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By Namavari. H., M. Ashouri, M. R. Sarhadi, S. H. Mansouri, A. Sarrafi

The splash phenomenon and its effective parameters in metallurgical converters have been studied thoroughly for decades. The detailed studies of processes such as tuyere blockage, wave formation during air injection, entrapped phases, and also processes which control the formation of bubbles in viscous fluids are not feasible yet. In this research, we have used a converter-shaped vessel made of flexi-glass. Water and oil have been used as matte and slag phases respectively. The effective operational factors responsible for creation of splashing have been studied such as air flow rate, tuyere angles, depth of tuyere submergence, tuyere blockage, density and viscosity of liquids, liquids heights, etc. The results have been found as follows: the amount of splashing increases slowly as air flow rate increases. However, as the air flow rate reaches a critical value (depending on the physical specification of converter) the amount of splashing rises sharply, because the flow of air inside the liquid changes from bubbling into a jet stream; and most of the splashed materials are in the form of filaments instead of droplets. Changing tuyere angle from horizontal towards vertical position will increase the turbulence level on the fluid surface and causes an increase in the amount of splashing. The effect of tuyere submergence is related to the converter opening angle. As the converter opening angle is shifted towards the hood position, the amount of tuyere submergence and splashing will increase. As density of the liquid increases, the number of droplets splashing increases with a decrease in drop size. Therefore, the total amount of splashing decreases. However, as viscosity of the liquid increases, the splashing material increases due to the changes in the splashed material from droplet shape into filament form. The height of liquid inside the converter, depending on the relative height of heavy phase and light phase, is an important parameter regarding splashing. As the relative height of heavy phase to light phase increases the splashing will decrease. The tuyere blockage will cause the pressure in the inlet manifold to increase; and in real cases will increase the splashing. Finally, we have development a model based on dimensional analysis to relate the above parameters in order to calculate the amount of splashed material.

Jan 1, 2007

By T. Beamish, I. Vasilev, T. Nikolov, E. Marinov, D. Kirilov, P. Barrios

In April 2005, Umicore Copper de-merged from Umicore Group and created a new independent Copper company called Cumerio. As a separate company, Cumerio is a major European copper smelter and refinery and a leading producer of copper products such as wire rod, billets, cakes and specialty rod with a total production capacity of copper products in excess of 500,000 tpy with production plants in Belgium, Italy and Bulgaria. The Pirdop Smelter is the only state-of the-art smelter in South East Europe and it makes Pirdop the natural hub for the copper industry in the region. In order to be competitive in the international market the main challenges facing Cumerio are to maintain its low cost structure and to achieve higher production volumes while reducing its impact to the environment and striving for continuous improvement of the production process. Cumerio's state-of-the-art smelting facility in Pirdop has recently increased the anode production capacity to 250,000 tpy by the installation of the third evaporative cooler on the converters section that allows operating with three-hot converters. In April 2007 a general shut-down for repair and modification on the Flash Smelting Furnace and Waste Heat Boiler is envisaged. At this time a revamp of one of the existing Sulphuric Acid Plants is planned, resulting in a further copper capacity increase to 275,000 tpy with modest Capex. In 2005 Cumerio received from the Bulgarian Ministry of Environment and Water the Complex Permit under the EU IPPC criteria. Accordingly an Environmental Compliance Program was defined targeting a large reduction in the secondary emissions. The system will be commissioned in May 2007. In order to better integrate the smelter and refinery in Pirdop and to respond to the growing demand for cathodes in the region, a new state-of-the-art Electrolytic Refinery with an installed capacity of 180,000 tpy will replace the existing refinery. The new refinery is expected to be fully operational as from early 2008. This paper describes the challenges and the projects.

Jan 1, 2007

By E. Esmaeilzadeh

There arc 8 primary ball mills in the concentrator plant and their task is material crushing. At the time of balls charge to mills, a lot of noise is produced. This noise would affect all grinding areas. The aim of this research was a reduction about 16 dB at source sound power level (SWL was 129.1 dB). With considering two noise control principles, noise producer sources and propagation paths were specified. For removing and reducing of noise producer sources, rubbers with a thickness of 5-20 mm were used on the all inside surfaces of charge box, ball transferring box and exit canal. For increasing transmission loss and damping coefficient of charge box body, rubber with thickness of 1 cm at outside surface of box was used. For reduction of noise propagation a secondary metal cover was designed and made. This cover includes two parts and was set around the charge box. Glass wool (75 kg/m3) with 10 cm thickness was used as acoustical absorbent between free space of two body's layers and from secondary cover side. The of the rest space was left empty. After installing of secondary cover on the ball charge box no.4, SWL showed a reduction about 16 dB. For studying of control system effect on noise reduction at points far from of charge place, measuring results at these points showed the maximum reduction 12.1 dB and the minimum 11.8 dB.

Jan 1, 2007

By C. Caballero, M. Rosales, C. León, A. Valencia, R. Fuentes, A. Moyano

Slopping is the formation of waves in the converter due to the gas injection by tuyeres. Those waves produce a premature wearing of the refractory lining of the reactor due to its great amplitude. The affected zones are the tuyere line (outlet gas from tuyeres) and the front of this line. In the present work, a theoretical and experimental study is made to develop a theory that determines the variables involved in slopping, characterizing the more important parameters of operation in the phenomenon of slopping. In addition, this theory will allow for determination of new technological alternatives of the blast injection permitting to depress the slopping phenomenon.

Jan 1, 2007

By M. Gruber-Pretzler

Technical Sn- bronzes tend to form both macrosegregations and microsegrega¬tions during DC-casting due to the particular thermodynamic properties and kinetics of phase transformation. As a result a heterogeneous cast microstructure forms that is some¬times a reason for a decrease in workability. The extent of macrosegregations in DC-casting can effectively be influenced by casting parameters like casting velocity, primary cooling or inlet geometry which in fact change the relative flow between the melt and the forming solid. In order to understand the influence and interaction of the related phenom¬ena, simulation methods are applied. The solidification of the strand as well as the forma¬tion of macrosegregation are simulated with a two phase volume averaging model. The velocity field of the melt flow is explicitly calculated by solving the corresponding mo¬mentum conservation equations. Within the mushy zone the local formation of microseg¬regations in the presence of feeding flow is estimated. The thermodynamics of the Cu-Sn system is accounted for and it is distinguished explicitly between interface and average concentrations. To investigate the influence of feeding flow on the formation of mac-rosegregations, a study has been performed. Based on this result, the phenomena of mac¬rosegregations are described in a detailed discussion.

Jan 1, 2007

By A. Haldar

This study focuses on the flow characteristics of hypereutectic Al-Si alloys in thin sections. The pattern assembly consisted of spiral horizontal patterns, 6.25 mm (0.25 inch) and 12.50 mm (0.50 inch) in thickness with a common sprue. Al-Si alloys with silicon levels of 14%, 18% and 22% were poured with superheats of 60°C, 115°C and 170°C. It was observed that metal fluidity (in terms of flow length and metal velocity) increased with increase in silicon levels and superheat for both section thicknesses. It was also observed that, for a section thickness of 6.25 mm (0.25 inch), silicon level had more pronounced effect on the metal fluidity. For 12.50 mm (0.50 inch) thickness, both silicon level and superheat affected the metal fluidity. The surface hardness of the castings increased with an increase in silicon level of the alloys at the gate and the flow tip. Detailed study of the flow tip was also carried out with a view to understanding the effect of silicon level and superheat on undulated flow length, surface hardness and microstructure.

Jan 1, 2007

By J. Contreras

In the period 2003-2004, the situation of the copper concentrate market was unfavourable for smelters and refineries, with low TC/RC values and euro-dollar parity affecting European companies negatively. Within this scenario, Atlantic Copper decided to develop a plan to increase its competitiveness and to improve its results in these market circumstances. The plan affected all departments in the Company and was based mainly on cost reduction in energy and manpower. A general analysis of the Complex's overall efficiency was carried out and, based on this analysis, two major Projects emerged, "Primavera" and "KF". Each Project consisted of smaller sub-projects which aimed at improving the areas which could perform better according to our general analysis. The paper describes how this entire project developed and the final results obtained by the Company.

Jan 1, 2007

By D. M. Aloi

In today's evolving and globalized world, mining companies are being pressured to move beyond compliance towards long-term sustainability and sustainable development. Companies are expected to "engage" with communities and measure the success of these engagements without a clear understanding of "how" to do this. This move, away from "Corporate" Social Responsibility (CSR) and compliance, develops more of a focus on "Community" Social Responsibility and sustainability. This shift in focus leads to the development of world-class projects that provide sustainable development for people, reduces the incidence of costly delays, and promotes good global citizenship for corporations. The process of "engaging" communities in mining project design and development leads to a stronger license to operate and sustainable development. To create this mutually beneficial relationship between communities and companies, communities must be "engaged" in the mining process as early as possible, preferably during the exploration or the concept phases. How to create this "engagement" remains elusive. How to measure the progress of this engagement is also problematic. The quantitative and qualitative metrics needed to measure both positive and negative impacts of the mining and community relationship will be discussed.

Jan 1, 2007

By V. Ramachandran

The successful advent of solvent extraction (SX) reagents for copper recovery and improvements in electrowinning of copper to produce LME grade A copper cathode have paved the way for the hydrometallurgical treatment of copper oxide and low grade sulfide ores. This has resulted in about 25-30% of the world's copper being produced today by the Leach-SX-EW process. The obvious next step was to develop processes for the hydrometallurgical treatment of copper sulfide concentrates, as an alternative to a typical smelter-refinery complex. The current paper updates the processes that have been developed to date with emphasis on processes that are being commercialized or that are seriously under consideration for commercialization. Most of the discussions relate to the hydrometallurgy of chalcopyrite concentrates, which account for about 70% of the world's known copper reserves. In summary, in the last thirty years, the hydrometallurgical treatment of copper sulfide concentrates has attained full maturity and will be a serious option to contend with while evaluating any future new copper plant.

Jan 1, 2007

By O. C. Rojas, J. Sanhueza, J. C. Vargas

Empresa Nacional de Minería (ENAMI) is dedicated to the promotion of small and mid scale Chilean mining industry. Paipote, ENAMI Copper Smelter, processes a variety of mineral products as the result of this promotion. The mineral products characterize a wide variation of copper, iron, sulfur and precious metals content as well as the significant dispersion in the content of impurities, such as arsenic, antimony and bismuth. The Smelter Modernization Program, initiated in1997, introduced a series of technological and operational changes. The development of operational planning and control strategies was necessary to optimize the blending of a wide variety of concentrates and the control of metallurgical processes in order to ensure the stable operation, fulfillment of environmental regulations and the quality of produced copper anodes. A permanent optimization process carried out in the last decade led to the permanent increase of the smelting capacity and the production of anodes and sulfuric acid. Additionally, introduced improvements affected the smelter efficiency and metallurgical recovery, demonstrating the possibilities of the optimization of a small smelting facility reflected in good metallurgical and economic results. This paper presents the smelter evolution, introduced technological and process control changes as well as incorporated new reactors and equipment as a continuous process of optimization.

Jan 1, 2007

By M. R. Coffin

In recent years, improved operation of the Kidd smelter has resulted in an increase in blister production capacity. Due to manpower and equipment limitations anode production and treatment rates could not be increased without incurring significant additional operating expenses. The option chosen to expand casting and refinery capacity to meet the available blister supply was to increase the anode thickness while maintaining the same anode exchange cycle in the refinery. This has resulted in a cathode production increase of almost 10% for minimal expenditure. Equipment and process modifications required to cast and refine the thicker anodes are discussed in this paper, along with the Six Sigma methodologies used to identify them. Key areas covered are Hazelett continuous caster operation, refining process parameters, plating performance and cathode quality.

Jan 1, 2007

By K. Yoo

Chalcopyrite is the most abundant copper sulfide mineral, which is normally processed using pyrometallurgical methods (i.e., smelting) to produce copper metal. Smelting has several major disadvantages, such as high gas-handling costs, high capital costs, saturation of sulfuric acid market, and inability to treat low-grade concentrates and to recover some by-products, such as zinc, nickel and cobalt. The development of hydrometallurgical processes for chalcopyrite is desirable to overcome the problems of smelting. Because chalcopyrite is refractory, the leaching rate for chalcopyrite is very low. Therefore, increasing the leaching rate has been extensively investigated, both in sulfate and chloride media, as well as in the presence of bacteria. Chloride leaching processes have shown relatively high leaching rates. The mechanism of the chloride leaching process has been investigated, but the behavior of chalcopyrite leaching in chloride solution is not clear. Therefore, the effect of the solution redox potential on the leaching rate of chalcopyrite in chloride solution was investigated. In the present study, leaching experiments were carried out using 0.1 M chloride solutions and the results indicate that high leaching rates of chalcopyrite can be achieved at relatively low solution redox potentials.

Jan 1, 2007

By D. Allen

Faced with decreasing ore grades and harder ores, many mines today are forced to become more efficient with their approach to processing. Variability in ore hardness, mineral liberation, reagent consumption, sliming, and leach responses are all a function of the minerals present and their concentration. Modern semi-automated X-ray Diffraction (XRD) analyses using Rietveld refinement techniques, in conjunction with high speed quantitative Near Infrared (NIR) analyses, provide reliable quantitative mineralogical ore profiling. By the implementation of XRD with NIR, mining, milling and leaching operations no longer need to be dependant on visual estimates for GeoMetallurgical Modeling and are provided with a valuable forecasting and production control tool. This paper will illustrate the development, plant implementation and application of XRD and NIR at several copper operations.

Jan 1, 2007

By Dave Bulled

"This paper describes the design of a molybdenite flotation circuit using FLEET technology applied to kinetics data produced from laboratory flotation testing and distributed across the blocks of a mine plan using a geostatistical approach. The geostatistics assigned the statistical error that arises from having a limited amount of sample testing data to the kinetics estimates of each block of ore in the mine plan. The final design then included a quantification of risk based on the accuracy of the block flotation kinetics and model fitting. The design made reference to the extensive technical reports describing earlier metallurgical test work including some pilot plant work over thirty years ago.The testing involved conducting MinnovEX Flotation Tests (MFT) to determine the rougher flotation kinetics at the specified reagent conditions and rougher-cleaner tests to determine the change in kinetics resulting from regrind. These flotation kinetics were used within FLEET simulations to create a full-scale flowsheet and plant design including recommended equipment sizes and the forecast of operating results. Measurement of detailed flotation kinetics for a wide range of samples allowed the effect of size of grind and efficiency of classification (i.e. width of size distribution) to be predicted for the whole ore body.INTRODUCTIONAdanac Moly Corp. proposed to develop a 20,000 ton per day mill to produce high quality molybdenite concentrate from its Ruby Creek resource in north-western British Columbia. It is a relatively clean low grade porphyry-monzonite occurrence containing minimal quantities of other sulphides such as chalcopyrite, pyrite, sphalerite and galena. Molybdenite occurs mainly as coarse flakes with lesser amounts of finer sized values. An optimum plant design was required to can achieve the predicted operating results, at a known level of risk, while treating the variability inherent in the ore body."

Jan 1, 2007

By K. Koyama

As a study to establish a new energy-saving copper recycling process, the copper deposition at a cathode and oxidation of copper(I) at an anode from ammoniacal alkaline solutions containing Cu(I) or Cu(II) were investigated in order to examine the feasibility of electrolysis in this solution.. The current efficiencies were greater than 95% in the current density range of 200 to 1000 A m-2. The current efficiency decreased with the increasing Cu(II) concentration and temperature. In the batch-type electrolysis at the anode, during the initial stage, the current efficiencies were 100%, and the anode potentials ranged from 0 to 0.15V vs. SHE at a current density of 100 A m-2. During the subsequent stage, the current efficiency decreased with time, and the anode potential was around 1.35V vs. SHE where oxygen evolution at the anode surface was observed. As a result, the present electrolytic method can be the core technology in the said copper recycling process.

Jan 1, 2007

By G. V. Fernandez

Sociedad Minera Cerro Verde S.A.A leaches secondary copper sulfides. In recent years, the mine has introduced innovations that have improved the management of mineral crushing, agglomeration, curing, and leaching. The crushing plant, for example, uses the concepts of degree of balance and percentage of time in an operationally balanced state which, displayed in real time, facilitate more intensive and uniform utilization of the crushers. High agglomerate quality is ensured with the correct dose of moisture, which is adjusted to the changing characteristics of the mineral through the use of electrical conductivity measurements. The amount of acid used for curing the agglomerate is also adjusted by using quality control information. Finally, the stockpile irrigation regime is managed using the criteria established by the "Lixiviant Request Rate", which optimizes the addition of leaching solution, creating such benefits as faster recovery, and reduced acid and energy consumption.

Jan 1, 2007

By H. P{ops

This paper summarizes important developments that have occurred in the mining and subsequent production of copper into rod and wire from 9000 B.C. until the present time. Principles and practices associated with continuous rod production are discussed from a metallurgical perspective, and include the effects of oxygen content and impurities. A brief historical review is also given of important wire drawing events dating back thousands of years. Finally, predictions concerning the future of the wire and cable industry are presented with particular emphasis upon copper wire, technology in this market, and competitive materials.

Jan 1, 2007

By S. R. Izatt

The use of MRT, a highly selective separations technology, has long been demonstrated to be a cost effective, efficient, and environmentally sound process for extraction of a wide range of anions and cations that are commonly found in copper electro - refining and electro - winning circuits, as well as in environmental treatment operations. This paper provides an update of commercial MRT applications in the copper industry. Several recent installations and test programs are reviewed including recovery of bismuth from tank house electrolyte, and from chloride matrix selenium reduction solution which is generated in the anode slimes treatment process. Recovery and refining of platinum group metals originating in the anode slimes is also discussed. Various other base metal and other target separations of interest to the copper producer are also reviewed. The recovery products are high purity metal salts which can be marketed directly or readily reduced to metal.

Jan 1, 2007

By G. Plascencia, C. López, J. González, D. Jaramillo, M. A. Barrón

Air jet and molten matte interaction within a Peirce - Smith converter is analyzed during the first stages of blowing using Computational Fluid Dynamics (CFD), by means of the Large Eddy Simulation and Reynolds Stress turbulence models. Jet velocities ranging from 5 to 150 mis, which involve the bubbling and open jet regimes, were considered in 2 and in 3-D numerical simulations. As a result of the computer simulations, it was found that low velocities results in gas bubbling in the molten copper, whereas higher gas velocities results in well defined plumes. The consequence of such different behaviours results in an increment in the rate of refractory wear or in copper splashing respectively. The analysis of the results may lead to improve the design of the tuyeres currently used in copper converting. Bottom blowing of air is also explored in this work. Numerical results show a strong non-linear parabolic behaviour of the jet velocity on the average velocity of copper; which means that beyond certain jet velocity, the copper de-accelerates thus reducing its velocity. This may be due to the open nature of the jet, which prevents the momentum transfer from the injected gas to the molten copper.

Jan 1, 2007

In the flotation of a copper ore, entrainment of fine silicate and iron sulfide gangue minerals resulted in poor copper concentrate grade. In the cleaning stage, rejection of these gangue minerals was particularly difficult due to severe mechanical entrainment when the rougher concentrate was ground to 10 µm. To reduce gangue entrainment, polymeric depressants were tested. The rationale being that with the use of such polymeric depressants that also possess flocculation power, not only minerals-to-be-depressed can be made hydrophilic, but their particle size can also be enlarged. In this manner both the "genuine" flotation and the mechanical entrainment can be reduced. An effective polymer to reduce entrainment of silicate gangue mineral in sulfide flotation was identified from bench flotation tests conducted on single minerals. It was then applied to the flotation of a copper-gold ore confirming the beneficial role of the polymeric depressant in the reduction of fine gangue entrainment.

Jan 1, 2007