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By Z. S. Abisheva

The Zhezkazgan copper sulfide ore deposit in Kazakhstan contains both rhenium and the rare osmium isotope "osmium-187" (187Os) in the high isotopic purity of 99.4 ± 0.2%. This isotope is believed to have originated as a result of the disintegration of one of the rhenium isotopes, according to the reaction: 187Re75 ?> 1870576 + B- + v~ (where B is a 13-particle, v~ is a 3-disintegration antineutrino). The distribution of osmium and rhenium in metallurgical byproducts produced during the recovery of copper from these ores has been studied and process flowsheets for the processing of rhenium and osmium-containing byproducts have been developed.

Jan 1, 2007

By S. R. Stopic

The EU-financed INTREAT Project (Integrated treatment of industrial wastes to¬wards prevention of regional water resources contamination) addresses the environmental pollution associated with solid and liquid wastes/effluents produced by complex sulphide ore mining and metallurgical activities. The results concerning the electrolytic recovery of cop¬per from effluents formed after mixing of streams from Copper Refining, Precious Metals Plant and Electrolyte Regeneration in the Balkan Area will be shown. The waste water is characterized by low pH values and high contents of heavy metals, such as Cu, Ni, Bi, As, Sb. The majority of these waste water flow untreated into the natural water streams and through the network of existing rivers, which end up in the river Danube. The influence of current density and flow rate on the deposition rate, the quality of copper and the process efficiency will be presented. The full continuous process is based on cells with rotating disc cathodes and represents a pre-treatment step before common neutralisation in a cascade line

Jan 1, 2007

By D. G. Dixon

A novel technology for leaching copper from primary copper concentrates has been developed at UBC. This patented technology takes advantage of the galvanic couple between pyrite and chalcopyrite to ensure rapid and complete oxidation of chalcopyrite under mild conditions in acidic iron sulfate solution, without the need for microbes, ultrafine grinding, or chemical additives such as chloride, nitrate, or surfactants. Copper recoveries of 98% or greater can be achieved at 80°C under atmospheric conditions in as little as 4 hours of residence time. The process is selective for chalcopyrite over pyrite, generates near-quantitative levels of elemental sulfur, and is fully compatible with conventional solvent extraction and electrowinning of LME Grade A copper cathodes. In this paper, the fundamentals of the Galvanox ? process are reviewed, and selected results of batch leaching tests on various concentrate samples are presented and discussed.

Jan 1, 2007

By M. Doucet

The introduction of high-nickel anodes to CCR in 2006 resulted in an increase of nickel in anodic slimes. Removal of the nickel in these slimes to below 3.0% is necessary in order to prevent slag viscosity problems in the subsequent pyrometallurgical step. A lower specification of 0.5% was chosen in order to minimize Ni losses to the slag and to recover this nickel as NiSO4. A 2-stage autoclave process, which was patented by CCR in 1992, was chosen to treat the high nickel slimes. Laboratory and plant?scale tests were performed in 2004 in order to validate the results of this process with the present slimes. These results along with corrosion tests were used to design two brick-lined autoclaves. These autoclaves were installed in October 2006 and successfully commissioned within 8 weeks. A "Design of Experiment" test program was performed in 2006 on an alternative autoclave process that reversed the cycles in the patented process. The effects of temperature and acid content were modeled using the results. The alternative process will be validated with the new autoclaves.

Jan 1, 2007

By S. Asano

Hydrometallurgical processes for treating copper sulfide concentrates have attracted considerable attention over thirty years and many processes have been developed. However there have been still problems in those processes because of difficulties of iron removal and high purity copper production with low operating cost. Although SX-EW is highly cost effective method, it is difficult to process the chalcopyrite. Sumitomo Metal Mining Co., Ltd. (SMM) conducted a review of hydrometallurgical copper concentrate processing and has successfully developed a novel process for the hydrometallurgical production of copper from copper concentrate. In this process, copper sulfide is leached by chlorine gas under atmospheric pressure. Most of hydro metallurgical processes can leach only some of chalcopyrite under atmospheric pressure then they need high pressure leaching facility like autoclave. In this process, copper in chalcopyrite can be leached completely by controlling oxidation reduction potential and chloride ion concentration. Cu(I) ion in leached liquor is separated from Fe(I!) ion by SX using TBP then pure copper powder is produced by electrowinning. Results in batch and continuous testworks and pilot plant tests at Niihama Research Laboratories are presented in this paper. Cu2007

Jan 1, 2007

By M. Potesser

Higher prices for natural gas or oil have motivated the copper industry to reexamine the modes of oxygen and oxy-fuel burner usage at operating plants. With rising energy costs and the growing importance of environmental protection, burner usage and burner operations have become the focus of several investigations and optimization efforts. One possible approach to lower energy usage is through combustion using tonnage oxygen. When such oxygen is used, the flame temperature increases and operational efficiency is improved. As well, with the correct technology, due to the presence of lower levels of harmful substances such as NOx in the off gas, there is improved environmental performance. As regards copper production, furnaces are employed for both concentrate smelting or for melting and casting operations. The use of tonnage oxygen in concentrate burners for smelting provides for a higher thermal efficiency. For furnaces employed for melting, air-operated burners may in fact have an initial advantage because a long radiant flame is typically generated, thus providing for a higher degree of heat transmission. This paper describes the new experimental burner chamber of Messer Austria GmbH which provides for testing of the combustion of natural gas with oxygen or oxygen-enriched air and the use of special water cooling ducts that simulates a metal charge during melting, The operational effectiveness of the burner is determined from temperature and off-gas analysis data. The paper also discusses future trends in burner technologies including a new patented burner. Cu2007 - Volume III (Book 2) The Carlos Diaz Symposium ou Pyrometallurgy Edited by A.E.M. Warner, C.J. Newman, A. Vahed, D.B. George, P.J. Mackey, A. Warczok Toronto, Canada,

Jan 1, 2007

By J. Lui

At its Copper Cliff Smelter, bulk nickel and copper concentrate is processed in two Inca flash furnaces and Peirce Smith converters to produce Bessemer matte containing 0.6%Fe. After slow cooling and Matte Separation, Bessemer matte is converted into three main products using magnetic separation and flotation technology: (1) a nickel containing chalcocite concentrate (MK); (2) two types of copper containing nickel sulfide (ME and MR); (3) metallics (MYN). MK is further processed in the Inca top blowing bottom stirring MK Reactor to produce semi-blister copper containing ~4%Ni and ~3±1 %S. The semi-blister copper is then purified in the multi-purpose vessels (MPV) to produce blister copper by reducing Ni, Fe and S content through oxidation. High melting point NiO is formed inside the MPVs. The accumulation of solid NiO and other oxides requires periodic cleaning by adding reductant and furnace matte, a unique process called "washout" at Inca. For many years, the reductant used for the "washout" process has been 15%Si Ferro-silicon. With increasing cost and limited suppliers for 15%FeSi, alternative reductants were pursued. This paper summarizes the development and commercialization of new alternative reductants for MPV "washout".

Jan 1, 2007

By J. Suarez Condezo, E. Herrera Alarcon

The Ilo Smelter Modernization Project will require treating the slag from the Peirce Smith converters in Slag Cleaning Furnaces using pig iron technology. Currently the slags from the converters show variable magnetite contents. The copper contained in this slag is recovered in Reverberatory Furnaces, where the smelting rate was improved due to the high silica content of the converter slag. Preliminary industrial tests where developed to clean the slag from converters using pig iron. The results showed that the magnetite content has a significant influence in this process. This work describes the actions that are being implemented in the converter operation to control the magnetite content in the slag in order to maintain the high copper recovery of the smelter when the new facilities are commissioned. This task will demand a strong control of both the slag chemistry and converter practices in order to get the copper recovery considered as the design criteria (~97.4%).

Jan 1, 2007

By A. Bezama

For over a decade European countries have addressed contaminated sites by developing technologies for managing both polluted soil and groundwater. This development has not only been driven by health and environmental aspects, but also because of economic pressures, as the remediation and redevelopment of derelict areas can be a meaningful alternative to undeveloped areas for the establishment of new industrial, recreational, housing and service locations. In most developing countries, however, the subject of contaminated sites is a new environmental issue that authorities have recently started to deal with. Among these countries, Chile has just started to prepare the country's legal context as well as to foster the formation of research and investigation groups that will deal with the exploration, investigation and management of contaminated sites. That requires a comprehensive technical, scientific and legal support in this stage. Goal of this article is to present the state-of-the-art technologies for site remediation currently applied in industrialized countries, in order to identify the most interesting approaches that can be implemented within the Chilean situation, especially considering the influence of the copper mining industry on the soil and groundwater quality of the environment surrounding their production facilities.

Jan 1, 2007

By O. Bernal

The Sociedad Minera Cerro Verde S.A.A, a subsidiary of Phelps Dodge Mining Company, operates a copper mining facility located in southern Peru. This "mine-forleach" operation currently produces 90,000 mtpy of copper cathode from secondary sulfide ore utilizing crushing, leaching, solvent extraction and electrowinning processes. The leach solution handling and application rates have undergone constant development over the years. This paper discusses the improvements in leach application designed to: 1) satisfy the needs of the "lixiviant request rate", which requires the use of application rates as low as 3.5 L/h/m2 and as high as 15 Llhlm2 with variable rest periods according to the leach kinetics, and 2) alleviate the poor solution distribution on the surface of the leach heaps inherent to drip emitters. Low application rates result in poor surface solution distribution and the formation of upside down cones of dry, non-leached material in the top meter of stacked ore, with heavy jarosite and iron salt precipitation; moreover, ferric iron is lost as insoluble precipitates. On the other hand, high unit flows associated with poor agglomerate quality can lead to uneven solution flow patterns within the heap leading to solution short-circuits, fines migration, and ponding with adverse effects on acid consumption and recovery.

Jan 1, 2007

By W. Swidzinski

"Zelazny Most" post-flotation copper mine tailings pond is the only place to of storeing wastes for KGHM POLSKA MI EDZ S.A. The flotation tailings is are the main waste stream in copper mining in Poland. Sufficient storage capacity for tailings is crucial for , thus uninterrupted production of copper is crucially related to the possibility of storing wastes in the pond. The pond covers a Its over 14 km2 arca, almost 50 m high dams making this dame this construction one of the largest in the world. The risk assessment of potential damage due to un stable ility loss of dams or environmental contamination, as well as safely constructing damsincrease of dams within the design criteriaprocess, require quick access to a large amount of the monitoring data , which in vast amount have to be monitored, that needs to be analyzed and processed and reported, every day. This In the paper describes the numerical information system "SyZeM" , used for designated to the "Zelazny Most" pond, baseding on the Oracle database and Geographical Information System , to manage the graphical and descriptive data in coherent way., is presented. The main structure of the system, as well as the methodology of storing, processing and reporting the geological, geotechnical, hydrogeological, geophysical, chemical and survey data are shown. The aspects of Optimizing optimal and risk mitigation and safe management of copper wastes and risk mitigation with the help of "SyZeM" are discussed.

Jan 1, 2007

By C. A. Sosa-Blanco

Minera Sabinas in central Mexico treats a complex sulfide ore containing galena, chalcopyrite, sphalerite and argentite as valuable minerals, and in some cases important amounts of non-magnetic pyrrhotite. For high pyrrhotite ores, results obtained by selective flotation showed good grades and recoveries in the lead-copper circuit, but a commercial zinc concentrate could not be produced due to the high floatability of pyrrhotite. When this is the case, an alternative method was proposed to produce a bulk concentrate by flotation which is then leached to recover copper and zinc from liquor in a SX-EW circuit. Leaching was conducted in an autoclave in order to study the effect of temperature and pressure, but bioleaching tests were also conducted. Leaching lead-silver residues were treated by cyanidation in order to recover silver values. The results obtained by selective flotation and by bulk flotation with leaching of the bulk concentrate showed that the latter alternative increased zinc recovery by 30 % with similar recoveries of the other metals.

Jan 1, 2007

By S. Nikolic

"Calcium ferrite slags are currently used in a number of copper-converting processes. Despite the industrial importance of this system the phase equilibria have not been fully investigated. Characterization of this slag system is necessary to improve the control of process parameters, including fluxing and operating temperatures. Recently, a modified experimental method has been developed; this involves rapid quenching of slag samples equilibrated at high temperatures with the resulting phase assemblages analysed using electron probe microanalysis (EPMA). In the present study, experiments were completed under controlled temperatures and oxygen partial pressures using CO/C02 or H2/C02 gas mixtures. The investigated slags were supported during equilibration by a substrate of the primary phase. This technique removes the limitations arising from the use of crucibles and facilitates rapid quenching of the melt. Experiments were carried out at 1200°C and 1250°C (1473 Kand 1523 K) and in the composition range 0-40 wt.% Cu20, 0-25 wt. % CaO and 45-80 wt. % Fe203. Liquidus and solidus data are reported for the primary phase field of spinel between the oxygen partial pressures of 10-4.5 to 1 o- 6-5 atm. The analyzed compositions of liquids and solids are used to construct the phase diagram of ""Cu20"" -CaO-""F ez03"" system in equilibrium with metallic copper at fixed oxygen partial pressures."

Jan 1, 2007

By E. You

The concentrator at Kennecott Utah Copper currently has 4 lines with a configuration of one SAG mill feeding two ball mills. The slurry that reports to each ball mill will vary resulting in an unequal load of material. This configuration contains two separate sumps that receive material from a distribution box relying solely on natural slurry flow to feed each sump. The unequal split to each mill results in one mill receiving a greater amount of material. This will result in the equipment on one mill reaching limitations that may affect product quality and the operation of the equipment near maximum. The parallel mill in this condition will often have additional capacity that can be used but cannot be utilized due to the unequal split. The major consequences of this issue result in reduced throughputs and metal recovery. To resolve this condition an advanced control strategy was implemented to control the split in April of 2002 using equipment that was in place.

Jan 1, 2007

By H. E. Urtubia, C. W. Bailey

"BHP-Billiton’s Minera Escondida Limitada is one of the world’s largest copper producers. It treats a combined 88 million tons of copper ore per year through its two concentrators: Los Colorados and Laguna Seca. Over the past three years, metallurgical sampling has been performed at the Laguna Seca concentrator to calibrate both the JKSimMet and JKSimFloat grinding and flotation simulators. In the past, the calibrated simulators have been used to predict the effect of changes in operating conditions in the grinding and flotation circuits separately. To assist in the development of future processing options, predictions were required of the effect of changing grinding circuit conditions on flotation performance. This was achieved by using an integrated grinding and flotation simulation. The grinding circuit performance was predicted under different operating conditions (such as tonnage rate and product grind size) using JKSimMet, and these results were then used in JKSimFloat to predict the flotation performance for the new grinding circuit product. This combination of the simulators allows both the effects of residence time and grind size on flotation performance to be investigated.This paper presents the first combined grinding and simulation modelling and simulation case study using JKSimMet and JKSimFloat. The modelling and simulation methodologies for the grinding and flotation circuits are discussed along with the circuit simulations that were performed. The simulator predictions are presented in conjunction with independent laboratory results of the new operating conditions. The ability to predict flotation circuit performance based on changes in grinding circuit performance is also discussed. This methodology provides improved predictions of flotation circuit performance when grinding circuit changes (including grinding capacity increases) are made.INTRODUCTIONOver the past decade, the grinding and flotation research groups at the Julius Krutschnitt Minerals Research Centre - JKMRC (Brisbane, Australia), University of Cape Town (Cape Town, South Africa) and McGill University (Montreal, Canada) have been developing a methodology for optimising grinding and flotation plants using actual plant data together with semi-empirical sub-process models. The project is being conducted as part of the Australian Minerals Industry Research Association (AMIRA) P9 Project, titled “The Optimisation of Mineral Processes by Modelling and Simulation”. The project first commenced in 1962 and is currently in its “Nth” phase."

Jan 1, 2007

By G. K. Quainoo

Investigation by researchers on the application of various thermo-mechanical process histories on 6000 series aluminum alloys have found improvements in mechanical properties of these alloys. However, natural aging, which is unavoidable in the automotive processing line, has been found to have deleterious effect on subsequent artificial aging properties in these alloys. In this study, the evolution of yield strength during natural aging modeled by Lloyd and Gupta has been adapted to investigate the effect of cold deformation on the natural aging kinetics in AA61 11 by means of tensile testing, differential scanning calorimeter (DSC) and scanning electron microscopy (SEM). Also, intermetallic particles in the alloy were extracted from the matrix and XRD performed on them to ascertain their composition and their role on the kinetics in the alloy. The results show that cold work effect on the natural aging kinetics of AA6111 is in very good agreement with the model proposed by Lloyd and Gupta. The kinetics of natural aging in AA6111 aluminum also decreases with increasing level of cold work. This is attributed to dislocations serving as sinks which consume quenched-in vacancies formed during the early stages of clustering. The phases of the intermetallic particles identified in AA6111 are those of a-A15Mn12Si7 and a-A15MnSi.

Jan 1, 2007

By J. J. Montoro

The influence of blasting on the excavators’ efficiency, defined as mucking rate (amount of rock mucked per unit time) and mean bucket load (amount of rock loaded in each bucket operation), is investigated. Rock characteristics, blasting parameters (drill pattern, explosive energy, and charging), and the excavator’s performance (truck loading time and number of buckets to fill a truck) were monitored in eleven blasts in an open pit iron ore mine. ANFO, ANFO/emulsion blend, and watergel were used in the blasts and the powder factor was varied between 0.98 and 1.45 kg/m3. The mean bucket load is mainly affected by the bucket size, which is independent of the blasting parameters. Besides the relation with the mean bucket load, the mucking rate was found to be positively correlated with the explosive energy, whereas no significant correlation with the rock properties was found. The analysis of the data, together with other published works, suggests a non-monotonic relation of the mucking rate with the powder factor, with a maximum mucking rate at a certain powder factor. This is especially true when the useful work of the explosive per unit rock volume is used rather than the classical mass powder factor and when only the amount of explosive above grade is considered.

Jan 1, 2007

By Ryan Montpellier, Paul Hebert

"Prospecting the Future: Meeting Human Resources Challenges in Canada's Minerals and Metals Sector is a comprehensive sector study of the short- and long-term human resource issues and challenges facing the minerals and metals industry. The study's in-depth assessment of current and emerging human resource needs and gaps served as a foundation for the recommendations designed to maintain the strength of the minerals and metals sector well into the future. The study provides insight and identifies strategies relating to each of the following areas:•,An aging workforce•,Significant retirements on the horizon•,Human resources demand growth•,Supply challenge - education and training programs•,Under-representation of non-traditional groups•,Supply advantage - attractive features of mining•,Supply and demand gap"

Jan 1, 2007

By J. M. Menacho

As usually occurs in technological development, heap leaching knowledge has been built upon two parallel lanes, theory developed on fundamentals but relatively far from industrial applications, and operational know-how generated from empirical trial and error. As a contribution to close the gap between the above-mentioned lanes, the De Re Metallica process consulting group has been developing and applying fundamentalsbased modeling tools for industrial process design and process optimization of existing plants over the last ten years. As result, a library of models is now available with application to the whole production chain from blasting to electro winning. This presentation is centered in heap leaching and several real case studies are developed, showing how paradigms are broken when fundamentals are applied. Cu2007 - Volume IV (Book 1) The John E. Dutrizac International Symposium on Copper Hydrometallurgy Edited by P.A. Riveros, D.G. Dixon, D.B. Dreisinger, M.J. Collins Toronto, Canada,

Jan 1, 2007

By J. Schmidt

Cold drawing of copper wire rod is usually combined with an in-line annealing process to adjust the ductile microstructure of the wire again. One important key factor for successful annealing is the quality of the copper itself. Rod producers can check the recrystallization behaviour of the rod by different methods: chemical analysis, Spiral Elongation Test (SEN) as well as the Rapid Elongation Test (AR) are some examples of common testing methods. The comparison of the results of these methods does not always show sufficient correlations. The paper introduces firstly the SEN and AR-Tests and their different approaches to the mentioned task. The second step is to compare some results of the SEN-Test with the results of the AR-Test and identify causes of deviations. Thirdly, the effect of pre-annealing is discussed, which is especially common for wire rod with diameters of more than 8 mm.

Jan 1, 2007