Search Documents

By Peter C. Wood

This report describes research directed toward the preparation of chemical oxygen (02) sources which exhibited improved 02 storage and reaction characteristics when compared to potassium superoxide (KO2). The initial focus of the research was the preparation of calcium superoxide (Ca(02)2) by the disproportionation of calcium peroxide diperoxyhydrate. The Ca(02)2) was characterized by chemical, thermal, and x-ray analyses. Several methods for scaling up the Ca(02)2 synthesis process were studied. Next, the reactivity of Ca(02)2 toward humidified carbon dioxide (C02) was evaluated and was compare o that of K02 under flow-test conditions approximating those existing in portable breathing apparatus. The reactivities of mixtures of K02 and Ca(02)2 or lithium peroxide towards humidified CO2 were also studied. Finally, an analysis of two commercial, K02-based, self-contained self-rescuers was conducted to determine the potential weight and volume savings which would be possible if Ca(02)2 or a mixture of K02 and Ca(02)2 were used as a replacement for K02.

Jan 1, 1983

By J. A. Organiscak

Quartz dust is one of the most significant ongoing health concerns in coal mining today. Since the early 1980's, the U.S. Bureau of Mines has conducted numerous studies in underground and surface coal mines to identify the sources of quartz dust and its fundamental characteristics. This report presents data and conclusions obtained from these studies. The two most significant quartz dust sources were found to be the continuous miner excavating rock and the highwall drill operating in a rock overburden. The percentage of quartz was found to be higher in the smaller size fractions of dust when significant amounts of rock were mined by the continuous miner. Another factor theorized to affect quartz dust generation and size characteristics is the morphology of the quartz-bearing rock. Several laboratory studies were conducted to investigate capture efficiency of water spray technology and flooded-bed scrubbers with respect to the particle size of the dust. Water sprays and flooded-bed scrubbers were both found to be less efficient on smaller dust particles, and the scrubber was particularly less efficient on quartz dust. These results indicate that quartz control technology should be directed at controlling smaller sized dust particles.

Jan 1, 1990

By H. Herbert Hughes

Iceland spar is a variety of calcite ( calcium carbonate ) characterized by its purity , transparency , and perfection of crystalline structure . It takes its name from the country in which it was discovered . The actual demand for it is small , but the supplies of high - grade optical spar are so meager that the search for it has become international in its scope . Iceland spar is a scientific necessity , for without it research precision and technology would be hampered considerably . The earliest students of mineralogy were familiar with calcite , but the transparent variety was not discovered until early in the seventeenth century , when crystals of it were found in the bed of a stream in Iceland . It received little attention until 1669 , when Erasmus Bartholinus first recognized its powers of double refraction . The results of his investigation were published in a book , " Experimenta Crystalli Islandici , " which appeared in 1670. The law governing the action of the rerracted rays was discovered by Christian Huygens eight years later . The polarization of light rays in passing through Iceland spar was discovered in 1809 by Etienne Louis Malus , a French physicist , who published a paper describing the phenomenon . His work was closely followed by that of William Nicol , who in 1828 designed the Nicol prism which is still used as the source of polarized light in most optical instruments .

Jul 1, 1931

By J. A. Kosek

Work has been carried out under Bureau of Mines Contract HO 395132 to develop improved sensor cells for use in direct-reading detectors and diffusion exposure meters. A pumped CO sensor cell was developed which has a shorter response time, improved temperature cycle characteristics, and improved linearity and stability at high CO concentrations. Diffusion CO sensor cells have shown good response level stability and linearity up to 1000 ppm. In addition, a new sensor cell catalyst has been developed for NO2 sensor cells which has a much shorter response time and improved response stability characteristics.

Jan 1, 1982

By Herman W. Hill

This report summarizes research into the root causes of failures in mine power systems which impact safety and reliability. Abnormally low fault currents, due to arcing faults, self-excited systems, and fallen trolley wires are examined and quantified. The reliability of components which are critical for safety is studied, as well as reliability of components which are crucial to the mining pro cess. Failure rates are found through in-situ tests, accelerated life tests, studies of mine maintenance, and fault-tree analysis. Reliability data is used to predict fatalities and lost-time accidents through computer-aided fault-tree analysis. Analytical support tasks reported include the deriving of trailing-cable ampacities under cyclic loading, and the measurement of connected ground beds.

Jan 1, 1981

By d&apos, D. V. Andrea

Nine rock properties were determined for rocks coming from 49 locations and having a wide range of compressive strengths. Plots of the nine rock properties versus each other were prepared. A stepwise multiple linear regression analysis was performed to obtain several equations for predicting compressive strength. Both linear and curvilinear relationships were assumed between compressive strength and the other rock properties. The prediction equations had multiple correlation coefficients ranging from 0.947 for an equation with 1 variable (point load tensile strength) to 0.986 for an equation with 25 variables. Of the properties tested only point load tensile strength could be used alone to estimate compressive strength with fair accuracy.

Jan 1, 1965

By G. H. Martindill

Complex chemical and physical changes occurring during carbonization result in a heterogeneous system composed of gaseous, liquid, and solid phases, whose relative proportions and chemical compositions change constantly as temperature increases. Studies in which the participating variables are isolated and controlled should be useful in formulating the mechanism of coal carbonization. The most characteristic property of a coking coal is its ability to form a plastic mass at a certain stage of the carbonization process. During this period it is believed that fluidity of the coal influences the properties of the resultant coke. This report gives results of an investigation by the Federal Bureau of Mines of the influence of the maximum fluidity attained by the charge on the physical quality of the coke or char produced. As a first approach to the problem, researchers investigated high-melting-point pitches, which are relatively simple carbonaceous materials. The plastic properties of these pitches, prepared specially for this work, varied greatly; their fluidities, as measured by the Gieseler plastometer, covered most of the fluidity range characteristic of coking coals. Blending these pitches with increasing pro-portions of fine coke progressively reduced their fluidities. Coal-pitch and coal-coke blends also were treated; their fluidities were varied by changing their blending ratios. The various blends were carbonized in a small-scale carbonizer and the resistance of the carbonized residue (char) to abrasion was determined in a small-scale tumbler test, using the Roga drum.

Jan 1, 1960

By C. L. Brown

The frequency of mine fires during recent years, with an apparent increase in recent months, has focused attention on the necessity of reducing this hazard by every means possible. Investigation reports are available on 51 mine fires of electrical origin between August 15, 1949, and August 16, 1954. Nine other fires in the same period were suspected as being of electrical origin. Every mine fire is a potential hazard to underground workmen; it is remarkable that only six lives were lost as a result of these fires, since the injury list was very high. Modern mining methods, with increased power demands and extended distribution systems underground, involve greater electrical hazards and possibilities of costly production delays as a result of inadequate electrical service. Improvements in electric-power-distribution facilities in many underground coal mines is desirable. The purpose of this paper is to show the need for this improvement as revealed by studies and investigations of electric-power-distribution systems representative of those in a large number of coal mines.

Jan 1, 1955

By S. S. Todd

[The purpose of this investigation was to obtain, heat-of-formation values a four Common titanates and, to conjunction with other requisite data, to derive free-energy-of-formation values In tem peratures in the range of 1,600°-1,800° K. T ht four titanites are tricalcium ?ditanite !['a¬spheremr?raritanar( rint-tir.rniurn rill( 1 This rc rr,rt sul,rlc?nu?nIs :r },r; vinu~ hul,lrc.irse,n3i n wlti h eht-rmnnIN-ti i n c {ar.a ai?rc? pu -,csseeri (or, 11 in(c-rnxiLIic co mrc+unrls conraininL~ rir:,niurrl. 'f Lac? !1~:)mc? c?xpcrirnc'ntnl n-ut rhod w,i. rna~loycul. lic?.ats of for rn:ltion of rlre comi?c,unr4~ it 29S.N. ut re mca,urc?,l by tioItl[ion e':iIorrr)utrv, using a ctrneaR }ryrlrc,fllanric-hY rir~chlorie- ,aci l mixttrrt .is rhr c-zle~rinrrrric- fluid and rc.actic~n rtu,liura}.]

Jan 1, 1956

By Ben E. Lindsly

The study of "bottom-hole' samples follow,-is in natural sequence the study of samples3 obtained under high pressures at the well heads of flowing wells. The principal object of this phase of gas-solubility research, started actively in January, 1530, was to gain a more accurate knowledge of the physical and chemical characteristics of the oil-gas mixtures that exist in natural reservoirs. In possession of actual data regarding the condition of the oil; the quantity of gas liberated from solution upon dimunition of pressure; and the relative volumetric proportions of gas to oil at various pressures throughout the flow string in a well, it should be possible to predict, with a fair degree of accuracy, what physical changes these mixtures would undergo throughout the life of a pool. Such information not only is important in designing flow strings in flowing wells but is important also in solving problems relating to pumping efficiency and the power required for pumping. Although certain fundamental rata Mere obtained in the stud of samples taken at the well head, "bottom-hole" samples are more representative of subsurface mixtures of oil and gas because they are obtained at reservoir temperatures, and before the oil has had the opportunity of intermingling with extraneous gas; that is, gas which either was not in solution originally, or which was liberated from solution at some higher pressure, and later became mired with the original undissolved gas.

Jan 1, 1933

By C. C. Furnas

Despite the fact that a great many industrial processes depend on efficient contact between a gas stream and a bed of broken solids for their operation, the data in the literature are very meager. Several investigations3 have been undertaken, but the work has been limited in scope and application. BUREAU OF MINES PROGRAM OF RESEARCH For the past 10 years the United States Bureau of Mines has been engaged in research with the object of formulating a more or less complete quantitative theory of the workings of the iron blast furnace. Obviously, in order to do this one of the essentials is to have considerable definite information on the laws of gas flow through beds of broken solids. This report in a brief summary of the experimental work on the problem which has been done at the North Central Experiment Station. The complete report with more detailed tabulation of the data and explanations of the experimental procedure is in process of publication in the form of a bulletin.

Jan 1, 1928

By J. H. Wiggins

The evaporation of crude oil without doubt causes one of the largest single losses to which the oil is subjected after it is taken from the ground. The few days during which crude oil is stored on the lease before being taken by the pipe line, causes an aggregate loss per year from evaporation estimated at 122,100,000 gallons of gasoline in the Mid-Continent field alone. This has a value, at 22 cents per gallon, of $26,880,000 and represents about 3 per cent of the total gasoline produced in the United States from all fields and all sources. The following table shows this in more detail:

May 1, 1920

By John C. Machisak

THE INJURY data and experience at quarries and related plants of the United States are presented in this publication under the following general sections (A) General injury experience: Tables 1-3: Current data on number of injuries, injury-frequency rates, location, accident agency, degree of injury, and related employment data. (B) Injury experience at different kinds of quarries: Tables 4-5: Current data on number of injuries, injury-frequency rates, location, accident agency, degree of injury, and related employment, data. (C) Injury experience by States: Tables 6-20: Current data on the number of injuries, injury-frequency rates, accident agency, degree of injury, and related employment data. (D) Selected injury data: Tables 21-30: Current data on various selected factors of operating conditions at different kinds of quarries, including employment size-groups, length of shifts, comparative severity of injuries, and injury data and related employment experience at dimension-stone and nondimension-stone quarries and at underground quarries. (E) Historical injury experience: Table 31: Injury and employment data on the quarrying industry for 1911 through 1957. Statistical data on injuries and related employment in the quarrying industries have been collected annually from the operating companies since 1911. Reporting to the Bureau of Mines is voluntary; there is no Federal law compelling operators of quarries and related plants to supply such data. Data presented herein may not be complete for the entire industry. They are however, believed to be representative of the hazards common to all quarry and related workers. Moreover, the figures are comparable as between States-a significant fact in view of the lack of uniformity among the States with regard to the classes of injuries covered by State reports and other factors that tend to make it impracticable or impossible when using State records to

Jan 1, 1960

By John Nagy

Dust explosion data obtained in laboratory studies by the Bureau of Mines are presented for activated carbon, asphalt, charcoal, carbon black, coal, coke, gilsonite, graphite, lignite, miscellaneous carbons, pitch, tunnel dust, and mixtures of these materials with other ingredients. The explosion hazard is shown to increase as the volatile content of the dusts increases.

Jan 1, 1965

By C. S. Allbright

This report gives the results of analyzing three groups of crude shale oils by the Bureau of Mines procedure:4/ (1) Oils produced by standard Fischer assay determinations on oil shales from Brazil (Paraiba Valley) and the United States (Colorado); (2) oils produced from Brazilian shale by different retorting methods; and (3) oils from high-temperature retorting of Colorado oil shale in the Entrained Solids retort. It is the second in a series presenting data obtained by analyzing crude shale oils from various sources. The series furnishes information on the general characteristics and compositions of a wide variety of shale oils. Use of a standard analytical method on all samples facilitates comparison of different oils. The 18 oil samples analyzed in this project comprised 3 from assays of Brazilian and Colorado oil shales in the Fischer retort, 9 obtained by processing Brazilian shale in various other units, and 6 from entrained solids retorting of Colorado shale at 1,000° to 1,500° F. The crude oils from Brazilian shale contained about half as much nitrogen as the Colorado oils. Properties of the Fischer assay oils from Colorado shales agreed with some data that relate grade of the oil shale with properties of the crude oil from the Fischer assay. Comparison of results from Fischer assays of oils from the foreign and domestic shales shows that the oil from Brazilian shale contains more low-boiling material and less residuum than either of the two from Colorado shale. This fact is reflected in lower specific gravity, viscosity, and carbon-residue values for the Brazilian oil. Retorting Brazilian shale in the Entrained Solids unit at 1,120° F. produced an oil whose boiling range was generally lower than the boiling ranges of oils obtained by processing in three other retorts at conventional temperatures. The quality of crude oils from high-temperature retorting of Colorado shale in the Entrained Solids process varies with retorting temperature. As the temperature is raised within the range 1,000° to 1,500° F., the amount of the naphtha fraction in the crude oil increases to about 35 percent and the aromaticity to 98 percent.

Jan 1, 1956

By John E. Lambert

Automatic control of drum head continuous mining machines was investigated as a means of reducing respirable dust generated and operator variabitity. Literature survey, manufacturer interviews and mine visits were the major information sources. Technically feasible automation concepts were Identified to control sump and shear rates, cutter head elevation limits and sumping distance. These are the elements of a programmed cutting cycle which maintains peak penetrating force on the cutter, to maximize depth of cut and therefore reduce dust generation. Based on the industry surveys, successful underground hardware demonstrations must be completed in order to stimulate the market demand for these advanced control features.

Jan 1, 1979

By Harry R. Nicholls

Six different chemical explosives were detonated in a test series to com-pare their relative performance in granite. From 5 to 255 feet from the detonation point, strain, acceleration, and particle velocity were recorded and analyzed for amplitude and pulse shape. Strain energy was calculated from strain data, and displacement data were obtained from particle velocity data by integration. The results show that explosives which have a characteristic impedance more closely matching that of the rock generate larger peak amplitudes than explosives with a lower characteristic impedance. The results also show that as the ratio of characteristic impedance of exp1osive-to-rock approaches unity, more rock is crushed and a larger percentage of the avail-able explosive energy is transferred to the rock as seismic energy. The effect of characteristic impedance is shown to be greater than the effect predicted from acoustic theory and is believed to be indicative of shock wave effects at the explosive-rock boundary.

Jan 1, 1965

By Jr. Hazen

Two statistical techniques, the mean-square-successive-difference test and correlation, are used to investigate the problem of assigning an area of influence to an assay. Data from five hydrothermal deposits, Climax molybdenum, Cebolla Creek titaniferous iron, San Manuel copper, Piedra Hueca copper, and Butte copper, are studied. Two groupings of the assays are used for the mean-square-successive-difference tests. One group involves an increasing sample volume by reaveraging assays to represent a longer sample intervals, the other by regrouping assays to represent longer sample intervals without a change in sample volume.

Jan 1, 1967

By B. W. Madsen

A modified transpiration apparatus was devised by the Bureau of Mines to permit rapid and accurate measure of the vapor transport and vapor diffusion coefficients of antimony sulfide (Sb2S3) and other compounds at temperatures to 1,045 K. The apparatus was equipped with dual condensers and valves to switch the flow of vapor in a fraction of a second from one condenser to the other, thus allowing short-interval sampling under equilibrium conditions. Reliability of the technique was established by measuring the vapor pressure of ZnC12 as a function of temperature and comparing the results with published data. As part of an investigation of the vapor concentrations and species of accessory element sulfides associated with copper and zinc smelting, the apparatus was used to measure the rate of vapor transport and diffusion coefficients of vapor over liquid Sb2S3 as a function of temperature between 870 and 1,045 K. The calculated vapor density was combined with published direct measurements of vapor pressure to calculate the average molecular weight of the gaseous species. Average molecular weight of the vapor in equilibrium with Sb2S3 ranged from 286 to 112 g/mol over the temperature range studied.

Jan 1, 1983

By O. M. Schaus

The following is a description of the methods employed at the Eureka-Asteroid mine, which is situated on the Gogebic range, at Ramsey, Mich. The mime is operated by the Castile Mining Co. under the direction of Oglebay Norton & Co. This paper has been prepared in accordance with an outline furbished by the United States Bureau of Mines, and in one of a series, on mining methods and costs covering the principal minim operations throughout the United States. ACKNOWLEDGMENTS The author acknowledges the assistance of the mining organization of the Castile Mining Co. in the preparation of this paper.

Jan 1, 1930