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By Hillary W. St. Clair

The effective coefficient for rate of reduction of a sample of granular iron ore may be determined by passing the reducing gas through a bed of the are at constant flow rate and periodically analyzing the effluent gas, The method of analyzing the data is based on a mathematical model that takes into account the variation in composition of the gas and solids with time and position in the bed. A method is described for determining the value of the rate coefficient that gives best agreement between the observed and calculated analyses of the effluent gas.

Jan 1, 1967

By J. Roger Loebenstein

ASARCO Incorporated, the only domestic arsenic producer, terminated copper-smelting operations and the associated recovery of byproduct arsenic trioxide at Tacoma, W A. in 1985. It still shipped small quantities of trioxide from its remaining stocks in 1987. Imports for consumption of arsenic trioxide were slightly higher than in 1986. Domestic Data Coverage.-Shipments of small amounts of arsenic trioxide from remaining stocks by Asarco were reported voluntarily to the Bureau of Mines.

Jan 1, 1989

By J. R. Allsup

The Bureau of Mines studied the characteristics of simulated coal gas as an automotive fuel in two multicylinder vehicles in a standard and high-compression-ratio engine configuration. While using simulated coal gas fuel, increasing the engine compression ratio improved the fuel economy and vehicle performance but increased hydrocarbon emissions by 40 pct. photochemical reactivity of exhaust hydrocarbons was found to be extremely low using the coal gas fuel. An oxidizing catalyst used with the simulated coal gas fuel eliminated all but trace amounts of carbon monoxide and reactive hydrocarbons in the exhaust. Spark gap geometry and firing voltage were varied and, within the range tested, had little effect on vehicle performance and emissions using simulated coal gas fuel.

Jan 1, 1975

By Allen D. Look, Stanley M. Walker, Van Fleet. Leonard A.

"INTRODUCTION The hazards to be encountered in temporarily or permanently abandoned underground mines, quarries, and open pits are numerous, and hardly a year goes by without several reported cases of fatal or serious injuries occurring to unwary people who enter these old mines. Persons visiting mining areas for the first time, tourists, and young people, especially, proceeding in the spirit of adventure common to youth or to the venturesome have suffered many such accidents during exploration trips. The possibility of salvaging salable or usable equipment prompts men and boys to go into old mines, some through ignorance of the attendant hazards, but some jeopardize their lives hopeful of gain (in some cases pitifully small), thinking the hazards are not dangerous and that they can ""get away with it.""Persons fall into unprotected holes, some seek shelter from storms under high banks, and quarries and open pits are often chosen as places for recreation, picnics, swimming, etc; all such uses of these places are likely to be hazardous and to lead to accidents, frequently fatal.These hazards are known to men in the mining profession, and the danger to the public is realized by most of them. A solution to the problem has been sought at many mining meetings, and it is recognized that complete prevention of entry into old mine workings and surface mining areas is the ideal solution, but this, unfortunately, is not always practical; better education of the public, particularly children, should help to reduce the number of such accidents and will be effective in direct proportion to the extent and vividness of such education."

Aug 1, 1948

By A. J. Barry

Five makes of expansion-type shells and two types of bolts (mild-steel and high-strength) were used in 30 tests made in sandstone and shale roof, The results show that the anchorage obtained in both the sandstone and shale were stronger than either type of bolt. That is, the yield loads of both bolt types were exceeded before excessive anchor slip occurred. A relationship for evaluating the anchorage effectiveness of 3/8-inch-diameter, expansion-type bolts is presented. A comparison of test results indicates that the anchorage effectiveness of 5/8-inch- and 3/4-inch-diameter expansion-type bolts did not differ appreciably.

Jan 1, 1957

By Rex D. Thomas

Concentration of the kerogen (organic material) in oil shale was accomplished by centrifuging after pretreating the oil shale with carbonic acid to remove the carbonates and pretreatment with sodium hydroxide (pH 11.5) to remove the claylike minerals. Analysis of the materials obtained showed that the concentrations of organic sulfur and organic nitrogen compounds were not affected by centrifuging. These compounds are evenly distributed in the kerogen and are not strongly bound to the mineral constituents. Organic oxygen compounds, however, were concentrated in the light fraction. These compounds are more closely associated with the kerogen and are not bound to the mineral constituents. Iron compounds other than pyrite apparently are closely associated with the organic material.

Jan 1, 1970

Develop a safe, efficient filter for removing diesel particulate matter (soot) from the exhaust of underground mining machines equipped with water scrubbers. Approach The Bureau of Mines and the Donaldson Company, Inc., jointly developed a low-cost, disposable, pleated-media filter (PMF) system. The system is intended for use on Part 36 permissible equipment or other machines equipped with water scrubbers. The PMF is installed downstream of the water scrubber to take advantage of the cool exhaust produced by the water bath. This demonstration system was tested on three Jeffrey 4114 Ramcars and a Wagner LST-5 scoop at Utah Fuel Company's Skyline mine near Scofield, Utah. Figure 1 illustrates a clean filter element being inserted into the canister on the Ramcar. How It Works The PMF system consists of a water trap, an optional over-pressure relief valve, filter canister, and PMF Under normal operations exhaust from a vehicle equipped with a water scrubber is heavily laden with water, especially on immediate startup of the engine. The water trap is designed to remove most of the water droplets from the exhaust before they enter the PMF, thus improving PMF performance. The over-pressure valve is designed to limit the exhaust backpressure by venting off some exhaust gas before the: filter. It is attached to the water trap upstream of the PMF. Figure 2 illustrates and shows a break out sectional view of the location of the PMF on the Ramcar.

Jan 1, 1991

By D. J. MacDonald

The Bureau of Mines has carried out investigations on a method for producing zirconyl sulfate solution from zircon sand, comprising (1) reacting zircon sand with molten NaOH, (2) leaching the resultant fusion frit with water to remove sodium silicate and to convert sodium zircon-ate to hydrous zirconium oxide, and (3) leaching the hydrous zirconium oxide from unreacted sand with hot, dilute H2S04 to produce crude zirconyl sulfate solution. The following conditions were found to be suitable: reacting 0.6 kg of NaOH per kilogram of zircon sand for 10 min at 600° C; leaching the frit with 3 to 4 liters of water per kilogram of solids; leaching the residue with 5.1 liters of water and 1.25 liters of 98-pct H2S04 per kilogram of original solids for 10 min at 90° C; and filtering or decanting to recover unreacted zircon sand. A preliminary cost estimate is included.

Jan 1, 1982

By A. Visnapuu

High-grade synthetic rutile has been produced in the laboratory from domestic ilmenite concentrates by a new carbonyl process. The ilmenite was first reduced to convert the iron oxides to metal and then treated at temper-atures over 1000 C in high-pressure carbon monoxide (CO) to convert the iron to the pentacarbonyl. Rapid carbonylation was achieved in the presence of small quantities of selected promoters. Maximum iron removal occurred at temperatures between 110° and 130° C at CO pressures from 1,000 to 1,400 psig. Iron pentacarbonyl appeared as liquid and vapor in the reactor and could be removed by gravity flow and vapor transport. More than 90 pct of the iron was extracted in 2-hr experiments at pressures of 1,000 psig and above. The Ti02 product is porous owing to the removal of the iron, has the rutile crystal structure, and is suitable for chlorination. Waste disposal problems associated with the process would be minimal because the iron pentacarbonyl can be decomposed to produce iron powder or pellets for sale and CO for recycling.

Jan 1, 1973

By David A. Monaghan, Kenneth R. Maser, Adi R. Gurdar, D. Randolph Berry

9. Remote Sealing System Sensitivity 9. 1 Introduction In the previous sections a description of the overall system has been presented along with detailed descriptions of the equipment and techniques employed with the preliminary probing system, the seal em¬placement system and the seal checking system. In addition, the use of these subsystems in a specific mine application has been described in considerable detail. A broad range of parameters of interest was specified in the contract, as summarized in Section 1. 3. Most of these are a function of the general location; i. e. , the location of the mine, and the specific location; i. e. , the location of the boreholes. These parameters of interest include passage size, shape, depth, slope and water con¬ditions. The length, diameter and location of the boreholes within the mine passage and on the surface are critical parameters as well. A few additional parameters may affect one or more of the remote sealing subsystems. These include temperature, topography, rock and soil conditions, and underground water. While variation in these parameters will not render the system inoperative, consideration of them in the planning stages will simplify and expedite the field operation. In the following sections the effect of the various parameters on the remote sealing operation will be discussed. For clarity, the several tasks, borehole drilling and casing, preliminary probing, fly ash delivery, foam topping and seal checking, will each be considered separately.

Jan 1, 1973

Objective To develop and evaluate the effectiveness of safety training tools specific to the underground hard-rock mining industry. Background Scaling, the removal of loose rock from the roofs and walls of a mine by manual or mechanized means, may be necessary during any stage of mining. Manual scaling is very labor intensive, and mechanical methods can be too powerful and actually produce a less stable roof.

Jan 1, 2001

By J. J. Cummins

The Bureau of Mines heated at 150° to 350° C for 0.5 to 360. days Green River oil shale that had been previously extracted by benzene to provide information on in situ processing conditions, to determine the effect of low-temperature heating on the unconverted kerogen, and to determine the composition of benzene-soluble thermal products. The methods used in determining the composition of the soluble thermal products consisted of fractionation of the soluble material, elemental analysis of the soluble products, fractionation of the polar resins by ion-exchange chromatography, gas chromatographic analysis of [n]-alkanes3 and mass spectral analysis of the branched plus cyclic alkanes and aromatic oils. The methods used to determine the effect of low-temperature heating on the unconverted kerogen remaining in the oil shale heated residues consisted of carbon-hydrogen analysis, volatile material determination, carbon residue determination, and oxidation rate determination. In general, it was concluded that significant increases in the degradation of kerogen to oil occurred between the temperature range of 250° to 350° C; that the composition of the soluble products depends upon the temperature at which they are formed; and that the [n]-alkanes are pyrolytically degraded from the kerogen structure. In particular, the 250° C heating temperature is beneficial to the formation of branched plus cyclic alkanes. Also, the heated and unconverted oil shale kerogen and the soluble thermal products become more aromatic as the temperature increases from 150° to 350° C.

Jan 1, 1974

By Theodore Christos

The Bureau of Mines sponsored an investigation of the thermal oxidative degradation characteristics of certain solvents and hydraulic fluids used in underground mining operations. The following halogenated solvents were studied in view of their usefulness and their flame retardant property: tetrachloroethylene, C12C = CC12; 1, 1, 2-trichloroethane, CIH2CCHC12: and trichloroethylene, C12C = CHC1. The hydraulic fluids studied were representative of five groups approved by the Mine Safety and Health Administration for underground operation, namely: glycol-water solutions, mineral oil-water emulsions, synthetics other than phosphate esters, synthetic phosphate esters, and mixtures of phosphate esters with mineral oils and other ingredients. It was observed that the partially halogenated solvents present a greater potential toxic hazard than the fully halogenated materials, due not only to the easy production of hydrogen chloride but also to their ease of oxidation leading to the formation of phosgene and carbon monoxide. The pure phosphate esters exhibited the best thermal oxidative stability of the five groups of hydraulic fluids tested. A fluid containing phosphate esters mixed with mineral oils and other unidentified ingredients appeared to be the most hazardous On the basis that it produced very toxic acrolein and phosphine.

Jan 1, 1980

Now you know why there is concern about mine illumination. You have some idea about how the human eye works and about the problems of glare, peripheral vision, and accommodation. And you know that lighting in a mine presents special problems because of the dark surroundings and low reflectance. This chapter describes what can be done to improve conditions. This chapter begins with a short discussion about Federal Standards on mine lighting -- what they are and what is being done to carry them out. The chapter then describes different types of lamps that can be used for mine lighting, and discusses their advantages and disadvantages. Finally, the chapter lists some things that you can do personally to improve lighting, or can point out to others so that improvements can be made. The Federal Government is doing its part to improve mine lighting by establishing regulations. Lamp manufacturers are constantly studying new lamps to provide better equipment. And your company will do its part to comply with regulations. Better lights may not be here yet, but they will be soon. But in the end, you are the one who will be using the lights, and you are in the best position to see the improvements. You are also in the best position to see and tell others where further improve¬ments can be made.

Jan 1, 1976

By H. E. Sanford

"INTRODUCTION Of the occupations in and about coal mines, those of the haulage crews are among the most hazardous. Statistics indicate that the second largest number of fatalities about coal mines occurs during haulage operations and through the use or misuse of haulage equipment. Despite the fact that relatively few coal-mine employees are engaged continuously at haulage operations, approximately 20 percent of all coal-mine fatalities are attributable to haulage.Most of the hazards in haulage operations could be very greatly reduced if more serious consideration were given to the problems of the haulage crews and if sincere efforts were made to reduce the hazards. Underground haulage is similar in many respects to railroading; yet, railroading is now considered one of the safest of occupations a distinction that has been attained only by honest effort and whole-hearted cooperation on the part of all concerned. Underground haulage is also similar to street and highway operation and has in it some of the difficulties encountered in the reduction of traffic accidents the seriousness of which has not by any means been con¬trolled as yet, notwithstanding the fact that much effort has been expended through a multiplicity of laws, ordinance regulation, etc., as well as by thousands of enforcement agencies and officers.The men working on the locomotives are among the most important members of a coal-mine organization; without skilled haulage employees, the production of coal would be greatly retarded. Their jobs, particularly the job as brakeman, require physical endurance, agility, and mental and physical alertness; in thin coal beds, especially where the roof is not brushed and the coal is loaded into mine cars by hand, the need for these qualifications is greatly increased."

May 1, 1948

By Kathleen Madland Kowalski

In recent years the issue of human stress response in emergency workers has begun to receive attention. This paper presents a rationale for considering human stress as a significant factor in the management of emergencies It discusses the concept of stress, Critical Incident Stress in emergency responders, and intro¬duces the Critical Incident Stress Debriefing (CISD) process. It is suggested that in a disaster, the CISD process can improve the effectiveness of response teams on site, their turnaround time on site, and post disaster time off the job. This paper, prepared by a US Bureau of Mines research psychologist, offers some ideas to the mining industry in general, mine rescue trainers and more universally, to those responsible for developing emergency management plans.

Aug 1, 1998

By G. G. Morgis, J. J. Forbes

"INTRODUCTION The greatly diversified and increased uses of beryllium and its con& pounds in recent years have focused attention on the health hazards incident thereto. The Bureau of Mines has a fundamental interest in safety and the elimination or reduction of health hazards in the mineral and allied industries, and it recognizes that serious hazards are inherent in the production and use of beryllium and its compounds. This circular presents a review of the literature pertaining to such health hazards but does not describe original research by Bureau personnel. Most of the bibliography has boon either quoted in part or abstracted in an effort to present information in a comprehensive and readable form.In reviewing the literature, differences of opinions wore recognized in the writings of the respective authors, but no attempt was made to evaluate such differences. This presentation was devoted strictly to reporting without editorial comment.SUMMARYAlthough beryllium was known to industry for about 150 years, its toxicity did not present any serious problems in the United States until the advent of World War II, when the increased use of this element and its compounds brought to light several toxicologic reactions occurring primarily in the lungs and skin of workers handling it. The pulmonary effects, characterized as acute pnoumonitis and chronic pulmonary granulomatosis in beryllium workers, are far more serious than the dermatological manifestations.The addition of beryllium to the list of toxic industrial metals has boon so recent that there is still some confusion in the clinical picture. Data on magnitudes of exposure likely to be responsible for the production of disease are not yet adequate. There appears to be no relation between the severity of exposure and the development of cases some of those having had severe exposure have not developed a reaction, whereas those having a slight exposure in some instances have developed a response."

Jul 1, 1950

By Pablo Velasco

Ecuador had limited mineral output, al-though the Government attempted to stimulate metallic mineral exploration and also evaluated a gypsum and a phosphate deposit. A pilot plant to exploit gold deposits was established, and there was extensive gold exploration activity in southern Ecuador. Domestic output of iron and steel declined sharply. Among all minerals, petroleum output was the dominant factor with both exports and production increasing significantly over that of 1988. Crude oil exports contributed 63% of total export earnings and about 70% of the central Government's revenue.

Jan 1, 1986

Improve the safety of mine workers by developing a means of forecasting impending roof falls in underground mines. Approach The Bureau of Mines, through in-house and contract research, has developed the Roof Fall Warning Device. This battery-operated, portable electronic system forecasts roof falls by detecting and interpreting high-frequency rock noise, The technology has shown potential for detecting stress-related failures in a variety of underground environments. How It Works All geologic materials produce high-frequency acoustic emissions when they encounter an increase in stress. These ultrasonic frequency range events ( >20kHz) are well above the audible range of human hearing, very small in amplitude and duration, and can only be detected with sophisticated electronic equipment.

Jan 1, 1990

By P. W. Jeran, C. D. Sullivan, C. M. McCulloch

A series of geological surveys were completed in six coal mines in connection with a Bureau of Mines research program on methane control. The aim of these surveys was twofold: First, to study the overall geology of the coalbed, and second to use the resulting data to evaluate the influence of the geological characteristics of the coalbed on safe and efficient coal extraction. This report explains the advantages of geologic maps and fence diagrams in coal mining, and how the knowledge gained from such geologic investigations of mines can help control many underground problems.

Jan 1, 1975