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By J. W. Horne, W. B. Shirey

"INTRODUCTION The United States Bureau of Mines in cooperation with the State of Colorado at the University of Colorado has conducted experiments to determine the amount and composition of the noncondensable gases evolved when crude shale oil is distilled under pressure.Hydrogen sulphide is one of the components found in the complex mixture of gases produced by the distillation of shale oil under pressure. This paper deals with the apparatus and method used in determining the amount of hydrogen sulphide evolved in the laboratory experimental cracking stills.The study required a complete extraction of all the hydrogen sulphide from the gas stream after it left the water-cooled distillate condensers and before the as stream entered the charcoal absorber for removing the light naphtha. In devising the method it was necessary to take into account a constant variation of velocity, pressure, and percentage of sulphide in the total gas stream coming from the still.Ordinarily, the quantitative determination of hydrogen sulphide in Gas is made by analyzing small samples taken at regular intervals. This estimation can be accomplished by use of the Bunte gas burette as modified by Tutriler,4 or by a similar method. In the industries where the flow of as is constant end of uniform composition, this practice is sufficiently accurate for plant control. For experimental work where many variables have to be taken into consideration, as in the case at hand, these methods are not applicable."

Oct 1, 1931

By IRENE AITKENS

The emerald is the most costly of all gems , due to the scarcity of flawless stones . This fact gave rise to the ancient axiom , " As rare as an emerald without a flaw . The finer gems not only command the highest prices at all times , but when flawless are considered the most highly prized of all gem stones . George F. Kunz divides emeralds into two distinct classes : " Exceptional specimens , " which bring as much as $ 6,000 a carat ; and " fine- quality specimens , " which bring about $ 1,000 a carat .

Jul 1, 1931

By Gordon T. Austin

The combined value of production of natural abrasives, which include tripoli, special silica stone, garnet, staurolite, and emery, increased about 4% in 1990. The decrease in the value of tripoli production was the result of a decrease in total production. Emery decreased owing to a decrease in the volume of the material produced. Special silica stone experienced a decrease in unit value and in the quantity produced. Garnet showed an 8 % increase in quantity and an 8 % increase in unit value. Staurolite increased about 38 % in the quantity produced, and the value of production increased about 36 %. The fused aluminum oxide industry showed a 12 % decline in the quantity produced and a 13 % decline in the value of production. The silicon carbide industry saw a 47 % decrease in the quantity produced and a 23 % decrease in the value of production. Combined, the industries decreased 17 % in quantity and value compared with those of 1990.

Jan 1, 1993

By John R. Shattuck

Preliminary examination of the McCormick chromite property was made by the Federal Geological Survey and the Bureau of Mines during the spring and summer of 1943. In October 1943 an exploratory project was undertaken by the Bureau in cooperation with the Survey and was completed in February 1944.The urgent need during the war for high-grade lump chromite such as produced at the McCormick mine, was one of the pertinent reasons for the project. The McCormick mine is situated about 12 miles southwest of the town of Sonora, in the foothill belt of the Sierra Nevada Mountains, Tuolumne County, Calif. The chromite occurs as irregularly shaped lenses in masses of dunite contained in a steeply dipping, sheared, serpentinized zone of peridotite, near a contact with granodiorite.

Jan 1, 1949

By I. O. Salyer

This research was conducted with the objective of suppressing the respirable dust in coal mines by foam application. A formulation was developed for making a water-based, high-expansion, and limited stability foam. A horizontal boring machine was used as a laboratory coal mining model for generating coal dust. A modified laboratory foam generator was built. Foam was applied directly to the point at which dust was being formed by the cutter of the boring machine working against a block of coal. Coal dust was sampled with an impinger and analyzed for the particle count and particle size distribution. Coal dust suppression test results on freshly generated dust have demonstrated very clearly that in laboratory scale experiments over 90% of the respirable coal dust can be suppressed by foam. These tests were run when initial coal du t concentrations were 10 and 70 million particles per cubic foot (mppcf).

Jan 1, 1970

By H. H. Schrenk

One phase of Bureau of Mines work in health and safety, is promotion of the use of safe, satisfactory, and reliable respiratory protective devices. To insure that such devices will be available, the Bureau has established schedules of minimum requirements for self-contained breathing apparatus,3/ gas masks, supplied-air respirators (hose masks, air-line respirators, and abrasive blasting helmets, hoods, or masks),2 dispersoid (dust, fume, and mist) respirators, and nonemergency gas respirators (chemical cartridge respirators). Approval tests of self-contained breathing apparatus are conducted by the Safety Branch, approval tests of other types of respira- tory protective equipment are conducted by the Health Branch, These branches are in the Health and Safety Division.

Mar 1, 1948

By Martin J. Gavin

During the recent study of lubricating oils carried on in the San Francisco laboratory of the United States Bureau of Mines, it became desirable to distill the oils used in the experimental work at pressures as low as 10 millimeters (mercury column) absolute. In the effort to Overcome difficulties and eliminate sources of error, certain changes were made in the apparatus for vacuum distillation used by the Bureau of Mines for crude petroleum.4 These changes were described in R.I. 2819, issued in July, 1927. Subsequent to the publication of R.I. 2819 several other changes have been made, and the present form of the apparatus for vacuum distillation of lubricating oils is described in this revision of R.I. 2819. These changes were found to give more accurate checks on duplicate distillations. The major part of the credit for the laboratory work which developed the changes in the apparatus and method revised herein is due to Boyd Guthrie, assistant petroleum chemist, and R. V. Higgins, junior chemist, o the San Francisco laboratory, United States Bureau of Mines. DESCRIPTION OF APPARATUS The distilling flask employed is essentially the Hempel flask as used by the United States Bureau of Mines for the analytical distillation of petroleum.5 he complete apparatus is shown in Figure 1. The fractionating column and exposed portion of the flask is wrapped with 4 inch asbestos rope and then surrounded by a cylindrical hood of 1/8 inch pliable asbestos sheet with a narrow air space between the wrapping and the cylindrical hood. This was found necessary to prevent any radiation or convection heat losses from the column, and resulted in obtaining a more even and constant fractionation by eliminating any dephlegmating action caused by temperature changes around the column.

Jan 1, 1930

By F. S. LOTT, I. S. CULVER

The number of petroleum refineries in the United States decreased during 1948 from 390 to 375, continuing the trend to fewer units of larger individual capacity that has persisted since the peak in number of plants was recorded on January 1 , 1936. Large - scale construction of new processing facilities continued through 1948 with a resultant gain in daily crude-oil throughput capacity of installed equipment from 6,034,252 barrels on January 1 , 1948 to 6,438,995 barrels on January 1 , 1949. The capacity of the average refinery to process crude oil therefore increased during 1948 from 15,472 barrels daily to 17,171 . The principal areas of expansion of facilities were the strategic seaboard districts of the Texas and Louisiana Gulf Coast and the East Coast , and the important Indiana , Illinois , Kentucky, etc. , district that supplies markets in the upper Middle West region . These four districts accounted for 79 percent of the total new capacity added in the United States in 1948. The relatively small petroleum- refining industry of the Other Rocky Mountain district experienced a vigorous expansion in 1948 that will continue during 1949 . Capacity building on January 1, 1949 , amounting to 341,500 barrels daily, was 25,750 barrels lower than the comparable total on January 1 , 1948, but was the second highest on record . New construction was heavily concentrated in the Texas Gulf, East Coast , and Indiana -Illinois

Sep 1, 1949

By R. S. Dean

The principle of explosive crushing depends upon the fact that an expandable substance contained within the pores of a solid body will disrupt such a body upon expansion. Such expansion may be obtained by the detonation of an explosive or by the sudden release of pressure of a superheated liquid. That this principle of disruption may be applied to minerals rests on the fact that cracks, cleavage planes, and pores exist in all minerals to an extent hardly conceived possible heretofore. Crushing by this method takes advantage of forces applied from within the mineral rather than from forces applied from without. The application of a force from within would appear to be more effective.

Jan 1, 1932

By J. A. McAllister

In the course of a study of domestic Manganese resources, 2-ton representative samples of ore were taken by Bureau of Mines' engineers from the Payday claim, Weber County, and the Newcomb-claims, Rich County, Utah. The Payday No. 1 deposit is situated 13 miles northeast of Huntsville, Weber County, Utah. The manganese ore is a. replacement deposit in limestone and consists of manganese oxides imbedded 'in clay and also as the cementing agent consolidating small pebbles and pieces of quartz and limestone.

Jan 1, 1949

By I. N. Beall

The present survey indicates 'that the average volatility of motor gasoline now being marketed throughout the country falls well within the limits of Federal Specifications. As would be expected, there is a slight decrease in volatility as compared with the gasoline marketed last wine:., but on the average the gasoline sold today is about the same as that sold last summer. During the past five years the Bureau of Mines has made semi-annual surveys of the gasoline marketed in the United States. To obtain a sample of each gasoline sold is obviously impracticable, but the cities in which samples have been collected have been so chosen as to be representative of the more important marketing territories. It is believed, therefore, that the samples obtained are indicative of the quality of gasoline marketed throughout the country.

Jan 1, 1925

By S. H. Ash

[On December 2, 1932, the Governor of California called upon the representatives of the mining industry of the State to attend a meeting at Sacramento to discuss ways and means of assisting is relieving some of its perplexing and extremely distressing problems, particularly the mounting cost of accidents which faces the industry with an industrial insurance rate for classification of $11.85 per $100 of pay roll, effective January 1, 1033. The significance of this fact is at once apparent when it is realized that the classification rates per $100 of pay roll for mining have steadily increased for some time, as follows: $3.91 in 1924, $5.54 in 1925 and 1926, $8.04 in 1927, $8.53 in 1928, $9.05 in 1929, $9.42 in 1930, $10.54 in 1931, $10.99 in 1952, and $11.85 in 1133. In other words, the cost rates have acre than doubled, wile statistics indicate that the accident rates nave shown an entirely different trend. At the meeting mentioned, one of the management officials sounded an effective keynote when he declared that a spade should be called: a spade. The perplexing problems of any industry can be approached best and remedies applied if that policy is kept to the front. It is appropriate to mention that high accident rates and a decrease in wages in recent years have unquestionably accounted in part for a unit cost rate, on a pay-roll basis; it also is well to explain that the policy years3 1926 to 1930, inclusive, are the years on which the accident-cost experience for 193: is based. That accident rates :lave not undergone the expected beneficial chance in California's experience is apparent in the words of a Bureau of Mines report:4]

Jan 1, 1933

By Richard A. Watson, James A. Powell

A seismic system which utilizes in-mine geophones to detect trapped miners has been developed. Tests at the Bureau of Mines Safety Research Mine at Bruceton, Pa., and at two operating mines indicate such a system has a maximum detection range in excess of 1,000 feet. The system is field worthy and portable and requires less than 30 minutes to set up and check. Real-time detection is possible.

Jan 1, 1976

By D. C. Crowell

This publication presents the results of a laboratory investigation of displacement of gas by injection or imbibition of water into sandstone models under essentially isobaric conditions. A brief discussion of scaling requirements is included. The influence on residual gas saturation of independently varying the parameters of dimensional ratios of the porous media, rates and methods of flooding, surface tension, initial water saturation, and permeability is shown. Of these variables, increased initial water saturation and decreased surface tension reduced residual gas saturation significantly, whereas variations in flooding rate and dimensional ratios had no apparent effect. No correlation was evident between absolute permeability and residual gas saturation.

Jan 1, 1966

By R. J. Hundhausen

The Takilma-Waldo copper district in Josephine County, Oreg., was studied by the Bureau of Mines from September 1950 to April 1.951 and from December 1953 to April 1954. Funds for the investigation were provided by the Bureau of Mines and the California-Oregon Power Co., Medford, Oreg., on a cooperative basis. The copper mines in the district are credited with a total production of ore worth $1,700,000. Since 1933 the mines have been unproductive and, except for minor exploration, largely inactive. The history of the district indicates that the copper deposits were mined principally during periods of high metal prices.

Jan 1, 1956

By Edward D. Thimons

As U.S. mines go to greater depths, the high temperatures and humidities characteristic of such depths make it difficult to maintain a comfortable environment in working areas. Better techniques for cooling these deep working areas are needed. At the Homestake gold mine in South Dakota the Bureau of Mines has tested a water spray cooler inserted into the fresh air vent tube entering a warm stope. The cooler supplied more than 6 tons of refrigeration to the stope air, which dropped from an inlet temperature of 83° F dry bulb and 75° F wet bulb to 73.5° F dry bulb and 71.5° F wet bulb. These preliminary results show the water spray cooler to be a feasible concept. However, there is a need for substantial refinement and further testing, and work on the concept will be continued under contract to the Bureau.

Jan 1, 1979

By J. W. Walkiewicz

Studies were conducted by the Bureau of Mines to develop a method for fabricating Sm-Co permanent magnets. This method consisted of arc-melting, crushing and grinding the alloy, alining and pressing the powder, and sintering the green compacts. Results indicated that the optimum composition was 36.7±0.3 weight-percent Sm and 63.3±0.3 weight-percent Co. This composition was obtained by blending together Sm2C07 and SmCo5. The maximum values exper¬imentally obtained were MHC = 27.4 kOe, BHc = 7,510 Oe, Br = 7,810 G, and (BH)max = 15.1 MGOe. The optimum sintering temperatures and grinding times for maximum MHc and (BH)max were determined. Lowering the grinding temperature from 0° C to -60° C resulted in a significant increase of magnetic properties.

Jan 1, 1973

By L. H. Kalenowski

The metal lithium, its alloys, and its salts are becoming Increasingly important as industrial materials. Lithium metal, because of its great affinity for elements, such as nitrogen, hydrogen, oxygen, sulfur, phosphorus, carbon, and silicon, has become important for a wide variety of uses, ranging from purifying helium gas by removing the nitrogen to scavenging molten metals of undesirable impurities. The excellent fluxing properties of lithium salts have found increasing use in such applications as fluxes for welding aluminum and in lower melting ceramic glazes and coatings. Lithium chloride is one of the most hygroscopic salts known and is widely used as a dehumidifying agent. .About 17 lithium minerals are known. Four of these have commercial importance: Amblygonite, lepidolite, zinnwaldite, and spodumene. Spodumene is the most important source of lithium and lithium salts at present, but sizable deposits of amblygonite occur in the pegmatite area of the Black Hills of South Dakota. The size and nature of these deposits preclude the, possibility of, any assurance of an adequate supply of amblygonite for an operation processing only this mineral. Frequently spodumene and amblygonite occur associated in pegmatite minerals. Preliminary investigations indicate that a simultaneous recovery of spodumene and amblygonite can be made by froth flotation. A single process for treating spodumene and amblygonite or mixtures of thorn, would make possible more use of amblygonite as a source of lithium and obviate the separation of spodumene and amblygonite when they occur together.

Jan 1, 1952

By Charles L. Kimbell

The final 26 tables of this chapter, tables 14-39, extend and expand the statistical series on production that was started in the 1963 edition of the "Area Reports: International" volume of the "Minerals Yearbook" and that was subsequently updated and expanded in the 1965 and 1967-88 editions. In this year's edition, for the first time, a column has been added to each of these tables providing a 5 year average for 1985-89, inclusive. This should provide a clearer picture more rapidly of the role of each major producer over the 5-year period. The listing order of major producers, however, continues to be, as in past years, in descending order of rank in the year of review, 1989. With the inclusion of silver and uranium oxide in the 1988 edition of this chapter, this group of tables now includes each of the crude minerals that ranked from 1st to 19th in 1983 in terms of value of their output (as well as four others of lesser rank). These 23 crude mineral commodities accounted for 93% of the estimated value of world crude mineral of world crude mineral production in 1983. In addition, world output of five key down-stream products-aluminum, steel, cement, nitrogen in ammonia, and refined oil are included because of their significance as products.

Jan 1, 1992

By W. A. Stickney

The Bureau of Mines conducted beneficiation and smelting studies on siliceous offgrade manganese samples to indicate effective methods of manufacturing silicomanganese from materials that cannot be economically beneficiated to meet General Services Administration (GSA) specifications for stockpiling. Laboratory and pilot-plant flotation tests were conducted on 2 samples, 1 from the waste-tailings dump of the Domestic Manganese & Development Co , Butte, Mont., and the other from the Nettie mine in the Butte-Philipsburg area. Smelting tests were made on the combined concentrates from the pilot-plant flotation tests and on part of the tailings sample The flotation scheme found to be adequate in laboratory tests and later in the pilot-plant tests consisted of flotation by a fuel oil-tall oil emulsion in an acid circuit (pH )-1-.8 to 5.0). The oil-emulsion reagent flocculated the manganese minerals and selectively floated them from the siliceous gangue, In the pilot-plant flotation test on Butte-mill tailings 90.1 percent of the manganese was recovered in a concentrate that analyzed 32.6 percent Mn, 4.8 percent Fe and 28.1 percent Si02. In the test on Nettie mine ore 90.8 percent of the manganese was recovered in a concentrate that analyzed 36 6 percent Mn, 5.5 percent Fe, and 26-4 percent Si02.

Jan 1, 1956