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By F. E. Diebold

The methodology for describing the geochemistry of elements in a coal seam have been developed. This has been applied to the Rosebud Coal Seam, which is an economically important member of the subbituminous coals of the Fort Union Formation in Eastern Montana. The method development has involved a detailed study of two popular techniques for determining the metal geochemistry of coal, namely, whole coal analyses and coal physical fractionation. The mathematically contrived element associations (whole coal analyses technique) and the element concentration trends in the float and sink fractions (physical fractionation technique) are considered to lead to only qualitative conclusions concerning the chemical associations of the elements in coals. Additionally, the processes taking place with the coal during low temperature ashing in an oxygen plasma are experimentally investigated and shown to be of sufficeint extent that the use of such low temperature ash for deciphering element geochemistry is questionable. The method developed in this study is a chemical fractionation that involves the sequential leaching of coal with water, 0.5 N HC1, 3 N HC1, 2 N HNO3, and 48% HF. These leach solutions are shown to selectively dissolve the predominate inorganic phases, sulfates, Ca and Mg carbonates, Fe sulfides and K alumino-silicates and quartz, respectively. These phases were identified with the use of XRD, SEM, EM and leaches (water and 0.3 N HC1) of whole coal and low temperature ash. The incorporation of the anion-exchange step in the leaching scheme was investigated and was observed to warrant further study of such intensity to be, at the time, unuseable. The use of this sequential leaching technique on several coal samples from the same seam generates element concentration trends that can be quantitatively interpreted with respect to the chemical associations of the minor and trace metals in the coal seam. The properties of the various seams of economic importance in the Fort Union Formation in Eastern Montana are compiled and presented. The subsequent conclusion is that there is not a large variation in the properties of these coal seams and that the variations within the Rosebud are within one order of magnitude. The chemical fractionation technique, investigated in this study, was applied to composite tipple samples of the Rosebud seam. Each composite sample represented 76,800 tons of coal. A minimum of 32% of the Ca and Mg are present as separate water soluble sulfates. An excess of the sulfate ion in the water extracts shows the predominating influence of the ion exchange capacity of the organic compounds in the coal. Based upon the CO content of the coal and the HC1 leachate data, 25 to 30% of the alkaline earth elements exist as separate carbonates and the remainder are associated with the organic compounds. The small fraction of the illite that dissolves in the HC1 and HNO3 leachates accounts for the K and Al. Slight dissolution of the pyrite in the HCl solvent occurs, the small amounts of Li and As do not relate to any known phase and Mn is present as a separate carbonate phase. Fe and a significant amount of the As exist in the pyrite that is dissolved in the HNO. Se is equally partitioned between the pyrite and the organic compound~. Most of the trace elements are found in the HF solutions. Li, V, and Cr were interpreted to be associated with the clay minerals (kaolinite and illite). Ni and Pb appear to be present as separate phases and 50% of the Hg is HF soluble but is not chemically related to any known inorganic phase.

Jan 1, 1983

By A. F. Colombo, R. T. Sorensen, D. W. Frommer

The Bureau of Mines developed a flotation method for concentrating spiral tailing produced from pilot plant tests on the Champion mine ore fines . The feed material contained about 49 percent Fe and 15 percent SiO2 and was posed mostly of specular hematite , muscovite , and chlorite . Bench- scale , batch flotation research developed a reagent suite composed of tall oil - fatty acid , fuel oil , sulfuric acid , sodium fluoride , and sodium silicate for recovery of iron minerals in the froth product . Concentrate made with the reagent suite contained 87.3 percent of the iron and analyzed 65.6 percent Fe and 1.9 percent SiO2 . Continuous flotation tests were made with a nominal feed rate of 400 lb /hr , but without middling recirculation . Using nearly the same amount and complement of reagents as in the batch tests , three similar continuous tests gave concentrates averaging 63.9 percent Fe and 3.1 percent Sio while recovering about 86 percent of the iron .

Jan 1, 1964

By W. J. McKenna

This paper, describing the milling practice at tine lead-zinc concentrator of the International Smelting Co., is one of a series of papers on milling methods being prepared by the United States Bureau of nines. The concentrator is operated as a unit of the International Smelting Co. and is located about 40 miles southwest of Salt Lake City, at Tooele, Utah. The Tooele Valley Railroad, operating between the plant and Warner, Utah, a distance of 6.5 miles, makes connection with both the Union Pacific and Denver & Rio Grande Railroads.

Jan 1, 1933

By Arthur L. Murray

"While serving as surgeon with rescue car No 11 of the U. S. Bureau of Mines, the writer visited the principal metal-mining camps of Utah during the latter part of 1919. In visiting the mines, meeting and conversing with miners, and talking over the medical situation with physicians in the various camps, the number of cases of lead poisoning encountered was great enough to attract attention.With a view to procuring more definite information as to the number and distribution of cases of lead poisoning throughout the State, a study of the records of the State Board of Health was undertaken. Utah had no ordinance re¬quiring the reporting of occupational diseases, so it was not possible to secure data an cases A study of the mortality records by years gave the following results.:Year Deaths from lead poisoning.1910,11911,01912,21913,11914,61915,41916,11917,31918,11919,2These few deaths would seem to indicate a fairly low case rate, but when it is realized that lead poisoning is rarely an immediate cause of death and that the train of sequelae in this disease frequently leads to chronic involvemeets of the digestive, nervous, circulatory or genito-urinary systems, it is apparent that the number of deaths showing lead poisoning as the cause can not be taken as an index of the cases prevalent. The time elapsing between the presence of the active signs of lead poisoning and the terminal illness from pathologic conditions excited by lead absorption may be years, and the initial cause, lead poisoning, is frequently lost sight if entirely, hence the death certificate shows no evidence of the primary cause."

Aug 1, 1921

By E. J. Matson

The Bureau of Mines has been investigating deposits of critical and essential minerals in the United States since 1939. The Rush Creek lead-zinc deposit, Mono County, Calif. (fig. 1), was examined by W. T. Benson in July 1944 and again in September 1945 by D. W. Butner, engineers of the Bureau of Mines. From the results of these preliminary examinations, a core-drilling program (fig. 2) was started in August 1946 and continued until November 1946, when work was stopped on account of inclement weather. Field work was again started in May 1947 and completed in June 1947. The drilling program was laid out to develop the horizontal .and vertical extensions of showings exposed in surface pits.

Jan 1, 1949

By Welby G. Courtney

The Bureau of Mines conducted an exploratory field survey to determine the amount of airborne coal dust, the size distribution of the dust, and the rate of dust deposition in coal mine airways. The survey was taken at eight underground locations in operating coal mines. The rate of dust deposition in the airways depended upon the concentration of air-borne dust and decreased exponentially with distance from the dust source. The rate was seemingly independent of the size of the airborne dust particles. The rate of deposition, along a return, for the coal dust from a fade being mined with a continuous mining machine closely matched the rate for the rock dust from a trickle duster. A sample rock-dusting schedule for that return is presented; that is, the trickle duster should be operated for 3-112 hours after every five shifts to protect the average deposit of new float coal dust in the return, but operation after every three shifts is preferred, to protect an occasional heavier deposit.

Jan 1, 1982

By C. B. Kenahan

A summary of Bureau of Mines research on recycling, reuse, and disposal of mineral-, metal-, and energy-based wastes is presented, accompanied by an extensive bibliography of related publications. The Bureau's waste recycling and disposal program is directed toward the following four main areas of research and development: (1) extraction of mineral, metal, and energy values from urban refuse; (2) upgrading and recycling of automotive and related ferrous and nonferrous scrap; (3) recovery, utilization, and stabilization of mine and mill processing wastes, and (4) recovery and reuse of values from industrial waste products. This publication updates Bureau of Mines Information Circular 8529, which was issued August 1971.

Jan 1, 1973

By J. E. Chilton

The Bureau of Mines has examined the operation of an oxygen sensor manufactured by the City University, London, England. The sensor produces a current proportional to the oxygen concentration by reacting oxygen at a nonconsumable cathode. The sensor design is unique in that the primary mode of oxygen transport to the cathode is by diffusion through a capillary, The sensor using this design has a stability of 0- to 0.02-pct reading change per day over a 4.7-month test, small temperature coefficient of 0.29-pct reading change per °C, and small pressure coefficient of 0.34-pct reading change per 1,000-ft altitude change, If this sensor were incorporated into an oxygen detector or monitor, this would be a distinct improvement in electrochemical-type oxygen analyzers and would be useful to the mining industry.

Jan 1, 1983

By B. B. Letson

The heats of formation of lithium chloride and lithium oxalate were determined with the aid of a Bureau-developed, glass Dewar-type solution calorimeter which uses thermistors as its temperature sensing element. Values obtained at 298.15° K were -98.38 ± 0.54 kcal/mole for lithium chloride and -329.02 ± 0.79 kcal/mole for lithium oxalate, using graphite as the standard state for carbon.

Jan 1, 1965

By Foster Fraas

This report describes the application of pulsed magnetic fields derived from alternating and intermittent magnetizing currents. Application of such pulsed magnetic fields to the matrix-type separator permits (1) the complete discharge of the magnetic fraction with wet feeds and (2) the dry separation at particle sizes down to 325 mesh. At smaller particle s indications are that frequencies above 60 hertz will be required. Applications of intermittent magnetizing current to the cross-belt separator give the cross-belt-separator an advantage over the conventional constant-field cross-belt and induced roll separators; the intermittent current enables the cross-belt separator to separate matted fibrous and magnetically coagulating feeds, a type of feed that occasionally occurs with mineral, industrial, and secondary materials.

Jan 1, 1973

By Victor E. Kral

The Valery fluorspar deposit , also known as the Hamilton deposit , is northeast of Lovelock and 4 miles by poor dirt road east of U. S. Highway 40 . It is in the Humboldt Mining District , on the west side of the Humboldt Range , at an altitude of 6,000 to 6,500 feet . The property was examined by the Bureau of Mines on February 83/ and April 8 , 1944.4/ The last examination was made with an engineer of the Geological Survey.5/ Exploring by means of trenches , cuts , shaft sinking , coyote holes off the shaft , and a small amount of prospecting with short drill holes , was begun in January 1945 and was completed June 30 , 1945. An engineer6/ of the Geological Survey visited the property in April and again in June 1945 to complete a topographic map of the area and to note the results of exploration by the Bureau of Mines . Only minor surface exploring had been done on fluorspar occurrences previous to the Bureau's work . No mining equipment or living facilities are on the property .

Feb 1, 1947

By Nicholas Kyriazi

A joint effort by the U.S. Bureau of Mines and the U.S. Mine Safety and Health Administration (MSHA) was undertaken to determine how well self-contained self-rescuers (SCSR's), deployed in accordance with Federal regulations (30 CFR 75.1714), survived the underground environment with regard to both impact damage and aging. This report presents findings regarding laboratory-tested SCSR's from 1982 through 1990. The SCSR's were tested on human subjects and on a breathing and metabolic simulator (BMS). These results indicate that most of the apparatus, if they pass their inspection criteria, perform as expected except for units with manufacturing defects or design deficiencies. However, when the apparatus are carried in and out of the mine daily and stored at the working section, they may suffer abuse. Physical signs of abuse, unless extremely obvious, are frequently not detected by the miners or mine operators. This poses a potential danger to a user in an emergency. Recommendations include improved training in inspection procedures.

Jan 1, 2010

By J. F. Barkley

"Conservation of fuel in boiler-plant practice is one of the major projects of the Bureau of Mines. The large central stations with their corps of trained operators and with refined equipment obtain relatively good efficiency. It is in the many smaller isolated plants that the large fuel wastes are apt to occur. Some operators seem to feel that their responsibility is largely expressed in the phase the phase ""carry the load,"" rather than ""carry the load and carry it efficiently."" Often equipment is not provided to give sufficiently accurate guidance to the operator.In within many such plants, it is interesting to note how frequently the same mistakes occur. The following quite typical example illustrates some of these circumstances and their effort on operation. The boiler plant consisted of two 1000 hp. boilers equipped with multiple retort under-feed stokers. These were horizontal water-tube boilers with horizontal baffling, having a high bridge wall at the back of the stoker. One boilers was used to carry a summer carry a winter load of about 1250 hp. The operators felt that one boiler was not sufficient to carry the winter load. No instruments are available for the operator's use, excepting the steam ores sure gases."

Mar 1, 1925

By V. E. Edlund

Laboratory batch flotation tests were conducted on copper converter slags to evaluate the relative merits of recovering copper from slow-cooled versus water-quenched slags. Three slags containing 1.6, 5.0, and 6.6 percent copper were used. More than 90 percent of the copper was recovered in a rougher concentrate leaving a 0.2- to 0.3-percent copper tailings when treating slow-cooled slag. Lower recoveries and higher copper tailings ranging from 0,5 to 0.6 percent copper were obtained from quenched slag. Grindability studies were made on the respective heat-treated slags. Quenched slags proved more difficult to grind than slow-cooled slags. Cost studies showed that (1) the cost of slow cooling and crushing off-sets any advantages of higher copper recoveries from slow-cooled slag, and (2) water-quenched slag, which requires no crushing preparatory to grinding, could be treated more economically. Costs based on processing 1,000 tons of slag per day would be $1.85 per ton for quenched slag versus $2.37 per ton for slow-cooled slag.

Jan 1, 1971

By G. R. Hopkins

[Apparent progress in fuel economy at petroleum refineries, as measured by the average amount of .seat units required to refine a barrel of crude oil, received a set-back in 1935, when the average rose to 562,00 B. t. u., compared with 562,000 B.t.u. in 1937 (see fig. l). The primary factor in the rise in average heat requirement's per barrel of crude oil refined in 1938 wan the decline in total runs to Invariably the average requirement increases when crude ins to stills decline, and vice versa. In other words, annual gains in fuel efficiency at refineries arc masked by the degree to which the capacity is utilized. Additional crude runs give lower average e heat requirements in two ways - first, because they are mane with the c expenditure of comparatively small amounts of auxiliary heat, and, second, because the additional runs generally represent simple topping operations. In 1938 crude runs, to stills declined 1.6 percent (from 1,183,440,000 barrels in 1937 to 1,165,015,000 barrels in 1938), but the total heat consumption declined only 0.4 percent, or from 663,866 billion B. t. u. in 1777 to 660, 56 billion in 1938 .]

Jan 1, 1939

By S. P. Howell

"Technical statistical study has been made of accidents in the anthracite region of Pennsylvania in which explosives were involved. The data have been taken from the accident reports in the files of the department of mines of Pennsylvania, supplemented by inquiries in the field.This study has disclosed a wealth of information regarding the nature and the cause of accidents that occurred where different means of firing shots of explosives were employed. In the anthracite region shots are fired with fuse, with squibs, and with electricity,Many of the salient features of this accident experience are illustrated in this report of investigations, and a number of recommendations are made to reduce the hazards of each of these three methods of shot firing.Experience seems to demonstrate that, under conditions in the anthracite region, electric firing of shots is substantially the safest method; that accidents wherein fuse is employed are more frequent than accidents in which electric firing is employed; and that the number of accidents when squibs are employed far exceeds those in which either fuse or electric firing is used."

Mar 1, 1930

By E. S. Shedd

Misch metal was electrowon from a treated bastnasite concentrate in a REF3-LiF-BaF2 electrolyte at 950° C. The metal was prepared and tapped from a 1,000-ampere cell, and nearly 100-percent utilization of the rare-earth oxide was achieved. Prolonged operation in a smaller cell (40 amperes) indicated that the composition of the misch metal product was reasonably constant, and no significant increase of impurities, with the exception of carbon, was noted.

Jan 1, 1970

By James S. Browning, W. H. Eddy

Laboratory batch and small - scale continuous flotation tests were conducted on a ferruginous barite - fluorspar ore from near Sweetwater , Tenn . , to determine the feasibility of producing commercial - grade fluorspar and barite concentrates . The lignin sulfonate - sodium fluoride - fatty acid method of floating fluorspar produced acid - grade concentrates . Flotation of the barite from the fluorspar tailing using petroleum sulfonate yielded concentrates suitable for use as a weighting agent in oil -well drilling muds . The continuous flotation tests , treating about 150 pounds of ore per hour , yielded fluorspar concentrates that assayed 98.3 percent CaF2 and barite concentrates that assayed 91.2 percent BaSO4 . The recovery of the two minerals was 91.2 and 85.2 percent , respectively .

Jan 1, 1964

By Merle L. Bowser

The Bureau of Mines has constructed a miniature oxygen deficiency alarm system using an electrochemical cell as the sensor. Distinct audible signals are produced at either of two preselectable oxygen levels which can be varied from approximately 10 to 20.9 percent oxygen. The high or cautionary range produces a 500-cycle-per-second tone pulsed at about a 1-cycle-per-second rate, whereas the lower or more dangerous oxygen level produces a continuous 500-cycle-per-second tone.

Jan 1, 1968

By Helen E. Edwards

The Bureau of Mines is engaged in a systematic evaluation of the thermodynamic properties of combustion gases. These studies are designed to provide basic thermodynamic information of high accuracy facilitating the theoretical study of flame and combustion phenomena. This report is the third of a series3/ presenting results of the study for particular fuel-oxidant systems. The equilibrium composition of the products of combustion and the adiabatic flame temperatures of specified oxyacetylene systems have been computed.

Jan 1, 1953