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By T. N. McVay

The Bureau of Mines has developed a field test for detecting the presence of columbium in a variety of minerals containing the clement. The test consists of fusing the mineral or rock powder with potassium pyrosulfate in a porcelain crucible, digesting the melt with hot dilute hydrochloric acid to release the columbium oxide (Cb205), and subsequently reducing the columbium oxide to a lower oxide by adding tin, which gives a blue color to the contents of the crucible. The method will detect 1 percent of contained columbium oxide (Cb205) in a mineral sample provided no tungsten is present. If a mineral containing appreciable titanium is test,-!d in the same manner, the solution in the crucible becomes violet. In the presence of columbium, titanium at first causes a violet coloration of the solution, which after a few minutes is masked by the stronger blue of the reduced columbium oxide. Although tantalum oxide (Ta205) does not interfere with the columbium test, tungsten gives a blue color that is indistinguishable from the color obtained with columbium. A simple method is available to detect the presence of columbium in the absence of tungsten, but when the presence of tungsten is suspected, the sample must be subjected to somewhat more elaborate chemical tests to determine the presence or absence of columbium. Although these latter tests can be made in the field, several steps are involved that arc best performed in the laboratory with simple equipment.

Jan 1, 1962

By O. M. Bishop

The Douglas fluorite property is in the Empire district of eastern Pope County, Ill., which lies near the west boundary of the productive Southern Illinois fluorspar field in Hardin and Pope Countios. Production from mines on the Douglas property accounts for about one-half of the 72,000 tons of fluorspar with which the Empire district is credited. This output was from the Sycamore, Pierce, Slapout, and Empire veins, which are normal fissure veins of little displacement along which there has been local wall-rock replacement by fluorite.

Jan 1, 1949

By Raymond M. Stateham

A portable, handheld infrared scanner has been used to detect abnormal surface temperature on dumps of flood-generated trash near Wilkes-Barre, Pa. Three of eight dumps examined had thermal anomalies on the surface, indicating temperature buildup at depth. The anomalies found with the scanner were verified by measurements with a thermocouple probe or a carbon monoxide detector. One week after the investigation was completed, open fire broke out at the site of one of these thermal anomalies; about 6 weeks after the investigation, a thermal anomaly in another dump was verified when a trench was excavated in the dump.

Jan 1, 1973

By W. P. Diamond, A. C. Smith, J. A. Organiscak, T. P. Mucho

The U.S. Bureau of Mines conducted a worldwide literature review of bleederless ventilation practices to evaluate their use as a spontaneous combustion control measure in U.S. coal mines. Factors that must be taken into account in the design and use of these systems include seal construction, the use of ventilation control devices, the use of methane-drainage systems in gassy mines, and the ground control plan. Monitoring for the detection of spontaneous combustion and the control of methane when methane-drainage techniques are employed is critical to the successful use of a bleederless ventilation system. This report describes the types of ventilation systems used throughout the world and the spontaneous combustion risks associated with these systems. Methane-drainage systems used in conjunction with bleederless ventilation systems are discussed. Ground control considerations such as pillar design, entry stability, and seal usage are reviewed. Monitoring systems for spontaneous combustion detection, methane-drainage control, and behind seals are examined. Finally, methods for evaluating the spontaneous combustion hazard of a mining operation to determine when the use of a bleederless ventilation system is warranted are reviewed.

Jan 1, 1994

By M. H. Stanczyk, I. L. Feld

Dewatering of typical Florida phosphate rock slime by electro - osmotic techniques was investigated to determine if a compacted , plastic solid product could be obtained with simultaneous recovery of the water for re - use . Tests with porous cathodes and rod - type anodes imbedded in dilute slime charges of up to 4 tons in weight showed that the slime could be dewatered to about 35 percent solids . The dewatered products had the consistency of modeling clay . In the large - scale tests using 2.5 - foot electrode spacings , about 21 kilowatthours of power were consumed per ton of water removed in thickening the slime from 17 to 25 percent solids , but the rate of water removal was so slow that the process was not considered commercially feasible . Other tests made with electrode spacings of from 2.5 to 8 feet showed that more rapid dewatering could be obtained but that the power required was excessive . However , for special uses such as stabilizing slime pond dikes where the cost of dewatering might not be a prime requisite , high voltages could be used to rapidly remove the water . Tests of 400 - pound slime charges using a combination of electroosmosis and vacuum filtration showed that the rate of dewatering could be expedited . The average power required to thicken a ton of slime from 15 to 35 percent solids was 5 and 50 kilowatt - hours when operating the electroosmotic filtration cell at potentials of 20 and 100 volts , respectively . calculated filtration area of about 10 square feet per ton of slime treated per day was required to thicken the slime from 15 to 35 percent solids .

Jan 1, 1964

A significant amount of information regarding the crushed stone and sand and gravel industries in each State is available from State agencies and State trade associations. These organizations continuously monitor the State mineral industries and are therefore an important source of detailed information at the local level. This third edition of the directory was prepared to provide a listing of government agencies and trade associations that can assist the users interested in obtaining detailed listings of crushed stone and sand and gravel producers, in addition to the information published by the U.S. Bureau of Mines.

Jan 1, 1994

By J. C. White

A research study was conducted to devise a method for producing phosphoric acid directly from unbeneficiated Florida phosphate matrix. This research was performed as part of the Bureau of Mines, U.S. Department of the Interior, goals of improving minerals and metals recovery from domestic resources and of minimizing the environmental impact associated with mineral recovery operations. This report describes research in which unbeneficiated, dry, south-central Florida phosphate matrix was digested with sulfuric acid in a continuous-circuit, five-tank reactor to yield phosphoric acid and gypsum residue. Feed capacity of the reactor was 100 pounds (45 kg) of dry matrix per 24-hour day. When digestion was carried out at 185° F (85° C), acid filtration rates of up to 420 pounds of P20S per square foot per day were attained. Combined iron and aluminum impurities in the product filter acid were about 60 percent greater than values reported in commercially produced acid derived from concentrate. phosphate recovery was 87 to 90 percent of the phosphate contained in the as-mined matrix.

Jan 1, 1978

By H. B. Humphrey, F. E. Cash

From 1900 to 1929 , 1,005 or approximately 30 per cent of all fatalities in the coal mines of Alabama were caused by fires or explosions of gas and dust . In the 3 -year period from 1927 to 1929 only 15 men were killed by these causes , a reduction from 30 to 9 per cent of the total . Notwithstanding this marked improvement , which is due largely to the efforts made by the State inspection department , the operators , and the Bureau of Mines to stamp out this type of disaster , Alabama still has more than its share of such fatalities which can and should be prevented. A list of explosions from 1894 to 1929 compiled from information obtained through the records of the State Inspector's office , the reports of Engineers of the Bureau of Mines , and the operators , is given in Table

Oct 1, 1930

By David C. Oyler, William P. Diamond

Three long horizontal holes were drilled from a directionally drilled sur¬face hole at the Emerald Mine near Waynesburg, Pa. The purpose was to adapt the technique of directional drilling for use in draining methane from coalbeds. A 504-m (1,652-ft) long, 76-mm (3-in) diam¬eter, circular arc pilot hole was drilled, using a downhole mud motor, to enter the Pittsburgh coalbed at a verti¬cal depth of 305 m (1,000 ft). The hole was reamed to 222 mm (8-3/4 in) and was cased to a measured depth of 486 m (1,595 ft). Three 76-mm (3-in) diameter horizontal drainage holes were then drilled, totaling 2,909 m (9,544 ft) of horizontal hole. Improvements in drilling methods increased the average drilling rate from 20.4 m (67 ft) to 64.9 m (213 ft) per day. The cost of drilling the directional and horizontal holes (using a Government-owned drill rig) was $1,169,530, a figure inflated by inexperience and by delays caused by lost-circulation problems and fishing operations. An estimated total drilling cost of $960,000 (including rental of a drill rig) for an improved system, was determined by a detailed cost analysis. Initial gas and water production from November 1979 through May 1980 was low because of caving of the horizontal holes drilled in shale near the bottom of the casing.

Jan 1, 1982

By E. J. Kloos

The Bureau of Mines developed a test for evaluating gas masks designed to protect against phosphine gas; phosphonium iodide is used as a source of phosphine. Gas masks approved by the Bureau for respiratory protection against phosphine include the GMC-SS-1, Mine Safety Appliances Co.; the LG-10 and LG-10G, Willson Products Division, The Electric Storage Battery Co.; and the 084-PHOV-R, Acme Protection Equipment Co.

Jan 1, 1966

By E. J. Kloos

The Bureau of Mines developed a test for evaluating gas masks designed to protect against phosphine gas; phosphonium iodide is used as a source of phosphine. Gas masks approved by the Bureau for respiratory protection against phosphine include the GMC-SS-1, Mine Safety Appliances Co.; the LG-10 and LG-10G, Willson Products Division, The Electric Storage Battery Co.; and the 084-PHOV-R, Acme Protection Equipment Co.

Jan 1, 1966

By R. H. Lien

The Bureau of Mines, U.S. Department of the Interior, has developed a flue gas desulfurization process as part of its goal of minimizing the undesirable environmental impacts associated with energy and mineral-processing plants. This process, known as the citrate process, involves absorption of sulfur dioxide (SO2) in a buffered solution of citric acid. The S02-loaded solution is regenerated by reaction of the S02 with hydrogen sulfide (H2S) to form elemental sulfur. As an adjunct to the citrate process, bench-scale research has shown that S02-loaded citrate or glycolate solutions can be regenerated by countercurrent contact with steam (stripping) in packed towers. Concentrated S02 is produced by condensing the steam from the stripper product. Thus, steam stripping provides strong S02 gas for liquefaction, sulfuric acid production, or reduction to elemental sulfur. Stripping steam requirements were determined for treatment of 0.25-, 0.50-3 1.0-, and 2.0-pct-S02 waste gases. Steam requirements decreased with increasing S02 concentration n the simulated waste gases. For example, 5 grams of steam per gram o S02 was required to remove 90 pct of the S02 from a simulated copper smelter gas (2.0 pct S02), while 30 grams of steam per gram of S02 was needed for 90 pct S02 removal from a simulated coal-fired powerplant gas (0.25 pct S02).

Jan 1, 1979

ESTABLISHMENT of an effective inspection system has been held essen¬tial to any international agreement that may be designed primarily to curb the testing of nuclear weapons. A number of reports and papers already have described basic inspection concepts and appraised various pro¬cedures, techniques, and methods as to their probable effectiveness in detecting and identifying violations under such agreement. This report results from a study of only one part of the contemplated inspection system, specifically the final phases embracing onsite investigations and mine examination techniques. The results and reports of earlier work were reviewed in detail, and subjects that were found to have been exhaus¬tively evaluated are recognized by reference and not redescribed here. In other instances, previously described techniques, methods, and clues were revaluated to define more clearly their practical value to the final objective of an onsite inspection. Previous documentation does not refer to a number of subjects, techniques, tools, clues, and methods considered by the study; this report treats these in detail, even though when applied singly or collectively their practical value may be questionable.

Jan 1, 1962

By F. F. Hintze

In the group of minerals used in making this study, the cyanite is associated with quartz, mica, and feldspar in the schist. The amount of quartz is variable, but it is always an abundant mineral. Both large and small crystals of quartz occur in irregular masses, rarely ever showing crystal outline. Mica is of the clear and dark varieties, the larger crystals being dark as a rule, and the finer crystals of light color. The present mineralogical composition of the mina is rather variable, as most of the original biotite and muscovite have suffered alteration, and much secondary mioa is present as a result of alteration of the original mica and other minerals present, especially the larger cyanite crystals. A large part of the mica now found in the ore is chlorite, with varying amounts of Jefferisite and others, especially sericite. These are in the form of aggregates, or felt-like intergrowths filling the spaces between the quartz, cyanite, and feldspar.

Jan 1, 1931

By James L. Hendrix

A study was made of the United States Bureau of Mines' chlorine-oxygen leaching process for complex sulfide concentrates. The investigation sought to determine the kinetic order and IT mechanisms involved in the reactions betweens sphalerite, and galena with chlorine. The influence of copper on the extraction rates was also studied. It has been shown the rates of reaction of chlorine in aqueous solutions with sphalerite and galena are both zero order at 373K with the rate limiting step being the chemical reaction. Addition of cupric chloride increased the extractions of both lead and zinc.

Jan 1, 1980

By J. L. Stauffer, L. J. Gaydos, L. M. Demers, D. C. Kuhn

"Eicosanoids and cytokines produced by alveolar macrophages (AM) are key mediators of pulmonary inflammation and fibrosis. In order to determine if eicosanoid production and cytokine production are altered in AM obtained from coal miners, we compared production of prostaglandin E2 (PCE2), thromboxane A2 (TXA2), leukotriene B4 (LTB4), interleukin-1 beta (IL-1B ), and tumor necrosis factor alpha (TNfa.) by cultured AM from normal human subjects and coal miners. The recovery of AM from miners' lungs by bronchoalveolar lavage was significantly greater than that from control subjects. Mean eicosanoid and cytokine production by AM from active miners was also increased compared to AM from control subjects, but this increase was not statistically significant. AM from control subjects produced significantly more TXA2 and TNFa. when exposed to lipopolysaccharide than did AM from miners. The cyclooxygenase inhibitor suprofen reduced PGE1 and TXA1 production and TNF0t. release but had no effect on LTB4 production or IL-1B release by miners' AM. The lipoxygenase inhibitor nordihydroguaiaretic acid attenuated TNFa release, as well as that of LTB4, but had no effect on IL-1B release. Inhibition of thromboxane synthase by UK 38,485 also reduced TNFa release by active miners ' AM but had no effect on PGE1, LTB, production, or IL-1 f3 release. The results of these studies suggest that occupational inhalation of coal dust may increase total lung eicosanoid and cytokine levels and reduce the reactivity of AM to bacterial endotoxin. Furthermore, coal dust-induced changes in both eicosanoid and cytokine release may be subject to pharmacological modulation.The alveolar macrophage (AM) is a primary defensive cell in the lung and is one of the first cell types to encounter inhaled mineral dust. The response of the AM to invading foreign material is designed to enhance the defensive capacity of the lung. However, in the case of occupational inhalation of mineral dust particles, this response may be inappropriate, resulting not in the defense of the lung but in chronic inflammation and fibrosis (Rom et al., 1987; Takemura et al., 1989). The reaction of the AM to chronic mineral dust exposure may involve the exaggerated release of paracrine mediators of lung function, including eicosanoids (oxygenated derivatives of arachidonic acid) and peptides, including cytokines and growth factors (Sibille & Reynolds, 1990). Eicosanoids are involved in bronchial and vascular smooth muscle reactivity, vascular permeability, fibroblast growth, and the recruitment of additional immune cells to the alveolar space (Barnard et al., 1992; Elias et al., 1985; Scott et al., 1982). AM-derived cytokines such as interleukin-1 beta (IL-1 B) and tumor necrosis factor alpha (TN Fa) have a variety of biological activities including the regulation of fibroblast growth and proliferation (Becker et al., 1989; Libby et al., 1989; Schmidt et al., 1984). Interestingly, in vitro studies with macrophages suggest that the production of cytokines may be linked to eicosanoid production, in particular that prostaglandin E2 (PGE2) may down-regulate IL-1 f3 and TN Foe production by the AM (Bonta et al., 1989; Kunkel et al., 1986; Monick et al., 1987)."

Dec 1, 1996

By Sarah P. Guerrino

This chapter summarizes data on crude nonfuel mineral production for the United States, its island possessions, and the Commonwealth of Puerto Rico. Included also are the tables that show the principal nonfuel mineral commodities exported from and imported into the United States and that compare world and U.S. mineral production. The detailed data from which these tables were derived are contained in the individual commodity chapters of Volume I and in the State chapters of Volume II of this edition of the Minerals Yearbook. Although crude mineral production may be measured at any of several stages of extraction and processing, the stage of measurement used in this chapter is what is normally termed "mine output." It usually refers to minerals or ores in the form in which they are first extracted from the ground, but customarily includes the output from auxiliary processing at or near the mines.

Jan 1, 1987

By Robert L. Lagace

This final report documents the work done by Arthur D. Little, Inc. (ADL) on behalf of the U.S. Bureau of Mines, Pittsburgh Mining and Safety Research Center (PMSRC) , on Contract H0122026 (which began in August of 1971) . Under this contract ADL provided technical assistance to the Bureau on a task basis on virtually all aspects of the Bureau's programs related to present and planned emergency and operational communications and miner location systems for underground coal mines. The work consisted of in- dependent investigations, analyses, experiments, breadboard and prototype hardware development, workshops and technology transfer seminars on mine communications, and on-going evaluations and guidance related to the Bureau's contracted programs on electromagnetic noise, mine communications systems, and trapped miner location. This final report documents the work in two volumes, Volume I, "Emergency and Operational Mine Communications," and Volume II, "seismic Detection and, Location of Isolated Miners." The Tables of Contents of both Volumes are included in each Volume.

Jan 1, 1974

By Roy C. Bartholomae

This U.S. Bureau of Mines study found that the performance of the active noise cancellation hearing protector in a reverberant field was mixed. The performance varied when the conditions changed from ideal to nonideal. The active noise cancellation (ANC) component provided substantial additional noise reduction from 125 to 500 Hz for all testing conditions (broadband noise or pure tones both with and without safety glasses). While the ANC under ideal conditions provided additional attenuation from 500 Hz and below, under nonideal pink noise conditions the ANC amplified noise below the 125-Hz third octave band. There was a middle band of frequencies at which the ANC amplified noise levels ranging from 630 to 4,000 Hz. The results for pure tones showed that attenuations were higher but that they followed the same general trend.

Jan 1, 2010

By T. T. Campbell

Although secondary recovery of lead and lead-tin alloys has been common practice in the United States during recent years, there is little published in-formation concerning recovery techniques. Available information does not cover metal recovery from wet dross skimmings. This investigation by the Bureau of Mines was undertaken to develop techniques that would allow lead-tin alloys to be recovered from wet dross skimmings containing large amounts of zinc chloride. A process was developed, on a laboratory scale, for recovering lead-tin alloys from wet solder dross skimmings. Straight water leaching, either with or without a second leaching operation carried out with a Na2C03 addition for removing chloride, produced a dross that could be smelted without further treatment. Overall recoveries averaging 92 percent of the metal values in the dross were obtained in the form of lead-tin alloys, which had an average tin content of 16 percent and lead content of 84 percent. The recovered alloy contained less than 0.02 percent zinc, as determined by both chemical and spectrographic analyses.

Jan 1, 1956