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By K. Krishnapisharody, S. Clark, M. Barati

Different gas purging methods to metallurgical baths have been applied to date, among which are top lancing and bottom blowing through tuyeres or porous plugs. Among these, the porous plug bottom blowing technique has shown higher efficiency in gas utilization than tuyeres and top blowing, due to smaller bubble size and lower liquid velocity. However, the studies related to bottom stirring of metallurgical baths are limited to slag-less or thin slag-covered melts. In particular, there is no examination of stirring ability in conditions similar to Falconbridge's Slag Make Converter, where the bath is covered with a thick slag layer and a stream of solids is charged on the bath from top. This study was undertaken to investigate the application of gas purging through a porous plug in stirring in and melting of the solid feeds. The spreading behaviour and melting time of a solid layer forming on a plume created by stirring were calculated using the existing models. The results show that formation of a thick solid layer, specifically in areas beyond the plume region is very likely. Nevertheless, the thickness of the layer and melting time do not appear unreasonably high. It is predicted that by proper controlling of gas flowrate and plug configurations, successful solid charging through the mouth can be practiced.

Jan 1, 2007

By K. C. Sole

In most copper solvent-extraction operations, an important consideration in choice of extractant is the requirement for high selectivity of copper over iron. Ester-modified aldoxime extractants presently offer the best Cu:Fe selectivity. In some plants, however, the process feed liquors contain significant amounts of manganese but little iron. Although manganese is not chemically extracted by oximes, trace amounts are carried over to the electrowinning circuit by physical entrainment. This may result in anodic oxidation of manganese which, in turn, can cause oxidative degradation of the organic phase when returned to the solvent-extraction circuit in the spent electrolyte. Many of these operations prefer to operate with higher levels of iron reporting to the advance electrolyte, as appropriate control of the Fe(II)/Fe(III) couple will ensure that manganese remains in the benign Mn(II) form. A new reagent, LS 4202, designed by Cytec, now offers the possibility of tailoring the iron co-extraction, so that appropriate Cu:Fe selectivity can be achieved in the solvent-extraction operation to maintain an electrolyte Fe:Mn mass ratio of >10:1, while retaining the other benefits offered by ester-modified aldoximes. The results of an integrated solvent extraction-electrowinning pilot-plant trial are presented, in which the performances of the conventional extractants ACORGA® M.5774 and LIX® 984N are compared with LS 4202. The Cu:Fe selectivity is demonstrated, along with results on the transfer of other impurities to the advance electrolyte.

Jan 1, 2007

By Sunil Koppalkar, A. R. Laplante

"A Pilot Plant was installed in one of the grinding circuits of the Dome Mill, Ontario, Canada. Tests were conducted on a KCCD12 Knelson Concentrator to systematically analyze the effect of operating variables on the performance. The main objective of this test work was to explore the effect of very coarse (6 mm) feed size on GRG recovery and performance of the Knelson concentrator. Preliminary results have shown that coarse feed size is deleterious to maximizing recovery. Size-by-size GRG recoveries have shown an unusual trend in the sense that recoveries do not decrease monotonically with decreasing gold particle size. Similar trend observed in one other full-scale unit has been compared. The observed trend is probably linked to the feed size distribution and top size.INTRODUCTIONKnelson Concentrators are the most widely used semi-continues centrifuge gravity separation units for the recovery of gold and platinum group minerals (Xiao and Laplante 2004). The main advantages over the competing centrifugal gravity units are their design, operating simplicity and good separation efficiency that make them the most common choice for gravity circuit. Despite some characterization at bench scale and a limited characterization at full scale, there is a lack of a comprehensive study of impact of operating variables on efficiency that reflects realistic full scale operating practice. GRG characterization studies, at bench scale, on these units provide information about the occurrence of gold in ore samples but fail to provide adequate information about the effect of operating variables for full-scale units. It is well known fact that such work is difficult to undertake on full-scale units owing to the difficulties involved in sampling and systematic variation of operating parameters. To tackle these problems, a pilot facility consisting of a 12-in CD Knelson Concentrator, a feed screen and tailing pump was installed in one of the grinding circuits of Dome Mill. This paper describes the work carried out and the results.Porcupine Joint Venture (PJV)Porcupine Joint Venture was formed in 2002 between Placer Dome Inc. and Kinross Gold Corporation. The JV utilizes the milling capacity of the Dome Mill to process ore from Placer Dome and Kinross mines. The Dome Mill circuit has gravity concentration, cyanidation and CIP circuits to recover gold. Gravity recovery has been used at Dome Mill since inception to recover gold: first by using conventional jigs, which were eventually replaced by two Knelson Concentrators in 1993, one in each of the grinding circuits. Three more Knelsons joined the circuit in 2002 to improve gravity recovery. An Acacia Intensive Leach Reactor was also added in 2002 to process gold concentrates replacing shaking tables (Chong et al 2004)."

Jan 1, 2007

By L. Tapia

The main disturbance for stability in primary grinding using SAG mills is related to continuous changes in the ore being fed to the plant, such as size and hardness. Searching for stability is the first step to accomplish, before trying to maximize the mill throughput. The time variability in the characteristics of the ore being fed from the mine to the plant must be known or inferred to perform adaptive changes in the grinding process control. In day to day operation, such information is not available in real time. Transport times and inventories between the mine and the plant complicate the situation. Under this scenario, Minera Los Pelambres implemented a grinding optimization strategy, based on the real time analysis of certain process variables, such as ore size, mill current consumption, pebble generation and throughput. As a result, both grindability and stability indexes are inferred. This is equivalent to inferring the ore characteristics by knowing its effect on the grinding behavior. These two indexes permit control of the SAG mill total charge level and hence, allow optimization of throughput by means of an expert control system.

Jan 1, 2007

By M. Sheedy

This paper discusses the short bed ion exchange technique for the removal of metal contaminants from copper electrolyte bleed streams. Processes for the selective removal of sulfuric acid, arsenic, antimony, bismuth, and iron will be discussed. A case study outlining the performance history of a short bed system for sulfuric acid removal followed by a two stage selective precipitation system producing a nickel carbonate by¬product at the Phelps Dodge Mining Company El Paso operation will be presented.

Jan 1, 2007

By G. B. Harris

A process for the recovery of copper from the waste oxide copper of a mined-out sulphide orebody is described. Hydrometallurgical recovery of copper from this and similar wastes has been tried several times previously without success. Leaching is carried out by sulphuric acid in columns under conditions that minimise the iron content of the pregnant leach liquor, and copper is then recovered by ion exchange rather than the more conventional solvent extraction. The resin is stripped by spent electrolyte and copper is electrowon. Results are presented for testwork originally carried out in 1993, and repeated in 2006, and the novel aspects of the process, leaching and ion exchange, are discussed. Finally, preliminary order of magnitude capital and operating costs are given, demonstrating that the process is cost effective.

Jan 1, 2007

By Sunil Koppalkar, Liming Huang

"Since late 1980s the research group led by late Professor Andre Robert Laplante at McGill University undertook fundamental studies and applied research of the Knelson Concentrator (KC) and developed a sustainable method to correctly estimate gravity recoverable gold (GRG). In the early time a concept of ‘free gold’ was used, it was defined as the gold that could be separated and recovered from gold ore by amalgamation. Due to health and safety hazards, its practical use had declined. Around 1994, a methodology using a 3-in Knelson Concentrator to measure gravity recoverable gold was established at McGill University. Through more than 10 years’ improvement and optimization, this technique had become a standard method to evaluate GRG for gold ores, gold plant streams and platinum group metals. Until 2006, about 200 GRG tests had been carried out at McGill University for the ores from all over the world. Recently, a modified version of GRG test (short test) with the advantages of reduced processing time and lower cost had been developed for the mundane needs of gold industry.INTRODUCTIONGold gravity recovery has evolved significantly over the past twenty-five years, mainly because of the advent of the Knelson Concentrator (Knelson 1988, 1990, 1992, Laplante 2000). Now, a series of Knelson Concentrators for different applications are manufactured and used in gold industry all over the world (Knelson Concentrators 2004).In 1980s the Knelson Concentrator gained acceptance from mining industry as an effective device for the recovery of gold from grinding circuit. Knelson Concentrator became the obvious choice because of its design features: a relatively long processing time without concentrate discharge (compared to some other centrifuges, such as Falcon Concentrator and Chinese Yunxi Centrifuge at that time), large throughput capacity, treating a wide size range of material, yielding a high grade concentrate with small mass that could easily be smelted. As more and more Knelson Concentrators were accepted in gold industry, mineral processing engineers faced with challenges: what are the separation mechanisms of the Knelson Concentrator? How much gold can be extracted for an ore if a Knelson Concentrator is installed? For answering these questions, a laboratory scale Knelson Concentrator was created."

Jan 1, 2007

By S. Theobald

Semi-finished copper and copper-alloy products are typically produced by casting, subsequent hot rolling or extruding and further cold working by rolling and drawing. The technological properties of the products depend not only on the chemical composition of the alloys but also on process parameters such as annealing conditions and degree of deformation. In each production step, measuring and control technology is an important tool for optimizing processes and ensuring constant high quality. This paper follows the product all the way from testing incoming scrap packages, chemical analysis of melts, mould level control in casting, non-destructive testing technologies in cold forming processes, controlling geometrical properties in the production process, to the final tests of technological properties. All test methods are focused on the applications and requirements of our customers, as the examples show.

Jan 1, 2007

By E. Herrera Alarcón, L. Mariscal Samaniego

The Teniente Converter (wet charge type) was commissioned in august 1995 and was designed to smelt 744 tpd (metric tons per day) of dry copper concentrates. Its products are white metal (73% Cu) that is sent to the Peirce Smith converters, slag that is cleaned in Reverberatory Furnaces and the process gases that are sent to the Sulfuric Acid Plant. Since its start up, the Teniente Converter smelting capacity was increased 1.6 times, from 800 tpd to 1,280 tpd using 33% oxygen-enriched air, and reaching an operative availability of 97%. By the other hand its campaigns have reached a record duration of 530 days without hot patching tuyeres and a partial refractory lining repair in the last four campaigns. This paper describes the most relevant improvements, as well as the strategies that had been used to reach these achievements.

Jan 1, 2007

By S. W. Marcuson

In the late 1960's concerns about the natural environment reached high levels within North America and provided activists with suitable platforms for exerting influence over the general public and politicians. In response a host of regulatory mechanisms were developed, statutes, voluntary measures, land grants, codes of practices etc. Emerging environmental awareness from the era provided impetus for rapid technological change that encompassed all industries, especially the base metal business. The resulting clean up impacted all aspects of copper production, dealing with issues such as waste disposal, water and air quality with specific impact on emissions of sulfur dioxide and particulate. This paper provides a perspective of these changes reviewing the macro-economic impact of environmental movement in mining with its specific implications to the copper smelting industry. The fundamental challenges that were faced by the old, but capital-intensive North American plants and the approaches taken to deal with the changing times are reviewed with special emphasis on the conceptual approach to smelter S02 abatement and different paths taken in the USA and Canada. The role of economics, sustainable R&D and presence of technical infrastructure that facilitated the change process is elucidated, and speculations are made about the future state of pyrometallurgy and the natural environment. Cu2007 -

Jan 1, 2007

By P. A. Riveros

This paper describes the leaching of the common copper minerals tennantite (Cu12As4S13), tetrahedrite (Cu12Sb4S13) and enargite (Cu3AsS4) in acidic media using Fe(SO4)1.5, FeC13 or 02 as oxidizing agents. At temperatures <100°C, tennantite dissolves slowly in Fe(SO4)1.5-H2SO4 media, and the rate is directly proportional to the area of the sized tennantite. The rate increases sharply with increasing temperature and the apparent activation energy is 69 kJ/mol. Increasing Fe(SO4)1.5 concentrations slightly increase the tennantite leaching rate. The kinetics of dissolution of disks of synthetic iron-bearing tetrahedrite in Fe(SO4)1.5-H2SO4 media are linear; the leaching rates are slow but increase significantly with increasing temperature, with an apparent activation energy of 120 kJ/mol. The dissolution of sized particles of natural Ag-bearing tetrahedrite in FeC13- HC1 solutions proceeds according to the shrinking core model, and both Cu and Ag dissolve at about the same rate, provided that the total chloride concentration of the solution is sufficiently high to solubilize the AgC1 reaction product. The leaching rates are slow, and the apparent activation energy is 116 kJ/mol. The addition of sulphate ions to the FeC13-HC1 system reduces the tetrahedrite leaching rate to values similar to those realized in the Fe(SO4)1.5-H2SO4 system. At <100°C, enargite dissolves slowly in either Fe(SO4)1.5 or FeC13 media, and the dissolution rate obeys the shrinking core model. The rate increases with increasing temperature and the apparent activation energies are 50-64 kJ/mol. The rate increases slightly with increasing FeC13 concentrations in 0.3 M HC1 media. The leaching of enargite at elevated temperatures and pressures was also investigated. Potentially useful leaching rates are achieved above 170°C, at which temperature sulphate, rather than sulphur, is produced. Lower temperatures (130-160°C) lead to fast initial leaching rates, but the dissolution of the enargite is incomplete because of the coating of the enargite particles by elemental sulphur.

Jan 1, 2007

By T. Velea

The most widespread methods for producing metallic copper are smelting of copper sulphide concentrates (which generates various types of polluting substances) and the hydrometallurgical route which consists of leaching in sulphate and chloride media (usually employing high temperature, high-pressure and special equipments). This paper presents a process, called VEPE, which consists of oxidizing copper sulphide concentrates in weak alkaline media (Na2C03 orland NaOH solutions), under low pressure and with air sparging. The oxidized concentrate contains less than 0.4% S. Copper is recovered from the oxidized concentrate by the standard leaching-solvent extraction-electrowinning route, with a total efficiency of 98% extraction. The proposed technology could represent a good opportunity to recover copper from sulphide concentrates in a clean, simple and profitable way.

Jan 1, 2007

By M. Bigdeli Karimi

In this study, the effect of strain level and holding time in semisolid temperature range via SIMA process on AS21 Mg alloy was investigated. Some cylindrical samples of this alloy with 1cm in height and 2.5cm in diameter (H/D=0.4) were compressed to 10%, 20%, 30% and 40% at 300-C. Then, the samples were reheated in semisolid temperature range at 614°C for various times. The results of optical microscopy and image analysis showed that with increasing of strain and holding time, dendritic structure changed to equi-axed structure, gradually. Also, the best conditions to obtain good globular structure were achieved. Furthermore, it was seen that after compression and reheating, Mg2Si intermetallics with Chinese script morphology converted to dispersed-fine particles which were distributed into the ci-Mg grains.

Jan 1, 2007

By J-L. Tang

A new rhcoforming processing of Al alloys with component shaping systems apart from slurry preparation systems is experimentally exploited, using the reversible multilevel-speed electromagnetic stirrer, the slurry transfer tool and its coating, the thin plate sample with five steps and rheocasting mould, all of which are independently developed. The results show that semi-solid A356 alloy slurry with shape factor of about 0.85 and particle size of 70~80 µm (under air-cooling condition) could be prepared in 20~25 s, fully meeting the production rate of high pressure die casting. The slurry could be smoothly transferred from the slurry preparation equipment to the rheocasting shot chamber while the slurry temperature of slurry decreases by no more than 3 . The tensile strength and elongation of the semi-solid rheocasting samples could be respectively increased by 11.6~18.2 % and 42.5~50 % compared with the traditional liquid die casting ones, and the rheoforming processing has close affinity with the traditional hot working processes.

Jan 1, 2007

By C. Phan

This paper outlines opportunities provided for enhanced management and process control by ISA PROCESSTM technology. ISA PROCESSTM technology has the core advantage of offering the potential for vastly improved electrode handling systems. This fundamental characteristic has enabled ISA PROCESSTM technology to develop management and process control systems that are modular, minimalist in their complexity and tailored to a tankhouse operating environment. A review will be presented on the current status of management and process control in ISA PROCESSTM tankhouses covering the central issue of electrode handling as well as electrolyte circulation systems, voltage monitoring, cathode plate tracking, and product tracking. Particular reference will be made of the recent development by Xstrata Technology (XT) and their technology partners, VRT Systems, of an Radio Frequency Identification (RFID) based solution for tracking ISA PROCESSTM cathode plates. The system encompasses fixed readers which identify plates passing through the stripping machines and the use of sophisticated tracking and database software enabling the development of cathode asset management and operational strategies. The performance of individual plates and batches of plates can be tracked through a full service history.

Jan 1, 2007

A line of nine self-aspirating W emco cells, part of the Rougher circuit at Division Salvador, Codelco Chile, was retrofitted to allow operation with forced air. Each cell could be operated self-aspirated or with compressed air supplied through a 4-inch line equipped with a mass flow meter. Gas dispersion was characterized for the two modes of operation. Metallurgical performance was compared under self-aspirated conditions and with different gas profiles under forced air conditions. Cell characterization demonstrated that with forced-air the cells could not evenly distribute air across the cell volume. Bubble size increased with gas velocity, as expected, with no difference between self-aspirated and forced-air operation. A systematic increase in bubble size down the bank was found. Cumulative bubble surface area flux down the bank showed no major differences between surveys. However, grade-recovery curves revealed that the highest recoveries were invariably obtained with forced air operation. Plotting concentrate mass recovery vs. enrichment ratio showed that the line performance could be controlled over a wider range when forced air was used.

Jan 1, 2007

By R. Ramirez

Atlantic Copper Refinery (Huelva, Spain) has operated the ISA permanent cathode technology since 1995. The current production rates are 260,000 t/y cathodes and 730 t/y anode slimes. These slimes undergo an atmospheric leaching in which their copper content is reduced from an average value of 24 % to 16 %. In June 2005 an optimization study of the leaching conditions was carried out aimed at lowering the copper content in the slimes to less than 8%. At the same time, a new mixer (Outukumpu Technology GLS-mixer) was installed in one of the three leaching reactors. As a result of the improvement of the leaching performance and to prevent the return of tellurium to the tankhouse, a cementation plant was commissioned in July 2005 to ensure a Te content below 50 ppm in the Cu-rich leachate. This paper describes the results of the improvement of the leaching conditions and the operation of the new tellurium removal plant.

Jan 1, 2007

By R. von Gal

Hazelett Strip-Casting Corporation has been producing the Hazelett® twin-belt casting machines for copper casting since the mid-1960s. The first commercial casters were developed for copper alloy strip and anode plate. In 1968, development work was started to adapt the twin-belt caster for copper bar casting to be rolled in-line into wire rod. Since then, 36 casters have been sold as part of the CONTIROD® system for the production of a substantial portion of the world&apos;s copper rod supply. A unique feature of the twin-belt caster is the mold&apos;s ability to comply with the size and shape of the cast bar as it shrinks during solidification. Maintaining contact between the mold and the bar provides a high rate of heat transfer as well as other benefits, including the prevention of surface imperfections caused by remelting in the mold. This paper will give an overview of the continuous evolution of the twin-belt caster technology with an emphasis on recent developments in compliant mold technology for copper casting.

Jan 1, 2007

By K. Yamaguchi

To contribute highly efficient and environmentally conscious copper smelting process, several topics in chemistry of the continuous converting were discussed. Through the reviewing the authors&apos; thermodynamic simulations, it is recognized that small amount and low copper content of the coexisting slag is preferable. Some discussions were added to the Takeda&apos;s diagram for Cu20-FeOx-CaO ferrite slag, and the activity curves of the constituents were derived. Thermodynamic calculations were carried out on the copper contents of the slag during the blister copper formation. The dissolution of copper in slag decrease somewhat with increasing temperature, but the effects of increasing S02 pressure and decreasing %S in copper are considerable to increase in copper content of the slag. The optimum oxygen enrichment in the supplied air, and regulation of the oxidation degree for the blister copper are important in practice. The gypsum phase separation in the calcium ferrite slag was also evaluated thermodynamically, and concluded that decreasing temperature, increasing CaO content or S02 pressure, and extensive oxidation of the blister copper tend to separate CaS04.

Jan 1, 2007

By C. Caballero, K. Itagaki, P. Morales, A. Moyano, J. Font

Codelco-Chile is considering different processing options for the new projected concentrate from the Alejandro Hales mine. This concentrate is featured by its high arsenic content of up to 6%. Thus, it is important for Codelco Norte Smelter to define the technical feasibility for processing this high-arsenic bearing concentrate in its main smelting unit as it is the Teniente Converter, which beside of its dual feeding system can enhance the arsenic removal by volatilization. The present paper which is a part of an extensive research work will focus in the performed industrial scale test for processing about 7,000 tonnes of a high-arsenic bearing concentrates in the Teniente Converter at the processing rate of about 2,300 tpd. The impact on the chemical quality of the produced high grade matte will be discussed, and the effect of the As removal by increasing the Teniente Converter processing rate of concentrates up to 3,000 tpd when producing 70% Cu in the white metal will also be addressed.

Jan 1, 2007