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By P. Taskinen, D. Lindberg, H. Viitala

The formation of copper chlorides in flue dust or deposits in heat recovery boiler of copper smelters or waste-fired boilers may lead to formation of corrosive partially molten deposits on walls and heat exchangers of the boilers. These deposits can contain various other metals, such as alkalis, Fe, Zn, Pb together with oxides and sulfates. In the present study, a thermodynamic model for copper-containing binary and ternary metal chloride systems within multicomponent CuCl-CuCl2-FeCl2-FeCl3- PbCl2-ZnCl2 system has been assessed and optimized based on own experimental phase equilibrium data, as well as literature data. The thermodynamic properties of the liquid phase was modelled using the quasichemical quadruplet model and a thermodynamic database was optimized to predict all available experimental data within the experimental error limits. The thermodynamic database allows for more accurate predictions of potential corrosion-related issues in various heat recovery boilers and waste-fired boilers due to formation of copper chlorides. INTRODUCTION In the copper flash smelting, flue dust can cause severe problems in the gas train, used for separating dust from the SO2-rich off gas, by forming corroding accretions on the walls of the heat recovery boiler. Formation of dust build-ups in the boiler need to be cleaned regularly and potential corrosion damage checked, requiring costly and unscheduled shutdowns of the flash smelting process. Compounds of copper and zinc among other elements having high vapour pressures may volatilize during the smelting of the copper concentrate, forming dust when the process gas cools down. Also, particles of solid or liquid iron oxides originating from the ore get transported with process gas to the heat recovery boiler as a result of entrainment in the flue gas (Miettinen, 2008) The dust deposit build-ups on the boiler walls are formed partly by direct impact of particles and partly by vapour condensation on the boiler walls. The initial deposition takes place by the condensation of vapours that contain zinc, lead, arsenic and other metals having high vapour pressures. Also, low melting point eutectic components of alkali salts such as chlorides and sulphates can act as sticky cohesive particles attaching to the boiler walls. The fine particles landing on the surface of the porous dust deposit layer react in the SO2-rich atmosphere of the boiler to sulphates. The process gas within the boiler contains SO2, O2, SO3, H2O and N2 that diffuse into the porous accretions to form a stagnant gas layer within the dust deposit structure. The composition of this gas layer may differ greatly from the composition of the process gas that is flowing on the surface of the accretion layer. Locally HCl and H2SO4 are formed and even a reducing atmosphere may exist within the dust deposit layer, allowing new reactions to take place. The local micro-atmosphere may enable metal sulphates to be reduced to secondary sulphides and even metallic components. Within the accretion layer, components may be formed that would not be stable in the gas atmosphere inside the boiler (Miettinen, 2008). This may be the mechanism by which for instance chlorides of Cu, Fe and Zn are formed within the deposit layer.

Jan 1, 2019

By Matthias Wörndl

A indústria siderúrgica demanda um acabamento superficial de excelente qualidade em placas (slabs), antes de seu processamento em laminadores. O limite da temperatura de fresagem de 300°C exigia um esfriamento com posterior reaquecimento, gerando elevadas perdas energéticas. A empresa austríaca Maschinenfabrik Liezen com ampla experiência na fabricação de fresadoras de grande porte até 300°C desenvolveu e fabricou uma revolucionaria fresadora de alta capacidade (600.000 ton/ano), para operar de forma contínua em 800°C; nesse desenvolvimento de hardware e software foram também incorporadas várias otimizações operacionais e ambientais, sendo o destaque a fresagem modulada/inteligente, com precedente relevamento topográfico e termográfico para a localização dos defeitos superficiais, para a posterior fresagem com profundidade variável para a minimização de material retirado e simultânea eliminação dos defeitos localizados.

Aug 17, 2017

It is well known that the electrochemical precipitation of metals from aqueous solutions is conducted by the electrochemical standard potential scale. This scale indicates the order of nobility of different metals. Consequently, the standard potential scale shows the nocivity of metals when they are present as impurities in aqueous solutions containing metals. In the hydrometallurgy of cobalt, nickel and zinc are co-deposited during cobalt electrodeposition. Nickel has almost the same chemical, physical and electro-chemical properties as cobalt. Furthermore, the electrochemical potential of nickel is relatively higher than that of cobalt. For this reason nickel is preferentially reduced at the cathode in the presence of cobalt. The presence of small amounts of zinc in solution leads to contamination of cobalt electrowon. In spite of its lower electrochemical potential in comparison to cobalt, zinc is reduced on the cathode because of its higher hydrogen-overvoltage. But, in the hydrometallurgy of zinc, small amounts of cobalt present solution will contaminate the zinc reduced at the cathode. This is easily explained by the fact that cobalt is more electropositive than zinc. The co-deposition mechanism of sulphur at the cathode is not yet well understood. Great attention has to be paid to the mechanism of co-deposition of sulphur during cobalt electrolysis. This work aimed to investigate the influence of some parameters on the co-deposition of nickel, zinc and sulphur during cobalt electrowinning. The following parameters have been investigated: Co2+concentration in the electrolyte, current density and ammonium sulphate (NH4)2SO4additions. It has been established that important nickel, zinc and sulphur co-deposition takes place at relatively low Co2+ concentration in solution. The behaviour of these elements with regard to the cathodic phenomena has been established.

Jan 1, 2005

By A. Kondratiev

A structurally-based viscosity model for fully liquid silicate slags has been developed and applied to the Al2O3-CaO-‘FeO’-SiO2system at metallic iron saturation. The model links the slag viscosity to the internal structure of melts through second nearest neighbour bonds concentrations taken from the quasi-chemical thermodynamic model. This viscosity model describes experimental data over the whole temperature and composition ranges within the Al2O3-CaO-‘FeO’-SiO2system at metallic iron saturation and can now be applied to other industrial slag systems.

Jan 1, 2004

By Ahmad F. Souri, Murad Abu-Farsakh

"In this study, the static lateral resistance of vertical and battered pile groups was analyzed using 3D finite element analysis. The battered pile group finite element model was verified using the results from a case study performed on the M19 pier foundation of the I-10 twin span bridge in Louisiana. The vertical pile group model was created by adjusting pile inclinations of the verified battered pile group model. The finite element models utilized nonlinear constitutive models for materials behavior and a soil-pile interface model. The results showed that the battered pile group had greater lateral resistance than the vertical pile group with 60-70% lower pile cap displacement. The largest lateral load share was found in the middle rows in the battered pile group, while it was in the leading row for the vertical. The soil resistance profiles showed that the vertical pile group mobilized greater soil resistance compared to the battered pile group.INTRODUCTIONThe lateral resistance of a pile-soil system depends on both pile stiffness and soil reaction. The soil reaction is a nonlinear function of deflection, depth, pile stiffness, and soil stiffness and strength. The lateral capacity of single piles is evaluated at the maximum deflection limit, and can be predicted using established methods such as the p-y curve method (e.g., Matlock 1970, Reese et al. 1974), elastic solution by Poulos and Davis (1980), the strain wedge model (Ashour et al. 2004), and the finite element method (e.g., Yang and Jeremic 2002, Comodromos and Pitilakis 2005, Isenhower et al. 2014). For pile groups, the lateral capacity of a pile-in-group is less than the isolated single pile case because the soil in front of the pile-in-group is weakened by the overlap of stress zones from surrounding piles. The latter is referred to as the shadowing or group effect (Fig. 1). Prediction of the lateral capacity for pile groups is based on the p-y curve method for single piles with the use of empirical factors called “p-multipliers”. The p-multipliers accounts for the shadowing effect, and are a function of pile-pile spacing and soil type (e.g., Brown et al. 1987, 1988, McVay et al. 1995). Moreover, the lateral capacity of pile groups is also influenced by vertical load, piles arrangement, and slenderness ratio (e.g., Rao et al. 1998, Patra and Pise 2001, Ilyas et al. 2004, Hussien et al. 2012).Battered piles refer to piles installed at an angle with respect to the vertical to increase their lateral capacity. The greater lateral resistance is achieved by the additional axial reaction in the pile. Battered piles are called “negative battered” when inclined in the load direction, and “positive battered” when inclined opposite to the load direction (Fig. 1). Previous studies concluded that the lateral resistance is highest in positive battered piles followed by negative battered and vertical piles, respectively (Murthy 1964, Meyerhof and Yalcin 1993, Zhang et al. 1999)."

Jan 1, 2017

By D. François-Bongarçon

When it comes to sampling theory, a bad sampler is a bad sampler, no matter what, and a sampler is either bad or good. It also is of critical economic importance to tell and understand the difference, especially in a metallurgical plant. In this paper, the grand principles of Sampling Theory are first recalled, then the most popular types of sample cutters for plants are critically reviewed. It is concluded that the industry has a lot of progresses to make in that direction, although improvements usually pay for themselves very quickly.

Jan 1, 2002

To the members of The South African Institute of Mining and Metallurgy We have audited the annual financial statements of The South African Institute of Mining and Metallurgy set out on pages 483 to 496 for the year ended 30 June 2004. These financial statements are the responsibility of the Institute?s Council. Our responsibility is to express an opinion on these financial statements based on our audit. Scope We have conducted our audit in accordance with statements of South African Auditing Standards. Those standards require that we plan and perform the audit to obtain reasonable assurance that the financial statements are free of material misstatement. An audit includes: ?examining, on a test basis, evidence supporting the amounts and disclosures in the financial statements, ?assessing the accounting principles used and significant estimates made by management, and ?evaluating the overall financial statement presentation. We believe that our audit provides a reasonable basis for our opinion. Audit opinion In our opinion, the financial statements fairly present, in all material respects, the financial position of the Institute at 30 June 2004 and the results of its operations and cash flows for the year then ended in accordance with South African Statements of Generally Accepted Accounting Practice. Auditors 30 July 2004 Council?s approval of the annual financial statements The annual financial statements for the year ended 30 June 2004 set out on pages 483 to 496 were approved by the Council on 30 July 2004 and are signed on its behalf by:

Jan 1, 2004

Flotation of Smithsonite by Using Siloxane Cationic Surfactants as Collectors

Sep 13, 2010

By J. E. McGill

The junior and small-scale mining sectors in South Africa play an important role in the livelihoods of numerous communities. Mining presents an opportunity, in the post-1994 democratic era, for many individuals to obtain access to much required empowerment and socio-economic development. These sectors are, however, not without numerous characteristics that pose problems for operators, legislators, and other role-players. Mining is inherently risky, with operators experiencing frequent difficulties and challenges throughout the life of mine. Opportunity exists, and needs to be enhanced, for junior and small-scale prospects and operations to include technical risk assessment techniques in documentation presented in search for funding, and in optimizing monthly planning and longer-term functioning. The focus here is to explore how the risk management cycle may currently be applied to a mineral resource suitable for exploitation by the junior and small-scale mining sectors. No management process can create additional value in the ground, but various available mechanisms can go a long way to quantifying the inherent risk that exists, highlighting the need to manage the risks and hopefully allowing the entrepreneur access to the intrinsic opportunities of the emerging mining sector in South Africa.

Jan 1, 2006

Reverse Cationic Flotation of Iron Ores - Floatability of Amphiboles at Depression of Iron Oxides by Starch

Sep 13, 2010

By Edwin S. Secor

The Federal Bureau of Mines conducted a field survey of 153 bituminous coal strip and auger mines to estimate coal recovery from surface mines in the Eastern United States. Recovery was calculated from field data by measuring coal losses resulting from mining coal and leaving barriers. Mean total recovery for strip mining in States east of the Mississippi River was 83.0 percent and ranged from 72.3 percent for Tennessee to 91.3 percent for Maryland. Mining losses and barrier losses were 10.1 and 7.7 percent, with standard deviations of 4.8 and 10.4 percent, respectively, indicating that barrier losses, although less than mining losses, were more variable. Mean total coal recovery varied only slightly for the two regions studied; 82.7 percent for Appalachia and 84.3 for the Midwest. Total recovery grouped by mining method--contour, area, and mountaintop removal--was 79.8,84.7, and 85.3 percent, respectively. Mean auger recovery was 35.9 percent; of the total average loss of 64.1 percent, over one-half resulted from design limitations while the remainder was attributed to operating losses. The wide recovery range at individual mines indicates the variability of the eastern surface coal mining industry. Because of this, care should be exercised in applying the results of this report to reserve estimates other than those of a general nature.

Jan 1, 1977

By João Paulo Sousa Coelho

A sedimentação consiste em uma operação unitária de separação entre sólidos e líquido, realizada em tanques denominados sedimentadores, que se baseia na ação do campo gravitacional sobre as partículas para decantá-las e removê-las da água. Sua eficácia é extremamente dependente do tamanho das partículas, tendo em vista que a velocidade de sedimentação é diretamente proporcional ao tamanho delas. Dessa forma, no espessamento das lamas, é imprescindível a utilização de reagentes químicos (coagulante e floculante) que possibilitem a formação de agregados de maior tamanho. Neste contexto, realizou-se esse trabalho para investigar o efeito da dosagem desses reagentes sobre a sedimentação de lamas de minério de ferro. Para isso, empregou-se o Planejamento Fatorial, por meio do qual se planejou uma série de ensaios de sedimentação, variando-se as dosagens desses reagentes. As variáveis resposta monitoradas foram: a área unitária de sedimentação, o índice de turbidez do líquido sobrenadante e o percentual de sólido do material sedimentado. Baseado nos resultados experimentais, concluiu-se que os menores valores de área unitária de espessamento foram obtidos em dosagens maiores de coagulante e floculante, ao passo que dosagens excessivas desses reagentes, especialmente de floculante, provocaram um aumento do índice de turbidez do líquido sobrenadante e uma redução do grau de adensamento da polpa espessada.

Oct 30, 2017

1. ACKERMAN, C. L. The Binary System Manganese-Zinc. Ztschr. Metall., vol. 19, 1927, p. 200. 2. ADKENASY, P., AND KLONOWSKY, S. Über die Manganatschmelze. Ztschr. Elektrochem., vol. 16, 1910, p. 107. 3. AKTIEBOLAGET FERROLEGERINGAR (assignees). Method for the Manufacture of Manganese Alloys Poor in Carbon or Silicon or Else Manganese. British Patent 163262, Apr. 28, 1921; U. S. Patent 1480267, Jan. 8, 1924. 4. Method of Producing Manganese or Manganese Alloys Poor in Carbon or Silicon. British Patent 174923, Jan. 25, 1922.

Jan 1, 1934

By John Wilson

This report describes the performance of Phase I of a project to design, analyze, and demonstrate a multilift longwall mining method applicable to mining coal seams twelve (12) feet or more in thickness. A non-simultaneous multilift operation is the most viable thick seam mining technique for introduction to the United States coal industry. In the case of the proposed site at Emery, Utah it will result in an increase in coal extraction from 30% with present methods to at least 50% and possibly more. The major technological advance involved in this project is mining a lower lift under a previously mined upper lift. To accomplish this, entries must be developed and maintained beneath the upper lift gob. This will necessitate the use of steel supports at frequent intervals throughout the lower lift' entry system. This has not been done in the U.S. to date. An economic analysis of the project indicates that, while this method will result in a higher than average cost per ton for coal mined, the coal would be competitive with current-operation in the area.

Jan 1, 1976

By Charles Albert Ashburner

The coal-fields of the United States have been variously classified as to their geographical positions. In 1887 I proposed slight changes to the classification generally used, for more convenient description of our coal-fields in my report on the statistical history of coal in the States during 1886 for the United States Geological Survey. This new classification seems to meet all practical requirements and has been generally adopted. The coal-areas are grouped in two divisions—the anthracite division and the bituminous division. The anthracite division, in a commercial sense, may be said to include the anthracite districts of Pennsylvania alone, although small amounts of anthracite are mined in Colorado and have been

Jan 1, 1890

By W J. Cowie

Several years of operating experience of over 100 gold recovery operations on the West Coast has provided a database from which the basic operating costs of these types of operations can be characterised. Using figures generated from the averaging of plant operating costs throughout the region and financial modelling using Lotus spreadsheets has been developed to analyse both existing and proposed developments. This type of modelling has several uses: 1. Identification of the impact on profitability of changes in management practices, finance costs, operating costs and revenue streams. 2. Project evaluation and planning. 3. Profitability projections for development financing. 4. Troubleshooting with existing operations. 5. Valuation of existing operations and properties.

Jan 1, 1987

By Ana Carolina Martins Silva

Os aços inoxidáveis dúplex ferríticos-austeníticos fazem parte de uma classe de materiais com microestrutura bifásica, composta por uma matriz ferrítica e ilhas de austenita, com frações volumétricas aproximadamente iguais dessas fases. Essa classe de materiais é caracterizada por apresentar interessante combinação de elevadas propriedades mecânicas e de resistência à corrosão e, por isso, é considerada bastante versátil, sendo utilizados nas indústrias química e petroquímica, de papel e celulose, siderúrgicas, alimentícias e de geração de energia. Este trabalho objetiva caracterizar as microestruturas do Aço Inoxidável Duplex SAF 2205, revelando as fases que se apresentam após tratamento térmico a 800ºC, em diferentes tempos, estudar a relação entre a dureza do material e a precipitação da fase sigma, além de determinar a cinética de precipitação dessa fase. Após obtidos os dados experimentais, dados de VV e composição de equilíbrio da fase sigma foram obtidos via Thermo-Calc. Ao final do trabalho, os resultados experimentais e de simulação são comparados e conclui-se que a nucleação da fase sigma é por difusão de Cromo na matriz.

Oct 30, 2017

By F. Habashi

"The rare earths industry started in Austria in 1887 by Carl Auer von Welsbach (1858-1929) Professor of Chemistry at the University of Vienna. The process was based on monazite sand transported from Brazil as shipping ballast free of charge. This made possible producing thorium, cerium, and other rare earths at a low cost, thus permitting the growth of the industry. However, once the Brazilian authorities realized the strategic importance of the sand, shipping was stopped. Brazil then started its own processing of the sand in 1949. The background for Auer’s work, the role of Robert Bunsen in Heidelberg, and the invention of the spectroscope will be presented. INTRODUCTIONHeidelberg on the Neckar (Figure 1) was the meeting place for chemistry students from all over Europe in the nineteenth century. Her university founded in 1386 had already a famous professor of chemistry and medecine in the Faculty of Medicine by the name Leopold Gmelin whose three - volume Handbuch der theoretischen Chemie appeared in 1817-1819, that became later a multi-volume monumental work. As successor to Gmelin came Robert Bunsen (Figure 2) in 1852 who made this university town the Mecca of chemistry students. One of his students, the English Henry Roscoe (1833-1915) who became later a distinguished professor in Manchester, described him as follows: ""As an investigator he was great, as a teacher he was greater, as a man and a friend he was greatest""."

Jan 1, 2012

At present, discounted cash flow analysis is generally accepted as the preferred method of valuation of mine projects in surface coal mining. One of the major reasons for that is its ability to take into account the time effect of money over the life-of-mine. As a looking-forward method, it requires forecasts be made with regard to economic, technological, technical, geological, and environmental conditions that will prevail in the future. All forecasts are inherently uncertain as they are a function of the uncertainty of all variables of the discounted cash flows analysis. This indicates that the only alternative for modeling the uncertainty in the project evaluation is the development of adequate risk models to serve the decision-making process. The paper offers a model of project cash flows at risk in strip coal mining, which is an integrated corporate risk management solution. The model is based on a stochastic approach that provides the answer to the question about how large is the deviation between stochastic cash flows and the planned value (or that used in the budget) at each time step of the discounted cash flows analysis, that is due to the uncertainty in the model variables. A solution is worked out for the allowable range of the stochastic cash flows variation that determines the probability of achieving the planned value of a mine project. The Monte Carlo simulation technique is used to model the stochastic behavior of the project variables. A case study of an opencast coal mine project is provided to illustrate the applicability of the risk model. The results obtained provide a new understanding of the mine project risk as a component of the project discount rate.

Jan 1, 2006

By A. H. Swart

Rock engineering is concerned with the design of rock structures generated by mining activities. Therefore, rock engineering designs have major implications for the safe recovery of mineral deposits and operating costs. The paper deals with a few challenges facing rock mechanics engineers operating in the hard rock underground mining environment in South Africa. Finally, examples are included, which may assist rock mechanics engineers in providing better designs, which could ultimately lead to further improvement in safety and lower operating costs.

Jan 1, 2005