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By Charles T. Steuart, Richard B. Berg

Tripoli and the related mineral commodities such as micro- crystalline silica have been mined for more than 100 years for their abrasive properties. Although abrasive and buffing compound markets are still very important, within the last 15 years the filler and extender markets in paint, plastics, rubber, adhesives, and sealants have increased substantially. Tripoli or microcrystalline silica consists almost entirely of very small quartz crystals, many less than one micrometer in length. Material mined from different districts differs in crystal shape, grain size, and texture of the rock, all of which influence markets. Most US deposits are now mined by surface methods, and both air floated and micronized products are marketed. Deposits of tripoli now mined in the United States occur in chert-bearing Paleozoic limestone in the central part of the country with producing districts in southern Illinois, central Arkansas, and eastern Oklahoma. Although deposits within each district are confined to specific formations and extend laterally within those formations, individual bodies form minable deposits that are typically several hectares in areal extent. Tripoli is white to cream to rose and characterized by high porosity and ease of disaggregation. DEFINITIONS Tripoli In the United States, tripoli was first used to describe the fine-grained, easily disaggregated material from Seneca, MO, be- cause of its similarity to a rock from the Tripoli region of North Africa (Hovey, 1894). The North African rock is actually diatomaceous earth, a material that is similar in appearance to the rock from Seneca, but is of entirely different origin having formed by the accumulation of siliceous remains of microscopic marine or fresh- water animals. Tripoli is best defined as a very fine-grained, generally porous rock that consists of microcrystalline quartz, typically formed by the alteration of a chert-bearing limestone. Tripolite A term used to describe a rock from the vicinity of Tripoli in North Africa which is diatomaceous earth (Quirk and Bates, 1978) Microcrystalline Silica Microcrystalline silica is the same material as tripoli, but the distinction between the use of these two names is dictated largely by convention and markets. Material produced from southern I1linois deposits and used in white pigment and filler applications is generally referred to as microcrystalline silica, whereas that used in abrasive applications, both from the Illinois district and from other states, is commonly called tripoli. Amorphous Silica Amorphous silica, a term formerly used to describe the material produced from the deposits in southern Illinois, is now replaced by the term microcrystalline silica. Amorphous silica came into use when even optical methods for the identification of very fine- grained quartz were not widely available and the Illinois product, composed of quartz grains too small to be seen with the unaided eye, was thought to consist of amorphous silica. The Illinois material is clearly crystalline quartz, as shown by X-ray diffraction analysis and scanning electron microscopy (Fig. 1). Novaculite Although originally used to describe a rock suitable for the manufacture of whetstones, novaculite is now defined more generally " - as a homogeneous, mostly white or light colored rock, translucent on thin edges, with a waxy or dull luster, and almost entirely composed of microcrystalline quartz" (Steuart et al., 1983). The more compact rock mined in central Arkansas from the Arkansas Novaculite is referred to as novaculite, whereas the more porous rock is referred to as tripoli. Rottenstone The commodity rottenstone is sometimes included within the general mineral commodity category of tripoli. Rottenstone is mined in Northumberland County in eastern Pennsvlvania and formed by the weathering of a siliceous shale of Devonian age (Faill, 1979, Berkheiser, private communication, 1991). This material is used as a filler and extender, but is apparently unlike tripoli both in origin and physical properties. Spiculite Spiculite is a rock consisting of siliceous sponge spicules having formed by the removal by solution of the carbonate matrix of a spicule-bearing limestone. Spiculite has been mined in Texas and, because it resembles tripoli in several aspects, is included in the discussion of deposits.

Jan 1, 1994

Planning the primary development of a mineral deposit usually is done only once during the life of a mine. As a consequence, not optimizing the primary development of a mineral deposit can cause disadvantages over the whole life of a mine and can lead to higher costs. As a contribution to an improved primary development design procedure beyond the already existing work a study of the identification and quantification of the influence of parameters on primary development based on operational data from working mining operations has been completed. Based upon such a quantification of the influence of parameters a sequenced decision model was developed, that enables to develop an initial concept for the design of the accesses from the surface based upon a few critical parameters. Such a model will not replace detailed planning work within a feasibility study, but it is intended to reduce the amount of planning efforts at an early project stage through providing information what are most likely economic solutions, based on simple rules.

Jan 1, 1997

By Surendra K. Mishra

Recent land ban act has put pressure on industry to decontaminate the waste streams before they could be discharged. However, for both metal and organic contaminated wastes, there are commercial incentives to recover usable resources. Recent technology developments have helped meeting such objectives. This paper reviews developments in treatment technologies for industrial wastes. Major chemical groups used in waste treatment are summarized.

Jan 1, 1994

By C. Roldan, C. Garcia, J. D. Miller, C. L. Lin

The ultimate recovery in a heap leaching operation is related to the degree of exposure of the valuable minerals in comminuted particles. Recently, high-resolution cone beam x-ray microtomography (XMT) has been used to determine this parameter. XMT technology consists of examining the extent of mineral exposure for each size fraction of ore in 3D, then, by algebraic calculations, the ultimate recovery can be estimated for different particle size distributions (PSD). To confirm the usefulness of the XMT technology for mineral exposure analysis, column tests were performed to determine ultimate recovery using three PSDs for two composites obtained from the copper heap leaching operation at Zaldivar-Chile.

Jan 1, 2003

By W. K. O’Connor, J. C. White, P. C. Turner

The US Bureau of Mines is investigating the cobalt and manganese resource of the West-Central Arkansas district through field investigations, mineralogical characterization, beneficiation and hydrometallurgical tests. Located within the Ouachita Mountains, these structurally-controlled deposits occur along the axes of anticlines that form the mountain ridges. Brecciated novaculite is cemented with a mixture of manganese oxides, primarily cryptomelane and psilomelane. Cobalt is concentrated within lithiophorite, a particular Mnoxide phase. Chemical analyses of head samples reported up to 25% Mn and 0.17% Co. Magnetic separation yielded products containing up to 41 % Mn and 0.22% Co at recoveries of 95% and 93%, respectively.

Jan 1, 1993

By Peter McKenna

A mineral rights holding can ultimately only be turned to account by the profitable mining of ore on that property. The evaluation of South African gold mineral rights properties must therefore be carried out by assuming that they have potential to form part or all of a future gold mine. Such analysis involves the simulation of many of the estimation procedures that are normally carried out in a full feasibility study of a new mining venture but using far less data. This paper describes in detail the evaluation procedures that may be applied to an individual property and then indicates how these techniques can be applied to a whole mineral rights portfolio.

Jan 1, 1989

By Barry K. Johnston, Norman W. Bainbridge, Neville C. Lockhart

CSIRO and its collaborators have developed a major R & D project on dewatering of coal. This involves sub-projects on (i) the fundamentals of coal-water associations; (ii) reducing the variability of product moisture levels from small coal centrifuges; (iii) process mechanisms and optimisation for fine coal dewatering; (iv) pilot scale testing, engineering development and innovation. Results from each of these sub-projects are presented, and the pilot facility incorporating a vacuum filter, belt press, membrane press, hyperbaric filters and centrifuges, is discussed. The vacuum filter and membrane press can be configured for electric-field assisted dewatering, which provides substantial enhancements in the rate and degree of dewatering for fine coal, coal tailings, and other suspensions.

Jan 1, 1995

By J. Hazen, R. Jenner

This project was developed at the PCS Phosphate Mine in Aurora, NC. This site includes a surface mining operation, beneficiation plant and chemical processing facility located in the coastal plain of eastern North Carolina. The phosphate ore being mined at this operation is a 10 to 12 meter (35 to 40 foot) thick colloidal deposit located approximately 30 meters (100 feet) below the ground surface. The ore is pumped to the beneficiation facility where it is separated into clay, sand and concentrate streams. The concentrate product is utilized at the chemical plants to produce a wide range of products including fertilizer, industrial phosphates and animal feed products. The Cyclone Dike Builder (CDB) project developed a technique for dewatering the beneficiation tailing sand stream and providing innovative placement for dike construction. Future material balance requirements at the PCS Phosphate mine required an improvement in tailing sand placement technique to accomplish strategic objectives. The water volume of the sand slurry forces significant quantities of sand out of the dike profile during deposition. PCS Phosphate and MetPro Supply of Florida developed a mobile high-density hydro-cyclone station to remove most of the water and significantly increase the density of the sand being placed for dike construction. This high-density sand slurry is then effectively controlled using minimal heavy equipment operation.

Jan 1, 2004

By R. Bruno

The problem of testing different production strategies has been studied in relation to reserves selection and a computer programme for ore production management has been developed. The case study presented concerns an underground rock salt mine in Sicily with different product lines and variable ore characteristics. A geostatistical block model of the deposit was constructed on the basis of the physical and chemical parameters that ultimately determine the type of end-product in operations according to different selection strategies were simulated using the model and taking account of both technical and 'commercial constraints. The structure of an ore production management programme running on a PC to select both the mining unit and the end-use of the ore is described.

Jan 1, 1989

By L. W. Stanger, Erich U. Petersen, William J. Tafuri, Donald M. Hausen, Douglas N. Halbe

Gold mineralization at the Mercur Mine was controlled primarily by structure and secondarily by lithology in Mississippian-age sedimentary rocks. Gold was localized where Sevier-age high angle northeast-striking faults are intersected by younger northwest-striking fault zones. The Lulu Graben is a northeast- striking fault zone composed of a south-dipping master fault coupled with subsidiary or antithetic faults. The Twist Fault zone, a sinuous, low-displacement , north-striking zone of fracturing, bisects the graben. Large- tonnage disseminated ore bodies formed east of the Twist Fault zone within silty, thin-bedded, bioclastic carbonates. West of the Twist Fault zone, gold was restricted to rock near peripheral faults surrounding a subvertical collapsed pipe developed within the graben. An overlying thick carbonaceous shale capped the ore zone. Presence of abundant limited- displacement faulting and of hydrothermal jasperoid is associated with cartonate-hosted disseminated gold. Conversely, increased fault displacement and widespread brecciation are associated with reduced dissemination of gold into normally receptive carbonates.

Jan 1, 1990

By D. M. Smith, M. J. Meulendyke, P. J. Moroz

An extensive program of marked ball wear testing (MBWT), laboratory corrosion studies, and worn ball surface analyses has been used to gain insight about the role of corrosion in the overall wear process. In some environments, localized corrosion is observed; the actual wear mechanisms in such cases are pitting/spalling and abrasion. Factors affecting the occurrence of pitting include the abrasiveness of the ore, corrosivity of the slurry, corrosion resistance of the media, and galvanic coupling effects. Elimination of pitting substantially improves overall wear resistance. When pitting is not observed, the contributions of general corrosion are significantly less.

Jan 1, 1988

Sphalerite is commonly floated in an alkaline environment and under such conditions the overall activation mechanism is obscured by the hydrolysis of Cu2+ and precipitation of Cu(OH)2. Electrokinetic and kinetic flotation tests show that the activation of sphalerite is a two-stage process; the activation products formed on the surface of sphalerite in near neutral and in alkaline solutions in the first rapid activation stage are "flotation-inactive". These layers, when formed in an alkaline solution, are unstable and are transformed into the "flotation-active" form in the second stage. However, the surface layers formed during activation in alkaline environment by copper in the presence of lead ions are very stable and even after a long conditioning time the flotation rate is not improved. Consequently, while both Cu2+ and Pb2+ activate sphalerite flotation, quite unpredictable effects may result when both are present in the solution.

Jan 1, 1997

The most common method used for cleaning the fine fraction in today's coal preparation plants is froth flotation. Past research and practice has found that froth flotation achieves excellent separation efficiencies for fine coals having only a small fraction of middling particles. However, its efficiency decreases sharply as the concentration of middling particles increases due to the flotation of high-ash particles having a small amount of hydrophobic coal present at the coal surface. Since gravity-based processes are much more efficient at treating middlings, the application of centrifugal washing for fine coal cleaning has been studied with an emphasis on the primary cleaning of fine circuit feed. Results will be shown from a parametric study using a Falcon centrifugal concentrator which reveals that the separation performance is a function of particle size, bowl geometry, feed solids content, and feed rate.

Jan 1, 1994

By Paul H. Rylund

Substantial priming was a considered necessity for proper initiation of ammonium nitrate-fuel oil mixes as ANFO began to carve its niche in the mining industry in the latter fifties. Heavy priming accompanied the introduction of prills and oil to many blasting operations, large charges of high explosives were commonly used at the bottom, top and frequent intervals through-out the column. As the quality of ammonium nitrate improved and operators became more experienced, primer costs began to diminish. Increased experimentation continued with reduced primer costs a main objective. Cast primers were introduced and became accepted as an excellent companion for ANFO. Although the trend toward larger diameter boreholes became increasingly popular, emphasis on lower and lower priming costs continued. A primer was simply required to produce any type of initiation within the ANFO column to be considered adequate. Suddenly ANFO priming had digressed from excessive to marginal. Early experimental data developed at "test site" and laboratory locations indicated that ANFO had a tendency to react inefficiently in the initiation region of the column unless substantially primed. This was evidenced by the presence of unstable reaction rates detected with newly developed detonation velocity measuring equipment. These 10" order or "transient" velocities were believed to originate because of inadequate primer strength or a primer diameter to column diameter mismatch. How-

Jan 1, 1972

By J. S. Stachulak

Inco Limited operates nine underground mines on the rim of the Sudbury Basin. These operations are situated near the City of Sudbury, 589 km (365 miles) west of Montreal, and 363 km (225 miles) north of Toronto. The ores are mined primarily for nickel and copper, and the principal minerals are pentlandite, chalcopyrite, and pyrrhotite. Total ore production from underground is in excess of 51,000 tons per day. The total volume of fresh air supplied to the nine mines is six million cubic feet per minute. There are 50 main fans in operation at these mines, powered by electric motors totalling 11,200 kw (15,000 hp). The trend in metal mining during recent years towards mechanization and high-tonnage production methods has greatly increased ventilation requirements. The flow of air must quickly dilute and carry away diesel exhaust fumes, dust created by mining operations, and the fumes of the explosives used in blasting. Mechanical ventilation is required to obtain the necessary volume and control, as natural ventilation pressures alone are, for the most part, inadequate and unreliable. In the event of a mine fire or other needs, close control of ventilation is essential. There are two unique heating systems presently in operation at Inco: Creighton Natural Heat Ex- changer and Stobie Ice Stopes.

Jan 1, 1989

By A. M. Abouzeid, R. Hogg

Materials transport is involved in all phases of mineral processing. Bulk transport is necessary for moving materials between unit operations and through processing devices such as grinding mills. Differential transport is a primary mechanism for most separation processes. The basic mechanisms of transport and flow in particulate materials are reviewed and their role in materials handling and storage and in the performance of processing operations such as grinding and separation are discussed. Specific examples are used to illustrate current understanding of these transport phenomena and to indicate important research needs and opportunities.

Jan 1, 1989

By Joseph Kurtak

When prospectors discovered mineralized outcrops in Pine Creek Canyon in 1916, little did they know the site was destined to become one of the world's greatest tungsten mines. Located outside Bishop in California's rugged Sierra Nevada mountain range, the mine's development imposed unique challenges to the hardiest of mining men. In its early years, the Pine Creek operation was plagued by bad luck and poor timing. But through the perseverance of a dynamic group of mining personalities, it would gain world class status. Pine Creek tungsten supplied much of the defense needs of the United States during World War II and put the Bishop area on the map as a major contributor to the nation's stockpile of strategic metals. The mine's history was shaped by world politics, the ups and downs of metals demand and economic survival through technological innovations. In contrast to many mines, Pine Creek's workings went horizontally into and then up inside the mountains - nearly to the ridgetops. This resulted in the name "Mine in the Sky" being attached to the operation. The origin of Pine Creek's ore bodies is related to the emplacement of a portion of the Sierra Nevada batholith about 100 million years ago. During the intrusive process, granitic magmas engulfed overlying calcareous sedimentary rocks, flooding them with silica-rich hydrothermal fluids and metamorphosing them to skarn. The fluids also contained tungsten, molybdenum and copper. They precipitated as scheelite, molybdenite and chalcopyrite, respectively, during the metamorphic process. The ore-bearing skarns occur as near-vertical tabular pendants in the intrusive rocks. These were later exposed by the uplift of the Sierra Nevada mountain range and glacial erosion.

Jan 1, 1998

By J. H. Kempton, D. Atkins, W. Locke

The scrutiny given to model predictions of pit-lake water quality has focused attention on the uncertainty associated with long-term predictions. Although comparison of probabilistic predictive modeling of water quality in existing pit lakes suggest that short-term predictions can bracket most parameters, un¬certainties in wall-rock reactions and the stability of groundwater composition and climate remain unquantified This overview of the uncertainties associated with longer-term predictions is presented as support for those considering policy decisions that must be made in the absence of reliable estimates of future conditions.

Jan 1, 2000

By J. Hanna, J. Jung

Researchers at The University of Alabama have recently developed a two-step method for the treatment of phosphorus sludge. The process includes the bulk removal of phosphorus by physical separation techniques followed by the remediation of the residual P4 in the sludge using a novel, wet, air-oxidation technique known as "HSAD." Tests made on electric furnace, phosphorus sludge samples have demonstrated that an essentially complete and fast removal of the contained P4 can be achieved by the HSAD wet oxidation treatment. Further studies were made to determine the applicability of the two-step process to sludges of different origins, pretreatments, storage conditions and P4 contents. The present work discusses the mechanisms and factors controlling the HSAD, wet, air-oxidation remediation approach.

Jan 1, 1993

By J. A. Brierley, Arpad E. Torma, Victor C. Storhok, C. L. Brierley, Batric Pesic

Chemical and electrochemical studies were performed during bioleaching of cobaltite concentrate with Thiobacillus ferrooxidans. The two principal minerals present in the concentrate were pyrite and cobaltite (CoAsS). During chemical studies, the effect of pH on dissolution rates was examined under uncontrolled and pH-controlled conditions. It was found that in the pH range 1.5-3.0 there was no pH effect if the initial pH was not controlled (maintained). When the initial pH was controlled, the leaching of Co, As, and Fe depended strongly on pH. Electrochemical studies were performed by using cyclic voltammetry and constant potential techniques. A sequential reaction mechanism was proposed for dissolution of cobaltite.

Jan 1, 1993