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"In mineral exploration and mining applications, it is sometimes necessary to reduce sampling error in order to improve representivity of individual sample assays. Historic efforts to reduce sampling error have relied on the belief that larger samples exhibit less sampling error. Justifications for this belief traditionally have coupled the binomial theorem with an ideal geological material consisting of ore and gangue particles of equal size and shape (an equant grain model) and empirical tests of geological materials, to illustrate an inverse relationship between sample size and sampling variance. To date, no proof exists of this sample size-sampling variance relationship in real geological materials exhibiting variations in grain size, shape, composition, and degree of liberation.Using first principles calculus and the formula for the mean, sample mass and sampling variance are proven to be inversely proportional in all geological materials. Distribution assumptions and physically ideal geological models are not used in this proof. Furthermore, algebraic manipulations of expressions describing the variances of equant grain models consistent with binomial, hypergeometric, and Poisson distributions reveal that these models also exhibit an inverse sample size-sampling variance relationship. Thus, the sampling behaviors of these models are numerically consistent with the sampling behaviors of real geological materials, and these models can be used to estimate sampling errors in real geological materials using simple sampling parameters."

Jan 1, 2007

By M. Kucharski

The model of the Outokumpu direct-to-copper process deals with a steady-state process the parameters of which do not depend on time. To give a prediction for the process outcome, "a modified black box" method, which ignores most of the chemical reactions in the furnace, was used. This method takes input and output parameters into consideration. The presented model describes the Outokumpu direct-to blister process in the form of the set of linear equations which give mass and enthalpy balances as well as the distribution of elements between blister copper and slag. However, only major substances where quantities in the feed charge exceed a certain level (for example 0.5 kg/ lMg of smelted concentrate) are taken into consideration. Minor elements are distributed among slag and metal phases in a different way. Some of the equations are derived from distribution coefficients. The value of distribution coefficients can be calculated from plant production data.

Jan 1, 2007

By . A. C. Atenas

Control of arsenic in the Potrerillos' Refinery electrolyte has been obtained by withdrawing a bleed stream of circulating electrolyte and ensuring the ratio of [O]/[As] in the cast anodes is maintained between 0.9 and 1.0. In order to achieve this control the anode oxygen must be adjusted, depending on the arsenic level in the cast anodes. It has been necessary to modify the time of the reduction step in the anode furnace refining process. Control of this ratio has permitted electro refining of anodes with high levels of arsenic, up to 3000 ppm, while minimizing the volume of electrolyte that must be removed for impurity control so as not to affect the copper concentration in the electrolyte. However this control strategy is not useful when the arsenic concentration in the cast anode is too high, because it is limited by the maximum oxygen concentration allowable for a good quality anodic. Costs have been reduced in anode furnace refining because it is no longer necessary to use alkaline flux injection to remove the arsenic in cast anodes.

Jan 1, 2007

In recent years, China and India have emerged as major players in the copper sector. Over the last decade, around 50% of additional global refined copper usage growth can be attributed to them. The paper provides an overview of the current and future copper supply and demand situation in both countries. Results from two market studies commissioned by the International Copper Study Group (ICSG) are complemented with recent copper statistics on North-East and South-East Asia, as well as further sectoral analysis. Developments and trends in copper mining and metal production, semis production, and major end use areas are highlighted. While providing insights into sectoral patterns and growth trends, the paper provides the basis for comparing structure and output of the copper sectors in some of the major copper-using countries in Asia. Afterwards, the current copper reservoir in use associated with infrastructure, buildings, industrial equipment, transportation systems and households is assessed using the ICSG Copper Flow Model. Finally, the identified copper flows are analyzed regarding the potential impact on the future world supply and demand situation.

Jan 1, 2007

By M. Massinaei

Recently constructed circuits have included multiple stages of columns in a variety of applications, from roughing to cleaning. The Miduk copper concentrator (in south-eastern Iran) is one of the unique mineral processing plants which use column flotation cells as rougher. As the bulk of final concentrate is produced by rougher columns, optimized metallurgical performance of these cells is crucial. This paper will present the study and optimization of, a froth washing system of columns. For this purpose, the cross-sectional area of orifices was increased and their orientation altered. Concentrate assay for copper and silica, in addition to bias rate were found to be the assessment criteria. Modification of the wash water system resulted in increasing the purity of rougher and final concentrate. Negative bias and short-circuiting of wash water into the concentrate launder were the main causes of improper froth zone washing in the former system.

Jan 1, 2007

By N. Afrin

The microstructure and tensile properties of AZ31B-H24 magnesium (Mg) alloy after friction stir welding (FSW) were evaluated. The grain size was observed to increase from approximately 5 µm to about 9 µm after FSW. The obtained Hall-Petch type relationship showed a strong grain size dependence of the hardness values. While the FSW led to about half of the yield strength of the base magnesium alloy, the ultimate tensile strength after FSW could reach about two thirds of that of the base alloy. The hardening capacity of the FSWed samples was about twice of that of the base alloy. The strain hardening exponent of the base alloy was found to be about 0.1 whereas it became larger than 0.3 for the FSWed samples. After yielding the base alloy showed a high initial and almost constant work hardening rate, corresponding to linear hardening stage II, followed by stage III with a decreasing hardening rate. Stage II linear hardening was observed to be absent in the FSWed samples.

Jan 1, 2007

By Martin Froehling, Curtis Mohns, Rahim Rajwani, Michael Fullam

"The Kemess mining and milling complex is operated by Northgate Minerals Corporation and is located in the mountains of north-central British Columbia, 430 kilometers northwest of Prince George. The complex consists of the Kemess South open pit mine and a 52,000 tonnes per day mill. Hypogene, supergene and leach cap ores are processed using conventional crushing, grinding, and flotation techniques to produce gold-copper concentrates with minor by-product silver value.The rougher flotation concentrate is re-ground in closed circuit before being cleaned to final concentrate grade. Historically, gold losses in the cleaner tailings were primarily associated with pyrite, with only minor amounts of free gold. More recently, with the processing of high pyrite ores, the major losses were found to be free gold less than 10 microns in size. The fine grind required for the high pyrite ores resulted in over-grinding of the free gold particles in the regrind circuit, contributing to poor flotation characteristics. It was thought that if this free gold could be recovered by gravity at coarser size in the regrind circulating load, the free gold losses in the cleaner tailings could be reduced.Preliminary test work carried out by Knelson Gravity Solutions indicated the potential for free gold recovery in the regrind circuit. A Knelson XD-30 Concentrator was installed with variable speed capability, and a series of optimization tests were carried out. In addition, cleaner tailings were characterized with gravity operating and with gravity not operating to determine the overall gold recovery benefit. The single Knelson XD-30 installation recovers ~10% of the total gold in the regrind circuit and increases overall recovery by 3% when high pyrite ores are processed."

Jan 1, 2007

By J. O. Marsden

Over the past decade, the copper industry has been through an extended downturn followed by several years of sustained high copper price. A number of new technologies have been developed over the past 10 years aimed at reducing costs by decreasing energy, labor, and materials requirements, or by increasing metal recovery. The energy intensity of different copper extraction routes and different technologies varies considerably and this has a significant impact on the economics of extraction. Based on average ore grade materials, the total energy for the extraction of copper typically varies from about 24-26 MJ/lb (6.7-7.2 kWh/lb) for the mining, crushing, milling, flotation, smelting and refining route to about 14¬16 MJ/lb (3.9-4.5 kWh/lb) for the mining, crushing, heap leaching, solution extraction and electrowinning route. New technology developments are providing opportunities for significant reductions in energy consumption for copper extraction, representing energy savings up to 20-25% in some cases. In addition, in many cases, these new technologies have introduced environmental, safety and health benefits over the incumbent technology. Some of these technology developments have been more successful than others, and many hold great promise for application in the coming decade. This paper provides an overview of the technology developments that have occurred, and explores the underlying reasons behind successful implementation.

Jan 1, 2007

By P. G. West-Sells

At Barrick's Zaldivar Copper Mine in Chile, the addition of sulfuric acid to the ore going to heap leaching is a major expense. A process in which a portion of this acid is replaced by elemental sulfur added to the heap has been developed by Barrick and Westcoast Biotech that has the potential for significant cost savings. Initial shake flask tests with plant raffinate solution indicated that oxidation of elemental sulfur by a culture of sulfur-oxidizing bacteria, some indigenous to the Zaldivar heap, showed a significant lag period. This lag period could be reduced by dilution of the raffinate, but dilution would not be economical to implement at Zaldivar. Short (0.75 m) column tests indicated that after the initial lag period, sulfur biooxidation occurred steadily and the acid requirement for obtaining the same copper recovery as the control without sulfur was reduced by as much as 13 kg/t. These tests were followed by taller (5.1 m) column tests that confirmed the reduction in acid consumption, with no negative effect on copper extraction.

Jan 1, 2007

By J. M. Shneerson

Gipronickel Institute, Saint-Petersburg will The copper concentrate was extracted from copper and nickel matte after its hydrometallurgical treatment and nickel removal. The concentrate containing 60-74% of copper was represented by two principal copper minerals, digenite and covellite. The oxidising leaching of this kind of concentrate was studied at the Gipronickel Institute. The effect of key parameters, such as temperature, oxygen partial pressure and initial solution compound, on the rate of copper dissolution and transfer of sulphur from sulphide to elemental form was investigated. It was shown that at temperatures about 90DC, the sulphur content of covellite converts to elemental form. Under autoclave conditions at 11ODC, the elemental sulphur dissolves as a sulphate-ion. At the temperature range from 50 to 90DC, the copper dissolution rate is in direct relation with temperature. By increasing the temperature to 130DC, this effect is reversed. Based on the research work, a technological flow sheet for the leaching of the copper concentrate was developed.

Jan 1, 2007

By T. Prietl

Metallurgical vessel linings are multilayered, consisting of refractory bodies, insulation materials, joints, and additional space to control for thermal expansion. A unique biaxial hot testing press (BHTP) was installed at the RHI Refractories Technology Center Leoben, Austria to enable the three-dimensional behaviour of complex vessel lining segments to be investigated under simulated service conditions. Using the BHTP, the heat up and thermo-mechanical behaviour of magnesia chromite brick lining segments with and without mortar filled joints were examined. The results obtained during the initial heat up provided validation of CFD modelling of the lining system. In addition, after the heat up and under steady state conditions, the lining behaviour during deformation-controlled compression and relaxation was examined. These analyses generated important data regarding the stiffness, joint compressibility, and brick damage of the lining segments after cyclic loading and unloading as well as the benefits of using mortar joints in the lining. These investigations were performed in collaboration with the Christian Doppler Laboratory for Secondary Metallurgy of Nonferrous Metals, University of Leoben, Austria. The BHTP has been operational since November 2004 and is providing information regarding the thermo-mechanical behaviour of different lining segments.

Jan 1, 2007

The effect of superficial gas rate distribution (Jg profile) on down-the-bank metallurgical response was tested in the rougher-scavenger bank (eight 10-m3 tank cells, 4 roughers and 4 scavengers) at Highland Valley Copper Mine's Cu/Mo separation circuit. Three Jg profiles were tested: (a) as found (i.e., typical practice), (b) increasing decreasing (i.e., increasing from cell 1 to 4 and decreasing from cell 5 to 8), and (c) decreasing-increasing (i.e., decreasing from cell 1 to 4 and increasing from cell 5 to 8). The Jg profile approach proved to be of considerable value. Profile (b) gave the best metallurgical results, i.e., the highest down-the-bank grade/recovery (increase in grade at constant recovery was approx. 3-4% compared to the as found case) and the most efficient Cu/Mo separation (cumulative Cu recovery was reduced by almost half - approx. from 20% to 12%, at 99% Mo recovery). The success of the evaluation prompted the implementation of profile (b). Detailed gas dispersion characterization tests (Jg and Db (bubble size)) showed significant discrepancies between the Jg measured directly (using the McGill University sensor) and the Jg calculated from field instrument readings (volumetric gas flowmeter) and machine dimensions (cell cross-sectional area). Tests were designed to reveal the source of disagreement. It was observed that a significant number of bubbles were not able to float (i.e., they were entrained with the tailings), the evidence appearing to be a significant number of very small bubbles (approx. 200-300 µm) which did not have sufficient buoyancy to rise. Consequently, rather than relying on the field instrument, the evaluation depended on the McGill University Jg sensor, which collects bubbles in a tube near the pulp-froth interface, thus providing significance to the data as the measurements were obtained from bubbles that almost certainly floated.

Jan 1, 2007

By M. Aushouri, S. H. Mansouri, N. Aminizadeh

A thermo-chemical model of the Peirce-Smith copper converter has been developed to predict the molten temperature. The primary assumption of the model was that all matte, slag and gaseous phases in the converter were in thermal and chemical equilibrium. In this model, the matte components were considered only as copper, iron and sulfur elements. In the slag making stage, all the reacted iron was converted to fayalite. The reaction rate of iron and oxygen in this stage was considered to be constant. The converter temperature was calculated by heat balance over time. The model was validated by a detailed comparison with measured industrial data. A good agreement was obtained. The converter temperature depends on process parameters such as oxygen efficiency and molten emissivity.

Jan 1, 2007

By M. J. Marinigh

Increased safety requirements, higher operational costs, greater environmental restrictions, and new competitive processing techniques are the challenges smelter operators must confront in order to remain economically viable. In converting furnaces which have tuyeres such as the Noranda Reactor and the Teniente, Peirce Smith and Hoboken converters, efficient tuyere line management is critical to optimizing blowing rates, increasing refractory life, and improving safety. This paper will describe recent improvements made to equipment used for tuyere punching, tuyere silencing, tuyere pyrometry and refractory drilling of tuyeres and how the proper application of the equipment can lead to operational and safety improvements.

Jan 1, 2007

By David Meadows, John Starkey

"As part of the ongoing project development for the Tenke Fungurume Copper-Cobalt Project in the Democratic Republic of Congo, Phelps Dodge Corporation has examined methodologies for determining the size of grinding mills to support a 7000 mtpd operation. Six samples were tested by Hazen Research, Inc. (HRI) to obtain the JK parameters using the JK Drop Weight Test, standard Bond crushing, and rod mill work indices, abrasion indices and by Dawson for Bond Ball Mill Work Index tests using crushed feed, and Standard Autogenous Grinding Design (SAGDesign) Tests, patented by Outokumpu. (See reference 8 below).The comparison of these results gives context to how the various measurements relate to each other and how they can be used to obtain an accurate design for the grinding mills required for the Tenke Project. This is the first published direct comparison between JK Drop Weight, standard bond work indices, and SAGDesign test results. The SAGDesign test includes a SAG test followed by a Bond BM Wi test done on SAG ground material.INTRODUCTIONAfter the presentation of the paper “SAGDesign Testing – What It Is and Why It Works” at the recently concluded SAG 2006 Conference in Vancouver, a question was asked about how SAGDesign ore hardness measurements compared with other comminution tests, specifically the JK Drop Weight Test and the parameters that are derived from such testing. At that time it was noted that a paper was being prepared for the CMP Conference in January to show how various ore hardness measurements compare with each other when done on the same samples.This paper will therefore present the first such comparison using test results from the Phelps Dodge Tenke Fungurume Project where six composite samples were examined by the tests noted below. A seventh sample was tested at Dawson but not at other labs. The tests were done at four different laboratories listed below and included the tests shown."

Jan 1, 2007

By P. Coursol

The Noranda Reactor Process (NRP) has been in operation now for more than 30 years and this mature process has attained a high level of performance. The NRP at the Home Smelter of Xstrata Copper treats a wide range of feed materials and a thorough knowledge of both process control and smelting physico-chemistry has been beneficial to help meet the required plant flexibility. In this regard, some level of predictive knowledge related to slag chemistry, in particular, the liquid and solid phases such as spinels or olivines, has been found to be beneficial. In the last decade or so, the availability of commercial thermodynamic modeling packages, such as Factsage1m have been utilized with advantage to help the plant optimize slag chemistry and minimize problems from difficult slags, for example, those the could arise from undue feed variability. This paper illustrates the application of this software in examining a range of operating parameters such as: %Fe in product matte, the %Fe/%Si02 ratio in the slag, the levels of minor slag components including CaO, Ah03, ZnO, and MgO, and the level of oxygen enrichment on the operating conditions of the NRP. The slag composition boundaries at the conditions affecting magnetite control and solid magnetite/other precipitated solid phases, as well the conditions influencing the slag liquidus ranges of NRP slags are also discussed with respect to the overall process chemistry.

Jan 1, 2007

The copper electrodeposition from sulphuric acid electrolytes in the presence of Thiourea and Gelatin as additives was investigated by electrochemical noise and cyclic voltammetry in conjunction with the scanning electron microscopy technique. This study was oriented to examine the utility of using electrochemical noise "EN" technique to characterize the electrowinning process and the deposit structure morphology as compared to cyclic cyclovoltammetry "CV", an electrochemical method generally used industrially. Both EN and CV techniques were successful to reveal the effect of different concentrations of Thiourea and Gelatin on copper electrodeposition process. In this study, CV has detected an excess of Thiourea leading to porous deposit. While, the electrochemical noise analysis in the time domain (skewness and kurtosis parameters) as detected the presence of nodules and has given useful information concerning the morphology of the deposit closely related to the macroscopic and microscopic studies.

Jan 1, 2007

By W. Torres Pino, L. Mariscal Samaniego

The Ilo Smelter has been continuously operating since 1960 with Reverberatory furnaces and Pierce Smith converters producing blister copper. The original installed capacity of 1.134 tons per day of concentrated was expanded in 1976. A process of modernization started in 1995 and 1998 with the installation of an El Teniente Converter, a sulfuric acid plant and an oxygen plant to reduce the gaseous emissions to the atmosphere. With the official approval of the Environmental Compliance and Management Program (Programa de Adecuaci6n y Manejo Ambiental - PAMA) in January 1997, Southern Peru Copper Corporation made a commitment to capture 91. 7% of the S02 generated at the smelter by January 2007. After an evaluation of six different technologies, the ISASMEL T process was selected because it can be easily adapted to the present operation, has a lower capital cost and it is a simple process. The fast learning curve to reach the total capacity will allow to fulfill the PAMA commitment in time. The project construction is in process and SPCC is prepared for a successful start-up and transition of the current operations at the end of year 2006. This paper outlines the factors considered by SPCC in its choice of ISASMEL T technology and describes the construction and the start-up activities of the new facilities.

Jan 1, 2007

By F. Flores

With the World Summit for Sustainable Development planned for 2002 in mind, nine of the world's largest mining companies decided to initiate a project to examine the role of the minerals sector in contributing to sustainable development, and how that contribution could be increased ? the Mining, Minerals and Sustainable Development Project (MMSD). This project assumed from the start that sustainable development could provide a useful framework to guide the minerals sector which main goal was integrating economic activity with environmental integrity, social concerns, and effective governance systems. The broad steps of MMSD project strategy can be grouped into four major categories: increase understanding of sustainable development; create organizational-level policies and management systems for implementing the principles of sustainable development; collaborate with others with common interests to take joint steps towards sustainable development, and; increase our ability to work towards sustainable development at the local, national, and global levels. In opinion of the article's author, to go ahead with the MMSD strategy and achieving the sustainable development objectives, it is necessary to consider the concept of self-organization, fundamental of the emergent new scientific paradigm, and the consequent epistemology and values that conform a supporting culture for sustainable development.

Jan 1, 2007

By N. Bakhshizadeh

In this investigation, the aging effect on creep behavior of A12024-10%SiC composite fabricated by powder metallurgy was studied. P/M bars were manufactured by hot powder extrusion method at 450°C with a ratio of 16 to 1. Creep specimens were over-aged at 187 ºC for 43 h. It was found that almost full density composite with relatively homogenous distribution of reinforcing particles throughout the aluminum alloy matrix could be attained by direct powder extrusion process. Creep tests were conducted at temperatures from 275 to 325°C under stresses from 25 to 60 MPa. The analysis of the creep mechanism determined that dislocation glide was the predominant mechanism of plastic deformation. The activation energy of the creep process was found to be higher than that of lattice self-diffusion in pure aluminum.

Jan 1, 2007