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By Beatriz Fausta Gandra

A preservação do refratário do cadinho é fator determinante para o prolongamento da vida útil de altos-fornos. Assim, o presente estudo teve por objetivo avaliar o efeito da variação da composição química do gusa (silício, manganês e enxofre) sobre o bloco de carbono do cadinho, com foco na obtenção de informações que permitiram inferir sobre a viscosidade e a tensão superficial do gusa. Isto foi realizado por meio de análises via microscopia de aquecimento e ensaios para determinar a penetração de gusa em bloco de carbono a altas temperaturas. Os resultados indicaram a tendência de elevação do ângulo de contato entre o gusa e o bloco de carbono a partir do aumento do silício e do enxofre no gusa. Por outro lado, verificou-se que o ângulo de contato reduz com o aumento do manganês no gusa. Dessa forma, o gusa contendo maiores teores de silício e enxofre penetrou de forma menos significativa no bloco de carbono, enquanto que o gusa com altos teores de manganês penetrou de forma mais intensa no bloco de carbono. Esses resultados permitem estabelecer faixas de controle da composição química do gusa, em consonância com as necessidades de preservação dos altos-fornos e de sua estabilidade operacional.

Oct 30, 2017

By B. Arjang

ABSTRACT: Ground stresses are one of the significant factors in the context of rockbursts and underground instability at some hard rock mines in Canada. Overcoring strain relief measurements using triaxiaI strain eel is were performed at depths between 60 to 1890 m at several mine sites to provide stress data for stability analysis and optimum mine design. Pre-mining ground stress determinations from 64 stress tensor analyses resulted in the following average stress gradients: Maximum horizontal stress. -Hmax - 8.18 - 0.0122 MPa/m depth Minimum horizontal stress. _-,,min - 3.64 - 0.0276 MPa/m depth Average horizontal stress. -11, 5.91 - 0.03-19 MPs m depth Vertical stress. '-, - 0.0266 - 0.008 MPa/m depth The maximum and minimum horizontal compressive stresses. with an average ratio of 1.75 ,0..45. prevail in east--west and northerly directions. respectively. Horizontal compressive stresses in excess of vertical overburden load were determined. indicating large variations in ratios to a depth of about 1000 m with decreasing trend towards depth. From present data. a particular regional zoning for the magnitude and direction of horizontal stress fields cannot be outlined. A common feature at mines with near vertical orebodies is that the maximum horizontal compressive stress acts perpendicular to strike while the minimum horizontal compressive stress is aligned on-strike. The vertical stress components approach the gravitational overburden load.

Jan 1, 1989

By B. J. Moore

This publication contains analyses and related source data for 352 natural gas samples from wells and pipelines in 18 States and 5 foreign countries. All of the samples were obtained and analyzed during calendar year 1974 as a part of Bureau of Mines investigations of the occurrences of helium in natural gases of countries with free market economics. This survey has been conducted in the United States by the Bureau of Mines since 1917. In late 1965, the survey was expanded to include foreign gasfields. The analyses published herein were made by mass spectrometer and a special helium analysis apparatus, which are described in Bureau of Mines Bulletins 4862 and 576.3 The results of the investigation of the occurrences of helium are published annually to make the information available as soon as possible to the gas industry and the public in general. Sixteen previous publications have presented the results of 10,479 gas analyses prior to 1974. The first three, Bulletins 486,4 576,5 and 617,6 contain analyses and related source data on

Jan 1, 1975

By J. D. T. Steyl, C. A. Biley

"The chemistry of electrolyte systems containing iron remains generally poorly understood despite their prevalence in many natural and industrial processes, particularly in hydrometallurgy. These systems are typically challenging to study and model due to their affinity for complex formation and precipitation even at low pH. Recent developments in the hydrometallurgical processing of nickel laterites at Anglo American have called for a deeper understanding of the fundamental chemistry of the Fe2(SO4)3–FeSO4–H2SO4–H2O system. This paper details the development of an internally consistent, Pitzer ion-interaction model of this system, with explicit recognition of important contact ion pairs (CIPs). The primary application of this model is a thermodynamic framework for the interpretation of kinetic processes occurring during iron(III) reduction with SO2. Adopting a rigorous thermodynamic basis for the system chemistry facilitates the formulation of simple rate expressions that are capable of inherently capturing complex effects. While the iron(III) reduction case study remains the focus of this work, the developments have more universal applications and the thermodynamic speciation model can be extended into other systems containing acidic ferric sulfate.INTRODUCTIONIron is present in nearly all hydrometallurgical refining circuits typically as both a necessary and unwanted impurity and needs to be removed and disposed in a safe and efficient manner. This is generally performed by precipitation to form a range of solids such as hematite, goethite or jarosite. Numerous studies in the open literature have focussed on the removal of iron from refractory gold sulfide ore (Berezowsky & Weir, 1989; Berezowsky et al., 1991) and zinc pressure leaching (Buban, 1999; Ismael, 2003), and PGM matte sulfide circuits (Dutrizac & Monhemius, 1986). Moreover, since ferric iron is a strong oxidizing agent, it has been used extensively as a leaching agent for sulfide minerals (Dreisinger, 2006). Given the outlook of challenging economic conditions, declining ore grades and increasing levels of impurities, effective iron management is going to become increasingly critical to all hydrometallurgical processes.Against this background, and considering the widespread importance of acidic iron sulfate systems throughout natural and industrial processes, it is unexpected that the knowledge of the fundamental solution chemistry of these systems contains such significant gaps, particularly at the conditions typically found in hydrometallurgical applications. Existing literature describing the measurement and modelling of solution speciation in these systems have highlighted their significant chemical complexity (Magini & Caminiti, 1977; Magini, 1979; Lee & Tavlarides, 1985; Stipp, 1990; Papangelakis et al., 1994; Gil et al., 1995; Majzlan & Myneni, 2005; Kormanyos et al., 2008; Yue et al., 2014). Partially responsible for the lack of quantitative speciation measurements is the strong tendency of ferric to hydrolyse at even low pH (Flynn, 1984), complicating the laboratory study of such systems. Moreover, the large number of aqueous species that may co-exist simultaneously makes the study of individual species and the modelling of the numerous interactions between these species extremely difficult (Dry & Bryson, 1988; Stipp, 1990; Majzlan & Myeni, 2005; Kobylin et al., 2007)."

Jan 1, 2016

By Enrique Solari

"El presente texto describe el trabajo de las minas de plata, oro y cobre durante la Pre-historia en Chile. En Hauntajaya y Yabricoya los indios trabajaron el cloruro de plata o plata córnea y la plata nativa. Sin embargo, los atacameños y diaguitas, fueron los únicos habitantes prehistóricos que practicaron la metalurgia, aunque no utilizaron el fierro en ninguna de sus formas, debido a su alto punto de fusión. Asimismo, en los primeros cateos o prospecciones que realizaron los indios, buscaban rocas y minerales, tales como la arcilla, el cuarzo, la cuarcita, el sílex, el lapislázuli, la obsidiana, la calcedonia, el jaspe, el ágata, el pedernal y los trabajaron con un gran conocimiento empírico de clivaje para la confección de herramientas y adorno. El método usado en la prospección de minerales fue a través del color, cobre, verde siticatado llamado por los indígenas 'Tanca"" y el carbonato de cobre (malaquita- azurita) llamado por los españoles como ""cardenillo"". Asimismo, los cateadores de minas prehistóricas contribuyeron en el norte de Chile, -en tanto bagaje de conocimientos- de los cuales, los cateadores hasta la época de la República, se sirvieron a la gran aventura de los derroteros de minas. "

Mar 1, 1967

Martin Marietta Aluminum, Inc. followed Howmet Aluminum Corp., Revere Copper and Brass, Inc. and Anaconda Co. in lifting August prices of 99.5 percent unalloyed aluminum ingot by 3 cents to 56 cents per pound. Prior to these moves, Kaiser Aluminum and Chemical Corp. raised its June ingot listings by 4 cents to 57 cents and Consolidated Aluminum Corp., 4.5 cents to 57.5 cents. Domestic merchants increased July quotes by slightly more than 1 cent to 51.3-51.8 cents per pound. ARSENIC The Occupational Safety and Health Administration (OSHA) issued new standards, effective August 1, for worker exposure to inorganic arsenic, a toxic substance linked by OSHA to lung and lymphatic cancer. The new standard will limit worker exposure to 10 micrograms per cubic meter of air over an 8-hour period, a drastic reduction from the previous standard of 500 micrograms for a like period. Implementation of the new standards may be the most difficult and costly for copper smelters where arsenic is associated with the copper feed material but problems will also be encountered by producers of arsenic containing products such as for pesticides and herbicides. The new standards allow use of personal protective gear for workers as an interim measure until plant engineering controls can be put into effect.

Jan 1, 1978

By Dirk Arts

En el 2012 Río Tinto minera inició el diseño del sistema de monitoreo y evaluación para medir el desarrollo social del proyecto La Granja en Cajamarca, Perú. En este sentido, el presente texto señala la medición de este desempeño social a través de un sistema comprendido en cuatro pilares como: seguimiento del compromiso de las partes interesadas y el manejo de las realciones comunitarias, medición de los resultados directos del proyecto y cómo contribuyen en el impacto social (modelo de resultados), el monitoreo de las tendencias y cambios sociales a nivel local y doméstico y el monitoreo de la reputación y nivel de consenso social. El objetivo es identificar el alcance, contribución y grado de influencia del proyecto La Granja en el cambio e impacto social.

Aug 1, 2014

By E. J. Roberts

Hydrometallurgical operations and many processes in the chemical industry require the separation of dissolved material from solids. One of the decisions which has to be made in designing a plant for such an operation is how this separation shall be accomplished. It is the purpose of this paper to set forth the general principles involved in such separations in order that the optimum flowsheet and equipment may be selected. Countercurrent Decantation with thickeners, or C.C.D. as it is generally known, is, of course, only one way of separating dissolved material from undis-solved. Other unit operations such as Countercurrent Filtration (C.C.F.) and Countercurrent Classification (C.C.C.) are widely used. The same principles may also be applied to centrifugally assisted decantation, as with nozzle or solid bowl type centrifugals, and to separations using screens, either gravity or centrifugal type. Another form of countercurrent washing applicable to granular materials is practiced in continuous ion exchange operations. All of these operations depend on two basic principles, or combinations of these principles. In C.C.D. type operations the solids are concentrated into the smallest possible volume of liquor in each step and the resulting pulp then mixed with a more dilute liquor and recon cen trated, the liquors separated from the more dilute stages being advanced to dilute the more concentrated liquor in a previous solids concentrate, as is shown in Fig. I. This will be termed the solids concentration-solution dilution principle, or, for short, solution dilution. countercurrent decantation- type circuits. The second principle used in washing solubles from solids is that of solids concentration-solution displacement. Here the solids are restrained from movement while wash solution is forced through the interstices in a counter-current fashion, as in Fig. 2. In the simplest application of this principle, once the "cake" has been formed, it is not disturbed until the operation is completed. In continuous filters, the cake is merely moved under the successive washes and the displaced filtrates removed as in Fig. 4. Often, however, after one or two displacement washes, a repulping step is introduced, the cake reformed and washed again. This procedure brings the solution dilution principle into play as well as the solution displacement principle. Merely thickening ahead of filtration, which is often operationally advantageous, does not hybridize he circuit. It still can be a pure solution displacement operation from the washing

Jan 1, 1961

By C. W. Davie

"This paper is the second of a series of progress reports4 on a study of the hydrometallurgy of manganese which is being conducted in an endeavor to make possible utilization of the large deposits of low-grade domestic manganese ores that occur in several States.There are at least four processes in which a knowledge of the action of SO2 gas on manganese oxides at elevated temperatures may prove of value.One of these involves dissolution of manganese from ores. The Bureau of Mines has investigated the hydrometallurgy of manganese by a process in which SO2 gas, a waste product at many smelters, is passed into water to form a solvent for manganese. Although several manganese minerals were readily dissolved, rhodochrosite (MnCO3) was attacked but superficially.5 Recent experiments have shown that a roast at 650 to 9000 C. converts the manganese of rhodochrosite to a form that is quickly dissolved by a weak SO2 solution.6 Introduction of smelter gases containing much as 5 per cent SO2 during such a roast would not add much to the cost of the operation, and might result in the formation of considerable water-soluble manganese sulpate.Another case involves a subsequent step in the hydrometallurgical process, namely, the formation of oxides of manganese with simultaneous evolution of SO2 by the heating of the MnSO4 produced by evaporating its solution.A third has to do with the roasting of zinc sulphide ores containing manganese as a preliminary to leaching. During purification of the solutions to be used for the electrolytic deposition of zinc the iron must be oxidized to make possible its removal. Manganese dioxide has been used for this purpose,7 and since manganese compounds are present in some zinc concentrates,8 it is of interest to learn what happens to the manganese in a zinc sulphide or on roasting, and what portion of the manganese in the roasted product might be available for oxidation."

Oct 1, 1930

By A. L. Garassino

Dans cet article on parle sortout de l'approche de calcule pour les pieux charges horizontalement avec particuliere reference aux curbes p-y et è une solution semi-empirique qui prende en consideration les variations typiques du module du sol avec la deformation obtenue par les données expérimentales. 1. INTRODUCTION The analysis of the piles under lateral loads depends very strictly from the pile stiffness and geometry, from the soil type and from the strain field. Different approaches were adopted in solving the problem. Some Authors developed methods for estimating the ultimate lateral resistance of piles and pile groups by conventional static approaches, as the Brom's widely known (1964) or by the plane strain solution developed by Davis (1961) or by empirical engineering con­siderations l

Jan 1, 1994

This paper reviews the development and operation of a small underground tin mine in NE Tasmania. Tin mineralisation was discovered in the Lottah area in the 1880s with early alluvial and eluvial workings leading to the development of large low grade open pit operations. Apart from short lived activities operations ceased in 1915. Intensive exploration in 1978 - 1981 outlined substantial tonnages of low grade tin mineralisation (0.2% Sn) of open pit material. An underground ore body was also located (800 000 tonnes 0.6 per cent Sn). Spectrum Resources Australia Pty Limited acquired a 98 per cent interest in the property in 1988. Mine and mill development began in early 1989 based on an underground mine utilising trackless mining using room and pillar with fill stoping. The milling circuit involves primary jaw crushing, Barmac secondary crushing to 1 mm, Mogensen and DSM screens with jigs and tables to make a wet concentrate. Final tin concentrates are produced by high tension and magnetic separation. Planned production rates are 500 t/day with a mine life of six to seven years.

Jan 1, 1990

With the proving of a mineable orebody at Orlando in May 1961, Peko Mines N.L. was faced with the decision of whether to mill the ore on site or to haul it 25 miles to central facilities at Peko. Orlando was a relatively small orebody, so that it was decided to haul, although no reliable assessment of possible ore haulage costs was available.The necessity for a good haul road was recognised from the beginning and a 17 mile, 12 ft wide, single seal bitumen road was constructed, to link the mine to the Stuart Highway and Peko. The initial selection of 20 ton capacity diesel-powered end-tipping ore carts was made, with the best information available at the time.Since then some 130,000 tons of ore have been carted over a period of 3 years, and this paper presents the experiences of this haulage operation and the lessons learned.A second mine has just been brought into operation at Ivanhoe, 19 miles from Peko. For this haul it was decided to use an ore haulage vehicle of the side tipping road train type, which would cart some 70 tons, or more than three times the load of the vehicles initially selected.Only about 5,000 tons had been hauled at the date of this paper, but preliminary figures indicate a cost 01 1· 65d./ton-mile as against 2·47d. for the smaller vehicles.It would appear that the road haulage of ore from small outlying mines to a central plant can be highly economical, if certain basic rules concerning haul roads and vehicle selection are followed. This paper does not try to determine the maximum tonnages and haul distances which would finally make road hauling uneconomical...

Jan 1, 1966

The design, specification, and performance evaluation of the Communications and Location portions of a Coal Mine Rescue and Survival System are described. The work was performed as part of a nine month effort to develop a mine rescue and survival system using existing technology and state -of-the -art hardware as recommended by the National Academy of Engineering. Three basic subsystems were developed, one for survival, one for communications/location and one for rescue. This report and related equipment manuals describe only the Communications/ Location Subsystem which was designed, fabricated, and tested by the Westinghouse Georesearch Laboratory in Boulder, Colorado. Two basic technologies were used. Electromagnetic signals propagating through-the-earth provide voice downlink and coded beacon up-link communications. Seismic methods were developed to provide means for locating trapped miners. Seismic signalling also provides a backup means for communications. Parallel development programs for the electromagnetic and seismic portions of the system were conducted. The resulting hardware and software have been partially tested in coal mines and under simulated emergency conditions in order to evaluate system performance. The results of these tests are discussed. Further testing is recommended in order to establish quantitative performance limitations tinder a variety of environmental conditions and to develop methods for improving system performance.

Jan 1, 1971

By J. C. Escobedo, J. M. Almanza, A. Flores, Cortés. D. A.

Secondary aluminum dross, which has been exposed for several years to atmospheric conditions, was characterized using chemical analysis, X-ray diffraction, optical and scanning electronic microscopy, and energy-dispersive spectroscopy. Based on the characterization, a method to purify the solids is presented. This method starts with the washing of the dross in boiling water to eliminate the soluble compounds like Na and K, followed by the physical separation of the metallic aluminum by milling and screening. Finally, an acid lixiviation process is applied using three different acid solutions, HCl, HNO3, and H2SO4. The best results were obtained using HCl. The main insoluble components of the dross after lixiviation were Al, SiO2, and Al2O3. MgAl2O4, AlN, Si, and Na2Al22O3·2H20 species were also found. Based on the alumina content, the solid product could be suitable as a raw material in the manufacture of castable refractories or metal matrix composites.

Jan 1, 2005

A rotating disc geometry was used to provide a uniformly accessible surface for a kinetic study of the cementation of cadmium, lead, and silver from dilute aqueous solutions. This work is an extension of studies carried out on the Cu-Zn and Cu-Fe systems for which the reaction rate was found to be completely solution phase mass transfer controlled.When the amount of material deposited was greater than 0·2 to 0·4 mg/cm2 there was an apparent enhancement in rate which is attributed to the formation of a roughened deposit. This same phenomenon was observed in the Cu-Zn and Cu-Fe systems. Again, the rate of reaction of each system investigated was found to be solution-phase mass transfer controlled.

Jan 1, 1971

By Maurice Bottiau

It is a quite challenging objective to aim at covering in one paper the most recent evolution in piling and deep foundations technologies. This report has to be understood within the limits of the session 2b. It will therefore concentrate on the technological evolution of deep foundation techniques, addressing design issues only when directly related to execution aspects. For the same reason, it will not address the related codes, as a separate session of this conference is specifically dedicated to this topic. Monitoring and deep excavations being covered in other sessions, they will only be addressed when clearly relevant. We will try to show, from a practical viewpoint what are the main changes and the most exciting or critical issues over the last years, as they appear from the topics addressed in the literature or in the papers published in this session of the conference. As the paper mostly intends to explain trends and critical topics, it cannot be exhaustive, neither can it give the full description of the case studies. The author invites the reader to read the full papers, for a more complete description. We have divided our report in three main topics: Piling, soil improvement and treatment and retaining walls. Anchors and tie-backs will not be treated, neither tunneling.

Jan 1, 2006

By E Selvapandian, R Barr

Arrium (previously OneSteel) initiated a desktop study into the performance of its hematite ore beneficiation plant in early 2010. The beneficiation plant utilises jig concentrators and spirals to upgrade low-grade hematite recovered during mining at the Iron Duke (ID) mine site located 60 km south-west of Whyalla. The study, conducted in conjunction with Mineral Technologies, identified a number of opportunities for improvement, which were validated by a series of sampling campaigns and a pilot plant trial. One of the major recommendations was to upgrade the ultra-fines processing circuit from a single-stage spiral circuit to a three-stage circuit. The upgrade of the ultra-fines circuit was estimated to provide a significant increase in fines production and grade.In order to capitalise on the strong iron price at the time of the project, Arrium decided to utilise a fast-tracked approach to design, construct and commission the processing equipment required to achieve the improvements identified. This decision introduced the risk of missing critical steps in the project development process, which could have potentially resulted in major issues in latter stages of the project. In addition to the challenges introduced due to the expedited time line for project completion, this project presented unique challenges due to its brownfield nature. One such challenge faced was the integration of the new equipment and control system software.Furthermore, the importance of the ID ore beneficiation plant (OBP) contribution to the companyÆs export commitments meant the upgrade work had to occur while minimising disruption to normal operation. This decision presented a set of new challenges to an already complex project. One such challenge was the need to build and commission the new spiral circuit in isolation from the operating plant.The aim of this paper will be to highlight some of the challenges faced in a complex brownfield project such as the ID OBP upgrade and discuss how they were managed to enable the successful commissioning of the process in early 2012.CITATION:Selvapandian E and Barr, R, 2013. Managing challenges faced in the brownfield commissioning of an ultra-fine hematite processing circuit at ArriumÆs Iron Duke ore beneficiation plant, in Proceedings Iron Ore 2013 , pp 533-538 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 12, 2013

By A. Sandberg, M. Nzotta, Du Sichen, N. N. Tripathi, K. Beskow

The present study was carried out to investigate the impact of slag refractory lining reactions on the formation of inclusions during ladle treatment of steel. The experiments were conducted on an industrial scale in the ladle at Uddeholm Tooling AB in Hagfors, Sweden. The inclusion chemistry and population during ladle treatment were studied along with the composition of the ladle glaze, taken from the ladle lining. The inclusions in the steel were classified into four groups according to the Swedish standard SS 111116. SEM/EDS analyses were carried out to identify the phases present in both the inclusions and the ladle glaze. The number of inclusions in the steel before deoxidation was found to increase with the ladle age, i.e. the number of times the ladle had been in use. A similar increase was also found after vacuum degassing and before casting. A great portion of inclusions before casting was found to be supplied by ladle glaze. This observation was further confirmed and explained by thermodynamic analysis. The present results show that ladle glaze is a major source of inclusions in the ladle at Uddeholm Tooling. Keywords: Slag/ refractory/ lining?reactions, ladle glaze, inclusions, inclusion chemistry, ladle treatment

Jan 1, 2004

By Pitter Huapaya, Enrique Segura, César Espejo

La reactivación química o lavado químico se realiza con la finalidad de retirar el carbonato, sulfatos y demás iones que incrementa la alcalinidad, los cuales también son adsorbidos por el carbón. Es en esta etapa que se vio una oportunidad de mejora debido a que luego del lavado químico debido al uso de ácido clorhídrico hay presencia de complejos de cloro que quedan adsorbidos en el carbón activado y al retornar al proceso de adsorción restan la eficiencia para el reusó en el proceso haciendo que el tiempo de saturación se reduzca, perjudicando a la ley del barren por saturación temprana del carbón y para contrarrestar se tiene que incrementar el número de desorción.

Sep 29, 2023

By William O. Vanderburg

[This circular is one of two papers on the tungsten industry in the United States end contains general information on the subject. The second paper which will be issued in the near future deals with the methods ailed costs of mining and milling tungsten ores. These two papers are abstracts from the general bulletin on tungsten which will be issued at some future time Modern civilization and progress depend largely on tools wherewith the forces of nature are brought under control and directed toward human comfort. These tools are made chiefly from metals derived from the earth's crust. During the present century powerful tools have been made available through the development of ferrous and. nonferrous alloys containing such elements as molybdenum, vanadium, titanium, tantalum, and tungsten, which were little used before 1900. One of the most important of these so-called rare elements is tungsten; its use ins alloys for high-speed cutting tool is partly responsible for the era of mass production. So widespread has the use of alloys become that the period may be termed an "Alloy Age".]

Jan 1, 1935