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By M. Alnot, J. A. Mielczarski, J. J. Ehrhardt, J. M. Cases

The flotation behavior of minerals depends on the balance between hydrophobic and hydrophilic species present at the surface of the minerals. The direct characterization of the interfacial products formed by the interaction of water and an aqueous solution of amyl xanthate with chalcopyrite, tetrahedrite and tennantite (the two former contain antimony and arsenic) were carried out by X-ray Photoelectron Spectroscopy (XPS) and infrared (IR) reflection spectroscopy. The experimental data collected from in-situ (IR ATR) and ex-situ (XPS, IR External Reflection) measurements have let us determine the types of the adsorption products and to propose mechanisms of interaction between the aqueous solution of surfactant and surface of the investigated minerals. It is shown that two major processes take place at the mineral interfaces: (i) the interaction with water and oxygen resulting in the formation of the oxidation products which are mainly hydrophilic (but also a hydrophobic product was found), and (ii) the adsorption of xanthate producing different types of hydrophobic surface products. The results obtained show differences in the composition of the outermost atomic layers of the investigated minerals which obviously will produce differences in the flotation behavior of these minerals. This work forms a good fundamental basis for a better separation between copper minerals containing arsenic and antimony, and chalcopyrite.

Jan 1, 1995

By Péter Siklósi, János Zámbó, Károly Solymár

It is fundamentally important to evaluate bauxites in a realistic, commercial way on the basis of the processing technology both for the supply of existing alumina plants and for the designing of new ones. The evaluation system developped by ALUTERV-FKI consists of chemical, mineralogical, texture and technological testing. The commercial value of bauxites is basically determined by their available alumina content and the caustic soda consumption required for their processing. However, their contaminants have to be taken into consideration, too. The commercial value of bauxites also depends on the processing technology and their possibly unfavourable chemical and mineralogical composition can be /at least partially/ compensated by R&D efforts. The selection of the optimum processing technology and the effects of further developing the same are demonstrated on monohydrate bauxites containing goethite and carbonates. Some of the technological solutions /desilication or deironing of bauxites, hydrothermal treatment of the digestion residue / make at the same time possible the complex processing of the bauxites, the profitable utilization of their main components.

Jan 1, 1984

By B. Rao Pothini, Julio H. Thaler, W. L. Finlay

The White Pine room-and-pillar mine started in 1955 from a suboutcrop, down gentle dips, and with a competent sandstone roof. As mining depths increased, extraction decreased 1% every 35 feet. Moreover, roofs became shaly and less competent, and regions of high fault and joint densities, sometimes with and some- times without high lateral stresses, increased the tendencies towards roof falls. Instinctive reactions towards narrower openings did not alleviate the problem. Careful consideration of rock mechanics principles culminated in the development of two variants to the conventional room-and-pillar mining system based on the concept of stress relief through load deflection. The two systems-EquiAdvance Cave, and PressureArch Panel Mining-are complementary. The objective of the former system is to provide relief from lateral stresses through advance caving and in the process also to achieve higher extraction at depth. Where surface subsidence cannot be allowed, the alternative PressureArch Panel concept is utilized to provide stress relief and moderately high extraction ratio. Both systems have been under trial for over three years and, together, produced over three million tons of copper ore. These two systems, and their production test results to date, are described.

Jan 1, 1977

By S. Monette, D. B. Dreisinger, D. Vleeschhouwer, G. B. Harris, G. A. Kordosky

A new process for the recovery of pure (>99.95%) palladium and platinum is described. The process, which has been tested at the pilot scale, comprises (i) the simultaneous solvent extraction of palladium and platinum by a new Schering Berlin reagent, TN 1911, (ii) washing of the loaded extractant to remove co- extracted impurities, and (iii) differential stripping of first platinum at pH 3, and secondly palladium with strong hydrochloric acid, and (iv) precipitation of palladium and platinum salts, followed by reduction to metal. The process is, unusually, a non-ammonia one requiring only small amounts of ammonia at the end where final purification may be necessary for particularly complex feed solutions.

Jan 1, 1993

By Kenneth J. Leib, Laurie Wirt, M. Alisa Mast

Chemical-constituent loads were determined for an alpine stream in southwestern Colorado that is affected by natural acid drainage from weathering of hydrothermally-altered rock and from acidic metal-rich discharge from abandoned mines. Base-flow loads were compared to storm-related loads using a tracer-dilution approach. A rainstom occurred during the tracer injection, providing the opportunity to measure metal loads before, during, and after storm runoff. Chemical-constituent loads during the storm increased by 1 to 2 orders of magnitude relative to base-flow conditions. The increase in loads was related to two distinct periods; (1) a flush of higher concentrations that occurred soon after rainfall began, and (2) the peak of storm runoff. The initial flush-having no measurable change in discharge--contained the highest loads of trace metals and dissolved iron. The chemical character of peak runoff was distinctly different, as evidenced by the highest loads of total and dissolved major elements and total iron.

Jan 1, 2000

By W. DR. Fritz

Technical progress depends on strategic objectives and a concept showing how to benefit from the effects of novel techniques in an innovation process and how to implement them creatively in harmony with manpower capabilities. With the invention of prime movers, it was initially power engineering which dominated the development of industrial history before it was replaced by production techniques resulting from the more widespread use of machines. With the advances in the field of data processing and with the introduction of novel communication techniques, it is information technology- which today is having an ever increasing impact on technological progress. The main objectives of information technology in this context are a positive influence on the ?time? factor as well as the provision of tools to handle the complexity governing many operational processes through a concentration of information for the decision-making process. The German hardcoal industry became aware of the chances inherent in these new technological possibilities for the optimization of operational sequences and of decision-making and planning processes as a potential for success at an early stage and it has worked out a purposeful concept for their implementation.

Jan 1, 1992

By Karel SPIRKO

The one-dimensional mathematical model of unsteady-state heat conduct ion through multilayer (wall and floor of airway consist of several layers of material and rock) and two-surface (dry and wet surfaces) airway wall and airway floor with convective heat and moisture transfer between their surfaces and mine air with time dependent changes of temperature and humidity has been developed on the basis of introduction of acceptable simplifications of description of heat and moisture transfer between rock mass and mine air. The analytical solutions for calculation of the surface temperature of any type of surface of airway wall/floor and for calculation of water vapour pressure near the wet surfaces at given time are obtained by means of the model presented. These solutions are illustrated for the case of general harmonic course of air temperature and humidity. Balance of heat and moisture transfer between surfaces of airway wall and floor and mine air is solved by an iterative method in the partial sections of airway. The temperature and the humidity of mine air on the outlet of each partial section of airway at given time are its resolutions and they are the input data for following partial section. By this way it is possible to solve complicated dynamic changes of mine air temperature and humidity in an air way system by relatively simple mathematical apparat.

Jan 1, 1991

By J. Luo

A major design problem for upper seam longwall gate roads that are to be constructed in a multi-seam environment is to predict the effects of stress field changes created by interaction. To quantify these effects, case study data were analyzed to develop empirical stress transfer relationships between seams for both longwall and room and pillar mining. Data analysis showed vertical movement and roof characterization in the upper seam to be controlling factors in damage prediction and, therefore, gate road planning and design. CMRR (Coal Mine Roof Rating) was correlated with the multi-seam roof characterization systems previously used. A WINDOWS-based software package named UGLY (Upperseam Gateroad Longwall Stability) was developed. Results from selected case studies were correlated with upper seam stress predictions.

Jan 1, 1997

By Michael Fellows

Epidote is a common hydrothermal alteration product in many copper deposits of the southwestern United States. In many of these deposits epidote, along with calcite and chlorite, generally characterize a distal or halo propylitic alteration assemblage, but the mineral can occur within the central potassic alteration zone as well. Epidote is also a common alteration mineral in deposits formed in calcareous host rocks -- the skarn or pyrometasomatic ore bodies. Within the past 15 years, studies of the major and trace element composition of other alteration phases, principally biotite, associated with base metal ore deposits have demonstrated that some hydrothermal alteration minerals are compositional distinct from their igneous or metamorphic counterparts: However, the use of major and minor element content to identify and zero in on mineral¬ized areas does not appear to be very promising. Little work has been published upon the geochemistry of epidote from this standpoint and the results of my work suggest that a similar conclusion can be applied to epidote. My work (Fellows, 1976) suggests that epidote minerals in hydrothermal alteration suites from porphyry copper deposits in the southwestern United States are generally iron-rich rather than aluminum-rich. As a group, these alteration minerals differ compositionally from epidotes of regional metamorphic terrains. I ascribe these differences to the variations in the oxidation character of the respective environments. However, it appears as though the use of major element compositional variations of epidotes as an exploration tool is severely limited. Epidote is a complex calcium-aluminum silicate. Replacement of aluminum by ferric iron establishes a solid solution series between

Jan 1, 1977

By B. K. Cantrell, D. H. Carlson, W. F. Watts, K. L. Rubow

The use of diesel equipment in underground coal mines is controversial because the National Institute for Occupational Safety and Health (NIOSH) regards "whole diesel exhaust" as "a potential occupational carcinogen." Threshold limit values (TLVs) are recommended for the gaseous pollutants CO, CO2, NO, N02, SO2 and some hydrocarbons emitted in diesel exhaust. There is, however, no TLV recommended for diesel exhaust aerosols (DEA) nor is there a standard method for sampling these aerosols. The University of Minnesota and the USBM have collaborated to develop a personal diesel exhaust aerosol sampler (PDEAS) that utilizes size selective, inertial impaction and gravimetric analysis. During the field tests of this sampler, numerous air quality measurements were conducted in underground coal mines that used diesel equipment. The objective of this report is to present these data and to assess the impact of diesel face haulage equipment on mine air quality. Air quality data were collected in four underground coal mines. The mines used continuous miners and diesel haulage equipment. Daily samples were collected at the section intake, haulageway and on haulage vehicles. Both full-and partial-shift samples were collected using a variety of aerosol instruments. These included the PDEAS and the micro-orifice uniform deposit impactor (MOUDI) that sample the mine aerosol diesel exhaust fraction. Two of the mines were also monitored for the major gaseous constituents found in diesel exhaust CO, CO2, NO, NO2 and SO2. These measurements were made by either collecting bag samples for subsequent gas analysis or by Palmes dosimeters. Concentrations of CO, C02, NO, NO2 and SO2 were well below regulated levels. The mine average DEA concentration determined by the PDEAS in the haulageway for the three mines surveyed was 0.79 mg/m3, with a standard deviation of 0.19 mg/m3. DEA contributed 65% of the respirable aerosol, at this location. These results were the same as the mean DEA concentrations calculated from size distribution measurements obtained using the MOUDI. This was 0.78 mg/m3, with a standard deviation of 0.22 mg/m3.

Jan 1, 1992

By P. Mousset-Jones, G. Danko

Rock thermophysical properties, i.e. heat conductivity and thermal diffusivity, were obtained for reference values at the Waldo Test Mine for mine fire simulation purposes. An in situ measurement method was chosen since it could include the effect of rock fractures. The REKA method (Rapid Evaluation of k and alpha) was used because it can measure conductivity (k) and diffusivity (alpha) simultaneously within an eight-hour measurement period. A total of six measurements were taken in three different holes, and at two different depths from the collar of the hole. Each measurement provided an averaged conductivity and diffusivity for a volume of rock of approximately one cubic meter. The boreholes were driven into the upper and lower limestone, two at right angles to and one parallel to, the stratification of the rock. Significant representative conductivity and diffusivity values were obtained for the whole mine by averaging the six measurement results. The thermal properties for the band of shale in between the two limestones were not measured in situ, but only in the laboratory. Problems were encountered in the evaluation because of unexpected heat conduction on one side of the symmetrically built probe. A modification was made to the previously developed evaluation method together with further testing and correction, before the final results were obtained. As expected, the in situ and lab- oratory measured values of k and alpha compared favorably, since the in situ rock was dry and relatively unstressed.

Jan 1, 1989

By A. S. Malicsi, Vathsala Rajagopal, I. Iwasaki

Corrosion and abrasion properties of a series of chromium-containing, cast-iron balls, with Cr contents ranging from 0% to 29%, were evaluated and compared with austenitic stainless-steel and mild-steel balls. Marked ball wear tests were performed on artificial ore samples consisting of 95% quartzite, with either 5% pyrrhotite or 5% chalcopyrite, under a nitrogen or oxygen atmosphere. The electrochemical mechanism was investigated by correlating the corrosive wear with the corrosion currents obtained from potentiodynantic polarization curves under abrasion. Flotation recoveries were determined on a 95% quartzite + 5% pyrrhotite sample ground with various cast-iron ball materials under an oxygen or nitrogen atmosphere. Electrochemical results are found to be in good agreement with flotation results and with corrosive wear data obtained from marked ball wear tests.

Jan 1, 1993

By Gregg Wilkerson

The Blind Springs Hill pumice beds are located 5 miles southwest of Benton, California in the foothills between the Benton Mountain Range and Blind Springs Valley. The best exposures of the pumice are in an area 0.75 miles west of Blind Springs Hill. The pumice is Quaternary ejecta material which came from the rhyolitic volcanoes in the Glass Mountain-Volcanic Tablelands area of Mono County. The pumice beds occur in two distinct layers separated by an unconformity. The upper layer is 0 to 11 feet thick and consists of coarse subangular pumice fragments, some of which are over 1.75 inches in diameter. The lower bed is medium to coarse grained with subangular fragments up to 1.0 inch. The lower bed is 0 to 9 feet thick. Overburden at the Blind Springs Hill deposit varies from 0 to 15 feet. There are approximately 1 million cubic yards of material in the deposit that can be mined. The size distribution in the deposit is mostly fine with only 10.6% of the pumice fragments being over 0.5 inch in diameter, the minimum size needed for stone-wash or acid-wash applications. Suitability of pumice for the textile industry is quantified by standard 15-minute abrasion and absorption tests. In the Blind Springs Hill deposit, the plus 0.5 inch fraction has an abrasion loss of 33% which is too high for stone-wash application but it has an absorption capacity of 36% which makes it suitable for acid-wash applications in the textile industry. The abrasion and absorption properties of this deposit are within the range of those which have been measured for other pumice deposits within the United States.

Jan 1, 1995

By R. L. Grayson

Following lip on a USBM-sponsored research project, the authors have utilized the knowledge-base structure and system concepts from the Sun Sparcstation-based worker scheduling system of the Mine Management Support System to develop a PC-based application. The new software adopts the nested-window concept to facilitate data collection and modification on personnel, their availability on a shift, and work priorities for a shift as well as to allocate manpower optimally on a work shift and delineate supervisory training responsibilities. The various components of the software are described in detail, along with enhancements made to the original system.

Jan 1, 1996

By Graham A. Mathieson

A detailed breakdown of capital and operating costs is an essential element in the planning and evaluation of any mining project. The OPCOST System was developed by Golder Associates to provide mining engineers with the facility to synthesize detailed cost estimates for all aspects of an operating or potential open pit mine. The system can also be applied to underground mines equally as well. Such estimates can be prepared at a variety of levels depending on the detail required by the project. The OPCOST System is a suite of computer programs linked through a common hierarchical data base. It simulates the thought and reasoning processes within the quantity takeoff and cost estimation phases of a mining project. The system was developed as a mining cost engineering tool on the basis that it would have to satisfy a variety of purposes, namely:

Jan 1, 1982

By F. P. Schwarz, A. J. Erickson, S. M. Weber

The Mount Hope stockwork molybdenum exposit, Eureka County, Nevada, occurs in a small igneous cauldron complex 32 to 38 mybp in age. The deposit is characterized by alteration zones and mineralized shells symmetrically distributed around multiple intrusives. For samples from the 25 000 meters of 1981-82 drilling, an appraisal of error in in-house sample preparation and in commercial assaying has been made. After splitting, drill core is crushed and reduced in volume (8:1 at 10-mesh, 8:1 at 70-mesh, 6:1 at 200-mesh) to supply 25 grams of 200-mesh pulp for replicate analyses. A 0.5 g portion of the pulp is used for dissolution and atomic absorption analyses. Factors which initially generated unacceptable data variances have been minimized by planning, repeat analyses, introduction of standards, and routine monitoring. Assuming that error between replicate assays defines a Gaussian distribution with its average ideally equal to zero, precision (from preparation including core splitting and analysis of 8400 pairs of molybdenum samples) is on the order of + 25%. The error distribution is not biased. Accuracy is approximately 4% lower than absolute as determined by replicate assays of commercially prepared samples.

Jan 1, 1992

By A. W. Khair

This paper presents an analysis of surface subsidence characteristics in room and pillar mining using physical models and laser holographic interferometry (holometry). The analysis included the effect of various geometric parameters and different overburden materials (sand and gelatin) and resulted in the formulation of a more realistic model material for laboratory simulation of typical geologic overburden. Previous work using this technique involved the use of sand to model over- burden and detailed results are presented elsewhere (1). The main emphasis of this work was to develop a gelatin based mixture which would provide a better model. Initial work during the development of this model included testing various ingredients and monitoring the time dependent characteristics of the model, such as the surface penetration resistance. This value indicated changing deformability/ridgidity of the model with time. Once several models had been developed, holometry techniques were applied. Initial tests showed that the stiffness of gelatin created a bridging effect over the mine models, thus restricting deformation. At this point, a 0.5 inch (1.27 cm.) layer of sand was placed directly over the mine model with the gelatin mixture on top. The approach was to model different zones of overburden movement that exist as an extraction occurs (2). The sand would represent the caved and fractured zones which occur above the excavated area. The gelatin models the continuously deformed zone which occurs between the fractured zone and the surface. Holometry techniques applied to this model yielded successful results.

Jan 1, 1986

By David J. Kruse

Accurate field measurements are essential when validating a conveyor design. They are fundamental in determining a conveyor's behavior, its long-term maintenance requirements, and the life expectancy/ condition of the installed equipment. Field measurements are also invaluable in forensic engineering, particularly when vital equipment has failed This paper will discuss a wide variety of data acquisition equipment, field measurement techniques and accuracies achieved State-of-the-art, custom designed monitoring equipment, as well as, ''08-the-shely instruments and sensors, will be discussed.

Jan 1, 2004

By J. den Drijver, M. Opahle, R. Inderst

Safety reasons render necessary the advanced calculation of the amount of methane degassing from a longwall in the scope of the ventilation planning of mines. Today empirical methods, which are based on observations of operational procedures, are used for the calculation of the amount of methane. Despite of constant improvement those calculations are not always sufficient. In particular calculations which are based on operational facts but not proved by experience are not reliable. Most of all these calculation procedures lack physical-analytical descriptions of the procedure itself, presenting only the effects on important parameters such as the distance between seams in the roof or floor or gas pressure. Tschersich [Tschersich 961 developed an analytical model for an advanced calculation by analysing the degassing of seams in the roof and floor and the physical parameters of gasflow. This model might correct the lacks of existing procedures and improve the precision and reliability of additional calculations. The model simulates the emission record in seams of the roof and the floor. It takes into account not only a multitude of parameters such as the distance to adjacent seams and gas pressure but also the depth of seams, gas content, rank of carbonification, rock temperature, face advance rate, initial and succeeding mining and the face length. In order to comprehend and to verify those correlations we extended the model of Tschersich and programmed this enlarged model using the computer language C++. Aim of this research is to guarantee a much higher accuracy in calculating methane emission caused by mining. The improved planning is expected to result in more safety and better prevention of high methane con- tent in ventilation as well as in a better use of the capacity of the mining equipment. The application [Drijver, lnderst 961 of the ex- tended model will also be very useful in the course of research projects as it allows computer simulation, i.e. in-situ research can be extensively limited or even replaced.

Jan 1, 1997

By Liguang Wang, Roe-Hoan Yoon

The thin film balance (TFB) technique was used to measure the equilibrium film thicknesses (H3 between two air bubbles in sodium dodecyl sulfate (SDS) and electrolyte (NaCl) solutions. The results were used to determine the magnitudes of the hydrophobic forces (K232) using the extended DLVO theory. The Km values determined from He measurement allowed us to predict disjoining pressure isotherms, which were found to be in excellent agreement with those obtained experimentally using a bike-wheel film holder. The rate of film thinning was measured at low SDS concentrations with varying amounts of electrolyte (NaCl) added. In general film thinning was controlled by the capillary pressure during the initial stages, while it was controlled by the surfaces forces during the later stages. At low NaCl concentrations, it was possible to predict the rate of film thinning using the Reynolds equation, provided that the driving force was corrected for the contributions from the hydrophobic force, which in turn were determined from the KZ32 values obtained from the He values measured experimentally. At high NaCl concentrations, where it was difficult to measure the equilibrium film thicknesses, the contributions from the hydrophobic forces were determined by fitting the film thinning data to the Reynolds equation. The K232 values obtained using both the equilibrium film thickness and the film thinning measurements showed that hydrophobic force deceased with increasing surfactant and salt concentrations. It was found that the hydrophobic force in foam films was very sensitive to the added electrolyte concentration.

Jan 1, 2005