Search Documents

By P. Zhang, S. Al-Thyabat

"Phosphate rock contains traces of rare earth elements (REEs) and can be a secondary source of these critical materials as large tonnages of phosphate rock are mined annually. Attention has mostly focused on the extraction of REEs from phosphogypsum, which contains more than 70 percent of the REEs reporting to phosphate concentrate, with only limited work conducted on REE extraction from sand tailings and slime even though they account for 16 percent and 15 percent, respectively, of REEs mined with phosphate matrix.In this work, phosphate flotation tailings were upgraded by gravity separation and froth flotation. Gravity separation was conducted using a laboratory shaking table, while flotation was conducted in a Denver D-12 flotation cell. The concentrated tailings were then leached by nitric acid followed by REE extraction with solvent and ion-exchange resin.The sand tailings were assayed as having 2.6 percent phosphate (P2O5 ) and 198.1 µg/g REEs. It was found that the shaking table could produce tailing concentrate assayed as having 8.6 percent P2O5 and 616 µg/g REEs but with only 20 percent REE recovery, while the froth flotation produced froth concentrate assayed as having 8.1 percent P2O5 and 368.2 µg/g REEs with 63.5 percent REE recovery. Leaching the flotation concentrate with 5.2 M (25 percent) nitric acid followed by extraction with solvent and ion-exchange resin yielded precipitates with REE contents of 0.926 and 0.314 percent, respectively, compared with 0.716 and 0.213 percent when table concentrate was used.IntroductionRare earth elements (REEs) consist of a group of 17 elements: the 15 lanthanides along with yttrium (Y) and scandium (Sc). They are rare not because of their scarcity in the Earth’s crust but because they are rarely found in economic and mineable deposits. REEs are called “seeds of technology” because of their importance to some critical technological industries such as renewable energy, hybrid cars, electronics and batteries. On average, an electric car or a hybrid car contains about 10 kg of REEs (Grasso, 2012; Radhika et al., 2011).REEs are usually categorized into light (LREE) and heavy (HREE). LREEs consist of lanthanum (La), cerium (Ce), praseodymium (Pr), neodymium (Nd), promethium (Pr), samarium (Sm), europium (Eu), gadolinium (Gd) and scandium (Sc), while HREEs consist of terbium (Tb), dysprosium (Dy), holmium (Ho), erbium (Er), thulium (Tm), ytterbium (Yb), lutetium (Lu) and yttrium (Y). About 200 minerals contain traces of REEs, but only three are considered economically significant: bastnasite, with the formula La,Ce(CO3)F; monazite, with the formula(Ce,La,Nd,Th)PO4; and xenotime, with the formulaYPO4 (Jordens, Cheng and Waters, 2013)."

Jan 1, 2016

By Roger C. Wilmoth

The most common method of treating mine drainage to prevent water pollution consists of neutralization and aeration. This process removes the acidity, iron, aluminum, and some other heavy metals, but does not render a water suitable for domestic or industrial use because of the high dissolved solids, hardness, and sulfate in the treated water. The Environmental Protection Agency (EPA), has been sponsoring and conducting research since 1966 on the use of reverse osmosis (R.O.) for the treatment of mine drainage. This process has been found to be highly effective in the removal of nearly all the dissolved solids. In addition, since R.O. is a concentrating process, potentials for recovery of valuable heavy metals are possible. This paper is a review of the state-of-the-art on the treatment of mine drainage by reverse osmosis.

Jan 1, 1972

By Taghi Sharizadeh, MAURICE SUNKPAL, ELAHEH TALEBI, PEDRAM ROGHANCHI

Excessive heat exposure is among the health and safety hazards that have adverse effects on the mine workers. The very nature of the underground climate makes it a convenient avenue for heat generation and accumulation from several heat sources including autocompression, equipment, and heat from strata. This study investigated the effects of clothing insulation and acclimation on the thermal comfort ofmineworkers who are exposed to heat in underground working environments. Several clothing ensembles have been considered to analyze the effect of the thermal resistance of clothing on the thermal comfort of workers. To investigate the impact of the clothing insulation, the thermal comfort limit of an underground miner was calculated in the form of maximum allowable exposure time for an 8-h shift. Parametric analyses were subsequently performed using an already developed thermal comfort model using MATLAB software. The results demonstrate that clothing insulation has a significant effect on the thermal comfort of mine workers. Increase in the clothing insulation decreases the maximum allowable exposure time of mine workers. This is especially true for the new and non-acclimated workers. Since acclimatized workers can tolerate a higher level of the dehydration and are capable of losing more water by sweat per shift, the maximum allowable exposure time for the acclimated workers are higher than non-acclimated workers. These analyses have shown that acclimated workers can have more continuous work per shift compared with non-acclimated workers. For example, in an environmental condition with clothing that a nonacclimated worker cannot work more than 5 h, an acclimated worker can work a full 8-h shift.

Jun 29, 2020

By L. C. Morales

During my College days in Mexico City, my Mineralogy Professor used to say "Mexico is the Horn of Plenty, rich in minerals, and it is easier to say which minerals are not found instead of stating all that exist. He said that the only ones missing are bauxite, diamonds and titanium ores." Today, twenty years later, a rutile mine in Oaxaca is in successful operation. Mexico has an area of approximately two million square kilometers, with volcanic activity, large shores and mountainous areas reaching as high as 6,000 meters above sea level. These conditions are favourable for most mineral deposits, some -of commercial value and others as a source of mineral samples only. (fig. No.1) In addition to vast mineral wealth, Mexico has -another valuable asset in .his people. Even before the discovery of America, natives were successfully mining metals, and during the Colonial --days, the mineral deposits were mined to increase the wealth of Spain, and it increased the --knowledge of mining. All this experience was passed along from generation to generation, and created a tradition of mining and minerals processing engineers, that currently account for approximately 182,000 persons supported by mining related activities.

Jan 1, 1994

By David D. Eyer

In today's world coal market, coal quality is becoming increasingly important. Often the coal quality parameters are one of the crucial considerations in the development of a coal mine. Because of the user's tighter specifications and because of strict environmental regulations, coal producers are being called on to predict with increasing accuracy, not only the quality of their product but also the variability of that quality. This area of reserve evaluation is naturally receiving a great deal of scrutiny. Consolidation Coal Company has developed reliable and sophisticated methods for predicting coal quality, but the company's efforts continue to search for even better techniques. The following is a step-wise summary of The methods currently used by consolidation coal company, with A recent project used as an example. Two of the newer, and as yet experimental techniques will be briefly discussed.

Jan 1, 1980

By James E. Lawver

Response surface methodology is a well-known and powerful technique for determining optimum conditions in flotation systems. One disadvantage is the onerous task of the numerical calculations and curve platting. This paper describes a system in which the investigator simply selects the range of several flotation variables after which the design of the experiment, data analysis, generation of response surface equations, and response surface plats are automatically carried out using a digital computer and a computer-driven curve plotter. Several typical response surfaces of important variables in phosphate flotation are presented as examples. An overview of the flow charting of the system is provided in the addendum.

Jan 1, 1978

By A. M. Anthony, A. Y. Atta, S. S. Magaji, U. Abubakar-Zaria

There are two major gold recovery methods: the hydrometallurgical technique, which employs cyanide solutions, and amalgamation method, which involves mercury (Hg). These methods present considerable health, safety, and environmental concerns. Past applications of alpha-cyclodextrin (α-CD) on gold scraps show that α-CD is not only inexpensive, but is also environmentally friendly. This research work used α-CD to recover gold from gold ores instead of gold scraps. The gold ore was sourced from Shanono gold deposit site Kano State,Nigeria. The gold ore was characterized by fire assay (FA) for the precious metal. The concentrate was digested with aqua regia (AR) for 24 h. Modified AR, where hydrochloric acid was replaced with hydrobromic acid, was used for the gold digestion due to the good match in molecular recognition between gold bromide ion (AuBr)− and α- CD in a second sphere coordination complex. The digestate was characterized using atomic absorption spectroscopy (AAS). Gold recovery using this technique is pH sensitive, and five pH values (2.0, 3.6, 4.0, 5.4, and 6.0) were investigated. FA analysis showed the Shanono gold ore deposit contains an average of 4.71 ppm of gold, AAS analysis showed highest gold recovery of 69% at pH 4.0, which is lower than recoveries from the metal scraps. This could be due to the presence of other gangue minerals closely associated with the ore. However, gold recovery using α-CD on Shanono gold ore has shown to have a higher yield of 69% compared to 35.5% yield obtainable by Artisan Small Scale Miners using mercury.

May 5, 2020

By Yongjun Peng, Yufan Mu

Pyrite depression in the flotation of copper ores is difficult due to the activation of Cu2+ ions on pyrite surface. In this study, the radical chain reaction involving the redox cycling of Cu(I/II) induced by sodium metabisulphite (MBS) was exploited to selectively depress the flotation of copper-activated pyrite at pH 8.0. Electrochemical measurements revealed that the presence of Cu2+ and O2 was essential to the formation of SO•− 5 through sulphite oxidation, the main entity to convert the activating species Cu(I)S on pyrite to Cu(II)-hydroxide/sulphate, causing deactivation of pyrite. The depression role ofMBS on pyrite flotation was closely associated with the type of grinding media which affected the electrochemical conditions of flotation. When forged steel was used as the grinding media, a high dosage of MBS was required to depress pyrite, but a low dosage of MBS could almost completely depressed pyrite when high chrome steel grinding media was used. This is because high chrome steel produced a stronger oxidation condition with a higher amount of Cu2+ and O2 which promoted the formation of SO•− 5

Jan 26, 2021

By Taghi Sherizadeh, Kutay E. Karadeniz, Dogukan Guner, Samuel Nowak

Underground mining environments bring occupational health and safety issues with some severe dangers such as mine disasters like explosions. During such events, miners might escape using main access openings, or find a safe haven like refuge alternatives (RAs) to wait and be rescued and evacuated to the surface. In this paper, RAs are explained with their early and current applications. A classification as permanent and portable is explained depending on the conditions and their abilities. This classification is followed by the utilization and survivability of RAs with the requirements and recommendations of the main mining countries. Based on the utilization and survivability constraints, basic human requirements, waiting for a rescue team, and the required physical specifications of RAs during the events are analyzed in detail for various countries with their regulations. Among these, the specification, resistance to the explosion, is discussed in particular, and the studies in the literature are examined in terms of structural deformation. The highest deformed zones, the beneficiation of reinforcing steel components such as stiffeners, and the simulation approaches are investigated through this review.

Sep 24, 2022

By İsmail İnce

The purpose of this study is to investigate the index-mechanical properties of igneous rocks by using the electrical resistivity method. Electrical resistivity, index (P-wave velocity, dry density, and porosity), and uniaxial compressive strength values of 48 different igneous rock samples were measured in the laboratory. Simple regression analysis was performed between index-mechanical properties and electrical resistivity values. Strong exponential and logarithmic correlations were found between electrical resistivity and the index-mechanical properties of the igneous rock samples.

Jan 21, 2022

How do you think the US Bureau of Mines closing will affect SME? The demise of the bureau represents a challenge, an opportunity and, above all, new responsibilities for our profession. A lot of good professionals are seeking new positions. A lot of worthwhile research is available for transfer to the private sector. Logic dictates that worthwhile projects of any defunded government activities should find support in the private sector. The bureau may be gone but its legacy is deeply rooted in the profession. The bureau’s contributions will be remembered as long as there are mines and miners. Its1994 research program was divided into three major areas: environ-mental technology; health, safety and mining technology; and minerals and materials science. There must be a place in either the government or private sector to continue these worthwhile activities.

Jan 1, 1996

By Michael Moats, Weston Hartzell

The stable domestic supply of gallium, indium, and germanium has been identified as a critical need for the USA. Electric arc furnace dusts processed to recover zinc produce a process residue that could be a potential source of these critical materials. An industrial zinc leach residue was characterized to determine the predominant mineral phases and leached with common mineral acids. Atmospheric agitated leaching using sulfuric acid and hydrochloric acid were examined to determine the extractions of gallium, indium, and germanium as a function of concentration, temperature, and time. Extractions of gallium were found to be similar to iron in all experiments. The maximum percentage of Ga, Ge, and In leached into solution were 82%, ~100%, and 89%, respectively.

Aug 8, 2023

By Molood Saeedi, Nima Sadeghi, Eskandar Keshavarz Alamdari

This study showed the kinetics of gold chlorination leaching from an anode slime complex containing copper, silver, barium, selenium, and tellurium. AgCl and BaSO4 control the rate of gold leaching, and the interface transfer and diffusion across the product was selected as the desirable kinetic model. The concentration of hydrochloric acid, chlorine gas flow rate, pulp density, and temperature have been precisely studied. The results showed that temperature and hydrochloric acid have a favorable influence on the leaching rate. However, the chlorine gas flow rate is inactive in the reaction rate. Furthermore, the leaching rate decreased with an increasing pulp density. The leaching process was controlled by the interface transfer and diffusion across the product, and the activation energy was determined to be 13.66 kJ mol–1.

Oct 19, 2021

By W. C. Bagby

The Dee disseminated gold deposit is the northernmost mine in the Carlin gold belt. We analyzed soil samples £ran undisturbed areas overlying the deposit to determine the usefulness of soil geochemistry in identifying ore zones. The depth of sampling ranged from 12 to 14 inches, depending on soil development. The -80 mesh fraction was analyzed by atomic absorption for Au, As, Sb, Hg, and T1 and by semiquantitative spectrographic analysis for Ag. Highly anomalous Au, Kg, As, Ag, and Sb are most closely associated with ore zones whereas T1 is more broadly dispersed. Hg is the only element that identifies deep ore.

Jan 1, 1984

By James L. Hendrix

This paper is intended to give the reader an update on the work being done at the Mackay School of Mines about the fate of cyanide on precious metals mill tailings waste. During the last two years several tailings impoundments have been sampled and analyzed for total and free cyanides. From our sampling program we are beginning to learn valuable information concerning the fate of cyanides in precious metals mill wastes. Included in this paper is a detailed description of our sampling and analytical techniques. Also, some of the data obtained from five sites are given.

Jan 1, 1986

By Samuel S. M. Chan

Rock surrounding mine openings frequently is an impermeable type such as shale or granite. Most rock, however, has joints, bedding planes, cleavage planes, or other potential discontinuities. Permeability to fluids (gas or liquid) may exist via natural joints or fractures in an otherwise impermeable rock. In the mining situation, tectonic and induced tensile and shear stresses may be great enough to cause joints to open or fractures to develop in previously solid rock. The rock, as a result, becomes less self-supporting and may - require artificial support such as rock bolts or timber. Simultaneously, as fractures develop, permeable paths may be created. If fluid can be injected into a previously solid and impermeable rock mass, a logical conclusion is that a fracture (crack) flow path must be transmitting that fluid. The U.S. Bureau of Mines Laramie (Wyo) Energy Research Center has been evaluating results of in-situ oil shale fracturing (hydraulic or explosive) and retorting experiments by. a fluid (air) injection , and borehole air flow profile logging technique since 1956 (1, 14, 15). In the oil shale case, it is imperative to know the location and flow capacity (permeability) of natural fractures, if they exist, and induced fractures that inter-connect vertical wellbores at depths of fifty to several hundred feet. By injecting air into one wellbore in a system of several wells and measuring input volume and pressure while simultaneously measuring the output of other wellbores, the minimum areal extent of interconnecting permeable fractures can be determined. Exact locations (depths) of fractures and individual fracture flow capacities between wellbores can be determined by air flow profile logging (14, 15). Knowledge of fracture locations and permeability is essential to rational experimental in-situ retorting design.

Jan 1, 1973

By S. R. Titley

Results of regional analyses of precious metal habits in Arizona ores lead to interpretations of a fundamental ore control related to geographic location that corresponds with crustal contrasts. Measurements of isotopic and trace element characteristics of Laramide ore-related intrusions lead to interpretations of crustal derivation of apparent ore-related magmas. Interpreted regionally, the numerous kinds of Laramide ores, which include porphyry copper deposits of this southern cordilleran region appear to be phenomena of a specific crustal lithology characterized by a basement of Proterozoic turbidites and (an interpreted) lower crust of amphibolite. This association with a specific basement terrane may be extended in principle from the United states into Mexico where faulted offsets of this basement are similarly favorable to formation of Laramide porphyry ores -to the exclusion of adjacent terranes. Whereas plate tectonic mechanisms may have triggered evolution of these ores, it is hypothesized here that crustal setting and crustal composition are more profound influences of metallogenesis.

Jan 1, 1992

By Connor Langford, Murray Gant, Ken Massé

For public organizations, preparing accurate project cost estimates is a critical component in capital project planning. Project delivery methods provide a structured approach to moving projects through the design and construction lifecycle, and typically use cost estimates as key inputs at each stage to determine if the project will advance. As design stages can occur years or even decades before construction contracts are awarded, estimates need to make reasonable assumptions about how the work may be executed (means and methods) as well as potential future market trends so that appropriate values for material pricing, labour costs, escalation, and owner’s costs can be included. This process is challenging enough during stable markets, as historic trends can often be misleading and require a suitable understanding of economic factors to use appropriately. When you mix in the market volatility that has been observed since 2020, developing accurate project cost estimates becomes even more challenging. In cases such as this, having a structured approach to cost estimating that includes an adequate risk-based reserves cannot be overstated as it provides the basis for ongoing project decisions. This paper explores some of the historic and more recent market trends that have impacted key aspects of project cost estimates for capital project planning. It also provides recommendations on how to develop cost estimates for infrastructure projects, with examples from Metro Vancouver, which plans for and delivers regional-scale services to 2.6 million residents. A brief commentary on the use of escalation clauses in contracts is also presented.

Jun 13, 2023

By A. K. Bakshi

An on-line rheometer, suitable for use with slurries, has been developed at Michigan Technological University. This rheometer can be used with both Newtonian and non-Newtonian slurries, and produces complete shear-rate/shear stress curves which characterize the time-independent rheology of the slurry. The sensor utilizes the Hagen-Poiseuille equation and Boyle's Law to calculate the shear rate, slurry flowrate, and shear stress from a series of pressure measurements. The design of the unit allows the measurement sample to be continuously collected from operating process streams in the often-hostile on-line environment. The shear rate/shear stress curves can be used to conveniently calculate the apparent viscosity at any given shear rate, and also to measure any yield stress or other deviations from Newtonian behavior.

Jan 1, 1999

By W. L. Dare

Land use planning is not a new concept in the United States but the emphasis has changed drastically since the early 1960's. Under the old interpretation we tried to expand our frontiers and develop our land, but as society has become more affluent and mobile the demand has grown to preserve those parts remaining undeveloped. There is something of a paradox inherent in this change of emphasis. While affluence has motivated our support to preserve the quality of the natural environment, industrial development is needed to support the affluence. Because we cannot accomplish all of each, sound planning and compromise will be necessary since it is unlikely that, the American people will want to surrender much of their life-style or their awakening environmental concern. Any industrial society, whether a goal reached or an aim yet ahead, is built largely on the use of mineral raw materials and energy, the physical base of nearly all activities and products. The standard of living which is important to us all is growing more dependent upon these minerals, metals, and energy fuels. Although reduction in consumption of raw materials may be acceptable to those at a certain economic level of a society, those who have not reached that level cannot be expected to accept a lowering of their present or anticipated standard of living.

Jan 1, 1974