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By L. Treadgold

The KOV, Kananga and Tilwezembe copper-cobalt deposits in the Democratic Republic of the Congo have lain dormant for over ten years due to lack of funding by the State-owned mining company, Gecamines. Nikanor Pic through its operating company DCP has secured the mining titles from the DRC government and has commenced redevelopment of these large copper deposits. DCP plans to produce 250,000 tonnes per annum of LME Grade "A" copper cathode and up to 30,000 tonnes per annum of cobalt salts. This paper describes the geology, re-development of the KOV mine and the two smaller mines, Kananga and Tilwezembe, the design of a new copper-cobalt processing facility and the challenges in refurbishing the associated infrastructure.

Jan 1, 2007

By M. Ruel

In today's highly competitive worldwide market, it is becoming extremely important for managers to make sure that all resources are used where needed the most. That way, all resources are generating added value, process control equipments are maintained in an optimal state for best performance, and final product is produced at least cost. Performance monitoring is the only way to ensure that everyone is working on top priorities toward the same goal. How can we add value to these warehouses of data? The data is there and the information is hidden; it is just waiting to be extracted. A process performance monitoring system is able to determine if a loop, a system, a unit, or a plant meets the expected performances. The system prioritizes the areas that need attention. It also provides historical reports of the plant status by areas, by loops, and by identified problems. This information is provided to different categories of users in an appropriate format for each one. The system also includes diagnostics and tools to detect and analyze problems.

Jan 1, 2007

By C. Ciriello

Six Sigma methodology, as applied within Xstrata (formerly Falconbridge and Noranda), involves a disciplined approach to managing projects, solving problems, improving performance, and leveraging information. The four (4) cornerstones of Six Sigma are the use of Philosophy (customer driven, desire to improve and discipline), Metrics (measurement systems), Methodology (scientific method and sequence of deliverables), and Tools (such as statistics, change management, and root cause analysis). This paper will outline the general steps of the Six Sigma methodology and demonstrate how each phase directly applies to a real plant metallurgical project aimed at reducing nickel losses of the rougher flotation circuit at Raglan. The main concepts of Six Sigma are described, along with the specific challenges, successes, and deliverables related to the project. It is also the authors' aim to demystify the basic Six Sigma principles.

Jan 1, 2007

By Ch. Wenzl

Anodes must have a certain physical and chemical quality in order to provide uniform anodic corrosion and meet the requirements of electrorefining, i.e. to achieve a high current efficiency, low energy consumption, low amount of anode scrap and low effort together with high cathode quality. Various properties of the anodes can be influenced directly by the casting process, which is the interface of pyro- and hydrometallurgy of copper. The aims of anode casting ? high output and long mould lifetimes ? are not consistent with good physical anode quality. The physical requirements of an anode are smooth surfaces, uniform weight and thickness, minimal edge effects, minimal distortion of the body and the lugs, as well as a homogeneous microstructure, in order to achieve uniform dissolution behaviour. The chemical quality of the anode copper is a task of electrorefining operations, but the elemental distribution within the anodes, which should be as homogeneous as possible in order to provide uniform anodic corrosion, can be influenced by the casting process.

Jan 1, 2007

By N. Hiroyoshi

In the leaching of chalcopyrite with sulfuric acid solutions, the copper extraction rate reaches a maximum at a given redox potential. This article reviews our studies on the determination of the optimum redox potential for chalcopyrite leaching. Shaking flask and column leaching experiments for a chalcopyrite concentrate were performed under various conditions, and the results were analyzed using a normalized redox potential defined from a reaction model assuming the formation of an intermediate CU2S from chalcopyrite. Factors, such as metal ion concentrations, solid/liquid ratio, and presence of iron-oxidizing bacteria, caused significant variations in the copper extraction versus time plots. However the copper extraction rate versus normalized redox potential plots were independent of the above factors and the copper extraction rate reached a maximum at the normalized redox potentials around 0.43. Converting the normalized redox potential to the solution redox potential gives the optimum redox potential for chalcopyrite leaching as a function of cupric and ferrous ion concentrations. This semi-empirical equation can be used to predict the optimum redox potential during leaching operation, and is useful to design the redox-controlled heap leaching for chalcopyrite.

Jan 1, 2007

By G. T. Fisher

A continuous process is used at Phelps Dodge Sierrita Inc. to produce copper sulfate pentahydrate via a solution extraction ? crystallization approach to supply the animal feed market. A review of the fundamental concepts of the process and unit operations is presented. Improvements in the process are aimed at achieving a controlled size distribution of product crystals (-40+80 mesh) with minimization of fines by primary nucleation and crystal breakage. An independent temperature control design was implemented for the heat transfer medium (water) in each crystallizer, albeit using common headers in and out of the chiller. This design was developed to maintain a controlled degree of supersaturation in each vessel while preventing localized spontaneous nucleation of fines and reducing encrustation of the heat transfer surfaces in each crystallizer. A model was developed to calculate the heat load and heat transfer coefficient of each crystallizer along with the saturation copper tenor as a function of temperature and free acid.

Jan 1, 2007

By G. Viramontes-Gamboa

Approximately 70% of world copper reserves consist of the mineral chalcopyrite, and much international effort has focused on its study. Ultimate objectives include the development of environmentally friendly alternatives to smelting, and technologies to treat low-grade ores, for which concentration and smelting are economically unviable. Unfortunately, chalcopyrite leaching is inefficient in H2S04-Fe2(S04)3-FeS04 solutions, which is considered to be the most desirable oxidizing medium for leaching of copper sulfides, since the chemistry is well known, corrosion of industrial equipment is negligible, subsequent copper recovery by SXlEW is well established, and environmental impact is minimal. The main reason for this inefficiency is the self-passivation of chalcopyrite. We have devoted considerable effort in the understanding of this phenomenon, and have developed a predictive electrochemical methodology capable of establishing a priori the precise range of potentials within which chalcopyrite leaches and where it is passivated. Since potential control is a critical parameter in chalcopyrite leaching, this experimental methodology can be very useful for establishing the best conditions to leach chalcopyrite. In this paper, the scientific foundations of this predictive experimental technique are presented, and its practical application is demonstrated by comparing its predictions with leaching experiments from the literature.

Jan 1, 2007

By K. Soga

DOWA has long been specialized in the treatment of complex massive sulfide ores from exploration through smelting. Its competitive advantage derived from ore dressing technology to dress and concentrate complex ore to various kinds of metals concentrates. With this technology, the company recovers as many as seventeen different nonferrous metals. Therefore, it is crucial for the environment management and recycling business both to recover valuable elements like gold, silver, copper etc. and to handle hazardous elements in safety. From this view point, the nonferrous metal industry has a potential to play an important role; that is "The Anchor of Recycling" or "The Joint of Recycling Loop". By utilizing these mining, smelting and refining technologies, know-how and facilities, DOWA became a leading waste treatment, soil remediation and metal recycling company in Japan. This knowledge is now being applied in China .

Jan 1, 2007

By Z. Trojanová

The deformation behaviour of ternary magnesium alloys AJ (Mg-Al-Sr) and AX (Mg-Al-Ca) were investigated in tension as well as compression tests. The samples were deformed at temperatures between 20 and 300 °C and at an initial strain rate of the order 10-4 s 1. The flow stress decreases with increasing temperature. The macroscopic work hardening rate decreases with increasing flow stress and temperature. The stress and temperature dependence of the work hardening rate is a result of the hardening and softening processes. Stress relaxation experiments were performed in order to reveal features of the thermally activated dislocation motion. Internal and effective stress components of the applied stress were estimated. A decrease in the internal stress was observed at elevated temperatures, which indicates recovery process (-es). A more detailed analysis of the estimated values of the activation volume and activation energy helped to interpret the thermally activated processes during plastic deformation. It is concluded that the deformation behaviour of the alloys depends on the activity of non-basal slip that is strongly influenced by temperature.

Jan 1, 2007

By A. Warczok

The mechanisms and kinetics of copper oxidation and reduction have been investigated in small scale thermal gravimetric experiments as well as in laboratory pilot scale, packed bed reactors. With blister copper flowing gravitationally down through a packed bed of ceramic particles, counter-current to low oxygen containing combustion gases, the rate of oxidation was found to be very high due to the large surface area created. Similarly, reduction by flowing copper through a packed bed of charcoal lead to rapid de-oxidation. Based on these laboratory measurements, fundamental rate data have been obtained. Modeling of industrial sized packed bed reactors using the laboratory results, opened up the possibilities of developing a new, very intensive, continuous process for copper fire refining. The developed mathematical model together with a computer process simulator, allowed for the design of the industrial-pilot installation to be built and tested at the ENAMI Paipote smelter in Chile.

Jan 1, 2007

By Wayne Phillips, Anatalia Silva, Robert Henderson, Tondo. Luis

"Kinross’ Paracatu Mine has 20 years of operational success as one of the lowest grade milloperated gold mines in the world. At year end 2005, Paracatu’s Proven and Probable Reserves were 1.18 billion tonnes at a grade of 0.40 g/t Au, containing a total of 15.2 million ounces of gold.In 2005, the plant processed 17 Mt of ore and produced 180,519 ounces of gold at a cash cost of US$274/oz. An investment of US$470 million has been approved to expand production to 61 Mtpa in 2009 which will extend mine life to 2036. During the period from 2009 to 2013 the project is expected to produce an average annual output of approximately 557,000 ounces of gold at an average cost of sales of approximately $230 per ounce.The soft, friable ore containing readily leachable gold associated with sulphides lends itself to simple processing. The process flowsheet consists of crushing, grinding, gravity recovery, flotation, concentrate leach and carbon adsorption to produce bullion bars. This paper describes the current operation, the deposit’s unique metallurgical features and the future expansion plant that has been designed to optimise recovery of gold.INTRODUCTIONRio Paracatu Mineração (RPM), a wholly owned subsidiary of Kinross Gold Corporation, operates the Paracatu mine. The mine is located in Brazil, 230 km south west of Brasilia in the north west portion of the State of Minas Gerais. The city of Paracatu, which has a population of 83,000 people, is just 2 km south of the mine."

Jan 1, 2007

By M. F. Vancas

Control of the interface elevation between the aqueous and the organic phases in typical settlers is a fairly straight forward principle. However, when looking at the details involved in actually designing the aqueous and organic discharge launders and weirs, one comes to realize just how sensitive the system is to small variations in operating conditions and/or parameters. This discussion focuses on the details that must be considered during design, looks at the various types of control systems typically used (from the basic manual systems through to full automation), and equally importantly, looks at what happens in an operating plant when the conditions and/or operating parameters change.

Jan 1, 2007

By M. Oliazadeh

The bioleaching of fine low grade copper sulfide ore is described. A sample of ground (> 1 mm) copper ore from Sarcheshmeh, Iran, was subjected to a series of agglomeration procedures and subsequently leached. The best agglomerate was obtained by using lime and sulfuric acid as binders. A column bioleaching test of agglomerated ore was then run for 105 days along with a non-inoculated control column having thymol as bactericide. The results show that about 77.5% of copper was extracted in the bioleaching, whereas the control column achieved only 57% copper leaching.

Jan 1, 2007

By K. Murase

Potentiostatic electrodeposition behavior of dendritic copper from acidic copper(I) chloride (cuprous chloride) baths containing sodium chloride and sodium bromide was investigated. The morphology, or appearance, of copper dendrite and the sodium content in the dendrite as an impurity were both influenced by deposition potential (0 to ?150 mV vs. SHE) and bath temperature (R.T. to 60 C), while the current efficiency for the deposition was 99% or more irrespective of the deposition conditions examined. The bath pH did not affect the deposition behavior in the pH range of 0 to 2. Bath temperature was found to be the most important factor influencing the deposition current. The current density of the dendrite deposition on a titanium cathode was lower than that onto a copper cathode with the same substrate surface area. The reproducibility of the current for the dendrite deposition was poorer when an as-polished titanium cathode was used, although it was improved by surface treatment of the cathode with an HF-HNO3-H3PO4 solution before electrodeposition. The deposition behaviors were discussed with the potential-pH diagram of the Cu-Cl-H2O system.

Jan 1, 2007

By J. J. Crowder, A. L. Coulson

Ground support is a significant component of underground mining costs. The rehabilitation of failed support, however, is often much more expensive than the initial installation. This paper investigates whether the right type and length of support can be designed correctly the first time, through forward modelling of the support and the mining process. Back analyses demonstrate how high-quality instrumentation and monitoring can help with the estimation of the post-peak (post-failure) rock mass parameters required for a comprehensive analysis. A hybrid modelling approach combines a three-dimensional mine-wide boundary element model with a non-linear finite element model to allow for the failure process in the rock mass. The back analyses demonstrate that, for the case study site, the post-peak Generalized Hoek-Brown value of mr must be reduced significantly in order to properly simulate displacements observed in instrumentation data. High-quality instrumentation data is the key to post-peak rock mass parameter calibration. The procedures outlined in the paper highlight the need for a new hybrid numerical modelling package that can use the influence of three-dimensional mining-induced stresses to predict displacements in, and potential failure of, rock masses surrounding mining infrastructure in order to radically alter strategic and tactical mine design.

Jan 1, 2007

By Y. C. Kim

This paper discusses Air Liquide's patented SPALTM (Surface Protection Air Liquide) technology and process for the inerting of coreless induction furnaces using cryogenic liquid gas. Air Liquide Canada Inc., in collaboration with Riverside Brass and Aluminum Foundry Limited (Riverside Brass), conducted plant trials to demonstrate the applicability of the SPALTM technology for copper-based alloys. Results showed that with SPALTM, Riverside Brass benefited from a significant increase in metal yield as the level of dross formation was drastically reduced. Together with the many other benefits of this technology, SPALTM demonstrated to be a non-negligible cost-effective solution to reduce metal production costs. In an effort to optimize the argon flow, different flow rates were used and the oxygen level above the metal bath was measured to pinpoint optimal flow. The results of metal yield, charge mix, dross formation, and melt temperature are compared with and without argon. The metal yield improvements are dramatic and calculated net savings are presented hereunder.

Jan 1, 2007

By M. Meratian

The in-situ methods have been developed in production of aluminum matrix composites. A commonly adopted in-situ method involves reaction between a metal oxide and aluminum to produce alumina particles or whisker reinforcements. Aluminum-alumina particle composite was fabricated by in-situ method where alumina particles were produced from reduction of copper and silicon oxides by melting and casting aluminum. Aluminum matrix composites reinforced by Copper and Silicon alloying elements and alumina particles have been obtained. The size and shape of alumina particles were studied by scanning electron microscopy (SEM). The size of alumina obtained from mixture of SiO2 and CuO was bigger than the alumina particles obtained from CuO.

Jan 1, 2007

By C. Cano

One of the main concerns within the mining industry is to minimize the impact of tailing facilities to the environment and nearby communities. Since the implementation of the first thickened tailings disposal (TTD) methodology at Kidd Creek in 1964, the thickened tailing disposal has been growing alternative disposal technology to mitigate the environmental impacts. Technical investigations on the TTD technology have been studied in detail to counteract the increasing shortage of water resources. One of the benefits observed with TTD is its resistance to potential earthquakes, particularly in zones with high seismic activity (Los Andes). TTD technology optimizes the maximum possible density for the material and generates a negative internal pore pressure in the material due to the surface and sub-surface water evaporation. This internal pore pressure should be enough to resist the pores pressure to which tailings are subject due to an earthquake action. The objective of this study is to verify the Shrinking Limit (SL) of thickened tailings during initial deposition and in the long term and the ability of tailings deposited by TTD would resist liquefaction. Fresh tailings coming from a flotation process of a copper plant concentrator were used. The samples put under cyclical three-dimensional tests associated with maximum credible earthquake magnitude range of 7.0 8.0 to develop a curve for the safety factor v/s depth for dry densities related to the maximum density obtained at the SL. At a dry density of 1.65 t/m3 liquefaction did not occur at any depth. At 90 % of dry density of 1.51 t/m3, liquefaction did not occur at earthquake magnitudes of 7.0 or 7.5 nor at any depth but liquefaction occurred at magnitude 8.0 between 0 m and 14.5 m; below 14.5 m, liquefaction does not occur.

Jan 1, 2007

By G. P. Cooper

A comprehensive computational heap leach model was used to evaluate options for operating a chalcocite-ore heap leach process. The stockpile leach model is based on the computational fluid dynamic software framework PHYSICA+ and incorporates various physical and chemical phenomena to simulate fluid transport, mineral reaction kinetics, bacterial effects, and heat, energy and acid balances for the overall leach process. The leach model is calibrated against small-scale column leach tests, and simulation results are validated against closely controlled column pilot-scale tests. For a given set of ore conditions, the effects of raffinate irrigation rate are examined. Several options for pulse leaching were investigated, and the effects on copper recovery and pregnant leach solution (PLS) grade are described. Model simulations indicated that pulse leaching could be used to control copper grade of the PLS. Finally, an analysis of inventory issues is presented for various lift heights including multi-lift simulations to examine potential operating options. U sing irrigation rate, raffinate copper grade, and lift height as variables in a factorial design of experiments, the simulations showed that raffinate copper grade is the main factor that affects the soluble copper inventory grade.

Jan 1, 2007

Over the years, efficient on-line monitoring of performance and status of an electrolytic copper refining process has been challenging due to the need for complex electrical measurement systems and the management of the enormous volume of data. Recent innovative developments by Kennecott Utah Copper Corporation and Outokumpu Technology in wireless cell voltage and individual cell temperature sensing opens new possibilities to improve and modernize tank house management. This paper describes the powerful Outokumpu CellSenseTM refinery monitoring system for efficient interpretation of data produced by wireless CellSensorTM system with traditional refinery measurements. Examples from commercial tank house installations demonstrate the benefits of the system to improved process control and operation. The Outokumpu CellSenseTM monitoring system is simple to operate and accessible to all the plant operation teams.

Jan 1, 2007