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Determine whether the total delay time in blasting may be safely increased beyond the currently permitted 0.5 s, without igniting a methane or methane-coal dust atmosphere and determine the minimum borehole spacing to avoid misfires. Approach At present, regulations limit the delay time used in short-delay blasting to a total of 0.5 s. Many in industry and government would like to see this total delay time increased to 1 5 to permit an increase in the number of different delays available for short delay blasting and an increase in the time between delay periods. The Bureau of Mines conducted research to determine whether the total elapsed delay time for blasting coal in underground mines could be safely expanded, with resulting improvements in productivity. The research was conducted at a surface mine in St. Clairsville, Ohio. Experimental shots were conducted in several pits, each of which had a 5-foot-high coal seam (Pitts-burg No.8) in a 50-foot highwall. The coal seam and a mobile gallery provided a good simulation of an underground coal face. The Bureau also examined the relationship between borehole spacing and misfires, to check on reports over the past few years that permissible explosives frequently misfire. These reports were not well documented, but were numerous enough to warrant investigation. Misfires of permissible explosives in an underground coal mine can be very hazardous; a burning cartridge of explosive may be ejected from a borehole and ignite the gas or dust in the mine, or a misfired cartridge in the muck pile may detonate during drilling and mucking operations, causing serious injuries.

Jan 1, 1986

By Robert H. Merrill

A method of determining the strength of a mine roof layer in place is described in this report. The method was tested on a limestone roof layer 50 feet wide, 100 feet long, and 20 inches thick. In place measurements were accomplished by introducing air under pressure into a separation between the layer and the overlying roof, and as pressure was increased, the corresponding strain and deflection of the roof layer were measured until the roof failed. The ultimate strength of the roof agreed with the tensile strength of the roof rock (modulus of rupture) as determined in the laboratory; the modulus of elasticity as measured in place did not agree with the laboratory-determined values; the deflection and tensile strain in the layer in place showed good agreement with the theory of a body-loaded beam clamped at both ends. This procedure for determining the strength of a mine-roof layer is safer and less costly than successively widening a roof to failure. For example, it would have been necessary to mine the room to a width of 114 feet and a length of 228 feet to produce failure in this roof layer. The method is not necessarily limited to limestone; any thinly bedded rock type can be tested by this procedure when there is an open parting over the mined area.

Jan 1, 1958

By W. E. Wallace, V. Castranova, P. Hathaway, F. H. Y. Green, E. D. Recad, V. Vallyathan, M. J. Keane

Inhaled particle contact with pulmonary surfactant in the hypophase lining pulmonary alveoli was modeled in vitro by exposing two respirable sized dusts, kaolin and silica quartz, to lecithin, a major component of pulmonary surfactant, emulsified in physiologic saline. Lecithin adsorbs to the dusts upon incubation at 37º C and suppresses their cytotoxicity as measured by pulmonary macrophage and erythrocyte assays, suggesting that pulmonary surfactant provides a defense system against prompt cell membrane lysis by inhaled dusts. Subsequent pulmonary macrophage phagocytosis and lysosomal enzyme digestion of the coated dusts was modeled in vitro by incubation with phospholipase A2 for one hour. With increasing lipase activity, silica hemolytic potential was restored to native silica levels. Kaolin was retoxified to levels far in excess of native kaolin hemolytic potential. Elution, thin layer chromatography and phosphate assay of treated dusts indicate most lecithin on silica is digested to lysolecithin and desorbed, silica retoxification being due to surface and adherent lysolecithin effects. Most lecithin on kaolin is not digested in this same time; that which is results in adherent lysolecithin which is responsible for the kaolin retoxification. Digestion with phospholipases A2 and C together produces only weakly retoxified kaolin. Results suggest that surface adsorption properties which control the adherence of prophylactic surfactant distinguish the pathogenic potentials of quartz, kaolin and mixed dust.

Jun 1, 1988

By R. F. Abernethy

The work discussed in this report was done by the Bureau of Mines to develop a method for determining trace amounts of fluorine in coal. Samples of coal mixed with calcium oxide as a fixative agent for fluorine were ashed at 600° C and the residue was fused with sodium carbonate. The melt was dissolved in phosphoric and sulfuric acids and distilled to separate the fluorine) which was determined in the distillate by a SPADNS-zirconium spectrophotometric method. Fluorine determinations of 83 commercial coals ranged from 0,001 to 0.019 percent.

Jan 1, 1967

By N. S. Dalal, X. Shi

"The oxidation of NADPH by vanadate(V) in the presence of glutathione reductase showed typical enzymatic kinetics. The oxidation was inhibited by N-ethylmaleimide, a glutathione reductase inhibitor. Superoxide dismutase had no significant effect on the oxidation, indicating non-involvment of the superoxide radical. The vanadate(V) reduction was found to be a one-electron transfer process. These results suggest a new pathway for vanadate(V) metabolism and a new function of glutathione reductase. Compounds of vanadium(V), such as NaV03 , exert potent toxic effects on a wide variety of biological systems (1-3). Despite intense current activity, however, the biochemical mechanism of vanadate(V) toxicity is still not well understood (1- 14). It is believed that one of the important pathways involves the oxidation (by vanadate(V)) of NAD(P)H (15, 16), but, to our knowledge, there has been no report of the identification of any vanadate(V) reductase. With a view to finding if there exists any vanadate(V) reductase, we have investigated the oxidation of NADPH by vanadate(V) in the presence of glutathione reductase. Glutathione reductase (GSSG-R)2 was selected because our previous studies have shown (17) that GSSG-R can act as a reductase for chromate(VI), which is isoelectronic with vanadate(V). We find that GSSG-R does indeed function as a NADPH-dependent vanadate(V) reductase, thus pointing to a new pathway for the metabolism of vanadate(V), as well as to this property for GSSG-R. MATERIALS AND METHODSSodium metavanadate (NaV03 ), henceforth vanadate, was purchased from Aldrich and its solution was always freshly prepared. The GSSG·R used was from bovine intestinal mucosa and was purchased from Sigma. The oxidation of NADPH was followed photometrically as the decrease in absorbance at 340 nm. The spin trap, 5,5-dimethyl- pyrroline-N-oxide (DMPO), was purchased from Aldrich and used without further purification, since very weak or no spin adduct signal was obtained from the purchased sample when used alone.ESR spectra were obtained at X-band (9.7 GHz) using a Bruker ER200 ESR spectrometer. The magnetic field was calibrated with a self-tracking NMR gaussmeter (Bruker, Model ER035A) and the microwave frequency was measured with a digital frequency counter (Hewlett-Packard, Model 5340A). An ASPECT 2000 computer was used for data storage and analysis. The concentrations given in the figure legends are the final concentrations. All experiments were carried out in the phosphate buffer solution (pH 7.2) and at room temperature."

Jan 1, 1990

By W. R. Wrzensinski

This report presents the findings from a l-yr Bureau of Mines program in which sulfur concrete reinforcing materials were tested and evaluated to determine their resistance to corrosion. It also summarizes the permeation characteristics of sulfur concrete and the exemplary performance of precast, reinforced sulfur concrete structures in various industrial environments. The Bureau is furthering the development of sulfur concrete technology as part of a larger effort to find uses for the Nation's plentiful sulfur resources in construction materials. Sulfur concrete is a corrosion-resistant material that can be used in acid and salt environ-ments where conventional materials fail. Penetration of corrosion-inducing agents is minimized because of the low permeation characteristics of sulfur concrete.

Jan 1, 1988

By G. H. Hopkins

Like most industries, the refining industry has in recent years been confronted with the problem of a decreased martin of profit, due both to a general lowering of prices and to rising costs. This has resulted in accelerating a program of increased efficiency an evidenced by improved methods and the installation of equipment designed to affect a number of economies hitherto regarded as unimportant. Perhaps the most important of these has been that of fuel economy for, as is not often realized, a refinery consumes about one-tenth as much fuel as it produces. A recently completed canvas., made by the Bureau of Mines for the purpose of determining the trend of fuel consumption at refineries in the United States, showed the following outstanding points, (1) a decrease in the use of oil for fuel in 1926 of approximately 4,000,000 barrels as compared with 1925; (2) a small decrease in the use of coal; (3) a material increase in the use of gas, both natural gas and refinery gas; and (4) a considerable increase in the use of petroleum coke.

Jan 1, 1927

Minimize failures or inefficiency in the operation of in situ mining wells. Approach The proper design, construction and development of wells are important to any in situ leaching operation. To permit cost-effective production from an underground ore body by leaching it in place, many wells are normally installed. Construction and maintenance costs increase with the number of wells, and poor construction and maintenance procedures result in production losses and negative environmental impacts, To minimize these losses and impacts, the Bureau of Mines conducted an investigation to determine the optimum in situ well construction and operating procedures for the minerals industry. Factors considered during the investigation included drilling equipment and procedures; types of well casing and grouting; completion methods, e.g, screening or perforation; and system maintenance. The data collected were used to prepare a manual that offers guidelines

Jan 1, 1984

By Wilder D. Foster

In estimating the hazardous qualities of a dusty atmosphere it is frequently desirable to determine the composition of the air-borne dust. Samples collected from ledges or from the rock itself are Likely to be unsatisfactory for this purpose owing to the possibilities of differential disintegration of the rock and of variations in settling rates of the different components of the minerals. It may be necessary, therefore, to collect samples of dust from the air. Samples collected from the air may be analyzed chemically, by X-ray diffraction, and by the petrographic microscope. Chemical methods are unsatisfactory owing to the small samples usually available and to the limitations and complexities of: present methods. X-ray technique requires expensive apparatus not ordinarily available except in research laboratories. Owing to the simplicity and rapidity of petrographic is examination of atmospheric mineral dusts, it was considered worthy of further study.

Jan 1, 1938

By Gordon H. Dechman

This Bureau of Mines report presents an iterative approximation method for microseismic source location that was developed to adapt microseismic techniques for rock structure analysis to investigations of surface problems, such as slope failure in an open pit mine. The source location method and two derivative location algorithms are described in detail, and the speed and accuracy of the two algorithms are compared.

Jan 1, 1977

By U. E. Brown

This papery describing the mining methods employed by the Bunker Hill and Sullivan Mining and Concentrating Co. at Kellogg, Idaho, is one of a series being prepared by the United States Bureau of Mines on mining practices, methods, and costs in the United States. The Bunker Hill and Sullivan mines are situated in the western part of the Coeur d'Alene district at Kellogg, Shoshone County, Idaho. The mines were discovered during the summer of 1885 and except for two short periods of labor trouble, between 1890 and 1900, have been in continuous operation. About 575 men are employed at the mine. The production is about 1,400 tons of lead-silver ore per day. This is treated in the company's concentrator and smelter at Kellogg.

Jan 1, 1931

By H. H. Schrenk

[A colorimetric method5/ for the determination of benzene in amounts as low as 0.001 mg has been developed recently at the U.S. Bureau of Mines Pittsburgh Experiment Station by the authors, with the assistance of chemical personnel fro a the Allegheny County (Pa.) Relief Works Division. The method is based on the direct nitration of either liquid - or gas - phase benzene, followed by neutralization, extraction with butanone, and final treatment with sodium hydroxide which produces a violet color. The color is matched with color standards of known values. Although the method is adaptable to many conditions the primary objective was a procedure that would be suitable for hygienic investigations. The development worth included a study of possible interference by chemicals that be present in those situations in which the method. would be employed. In this study it was found that a specimen of hexane prepared by the Gulf Research Laboratory, Pittsburgh, by fractionation of West Virginia natural gas gave positive result for benzene, whereas a specimen of pentane prepared in the same manner showed only a trace, and specimens of n -heptane and octane (2,2,4 trimethylpentane) supplied by Eastman Kodak Co. save a negative result. According to information obtained from the Eastman Kodak Co. the latter two compounds were highly purified, the n-heptene being prepared from line and the octane synthesized in the laboratory. On nitration of a larger amount of tae natural hexane a visible quantity, of needlelike crystals which resembled those of m-dinitrobenzene was obtained. The hexane from this nitration was recovered by distillation and again nitrated, but no crystals or colorimetric indication of benzene was obtained. This imitated that the specimen of natural hexane contained a substance which at least had the chemical behavior of benzene.]

Jan 1, 1935

By Allen L. Frank

A portable radon diffusion chamber has been tested with electrical collection of the radon daughter nuclei for enhancement of sensitivity. The detector size was small enough to be worn suspended from the belt. With a battery-supplied high voltage the sensitivity was found to be 1.43 tracks/cm2 per pCi-hr/l of ambient radon at Sot relative humidity. The track densities on the surfaces of the CR-39 plastic nuclear track detectors were found to be non-uniform, making difficult the determination of average densities with high accuracy. The fabrication of electrets for use in the detector was investigated in accordance with published techniques with negative results.

Jan 1, 1983

By W. E. Wallace, P. S. Mike, C. A. Hill, V. Vallyathan, M. J. Keane

Respirable quartz duet and a kaolin clay dust have been found to be of comparable cytotoxic potential in vitro on a specific surface area basis (Wallace, et a1,1985), despite the distinctly different potentials of quartz and clay for causing pneumoconiosis or pulmonary fibrosis (Sheers, 1984). A respired particle depositing in a respiratory bronchiole or alveolus will contact a pulmonary surfactant hypophase, of which a primary component is diacyl glycerophosphorylcholine, or diacyl lecithin (DPL) (Clements, et al, 1970). Several studies have found that adsorption of such surfactant suppresses in vitro cytotoxic effects of quartz dust (Marks, 1957). Subsequent phagocytosis and digestion by a macrophage may remove the coating, restoring cytotoxic potential and initiating disease processes (Iles, 1979). Adsorption of dipalmitoyl lecithin (DPL) from emulsion in physiologic saline by respirable sized quartz dust and kaolin dusts, and consequent diminution of the dusts' hemolytic and macrophage cytotoxic potential have been reported (Wallace, et al, 1985). This report presents additional data on the cell-free in vitro phospholipase A2 enzymatic digestion of dipalmitoyl lecithin adsorbed on a quartz and a kaolin respirable sized dust (Wallace, et al, 1988) to investigate mineral specific differences in the rates of digestion and of consequent restoration of dust membranolytic potential. Respirable crystalline alpha quarts used was eighty percent smaller than 5 micorometer aerodynamic diameter with a nitrogen adsorption specific surface area of 3.97 m2/g. Respirable kaolin dust was ninety percent smaller than 5 micrometer diameter and had a specific surface area of 13.25 m2/g.

Jan 1, 1988

Improve the health and safety of underground mine workers by finding ways of keeping them away from unsupported areas of the mine. Background Roof falls have been the leading cause of fatal accidents in the underground coal mining industry. During 1985-89, 92 coal miners were killed by falls of roof and rib, with more than 4,000 miners injured. According to accident investigation reports from the Mine Safety and Health Administration, 47% of the victims of these fatal roof fall accidents were in the area of unsupported roof al the time they were killed. There is an urgent need to find out why miners go under unsupported roof and to devise strategies for preventing this unsafe behavior. Approach To discover what can be done to prevent miners from going under unsupported roof, confidential interviews were conducted with 297 miners who work in the face crews of 6 different coal mines. The interview topics included company policies and actions regarding going under unsupported roof, how foremen react to people who go under unsupported roof, circumstances likely to cause some people to go under unsupported roof and how to prevent these situations, and observations concerning those who go under unsupported root.

Jan 1, 1991

By Joseph Cervik, Gerald L. Finfinger

The Bureau of Mines conducted an experimental degasification project in Island Creek Coal Co.'s Virginia Pocahontas No. 5 mine. Methane from the over- lying Pocahontas No. 4 coalbed was entering mine workings in the Pocahontas No. 3 coalbed through fractures in the roof rock. Small-diameter (1-5/8-inch) holes were drilled into the overlying coalbed to reduce the gas pressure and intercept methane flows, which were piped to the surface through an under- ground 6-inch-diam steel pipeline. The total methane flow rate from the vertical holes averaged 150,000 ft3/day for the first month. Methane flows into the mine were reduced by 47 pct, thereby demonstrating the effectiveness of this form of degasification in reducing ventilation requirements and providing a safer working environment.

Jan 1, 1979

By T. T. Read

"Education is the one thing which is unanimously regarded as valuable. The growing complexity of modern life, with its intricate organization, the manifold kinds of mechanical equipment that are used, and the constantly growing, necessity for the speedy and accurate interchange of information and ideas, make education an asset that constantly increases in value. The number of things that may profitably be known has grown so large that the field of education has been divided, and attention is often directed to only those things that are most immediately valuable. Modern educational facilities are often directed to what may be called corrective, work; the, providing of people with information that they teed in the conduct of their daily lives, but which for various reasons they have not previously had facilities for acquiring. The value of special education in the industrial world has been so thoroughly demonstrated that far-seeing managers of mining enterprises are always interested in the educational facilities existing in the community where their work is carried on.The educational facilities of a modern community may be classified in several ways. They may be divided into;1. Facilities for general education, for the purpose of increasing the whole field of knowledge of the student.2. Facilities for special education, which are intended to remedy a specific defect, or to give proficiency in some special field. This may be divided as follows;a. Training for work, intended to fit an employee to adequately perform the task assigned to him, this ranges from brief instruction by a foreman or fellow-worker up to definite training courses in which the employee dose nothing but study for a period of several weeks or months, being paid during this period a wage that may range from a nominal amount up to practically full time salary. The student's educational preparation may already be fairly advanced. Some of the manufacturers of electric machinery maintain, a school similar to that just described for graduates of engineering colleges. In other cases the only pre-requisite may be a common school education, as in the schools for operators, maintained by the telephone companies."

Apr 1, 1920

By R. D. Leitch

Beside many other damaging effects of acid mine drainage, corrosion of pipe lines and pumps frequently adds much to mine operating costs. Not only is it often necessary to install special and relatively costly acid-resistant materials, but even these may require frequent replacements. It is not unusual for ordinary steel pipe to last only a few days in some highly acid waters, while other common materials, though more resistant, frequently last only a few weeks. In the spring of 1935, local PWA authorities offered to assign a number of persons to various problems under the direction of regular employees of the Bureau of Mines. It was believed that at least some simple tests on as many different kinds of acid-resistant pipes as could readily be obtained might produce interesting and valuable information for the mining industry. This paper describes the tests and some results that have since been noted.

Jan 1, 1938

By Maurice Deul, Herbert H. Fields, John H. Perry

The Bureau of Mines has been promoting health and safety in mining since its establishment in 1910. One area of research covers methane control in coalbeds; this report describes a multipurpose borehole used for both degasification and the production of commercial-quality gas. The multipurpose borehole was drilled into a barrier pillar, and seven horizontal degasification holes and one pressure point hole were drilled radially out from its perimeter. On January 28, 1974, after 505 days of degasification, a compressor was installed to the exhaust stack of the multipurpose borehole (2), and pipeline--quality gas was introduced into a commercial pipeline. As of February 4, 1975, over 171 million cubic feet of gas had been purchased by the gas company. The in situ pressure at a depth of 200 feet into the coalbed and the average gas flow and water flow from the degasification holes as they were completed and closed off were 203 psig, 1,200,000 cfd, and 6.8 gpm, respectively. Twenty-four hours after the seven holes were connected through individual pipes to the atmosphere, the total gas and water flows and the in situ pressure dropped, respectively, to 971,000 cfd, 1.3 gpm, and 18 psig. Five hundred days later, the corresponding values were 620,000 cfd, 0.15 gpm, and 10.5 psig. Daily flows have been as high as 800,000 cfd, and as low as 360,000 cfd, during the last 500 days. On February 4, 1975, after 882 days of degasification, 576 million cubic feet of gas had been removed from the Pittsburgh coalbed; apparently a much larger area of virgin coal is being degasified than is defined by the holes. This study indicates that horizontal boreholes drilled into a coalbed from the bottom of any shaft will effectively remove gas from the Pittsburgh coalbed.

Jan 1, 1975

To develop a simple device for rapidly determining the shearing strength and angle of Internal friction of coal and rock in situ. Approach Use a portable, permissible, hydraulically operated device in boreholes as deep as 100 feet into the rib, floor, or roof of the mine. How it Works The device, called a Borehole Shear Strength Tester (BST), is inserted Into a 3-inch-diameter borehole to the desired depth, locked Into position, and activated to shear the rock or coal in the borehole walls. The normal and shear pressures exerted by the BST, which are recorded during the test, are used to calculate the shearing strength and the angle of internal friction. The BST consists of 3 main components and several minor components. Main components are: ? A shear head with 2 shear plates that bite into the rock when normal pressure is applied. ? A hollow hydraulic jack with RW drill rods that pull the shear head when shear pressure is applied. ? A console with a hand pump and two hydraulic gages to activate the device and to indicate the pressures that apply the normal and shear faces to the shearing plates.

Jan 1, 1981