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By Antony Amberg, Gonzalo Saldías, Romke Kuyvenhoven, Catherine Souza, Heriban Soto, Francisco Soto

"Vizcachitas is an advanced stage copper–molybdenum porphyry deposit, fully owned by Los Andes Copper and located in Central Chile. The property contains an indicated resource of 1,038 million tonnes grading 0.37% Cu and 0.012% Mo, and an inferred resource of 318 million tonnes grading 0.345% Cu and 0.013% Mo (Coffey & Alquimia, 2014). The deposit occurs in the same geological belt as several other giant copper-molybdenum porphyry deposits including Río Blanco-Los Bronces, Los Pelambres-Pachon and El Teniente. In 2018, the original Preliminary Economic Assessment (PEA) study from 2014 was updated; this paper presents the geometallurgical testwork that was performed to support that update. The testwork focused on the metallurgical characterization of 40 DDH samples and the development of a more profound orebody knowledge by relating geological features with metallurgical performance. The scope of work included complete chemical and mineralogical QemSCAN characterization; SAG, ball mill and abrasion testing; complete rougher and cleaner kinetics including locked-cycle-test; environmental ABA and settling tests on rougher tailings. The results show that the ore can be classified as medium-hard, with a hardness that is slightly below the average for large Cu/Mo deposits in the region. A good correlation was found between lithology and breakage characteristics, implying that the specific energy consumption (kWh/t) is well correlated to rock type. The results of the flotation tests were very encouraging and did not show significant variability. An overall Cu recovery of 91% can be expected for the flotation circuit. The use of a relatively coarse primary grind size gave good final recovery and grade for both Cu and Mo, and deserves further attention in future work, as this impacts positively both energy consumption and water recovery.INTRODUCTION Los Andes Copper Ltd. is a Canadian exploration and development company focused on the acquisition, exploration and development of advanced stage copper deposits in Latin America. The company owns 100% of the Vizcachitas project in Chile, the largest copper deposit in the Americas not controlled by the majors. Vizcachitas is a copper-molybdenum porphyry deposit, located 120 km north of Santiago, in an area of very good infrastructure."

Jan 1, 2018

By O. Jerez, A. Novoselov, L. Gutiérrez, J. Morales, U. Kelm

"In Chile, the evaluation to reprocess tailings for elements other than the traditional Cu, Mo, Au, and Ag, as well as projects to implement long-term monitoring of mining residue sites are key elements of the government’s roadmap laid out for the mining industry for the next two decades. Characterization routines for tailings and mining residues in general have to be adapted from traditional ore and gangue mineral and micro-chemical studies. This contribution summarizes key aspects for the regional mining industry for a basic characterization of tailings with emphasis on small- to medium-size operations with limited in-house facilities and funds to carry out extensive characterization programs. The oldest tailings in Chile were deposited almost a century ago; this fact gives importance to the recovery of past ore /gangue feed information, process circuits and changes (e.g. acid to alkaline flotation), process water provenance and recovery, meteorological registers, and routines of filling a tailings impoundment. Basic characterization should include X-ray fluorescence spectrometry combined with laser diffraction (LD) granulometry followed by X-ray diffraction (XRD), optical microscopy (OM) and automated mineral analysis (AMA) on a reduced set of samples identified by hierarchical cluster analysis. For this detailed stage, only coarse tailings are recommended for direct a study by microscopy and automated mineralogy (P80 >100 µm); for fine tailings (P80 ~30 µm) a combination of XRD and deposit type adapted sequential extraction are more informative options. In particular, for XRD of clay phases, losses of crystallinity may result in deviation of spectra from standard reference phases due to prolonged storage. To monitor surface alteration, scanning electron microscopy can be complemented by Raman spectroscopy to detect residual reagents on mineral surfaces. For reactivity modeling BET measurements are essential."

Jan 1, 2018

By Nicholas Enraght – Moony, Alvin Johns, Zhonghan Zhang, Zhang Xianhua, T. Choo

"The tungsten (WO3)-rich ores from King Island Scheelite (KIS) Mine, Australia, containing scheelite(CaWO4) were previously recovered by gravity separation and flotation of fine scheelite (1978-92) with an overall recovery of 76% when both circuits were operating. Recently extensive test work has been conducted both in China and in Australia on KIS ores, assaying from 0.50%-1.34%WO3, and tailings assaying 0.2%WO3(GZRINM 2009; 2011a; 2011b). A new approach, which aimed at improving both recovery and grade of concentrate by means of an innovative all flotation route WOF (Whole Ore Flotation), achieved excellent results: 90%-92% recovery to concentrate grade of 66%-70%WO3for the ores. The process is characterized by the use of selective reagents in flotation, including a newly developed collector for scheelite, GYWA. The WOF process also embraces the "Improved Petrov Method" in the cleaning of scheelite rougher concentrate. Earlier investigations found that the removal of sulfides by flotation prior to scheelite flotation was not necessary. It was also found that recycling of process water did not influenceresults. Two main ore types were tested as well as tailings from 2009to 2001(0.20%WO3). In addition a flow sheet using wet high gradient magnetic separation (WHGMS) in tandem with flotation was also investigated for the tailings."

Jan 1, 2014

By Lorenzo Reyes-Bozo, Ronaldo Herrera-Urbina, Pablo Higueras, Alex Godoy-Faúndez

"The copper mining industry in Chile and perhaps in other countries as well is faced with the challenge to implement the best practices in order to achieve a sustainable and more environment-friendly growth. Relationships between mining industry and society have been historically complex due to its environmental impacts. Whereas the ore grade has declined continuously, this has involved an intensive energy and water consumption thus increasing operational costs at different stages of the concentration process. In the case of copper sulphide ore concentration, froth flotation is the main technology used worldwide. The amount of the different chemical reagents used in flotation plants (i.e., collectors, depressants, frothers and modifiers) affects significantly production costs and has a negative effect on the environment as well. The objective of this research work was to evaluate the use of biosolids and their main components (i.e., glucose, proteins and humic substances) as more environment-friendly flotation collectors for chalcopyrite and molybdenite. For this purpose, microflotation tests were conducted in a modified Hallimond tube. In addition, FTIR and zeta potential experiments were performed to investigate the interaction of biosolids with these sulphide minerals. Biosolids and their main components may interact through physical and chemical ways due to different affinities with such sulphide minerals as chalcopyrite, pyrite and molybdenite, which are present in copper sulphide ores. In alkaline pHs, biosolids and their main components make the zeta potential of the sulphide minerals investigated more negative. These results may provide important information concerning the behavior of the main sulphide minerals in the concentration of copper sulphide ores at industrial scale, wherein mill processes could affect their surfaces properties. Therefore, biosolids and their main components may open an opportunity to be used in copper sulphide flotation plants to partially replace conventional reagents, which are more hazardous and less environment-friendly."

Jan 1, 2014

Most of the Indian coking coals are medium coking and of very high ash content. Beneficiation of these coals is a must for their utilisation in coke making. During washing while the ash content of the coal is reduced, the same is expected to affect the reactive-inert ratio and the proportion of various petrographic constituents in the clean coal. This will affect the coking behaviour, including the expansion characteristics, of such coal. An increase in expansion behaviour of coal increases the wall pressure and may damage the battery wall. Therefore, close monitoring of coking properties along with drop in ash is necessary for smooth use of the coal in coke ovens. An effort is, therefore, essential to understand the impact of washing on its coking properties. The studies were carried out with captive coals of Tata Steel, India. Three medium coking coal samples namely, VII A, VI A and XI SEB seam coals of West Bokaro Colliery were used for the study. The coal samples after washing to different ash levels were subjected to the following analysis: proximate, crucible swelling number (CSN), LT GK test, dilatometer and plastometer tests and petrography. The experimental data were then analysed to assess the relationship of various coking properties of the coal with its ash content. The studies clearly show that there is a strong impact of beneficiation of the coal on its coking behaviour. The impacts are more at lower level of ash in the clean coal. In general, the coking properties increase with a decrease in ash. This is primarily due to an enrichment of vitrinte materials in the clean coal and an increase in the reactive-inert ratio in the coals. However, the most important impact of the lowering ash is on the increase in the swelling nature of the coal. The coals with lower ash become highly expanding in nature. This may be very critical from operations of coke ovens point of view, especially stamp charged coke ovens. Necessary precaution should be taken in selecting the other coal blend constituents when these coals are beneficiated to a very low level of ash content.

Jan 1, 2014

By G. Onal, E. Gock, H. Dincer

"During the conventional chromite dissolution process; chromite ore concentrates were ground to at least <90 µm using the ball mill and after adding Na2CO3 and leaning material (instead of CaCO3 also residues from the leaching process) at a ratio of e.g. 1:0.75:1.2, depending on the specific formulation, follows the digestion e.g. in a rotary kiln, heated in countercurrent. The reaction time is 3 to 8 h. The calcine is comminuted and leached with water or a thin chromate solution. Depending on the type of ore used, the yield is 75-85 %. The disadvantage of the above-described process is that it is impossible, using current technology, to achieve a complete digestion of the chromite ores and that the chromium-containing residues have to be disposed of as special waste, involving a large financial effort.The subject of this study was the investigation of the effect of vibratory milling on chromite dissolution. The impact stress in the vibratory mill causes the mechanical activation of chromite, which is characterised by lattice defects. The degree of mechanical activation can be quantified by measuring the relative X-ray diffraction intensities at the parent lattice planes of chromite. Each relative X-ray diffraction ratio correlates with a certain degree of digestion. As opposed to vibratory milling, a complete digestion of chromite using a ball mill is impossible, even at extremely long grinding times.In this investigation a chromite concentrate from Pulpinar/Kayseri with content of 44 % Cr2O3 and the Eccentric Vibratory Mill was used. In order to verify the effect of the vibrating grinding on chromite dissolution, reaction kinetic investigations on digestion and leaching were carried out."

Jan 1, 2003

By Natalie J. Shackleton, Deryck de Vaux, Cyril T. O’Connor, Vratislav Malysiak

"The major losses of PGM and base metals in the beneficiation of platinum group deposits occur during the separation of gangue from the value minerals by selective flotation. A number of studies have shown that this negative impact on flotation is due to surface passivation, caused by various ions that may originate from the external water supply or, as is likely in the majority of cases, from the oxidation of the mineral surfaces and the grinding media. The objective of the study was to investigate the effect surface passivation and inadvertent activation have on flotation and how this can be managed so as to increase the separation of pentlandite and pyroxene. The aim was to minimise the percentage pyroxene reporting to the concentrate and simultaneously maximise the pentlandite recovery. The testwork incorporates the addition of an activator (copper sulphate), a complexing agent, such as DETA (diethylenetriamine) and a dispersant (polyphosphate) at pH 6 and pH 9 in an attempt to alleviate the surface passivation of pentlandite and inadvertent activation of pyroxene. Both synthetic minerals and plant ores were studied in order to determine the effect surface passivation and inadvertent activation have on mineral surface alteration and floatability. Zeta potential determinations, microflotation, ToF-SIMS (Time of Flight Secondary Ion Mass Spectrometry) analyses, laboratory batch flotation tests and continuous flotation testwork were used as tools to study the surface alteration and/or floatability.Zeta potential determinations and ToF-SIMS analyses showed that copper adsorption is non-selective. Both pentlandite and pyroxene become copper (II)-activated in the presence of copper sulphate and subsequently, in the presence of xanthate, adsorption of the collector will occur onto copper activated mineral surfaces. Zeta potential determinations also showed an alteration of the surface charge in the presence of polyphosphate, thereby inhibiting surface passivation of sulphides by slime coatings due to surface repulsion."

Jan 1, 2003

By Luís Marcelo Tavares, Marko Hilden, Malcolm Powell, Grant Ballantyne, Lian Liu

The t10 relationship developed by Narayanan and Whiten has underpinned a number of the JKMRC models and the characterisation of ore competence through impact testing with the drop weight tester. This usefulness is based on a consistent relationship between the t10 value and the overall size distribution that was noted for brittle rocks. However, like all characterisation tests this should be used only when the controlling conditions apply, which in this case is single impact breakage between two metal platens and within the range of sizes in which fragment sizes are normalizable. For any other mode of breakage the relationship should be confirmed before being applied. Soft ores or bimodal ores with widely different competence between dominant components have non-typical breakage signatures. Breakage via single point impact abrasion, compressed-bed breakage, low-energy surface breakage and incremental breakage, to name some of the other breakage modes, do not obey the general t10 relationship, so their outcomes cannot be used to provide a direct comparison. Inappropriate use of the t10 parameter can result in misleading conclusions about efficiency of energy use. These issues and alternative comparison techniques are presented and discussed in terms of choosing appropriate measures of efficiency of breakage, ore competence and energy required for comminution.

Jan 1, 2014

By T. Saastamoinen, N. Heino

"The Olserum deposit located in Sweden hosts an indicated mineral resource of 4.5 million tonnes over 0.6 % TREO, exhibiting a relatively high proportion of HREE. Beneficiation of a composite drill core sample was studied in the flowsheet of magnetic separation of magnetite followed by REE minerals flotation. Primary testwork was performed to select an effective REE mineral collector and then the parameters of grinding size, collector and depressant dosages, slurry pH and density, conditioning time and temperature, and flotation time were tested for optimization of REE flotation. The studies of process mineralogy showed that the REE-bearing minerals monazite, xenotime and apatite were successfully enriched from the concentrations of 0.6%, 0.31% and 2.6% in the feed to those of 17.0%, 8.9% and 65.0% in the concentrate with the recoveries of 79.0%, 81.3% and 71.0%, respectively. INTRODUCTION The Olserum deposit located in Sweden comprises lower grade placer material with higher grade apatite-magnetite veins and hosts an indicated mineral resource of 4.5 million tonnes at 0.6% TREO, with 34% of that being HREO (EURARE, 2017). The mineralization was studied by Andersson et al. (2018). At early stage, high-temperature REE is characterized by abundant monazite-(Ce) and xenotime-(Y) coexisting with fluorapatite and subordinate amounts of (Y,REE,U,Fe)-(Nb,Ta) oxides. During a subsequent stage, allanite-(Ce) and ferriallanite-(Ce) formed locally, partly resulting from the breakdown of primary monazite-(Ce). Alteration of allanite-(Ce) or ferriallanite-(Ce) to bastnäsite-(Ce) and minor synchysite-(Ce) at lower temperatures represents the latest stage of REE mineral formation. The mineralogy and beneficiation were firstly studied by GTK Mintec in the EURARE project for a composite drill core sample. The Olserum is considerably smaller than the Norra Kärr deposit. However, REE are hosted by xenotime and monazite, both of which have well established processing pathways, and meanwhile, the Olserum has a high contribution of the high value critical REE (dysprosium (Dy), yttrium (Y), neodymium (Nd) and terbium (Tb)), which provide a unique advantage for its exploration (Tasman Metals Ltd., 2013). In this paper, flotation of the REE minerals in the Olserum ore was studied."

Jan 1, 2018

By A. Demirag, F. Burat

"The most important metals in the jewelry sector are undoubtedly gold and silver. As a result of workmanship work done in the jewelry industry, the tiny metal and jewel fragments and metallic powders are scattered. Given the prices of gold and silver on the market, the dust that emanates from these workshops is of great importance. Gold recycling has become as important as raw material production within the mass market and gold production industry. In 2016, 29% of the world gold supply has been obtained through recycled gold production. Waste derived from jewelry activity is included in this category, and represents an essential component of this percentage. In the scope of this study, the recovery possibilities of Au and Ag from jewelry sweeps floor sample was investigated using flotation method. In the experiments, optimum pH value, particle size, the effect of dispersant, type and amount of reagent were investigated. As a result of these studies, it was determined that the optimum pH value was 6.5 and the particle size was -212 microns. It was observed that the most suitable reactive combination was Aero 242 and Aerophine 3418A and Na2SiO3 has no positive effect on recovery of Au and Ag as a dispersant agent. As a result of tests, a final concentrate containing 268 ppm Au and 2122 ppm Ag was obtained with 81.4% and 74.5% recovery respectively. INTRODUCTION Because of the softness of pure gold, it is usually alloyed with base metals for use in jewelry, altering its hardness and ductility, melting point, color and other properties. On the other hand, gold has some special chemical properties which in normal conditions, don’t react with water, dry or humid air, oxygen, ozone, nitrogen, hydrogen, fluorine, iodine, sulfur and hydrogen. In these days, gold is used in different sectors like jewelry, electronics, finances and investing, dentistry, medicine, aerospace, awards & status symbols. According to Deutsche Bank Research, the primary usage of gold is jewelry. It has been used to make ornament and jewelry for thousands of years. In this sector craftsmen learned that alloying gold with other metals like copper, platinum and silver to increase gold’s durability. Alloying gold with other metals changes the color of the products. Another significant sector of gold is electronics. Modern electronics want the use of noble metals, like gold, especially in the areas of information processing, telecommunications, and military and space electronics (Habashi, 1997). Electronic devices use very low voltages and currents which are easily interrupted by corrosion or tarnish at the contact points. Gold is the highly efficient conductor that can carry these tiny currents and remain free of corrosion. Electronic components made with gold are highly reliable. Gold is used in connectors, switch and relay contacts, soldered joints and connecting wires. Every sophisticated electronic device have a considerable amount of gold. This includes cell phones, calculators, personal digital assistants, GPS units, and other small electronic devices. Most large electronic appliances such as television sets also contain gold. Humankind has known silver since prehistoric times like gold because silver occurs in native form. The metal is found in the Earth's crust in the pure, free elemental form native, as an alloy with gold and other metals, and in mineral such as argentite. Most silver is produced as a byproduct of copper, gold, lead, and zinc refining. Silver is very soft metal like gold also, it is the highest electrical conductivity, thermal conductivity, and the lowest electrical contact resistance of all metals (Habashi, 1997). Silver is used in different sectors like industry, jewelry, electronics, photography silver good, and coins. The main usage of silver is supplied by electronics. Silver's unsurpassed thermal and electrical conductivity among metals means it cannot easily be replaced by cheaper materials. In addition to silver is using in ener"

Jan 1, 2018

By Jury P. Nazarov

"At present the traditional study of crystal lattices of nmerials in a topic “flota tion mineralogy ” is used up. The present investigation is development of the a sclsical approaches to t he analy sis of ideal crystal lattices and f ormation on the basic obtained results of consultation, having practical chara cter.The strategy of develop ment floatation reagents i s offered, which basic pr inciple – complementary assembling m olecules forming surface co mpounds so thatth e steric charact eristic of the “visitor "" (of a polar gro up of molecule SAS) corresponded to the st er ic requirements of the ""o wner"" (elementary cell of a mineral), or coincided inter molecular cavities). In itsh case process of for mation of surface com pounds ca n be considered(a first approximation) as a realization of a principle of the design er "" LEGO "".The approach, which basic idea consi deration actioonf reactant ions and ions of ele mentary cell as three-di mensional objects is developed. And at suchp paroach the laws of a ster eometry - laws describin g spatial effect s are applicable. Thus it is possible toconsider a miner al surface as a mat r ix - basis for formation of the requirem ents to polar group of a molleec cuollector, and or (it is possible) depressant. As a whole approach represents a generalized principle double com plementation, enveloping both power, and geometric asp ects (concept ""lock "" and “key "" - spatial conform ity. Figure 7 (left). Fragment of a crystal lat tice of ap atite. Oleic acid ions interact on ly with th e calcium cations locate d on a long axi s of an elementary c ell. Magenta colour represe nts the calciu m cations, which are n ot particip atin g in interactio n, as th e degree of screening by ions neighbours exceeds 1.Figure 2. (right)The illustration of space complementary. “Afterbuilding” an elementary cell of apatite (radical PO4) related molecules of the visitor – alkyl phosphate (polar group PO4). Cations of calcium are not shown."

Jan 1, 2003

By O. Güven

In recent years, there is an increasing demand on manganese consumption which stems from the important role of manganese in carbon steel production. And the growing need for manganese ores makes the beneficiation of low-grade manganese ores more economical. In this study, the characterization and beneficiation studies were carried out to propose a flow sheet for typical low-grade Turkish manganese ores. For this aim, different gravity separation methods were applied. According to the mineralogical analysis, the major mineral phases are pyrolusite (MnO2) and psilomelane (MnO2) while the major gangue mineral is radiolarite. Gravity separation tests were accomplished by using jigs, shaking table, MGS (Multi Gravity Separator) and in order to obtain products with high Mn ratio, high intensity magnetic separation was also performed. As a result, different combinations of flow sheets were utilized and a concentrate assaying 56.5% Mn with 85 % recovery was obtained.

Sep 1, 2012

By K. E. Waters, J. E. Nesset, F. Rosenblum, R. Langlois, J. A. Finch

"Some sulphide mineral mixtures when exposed to air and a warm and humid environment can exhibit a self-generating temperature rise, referred to as self-heating or spontaneous heating. The observed self-heating derives from the oxidation reactions of the active sulphides. In previous publications by the authors, it was proposed that the self-heating of sulphides proceed in three distinct stages; namely, Stage A, Stage B and Stage C. In Stage A (<100OC) the sulphides, in the presence of moisture are oxidized, generating heat through a series of sequential reactions and forming elemental sulphur as one of the products. In Stage B (>100OC) the elemental sulphur produced in Stage A is further oxidized to generate additional heat and SO2. Stage C (>~380OC), sometimes referred to as thermal runaway or roasting, is not addressed in this paper. This communication focuses on the type and role of elemental sulphur found in Stages A and B, and the sequence of reactions that is occurring in Stage A. The sequence is divided into two phases, the first based on galvanic interaction between the sulphide minerals that generates an acidic environment but little heat, and the second involving the production of H2S which rapidly oxidizes to produce heat and elemental sulphur. To date, data suggest that the primary oxidation product formed in Stage A is the stable orthorhombic a-S8 form of elemental sulphur. Above 96OC the a-S8 transforms to a monoclinic ß-S8 structure which is less stable and will readily oxidize to generate heat and SO2. Above 159OC a proportion of the ß-S8 sulphur will transition to a polymeric Sµ form of sulphur which can readily volatilize. INTRODUCTION Some particulate and granular materials, when exposed to appropriate atmospheric and physical conditions, can exhibit a self-induced temperature rise resulting from accumulated heat due to internal exothermic oxidation reactions. This phenomenon is commonly referred to as self-heating or spontaneous heating. Under favorable physical and environmental conditions, these reactions can elevate the temperature of a given material from ambient to the point of auto-ignition. Self-heating behaviour should not be equated to pyrophoric behaviour which describes a group of materials (e.g. certain finely powdered metals) that will ignite spontaneously in air below 55OC. There are numerous materials such as coals, hay, forestry wood products, food products to name a few that can exhibit self-heating behaviour. This publication continues the focus of the authors on the self-heating of sulphide mineral mixtures. Many of the metals of commercial use found in nature are in the form of these sulphides which must be mined, crushed, ground and concentrated prior to smelting or hydrometallurgical processing in order to produce primary metal. The issues of sulphide self-heating therefore pertain to the mining and processing of metals."

Jan 1, 2018

By Seoul National University, Ki-Ho Kim, Jong-Pyo Kim, Sung-Min Joo, Hee-Chan Cho, Hyung-Seok Kim

Aragonite was synthesized in addition of Mg2+ ion and SrCO3 seed by carbonation process, and the best condition and mechanism of the synthesis was studied by analysis of continuous pH change, ICP, XRD, and SEM. As MgCl2•6H2O addition increased, aragonite phase increased at condition of CO2 flow rate of 100 mL/min and stirring rate of 250 rpm. It was the dissolution of Mg(OH)2 that determined overall reaction time. As SrCO3 seed addition increased at 0.2 mole MgCl2•6H2O, the amount of aragonite increased and the aspect ratio was from 5 to 9. And it was thought that Mg2+ ion prohibited calcitetransformation of aragonite formed by SrCO3.

Jan 1, 2003

By Hossein Zarei, Masoud Kashani, Mehdi Safari

The feed of flotation unit in Angouran mine, as a part of Iranian Lead and Zinc National Corporation, contains about 34.26% zinc (about 12% Zn sulphide) and 10.14% lead (about 2% Pb sulphide). The grade of Pb and Zn in the final concentrate (rougher+scavenger), under optimal conditions (200 g/ton PEX, 500 g/ton zinc sulfate, 30 g/ton MIBC and pH = 7.5), was 63.18% and 13.01%, respectively, and the total Pb (sulphide-oxide) recovery was about 19% which included 95% Pb sulphide. The grade of Pb and Zn in rougher concentrate step was about 71.86% and 5.97%, respectively, when PEX (Potassium Ethyl Xanthate) was used as collector. While in the presence of PAX (Potassium Amyl Xanthate), the grade of Pb and Zn in rougher concentrate step was 66.8% and 10%, respectively. Tailing of the galena flotation (with 8.48% Pb grade and 34.92% Zn grade under the optimal conditions) was used as a feed for sphalerite and oxide section flotation.

Jan 1, 2014

By Volker Vogt, Wolfgang Sand, Eberhard Gock

"For about 20 years, the use of bacteria to control the flotation process for the production of raw material concentrates has been the subject of worldwide scientific and engineering efforts. The objective is to reduce the consumption of biologically non-degradable toxic reagents. The principle idea is to use the activity of bacteria in natural leaching processes – known since the middle of the last century – for controlling flotation processes.It was discovered that the selective activity of bacteria during the extraction of raw material concentrates by means of flotation could also be achieved with extracellular polymeric substances (EPS), excreted by bacteria. EPS, which is extracted by means of centrifuging bacterial cultures, can help to significantly reduce the use of cyanides, approximately 200,000 t/a are used for ore dressing today.The bacterium used was Acidithiobacillus ferrooxidans. In order to identify the bandwidth of the oxidation activity, 21 bacterial strains of the strain collection of the University of Hamburg were attracted to iron(II) sulfate and pyrite under defined conditions. All strains oxidized iron(II) sulfate ten times faster than pyrite.EPS has so far been derived from four strains. In general, EPS extracts are divided into a hydrophilic and a hydrophobic fraction. The hydrophilic fraction is composed of e.g. fucose, rhamnose and glucose; fatty acids such as dodecanoic acid, hexadecanoic acid, octadecanoic acid and nonadecanoic acid were found in the hydrophobic fraction. Pure mineral phases and mineral mixtures were used for the flotation tests. The outcome was reproducible results with technical flotation machines. The research results known so far are mainly based on investigations with micro flotation devices, which are usually used for the characterization of reagents and which do not allow a direct translation to the technical scale."

Jan 1, 2003

By Montaser S. EL Salmawy, Takahide Wakamatsu, Eishi Kusaka

"In conventional flotation, fluoride ions selectively would react with the aluminum site on the microcline surface and produce negative charged sites for amine to be adsorbed (Smith, 1976). According to this view, aluminum site is considered as a key feature in feldspar flotation. Generally, fluoride ion has been widely used as a modifying agent in silicate flotation. Since O'Meara's patent appeared on HF -amine reagent system to selectively float feldspar from quartz in 1942, relatively few contributions have been devoted in this issue. The reason might be that the process works very well, and accordingly there is no initiative to investigate in this area. However, due to the awareness of international community to restrict using of hazardous reagents like HF, sound engineering practice to search for alternative methods, not utilizing HF, has been launched. Inspection of literature, one can find several works dealing with this issue.In this contribution, the effect of ethoxylation of long chain alcohols on the quartz and feldspar flotation behaviors was investigated for surfactants of the octylphenol polyoxyethylene family. The tests were carried out with an average of 7.5 (Triton X 114), 9.5 (Triton X 100), 30 (Triton X305), 40 (Triton X 405) and 70 (TritonX 705) oxyethylene units. Electrokinetic and flotation studies on quartz have shown that at low pH values, quartz could be floated with polyoxyethylene octytlphenols. The possible mode of adsorption of these nonionic surfactants may be suggested to be due to hydrogen bonding between the oxygen of ether and hydrogen in the free hydroxyl groups on quartz surface. It was anticipated that the selectivity between quartz and microcline would decrease as oxyethylenic chain length increases."

Jan 1, 2003

By D. Moradkhani

Copper metal has important role in the basic industrials, as if it did not exist, modern human life would not develop! Copper leaching, as the first step, is important step in copper production processes. In this research, efficient factors on the leaching have been investigated. For this reason, four efficient factors on leaching namely pH, liquid to solid ratio (L/S), temperature and time, as independent variables, were optimized using response surface (RSM) with D-optimal. A quadratic equation was used to create response and contours. According to the results from analysis of variance (ANOVA), the value of determination coefficient (R2=96.77%) indicates that the model was good fit. Optimum experiment condition also was found: pH of 1, L/S of 8.24, temperature of 26.06 ? and time of 43.64 min. At this condition, the maximum recovery of copper was equaled to 92/38 in which good desirability achieved.

Sep 1, 2012

By H. Z. Kuyumcu

Associated with the development of a novel microbiological oxidation process for the conditioning of iron hydroxide slurries from ferrous mine waters, there is a realistic chance to make the contained iron available for a material utilization. The transformation of ferrous into ferric compounds is coupled with the precipitation of iron hydroxisulphate mostly in terms of the mineral Schwert-mannite. The further treatment of the iron hydroxisulphate has to be aimed on the processing for product recovery and product refinement. For many potential applications, e.g. in the ceramic industry, the pigment industry or for metallurgical applications, the removal of sulphate is essential. For the dehydration of the iron hydroxisulphate and the sulphate removal, microwave heating technology is a beneficial method. In contrast to conventional thermal heating processes the supply of energy in microwave application takes place directly within the material through the dissipation of electromagnetic energy, i.e. no heating medium is needed. It is a volumetric heating process regardless of the surface of the material. The rapid and targeted energy supply and the good controllability of microwave heating systems are advantages which have led to a wide variety of applications in industrial processes. Among the diverse use for heating of temperature-sensitive, chemical and pharmaceutical products as well as foodstuffs the number of applications also in mineral and solid processing increases. At the Department for Mechanical Process Engineering and Solids Processing of the Technical University Berlin the use of microwave technology for the treatment of iron hydroxisulphates has been investigated systematically within the framework of a cooperative research project. The paper at hand shows results from material conversion tests subject to a variation of the relevant process parameters. The reaction products are characterized and the process is compared with the conventional heating in a rotary kiln.

Jan 1, 2014

By Chen Dong, Yang Wenwang, Liu Zhineng, Tan Ming

"To meet the requirement of production expanding of a certain potash ore dressing plant in Xinjiang province of China, industrial test of XCF/KYF-50 flotation machine was performed to process potash ore. The tank of XCF/KYF-50 flotation cell is in U shape, 50m3 of volume. This flotation cell is able to suck slurry by itself, and can be arranged on the same base level without high difference. In this paper, two sets of XCF/KYF-50 flotation cells were adopted to replace 8 sets of 8m3 flotation cell in original flow sheet of flotation. Aeration rate, slurry suction capacity, power consumption and slurry suspension are investigated. The measuring results show the slurry suction capacity of the flotation cell is larger than 12.80m3/min and solid particles disperse evenly in the tank without deposition. Industrial test result indicates that the final grade of concentrate is 26.69% at the recovery of 90.95%, which is up to expected performance. XCF/KYF-50 flotation cell has advantages of high flotation efficiency, significant energy saving and reasonable configuration of automatic control system, this kind of flotation cell can meet the requirement of production expanding of this potash ore dressing plant well."

Jan 1, 2014