study using a semi-pilot operation of a one-stage fluidized bed reactor and the construction and operation of a three-step reactor prototype. Results show that the reaction proceeds according to the unreacted core model that imposes a compromise between CaCO3 conversion and SO2 capture. For high SO2 capture, the calcine from the reactor contained CaSO4 and CaO. A complete capture of SO2 from gases with 8 vol.% can be achieved with a mean reaction time of two hours at 800°C."

Jan 1, 2007

By Peter Barker, Terry Jones

"The Kelsey Centrifugal Jig (KCJ) utilizes the application of centrifugal force (and the resultant enhanced gravitational field) to conventional jigging technology principles to successfully and efficiently process materials where the valuable constituent particulates are very fine and/or where there is a small specific gravity differential between these and the gangue minerals.The KCJ is applicable to a broad range of fine mineral recovery duties, with current installations in the mineral sands, tin, tantalum, gold and nickel industries. Other areas of application are being developed with mineral commodities including tungsten, base metals, iron ore, chromite and apatite/feldspar.Information on the principles of operation of the KCJ, typical performance figures in a number of application areas, comparison to centrifugal concentrators, key elements for a successful KCJ operation and recent developments with the KCJ are presented in this paper to demonstrate the capabilities of the KCJ.INTRODUCTIONAfter a number of years of development by inventor Chris Kelsey, the first commercial KCJ unit was installed at the Renison Bell tin mine in Tasmania, Australia, in 1992. The subsequent decade saw the installation of further KCJ units in applications including tin, tantalum and mineral sands.Development and improvement in KCJ hardware continued and culminated in the introduction of the high-capacity Model J1800 KCJ and standard features such as an automatic screen cleaning system. This opened up further markets and resulted in Model J1800 KCJ installations in the gold and nickel industries, as well as further KCJ installations in the mineral sands and tin industries. In recent years, work has continued on application of the KCJ to many other duties in industries including tungsten, base metals, iron ore, chromite, apatite/feldspar, etc."

Jan 1, 2007