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By Y. Wang

Arsenic-bearing acidic effluent from hydrometallurgical processes contains many harmful metal ions and must be appropriately treated before discharge. In the present study, arsenic, copper, zinc, aluminum, and magnesium were co-precipitated by means of the Fenton reaction. The precipitates obtained under different conditions were investigated to determine their stability. The results indicate that pH value and hydrogen peroxide (H2O2) dosage have significant effects on the removal of various elements. Arsenic, copper, zinc, and aluminum (but not magnesium) can be removed at pH 5–6 and anH2O2/As mole ratio of 2 at ambient temperature. The precipitates were mainly amorphous and granular with particle size in the micrometre range. The arsenic concentration in leachate from the toxicity characteristic leaching test was 3.6 mg/L, which proves that the precipitates are effective in fixing arsenic.

Aug 3, 2023

By A. F. Spinks, S. P. Nicholls

"The Lower Orebody at Chingola Division of Nchanga Consolidated Copper Mines, Limited, is a stratified orebody that is mined by a continuous caving system. The accurate determination of the developed and semi-developed ore reserves has always been difficult. The new system proposed in 1971 is designed to update and, as new informa¬tion becomes available, to account for the depletion of, the reserves.There are three main inputs to the system. These are borehole data, survey data and extractions data. The borehole data are input to a geological borehole master file system, which holds every recorded detail of a borehole in an easily extractable form. These data can be extracted for ore reserve calculations or for contour mapping of orebodies and rock types. The grades for use in the ore reserve calculations are extracted from the relevant boreholes.The survey data are information on the position of the blocks and drifts, taken from plans, and information on the scraper drift and trough drive positions taken from sections. The information is extracted from the plans and sections using a D Mac pencil follower. The ore reserve is calculated from the survey data and the borehole data.Data on extractions are taken from scraper operators' logs, tramming records, skips hoisted records and accepted mill tonnages and grades. Using these data, the mill tonnages are reconciled back to the drifts, to deplete the current ore reserves.As new workings are brought into operation and further evaluation holes are drilled, the relevant data are input and the new developed ore reserve is calculated."

Jan 1, 2014

By J. L. Havenga, L. J. van der Walt, J. T. Nel

"SynopsisThe development of plasma technology at Necsa started in the early 1980s, when the applicability of high-temperature plasmas in the nuclear fuel cycle was investigated. Since 1995, this plasma expertise has expanded to other industrial applications, for example mineral beneficiation, nanotechnology, fluorocarbon production and waste treatment, all of which are also of relevance to the nuclear industry.Necsa has demonstrated the manufacture of plasma-dissociated zircon, zirconium metal powder, carbon nanotubes, silicon carbide (SiC), zirconium carbide (ZrC) and boron carbide (B4C) at the laboratory and pilot plant scale. These materials are commonly used in the nuclear industry. Zirconium alloys are used as fuel cladding material for nuclear fuel assemblies.Necsa manufactured the monomer tetrafluoroethylene (TFE), using 150 and 450 kW DC plasma systems, from which the polymer polytetrafluoroethylene (PTFE) was synthesized for use in filters and as seals in nuclear plants. With the nuclear renaissance at hand, it was demonstrated that plasma technology can be used to produce hydrofluoric acid (HF), which is used in the manufacture of fluorine gas (F2) for the production of uranium hexafluoride (UF6) directly from the mineral calcium fluoride (CaF2) without the use of sulphuric acid as in the conventional process. The recovery of valuable uranium from nuclear waste such as filters, oils, and solids with plasma processes will also be discussed. The destruction of low-level nuclear waste by a plasma gasification system can reduce the volume of this waste by several orders in magnitude, resulting in huge savings in the storage costs. Another product of plasma technology is the encapsulation process for nuclear waste and the production of vitrified product, which could be used as filler material for medium-level nuclear waste.IntroductionDuring the 1980s, a plasma research and development programme was launched at the erstwhile Uranium Enrichment Corporation of South Africa (UCOR) at Valindaba outside Pretoria. The main purpose of this programme was to develop alternative and more economical processes for the processing and manufacturing of uranium compounds used in the nuclear fuel cycle. The conversion of UO2 (as received from uranium mines) to UF6, which is needed for enrichment, conventionally involves several laborious, expensive, chemical processing steps. Plasma processes can eliminate several of the intermediate steps. Enriched UF6 is converted to UO2, which is pressed into pellets that are used in nuclear power plants. Plasma technology could also be used in a modified and optimized conversion process."

Jan 1, 2015

By C. Hartford, T. Holmes

Bulk-solids handling systems are often the most over-looked component and thereby weakest links in a processing plant’s value chain. Since their performance can dictate that of the entire operation, they actually deserve special attention. When designing a liquid handling plant, density and viscosity are well known and commonly used as design parameters. Bulk solids however, differ. While the design process is similar, the relevant parameters in handling bulk solids are instead friction, cohesive strength, compressibility, and permeability. These then vary depending on the mineralogy, particle size distribution and shape, moisture content, storage time-at-rest, temperature, and consolidation pressure. With so many variables, it becomes important to characterize each individual bulk solid across the full range of representative process conditions within the handling system, plant wide – or if you are not very lucky, suffer the consequences of poor material flow. Measuring flow properties and applying them correctly in bulk solid handling system design reduces project risk, saves significant capital, and drastically increases throughput, especially when done in the early stages of a project. Keywords: Flow Properties, Bulk Solids, Process Conditions, System Design

Jan 1, 2020

By P. E. L. Balestra, A. O. Filmer

The kinetics of the reactions involved in the non-oxidative dissolution of nickel concentrate in hydrochloric acid were studied by electrochemical and powder-leaching methods. It was found that the rate of non-oxidative dissolution increases with a cathodic shift in the mixed potential, which can be achieved by an increase in the nickel-to-sulphur stoichiometric ratio at the reaction surface. An unactivated concentrate with a sulphur content of 36 per cent exhibited a mixed potential of +O,3V (SCE) and could not be leached satisfactorily in 3 M hydrochloric acid at 60°c. When activated material (18 per cent sulphur) was leached, it had a mixed potential of -O,3V, and high iron and nickel extraction rates. Results reported by other workers on the non-oxidative dissolution of sulphides are explained in terms of the mixed potentials at which dissolution occurs.

Jan 1, 1981

By A. C. Lawrence

A new approach to the -study of human factors in stope productivity by A. C. LAWRENCE B. Econ., D. Com. (S.A.) (Member) The extent of the improvement in mean performance which could be achieved by reducing the variance between stoping gangs is examined, and it is shown that a worthwhile gain would result if variance were reduced by as little as 5 to 15 per cent. The problem of identifying human factors which contributed towards variance in gang performance was examined in one gold mine. A total of 342 'observations' on 49 stoping gangs were gathered, each observation consisting of a set of figures for 36 variables for one gang for one week. The variables included 'stope factors' such as face length, 'gang factors' such as the ethnic composition of the gang, and 'supervisory factors' such as the experience of the miner. These variables were related to 'tons trammed per week' as a measure of work performance. The findings showed that certain of the predictor variables accounted for 66 per cent of the variance in gang performance and about two thirds of this could be attributed to gang and supervisory factors, that is to the 'human factors'. The method suggests a basis for a new approach to the identification of human factors and is a promising step towards optimizing gang performance.

COUNCIL FOR 1988/89 President C.E. Fivaz President-elect Dr O.K.H. Steffen Senior H.G. Mosenthal Vice Presidents Junior R.D. Beck Immediate Past President B.C. Alberts Honorary Treasurer Dr H. Wagner

Jan 1, 1989

By S. M. H. Ahmadi, K. Barani, F. Moradpouri, R. Ghaedrahmati

As exploration is time-consuming, costly, and risky, determination of the erosion surface of a metalliferous deposit before geophysical surveying and exploration drilling might be very helpful. Geochemical haloes can be used to determine whether the erosion surface is supra-ore or sub-ore and thus reduce the risk of exploration operations. The aim of this investigation is to determine the erosion surface of the North ROK porphyry deposit (NRPD) in northwestern British Columbia in Canada using linear productivity (LP), which is the content of an element defining the halo multiplied by the width of the halo. A total of 2045 soil samples from the B horizon were analysed using ICP-MS for 36 elements, including Cu, Mo, Pb, Zn, Au, As, Ag, Ni, Co, Fe, and Mn. The data-set was snalysed to obtain the statistical parameters and the elements Cu, Mo, Pb, and Zn were chosen to calculate the linear productivity and the total linear productivity. These four elements were modelled using probability plots to identify and separate subpopulations in terms of anomalous haloes and background, including the threshold values of each subpopulation. The results of the probability plot modelling and thresholds values were then used to map the distribution of each element in a GIS to calculate the linear productivity. The total linear productivity indicated that the erosion surface is supra-ore. Finally, a 3D orebody model of the Cu, Mo, Pb, and Zn distributions was constructed using borehole data and used to validate the results.

Feb 6, 2023

Orebody modelling and reserve estimation are now subject to sophisticated procedures, but folded stratiform and stratabound deposits present particular problems in transforming coordinates of samples and blocks into their correct relative positions prior to deformation. In this paper an approach is taken whereby a geologically interpreted reference plane is used as a control. The study area is the Rio Tinto Minera copper mine near Santiago de Compostela, Spain. The transformation procedure on the 'unfolded' state is described, its limitations assessed and advantages considered.

Jan 1, 1987

By M. Lange

The postulation that primary platinum group metal (PGM) matte will chemically react with magnesia-chrome bricks when temperatures exceed 1500°C was tested. Magnesia-chrome brick samples were heated in contact with matte at 1300°C to 1750°C for 30 minutes, after which the refractory samples were analysed using reflected light microscopy and scanning electron microscopy. The samples were all completely penetrated by matte. As the temperature increased the matte also penetrated the fused aggregate grains and disintegrated them. The chromium concentration of the matte inside the refractory samples was found to be slightly higher than that of the bulk matte. At temperatures of 1500°C and higher, MgO, FeO, and magnesium-rich silicate crystals could be identified in the matte directly adjacent to the refractorymatte interface. Phase relations clearly indicated that chemical reactions take place between primary PGM matte and the magnesiachrome refractory material at temperatures above 1500°C, but that these reactions are more complex than expected from FactSAGE® calculations.

Jan 1, 2014

COUNCIL FOR 1990/91 President H.G. Mosenthal President Elect RD. Beck Senior J.P. Hoffman Vice Presidents Junior Or H. Scott-Russell Immediate Past President Or O.K.H. Steffen Honorary Treasurer OrH. Wagner

Jan 1, 1991

By R. MacRosty, R. Pula, P. Gebski, W. Braun

"This paper provides a progress update on three tapblock monitoring technologies that Hatch has been developing with our clients for non-ferrous smelting furnaces.The Tapblock Diagnostic System (TDS) is an advanced on-line monitoring system that uses temperature data along with embedded thermal model results to evaluate the condition of a tapblock over its campaign life. Hatch recently installed a second Tapblock Diagnostic System, some details of which are provided in this paper.The Tap-hole Acoustic Monitoring (TAM) system is installed on water-cooled copper tapblocks and uses the noise from the tapping channel to provide a qualitative indication of wear and deterioration of the tapping channel refractory. In addition, TAM can be used to monitor drilling and lancing performance, and potentially could also be used in the future as a guide for automatic drilling and lancing systems (Sadri et al., 2008).The third technology is the use of fibre optic sensors to measure temperature on the hot face and in the tapping channel of a tapblock. Fibre optic technology allows installation of numerous sensors in key locations where they are very sensitive to tapblock condition and also provide more extensive spatial coverage than is possible with traditional instruments. This paper provides an update on our efforts to address issues with premature failure of the sensor cables due to corrosion, and also converting the vast amount of data from the sensor cable into information that can be used by furnace operators."

Jan 1, 2014

By M. G. Maruma, L. A. Mampuru

"Mill liner wear is a major cost item in the mining industry and there is continuous research to prolong the life of the liners. Over the years it has become apparent that even though high-chromium white cast irons are highly efficient as abrasion-resistant materials, a combination of wear resistance and fracture strength remains difficult to achieve. Increasing the hardness of the high-chrome white cast iron (HCWCI), which improves the resistance to abrasion wear, is often accompanied by a deterioration in fracture strength. Operational conditions inside the mill require that the liner should be made of highly wear-resistant material with some fracture strength. Vanadium additions ranging from 0.2 to 3 wt% were made to HCWCI in an attempt to refine the microstructure. It was found that an increase in vanadium content promotes grain refinement. A content of 1.5-3 wt% gave the best results as measured by the maximum breaking strength.IntroductionOver the years it has become apparent that even though high-chromium white cast irons are highly efficient abrasion-resistant material, a combination of excellent wear resistance and fracture strength remains difficult to achieve. The exceptional wear resistance of highchromium white cast iron (HCWCI) is attributed to hard chromium carbides embedded in an austenitic/martensitic/pearlitic matrix. When the chromium contents exceed 12 wt%, interconnected MC3-type carbides of conventional cast irons are replaced by rodshaped and isolated M7C3 carbides (Powell, 1980), leading to an improvement in the impact toughness, ductility and fatigue resistance. However, the main M7C3 carbides in HCWCI are hard and brittle and can provide an easy path for crack propagation. This limits the applications of HCWCI, particularly in severe impact conditions. Most operations involving HCWCI are in crushing and grinding and the life of a part/liner is limited by its wear resistance. However, improving the wear resistance of HWCI comes at the cost of a significant reduction in fracture strength. Concerns about premature failure of HCWCI mill liners in the mining industries prompted a study to improve the wear resistance and mechanical properties of HCWCI."

Jan 1, 2016

By S. Schmachtel

Several possible physico-chemical properties of composite electrodes for oxygen evolution are presented to describe experimental data for which a mathematical model had been developed. On this basis, local electrical and electrochemical properties of a composite electrode were investigated with conductive atomic force microscopy (CAFM) and scanning electrochemical microscopy (SECM). It could be shown by CAFM measurement that the boundary between matrix and catalyst particles seemed to have special advantageous electrical properties. The SECM measurements showed the presence of mass transport phenomena with increased surface concentrations, whilst the thickness of the Nernst diffusion layer was very small. An intermediate was detected and assigned to be hydrogen peroxide. From all species involved in the oxygen evolution reaction (H2O2, H+ and O2), it was concluded that local active spots exist on the electrode on which hydrogen peroxide reacts to oxygen and protons. A two?step two-material process was suggested to explain the whole oxygen evolution mechanism.

Jan 1, 2008

By Sönke Schmachtel

Several possible physico-chemical properties of composite electrodes for oxygen evolution are presented to describe experimental data for which a mathematical model had been developed. On this basis, local electrical and electrochemical properties of a composite electrode were investigated with conductive atomic force microscopy (CAFM) and scanning electrochemical microscopy (SECM). It could be shown by CAFM measurement that the boundary between matrix and catalyst particles seemed to have special advantageous electrical properties. The SECM measurements showed the presence of mass transport phenomena with increased surface concentrations, whilst the thickness of the Nernst diffusion layer was very small. An intermediate was detected and assigned to be hydrogen peroxide. From all species involved in the oxygen evolution reaction (H2O2, H+ and O2), it was concluded that local active spots exist on the electrode on which hydrogen peroxide reacts to oxygen and protons. A two?step two-material process was suggested to explain the whole oxygen evolution mechanism.

Jan 1, 2008

COUNCIL FOR 1987/88 President B.C. Alberts President-elect C.E. Fivaz Vice Presidents Senior Junior Dr O.K.H. Steffen H.G. Mosenthal Immediate Past President Dr H. Wagner Honorary Treasurer Dr H. Wagner

Jan 1, 1988

By H. Zhong, S. Wang, Q. Lin

To improve the flotation performance of chalcopyrite collector, 2-(tert-butoxy)ethyl xanthate (TBEX) and its derivative O-(2-(tert-butoxy)ethyl)-N-ethyl-thionocarbamate (TBEETC) were designed and prepared by the introduction of a 2-(tert-butoxy) ethyl group into xanthate and thionocarbamate. TBEX and TBEETC were both prepared via the one-pot method with superior efficiency, which has significant commercial implications. The micro-flotation tests demonstrated that compared with sodium isobutyl xanthate (SIBX) and O-isopropyl-N-ethyl-thionocarbamate (Z-200), TBEX and TBEETC both possessed better collecting ability and selectivity for chalcopyrite. DFT calculations and XPS were utilised to investigate the flotation mechanism involving TBEX or TBEETC and chalcopyrite. The results demonstrate that although 2-(tert-butoxy) ethyl group does not interact with minerals directly, its introduction reduces the energy of HOMO, so that they can better accept electrons instead of donating electrons which leads to better interaction with copper atoms rather than iron atoms. Keywords: Chalcopyrite, flotation, thionocarbamate, xanthate, synthesis

Jan 1, 2020

By J. P. De Carvalho, R. Dimitrakopoulos

This paper presents an actor-critic reinforcement learning (RL) method to allocate trucks and shovels in open-pit mines, while defining short-term production scheduling of an industrial mining complex, given new information collected during operations. This new data obtained from sensors update the uncertainty of the orebody models. The RL agents interact with the mining complex environment; exploring the solution space, learning actions to improve metal production and equipment utilisation. A case study is presented at a copper mining complex, highlighting the method’s ability to adapt and make informed decisions while collecting new information.

Sep 1, 2021

COUNCIL FOR 1989/90 President Dr O.K.H. Steffen President-elect Mr H.G. Mosenthal Senior R.D. Beck Vice Presidents Junior ].P. Hoffman Immediate Past President C.E. Fivaz Honorary Treasurer Dr H. Wagner

Jan 1, 1990

By M. Z. Emad, S. Raza, K. Jalil, M. A. Raza, M. U. Khan, S. A. Saki

Dimension stone mining is Increasing because of growing demand from the building and construction industries. Diamond wire saw cutting is a popular dimension stone mining technique around the world. Estimation of the production cost for this method is critical for these operations. n this research a production cost model was developed for the mining of granite using a diamond wire saw. Cost and production data were collected from a granitic dolerite operation in Pakistan for a 4.5-year period, and analysed to identify the cost components. Fuel (34%), labour (15%), consumables (40%), and maintenance (5%) were found to be the four major cost components in this operation. A regression-based dimension stone production cost model incorporating statistically significant variables was developed. The data presented a strong correlation of production cost with fuel, labour, and consumables costs. Finally, a production cost model based on the consumption cost of diamond wire is presented. The model was verified using actual production cost data, which indicated 95% (R2 = 0.95) variance in the data between the predicted and actual production cost values. The model may help field engineers in computing their dimension stone operational cost during the cutting phase.

Nov 6, 2023