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By J. Engesser

This paper discusses the effect that water chemistry, and water treatment have on pre-fired pellet quality and bentonite-binding effectiveness. A discussion concerning the effect that water temperature, water chemistry, water treatment, and surface area have on disc filter productivity and filter cake moisture is also included. This report is a summary of the data that were presented in five previous research reports, which are listed as references in this paper.

Jan 1, 2003

By Eberhard Werner

Existing reports on the effects of mine subsidence on water wells and springs appear to be inconsistent. Some report quick and complete recoveries to pre-mining conditions while others indicate long-term or permanent effects. It is clear that topographic and geological factors as well as precise position with regard to the mine are important in determining probable effects of subsidence on aquifers. Ridgetop aquifers which are well above regional base-level are much more susceptible to disturbance by mining activities than those located topographically lower. Effects seen are attributed largely to increased permeability, both horizontal and vertical. of the aquifer rocks. The deeper aquifers usually show short term losses or water-table declines. but the effects on the ridge-top aquifers persist for longer periods or may be permanent. Subsidence enhances permeability. so that infiltrating water moves much faster to lower levels. causing pond and stream losses and declining levels in wells as well as declining flows of springs of the higher aquifers, while increasing levels and flows of the lower aquifers. Additional effects are shifts of spring locations caused by minor tilts due to differential subsidence and redirection of shallow flows by changes of horizontal fracture permeability. These effects are seen as mining of a panel progresses beneath the site. and are often repeated when adjacent panel mining fronts pass the site. Analysis of water well level and spring flow records indicates that the effects are greatest at the edges of longwall panels in the tensional regime. These effects are amplified for locations close to topographically steep terrain and in close proximity to fracture traces mapped from medium-to small-scale aerial images.

Jan 1, 1986

By Felicia F. Peng

Flotation process is particle hydrophobic surface-based separation technique. To improve the essential flotation steps of collision and attachment, and reduce detachment probabilities between air bubbles and hydrophobic particles, a selectively designed cavitaion venture-tube can be used to generate very high numbers of pico-nano bubbles to flotation column. Fully embraced by those high numbers of tiny bubbles, hydrophobic particles are readily attracting those tiny bubbles to their surfaces. The results of column flotation of Pittsburgh No.8 seam coal are obtained in a 50 cm ID and 162cm height flotation column equipped with static-mixer and cavitation-venture tube, using kerosene as collector and MIBC as frother. Design of experiment procedure combined with statistical two-stepwise analysis method are applied and attempted to made the optimizing the grade and recovery. The effect of independent variables on response has been explained. Combustible material recovery of 85-90% at clean coal product of 10-11 % ash are obtained from feed of 29.6% ash, with reduced amount of frother and collector than that used in conventional column flotation. The column flotation process utilizing the pico-nanobubbles can also be extended to the lower limit and upper limit of particle size ranges for better recovery minus 75 µm and 300-600 µm, respectively.

Jan 1, 2013

By FJ. Johnson

Polymer utilization has increased steadily over the past several decades; however, their usefulness is sometimes limited by natural forces. For example, polymers tend to degrade when subjected to elevated temperatures. This degradation can release toxic fumes, create excess smoke, and aid in the spread of fire. For these reasons, many polymers are filled with various compounds which impart flame retardancy (FR) properties. These fillers do not make polymers non-combustible; rather, they increase resistance to ignition and reduce bum rate. Also, they suppress smoke generation, which is important as up to 80% of fire-related deaths are due to smoke inhalation [1]. Therefore, methods to impart flame retardancy in polymers are industrially important. The early flame retardants used in polymers were halogen-based, working on the principle of inhibiting free radical formation in the vapour phase thus impeding combustion propagation [2]. Usually these were combined with antimony compounds such as Sb203 to decrease loading, yet provide the same FR qualities. However, questions have arisen recently concerning toxicity of halogenated flame retardants. Possible release of toxic compounds (such as dioxins) upon combustion has been reported [3]. Fear of future regulations concerning halogen addition has led to the search for different FR fillers. Two of the more common replacements for halogen-based systems are alumina trihydrate (Al(OH)3 or ATH), and magnesium hydroxide (Mg(OH)2)' These systems impart flame retardancy through heat absorption and by release of water of hydration upon their decomposition. ATH has a low decomposition temperature (230°C), limiting its use to unsaturated polymers, epoxies, urethanes, and some wire and cable formulations. However, some advantages of ATH over halogenated FR are that it is relatively cheap, doesn't generate toxic gases, is non-volatile, and is impervious to moisture [2].

Jan 1, 1997

By Harry H. Posey, John Woodling, Miriam L. Renkin

Natural acid drainage is generated from pyritic rock underlying 17 percent of the upper Alamosa River basin. About one-third of these acid producing rocks have nil carbonate buffering capacity; there the streams carry significant acid plus dissolved Al, Cu, Fe, and Zn. In part of the basin, aquatic life is limited by the natural acid drainage. In the four miles where the Alamosa flows through pyritic rock the river grows toxic to trout. Inhospitable conditions continue downstream for at least another four miles. The waters become refreshed, naturally, through metal dilution, metal oxide and hydroxide precipitation, and acid neutralization. Water quality fluctuates in seasonal cycles. Dissolved metals and acid, which are generated year-round by weathering, are stored over winter in the unsaturated zone in the retained water and in soluble metal- sulfate minerals that form by evaporation of acid-metal waters. Seasonal discharge variations cause metal concentrations and pH to shift in the trunk stream; the acid drainage source streams, however, shift only slightly by season. In early spring, metal concentrations and metal loads increase as metals and acid are flushed from the unsaturated zones by melting snow. Peak metal loads occur at this time, and precede peak flow by up to two months. Other metal load peaks occur during peak flow and monsoon flow, even though metal concentrations are diluted at that time by precipitation. In late spring and thereafter, discharge of neutral pH water wanes, so trunk stream pH falls and metal concentrations return to previous high levels. Metal concentrations appear to be low from November through January when dilution from precipitation is lowest, but rise in February to near peak yearly concentrations. In years with high monsoonal flows, metal-laden waters apparently flush from the unsaturated zone and metal concentrations remain low from about October through January. In years with low monsoonal flows, however, metal concentrations in October and November at least are higher.

Jan 1, 2000

By R. Q. Honaker, D. Tao, D. Taulbee, B. K. Parekh

A significant amount of energy exists in the waste generated by the coal and timber industries. In the coal industry, the energy loss is mainly due to the discharge of fine coal to the waste impoundment. Despite the fact that the fine coal has the greatest cleaning potential, dewatering, handling and transportation concerns prevent its use as product in many cases. Likewise, the sawdust generated from wood production has energy value and is used as industrial boiler fuel when the transportation distance is relative short. However, wood waste is often discarded into cumbersome landfills due to uneconomical transportation alternatives. Recent research found that these two waste materials can be combined to provide a high energy fuel of around 13000 btu/lb that can be easily handled and transported to end users.

Jan 1, 2004

For all the attention given to mining activities in Central and South America, Mexico, Indonesia and Papua New Guinea, it is sometimes easy to forget the activities taking place in one of North America's most important and largely untapped regions -Alaska. The Alaskan minerals industry employed about 3,406 people during 1995. That is a 23% increase from - - 1994. It also contributed about $719.8 million to the state's economy during 1995, a 10% increase. During the past few years, Alaska has seen significant increases in exploration and mining activity. Fairbanks Mining, an arm of Cyprus Amax, began producing gold during 1996 at its Fort Knox Mine, as did Nevada Goldfields' Nixon Fork gold mine. Kennecott's Greens Creek lead-silver-gold mine also reopened and USMX began operations at its Illinois Creek gold mine. In addition, several impressive exploration projects were under way in Alaska. Placer Dome reported good results at Donlin Creek project in southwest Alaska. Likewise, Newmont Exploration is getting serious about its True North gold project. And Nerox is nearing production at its Jonesville coal project in Alaska's interior. In November, about 400 miners gathered in Anchor- age for the Alaska Miners Convention. Throughout the conference and exhibition, attendees listened to updates on these precious- and base-metal and coal exploration and mining operations. They also learned that the state wants more miners to head north and help develop its natural resources. Alaska is ripe for a smelter The mining industry -Alaska's miners in particular - has a powerful ally in Sen. Frank Murkowski (R-AK). He is the chairman of the Senate Energy and Natural Resources Committee. During his luncheon address, Murkowski said it appears that it is economically feasible to extend the Alaska Railroad to northwest Alaska, taking advantage of the large coal and hard-rock mineral tracts in the Ambler mining district. He also renewed his push for building a major smelter in Alaska to process ore that would come from the Ambler mining district. Murkowski believes that Alaska's economy can be expanded by extending the railroad from Nenana to the Point Lay coal fields to open coal development. Along the way, the railroad would pass through the Ambler district, helping to develop the hard-rock deposits. An outgrowth of this additional mineral development, Murkowski said, could be a new smelter in Alaska. It could use power from the Tyee hydroelectric facility near Wrangell or from the Makushin geothermal project near Unalaska. Either site, he added, offers access to plentiful, relatively low-cost power, at tidewater to facilitate ore deliveries to the Pacific Rim. The Congressional Research Service has determined that there are enough mineral deposits and coal beds to make it possible to finance the extended railroad, he said. The 1,200-km (744- mile) rail extension would cost about $4.2 billion. The North Slope of Alaska contains up to 3.6 Tt (4 trillion st) of coal, Murkowski said, that contains less than 0.25% of sulfur and less than 4% moisture. It aver- ages 12,300 Btu in heat content. "That is a tremendous resource," he said. The Ambler mining district, meanwhile, has at least eight identifiable hard-rock deposits, Murkowski continued. These contain zinc, lead, copper, nickel, chromium, tin, barite, gold and silver. "All eight of these can generate ore concentrates at rates similar to Red Dog's cur- rent 725 ktla (800,000 stpy)" of zinc, he said.

Jan 1, 1997

By A. J. Benham, H. Kessler

In the UK a high proportion of land-won sand and gravel is extracted from sub-alluvial gravels and river terrace gravels located within river valleys. However, extraction from deposits of this type is increasingly proving to be less acceptable. Quarries within river valleys often have a high visual impact and the cumulative impact of these operations in close proximity to each other can be high (figure 1). River valley operations are almost always restored to open water. Whilst these may be attractive for nature conservation and provide leisure activities, they can also have a serious impact on the natural hydrology of the flood plain. Wet restoration of quarries located close to airports or airfields can also lead to concerns regarding increased risk of bird strike on aircraft. The Civil Aviation Authority recently suggested that an exclusion zone of 13 km be applied around all airports and airfields to reduce the potential for bird strikes on aircraft. This action is likely to have a serious impact on the availability of potential sand and gravel extraction sites in river valleys.

Jan 1, 2005

By Jan Visman, James W. Parkinson

GENERAL INTRODUCTION Sample collection, preparation and analysis are all steps in a single process designed to provide information about a much larger amount of material than the sample itself. For example, information about the ash content of a unit train load of coal may be derived from a single, relatively small sample of perhaps a few hundred pounds (liters) extracted from the entire shipment. These three steps can be thought of as links in a chain, allowing the simple analogy that the strength of the chain, or, in other words, the value of the information is only as strong as the weakest link. Sample collection, discussed in Part 1 of this chapter, is critical because analytical procedures can do no more than reveal the characteristics of the sample presented to the laboratory. If that sample does not properly represent the population to be characterized, neither will the analysis of that sample. Sample preparation is also a critical part of the chain. Any change in the nature of a sample between the time it is collected and the time it is analyzed will appear to reflect the nature of the population. For example, sample preparation procedures that allow air to partially dry the coal sample before reaching the laboratory will cause the sample analysis to indicate a lower moisture content than the sample originally had. Other changes can be more subtle. Second only to moisture loss, oxidation reactions generally cause the greatest problems. Oxidation of a coal sample can alter surface properties, changing flotation response. In extreme cases, combustion parameters, such as caking or agglomerating properties or mineral composition, such as pyrite content, can change. Water samples can also be altered by oxidation. For example, ferrous iron can oxidize to ferric iron, possibly changing water quality parameters such as pH. Sample analysis, the subject of Part 2 of this chapter, is the final link in the chain. Obviously, no laboratory procedure can correct for problems created by improper sample collection and preparation. At the same time, poor analytical techniques will create incorrect information about the total amount of coal from which the sample was extracted (the population) in the same manner as improper sample collection and preparation. The key to gaining correct information about the population is to view these three steps as parts of a single process. Following proper techniques through only one or two steps of the process will not produce accurate information.

Jan 1, 1991

By S. E. Restrepo

To innovate and make the operation sustainable it is necessary to identify the externalities and impacts completely. This paper presents the results of a proposed methodology to make circular economy initiatives viable in mining operations using these aspects: • Economic, safety, and environmental (HSE) risk analysis • Technology observation • Mineralogical characterization • Identification of potential waste uses • Use of government economic benefits The results of the project can be summarized as follows: • Implementation of new technologies in the aggregates process, • efficient use of water, • the valorization of waste to convert it into a by-product, • and access to tax benefits for investment savings.

Mar 2, 2022

By John Ralston, Jinming Duan, David R. E. Snoswell, Daniel Fornasiero, Jingwu Yang

The colloidal stability of synthetic silica spheres with clean, methylated and dehydroxylated sur¬faces was studied at different concentrations of dissolved gas and KCl electrolyte at a fixed pH of 4.2. A classic stability ratio/electrolyte concentration analysis shows that hydrophobic, methy¬lated particles undergo faster rates of aggregation with increasing concentrations of dissolved carbon dioxide. Similar data for hydrophilic particles and dehydroxylated particles show no change as a function of dissolved carbon dioxide concentration. Zeta potential data behave simi¬larly, showing a strong influence of dissolved gas only for methylated particles. The results are interpreted in terms of DLVO theory, with the surface-to-surface interaction dominated by the presence of very small protruding bubbles. Direct evidence for the existence of these very small gas bubbles (or "nanobubbles") was obtained using tapping mode atomic force microscopy. Small bubbles do not form on smooth, hydrophilic, or dehydroxylated silicon oxide water sur¬faces immersed in aqueous solutions under known levels of gas supersaturation. Randomly dis¬tributed small bubbles were observed over the whole surface of observation on methylated surfaces of controlled roughness. Bubbles formed on rough, methylated surfaces were larger and less-densely distributed than those on a smooth surface of similar hydrophobicity. The process of bubble coalescence was observed as a function of time. The macroscopic contact angle, measured with respect to the aqueous or gas phase, is very different from the microscopic contact angle detected by TMAFM and appears to be due to the influence of line tension at the pinned three¬phase contact line. The latter has a value of -3 x 10-10 N and acts to stabilize the small bubbles, flattening them and thereby reducing the Laplace pressure.

Jan 1, 2005

By Benjamin C. B. Hsieh

Many processes in the hydrometallurgical and chemical industries require the separation of dissolved material from suspended solids. Counter current decantation (CCD) with thickeners is one of the methods generally used. The process engineer needs a quick and accurate CCD calculation method. Several theoretical 1-12 CCD calculation methods are available in the literature . The simultaneous 1, 2 equation method for a complex circuit as used would take too long to solve the problems. Approximate equation method1 is not accurate and is for simple cases only. A shortcut method developed by Counselman3 contains no mathematical equation, and thus is not suitable for computer programming. Based on Counselman's method, Woody4 derived two simple equations in terms of percent soluble loss for two typical examples. Scandrett5 included a term for mixing in his formulas. This mixing efficiency was defined by Murphree6. Another method which depends on making volume calculations instead of using weights is presented by Mastin8 and Cahalan9. None of these methods is related to dissolution and pre¬cipitation reactions. Chen 10,11 demonstrated his methods for counter current leaching. His results are calculated from the general solution of a derived linear difference equation for constant underflow, and from the solution of a derived non-linear Ricatti difference equation for variable underflow. This paper concerns derivation of a general equation for CCD washing with provisions for adding and withdrawing the streams, and for leaching (dissolution) or precipitation reactions. These equations take several forms depending on the input information available. A set of simplified equations for continuous counter current washing and leaching is derived for determining:

Jan 1, 1972

By Gerald H. Luttrell, Rick Q. Honaker

A coal preparation plant incorporates a variety of solid-solid separation processes that operate in relatively independent parallel circuits. Studies have shown that total plant performance can be optimized by selecting circuit cutpoints that maximize total clean coal yield irrespective of the performance of individual circuits. Although the optimum cutpoints can be determined using simulation programs, these mathematical routines require detailed washability data and empirical partition information that is not often available to plant operators. In addition, routine fluctuations in the washability characteristics of the plant feed make this approach impractical to implement in industrial facilities. As an alternative, practical optimization criteria can be developed for plant operators through a fundamental understanding of scientific principles involved in coal cleaning operations. This article provides an overview of the most important optimization criteria and presents several industrial case studies that illustrate the financial benefits of this practical approach m plant optimization.

Jan 1, 2005

Copper cathode and Uranium Oxide production at WMC (Olympic Dam Corporation) Pty. Ltd. involves processing leach liquors through a copper solvent extraction plant followed by a uranium solvent extraction plant. This paper discusses the processing problems, metallurgical testwork and circuit changes made due to contamination of amine in the oxime circuit and vice versa.

Jan 1, 1996

By Ronald B. Stone

This paper describes a proposed solution to the problem of mining a 315 foot diameter unsupported sphere at a depth of 2700 feet in a salt dome by conventional mining methods. The proposed solution utilizes many of the varied technologies available to the mining engineer for solving mining and underground construction problems. The following are reviewed in the paper: A. The location of the sphere within the dome as required by construction criteria. B. The relation of the location of the access shafts to the sphere. C. The rock mechanics theory in relation to the salt dome and large size of the excavation. D. The proposed "honeycomb" method of mining which will be a partial answer to rock mechanics stability requirements. E. The equipment which it is recommended be utilized to accomplish the construction. F. The rock mechanics measuring instruments proposed. G. The methods of disposal of the mined salt. Conclusions and areas of further study are outlined in the final statement.

Jan 1, 1968

By Jan A. Nemcik

Steel mesh has been used successfully for many years to control friable roof conditions and prevent loose roof and rib material from caving into the roadway. Despite its extensive use, the installation of steel mesh is difficult to automate and many other products have been evaluated as an alternative for skin control. Ideally, the properties of these new products should be similar or better than those of the steel mesh. In particular, development of a strong and resistant shell that minimizes movement along the fractured rock and coal surfaces between the bolt anchors is recommended. A strong surface adhesion and the strength of a reinforced polymer skin can provide the necessary toughening mechanism required to enhance roadway surface support by forming a reinforced polymer/rock surface layer. Most of the Thin Spray-on Liners (TSL) evaluated in the mines are weak with slow curing times, and the plastic mesh currently used to support the coal ribs is relatively weak. Therefore, neither material can seriously compete with steel mesh. Currently, a new polymer product that cures in seconds and forms an instantaneous strata binder that surpasses the properties of steel mesh is under development at the University of Wollongong.

Jan 1, 2009

By L. Blain

In practice, geochemical analyses can be grouped in two broad categories according to their aim. Those that seek to determine the exact chemical composition of geological materials fall under the heading of assays, whereas applied geochemistry concerns itself with the detection of anomaly contrasts. Recent trends have blurred the distinction between both approaches for many users, as methods that were traditionally used for assays are being adopted in applied geochemistry and assays make increasing use of instrumental techniques. Nevertheless. it is important to keep a clear distinction between the two types of analyses because it has immediate practical consequences, cost is the most obvious, as well as fundamental implications. In the broadest terms, the goal of geochemistry is to strike an optimal balance between throughput and accuracy, at the lowest reasonable cost, while assays strive for accuracy. Traditionally, complete silicate analysis has been the concern of assayers whereas exploration geochemists have been more interested in base metal analyses where acid extractions of the elements, without dissolution of the silicate matrix, has been the norm. This kind of distinction is less realistic now, especially with the growth in lithogeochemical studies, and some overlap in methodology is unavoidable. However, where such overlaps occur the distinction remains in the emphasis of the work. A commonly used example is that although HF acid preparations are used by both, the emphasis in applied geochemistry is on sample throughput and batch analysis, whereas assayers are more concerned with the range of elements to be determined (Thompson and Walsh, 1983).

Jan 1, 1993

By J. Routh

Analysis of AI, As, Ba, Be, Ca, Cd, Co, Cu, Fe, K,. Mg, Mn, Mo, Na, Ni, Pb, Sb, Se, Sr, 11, V and Zn in various types of samples collected at Van Stone mine (a Pb-Zn deposit in Washington) and surrounding areas indicates that the concentrations of several elements in water, soil and sediment are higher than their background. values. Concentrations of metals in water decrease sharply downstream and are below the maximum contaminant levels specified for drinking water. Under present physico-chemical conditions, contamination of water is insignificant but the enrichment of heavy metals is found in soil and sediment.

Jan 1, 1994

By Kim Lapakko

As part of a project funded by the US EPA, through the Western Governors' Association, the recent literature on the prediction of acid drainage from metal mine wastes was reviewed. Static tests such as Acid Base Accounting, Modified Acid Base Accounting, B. C. Research Initial Test, and APP:S Test attempt to quantify the total capacities for a mine waste to produce and consume acid. In kinetic tests (e.g. humidity cells, soxhlet extraction, elevated temperature oxidation, column tests, batch reactor tests, B. C. Research Confirmation Test) mine waste samples are subjected to oxidation and the resultant drainage pH is assumed to reflect that of mine wastes dissolving in the field. This paper summarizes information presented in the recent literature on static tests.

Jan 1, 1992

By H. B. Charmbury

In the United States and in Pennsylvania in particular the coal mine drainage problem is of continuing and growing interest to the coal mining industry, the state government, the federal government and the public at large. The 1965 amendments to Pennsylvania's Clean Streams Law prohibit the discharge of acid mine drainage into the streams of the Commonwealth after January 1, 1967. Because of this new legislation, the coal mining industry and state government are extremely aware of the necessity for new techniques for treatment and prevention of the flow of acid mine drainage from the active mines of the Commonwealth in order to keep the coal mining industry in business in Pennsylvania. Approximately one-third of the total volume of mine drainage presently polluting the streams of the Commonwealth originates from "active" coal operations and two-thirds comes from "abandoned" mine discharges. As early as 1963 it became evident that the Commonwealth of Pennsylvania and the coal industry in Pennsylvania would have to take active steps to abate the mine drainage pollution of Pennsylvania's streams and rivers. This became quite clear during the deliberations in Harrisburg which climaxed a twenty year struggle for effective strip mining legislation. The bituminous strip mining law enacted that year made it unlawful to have any acid discharge from active stripping operations.

Jan 1, 1968