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By W. Z. Yin

With increasing of mining depth, many iron ores in Liaoning Province contain carbonates such as siderite and ankerite. The emergence of these carbonates in ores creates a fatal impact on the running producing process of anionic reverse flotation in Dong Anshan Sintering Plant, which leads to ?concentrate and tailing no separated?. And its reason is still unknown. Moreover, siderite, despite that its ferric theoretic grade is only 48.2%, however, do not affect the blast furnace utilization factor, therefore, can be used as raw materials in ironmaking. In order to solve the separate problem of iron ore containing carbonates, five pure minerals, martite, magnetite, quartz, siderite and ankerite, were selected for a series single flotation experiment. The aim was to discover the flotation difference of these minerals, furthermore, to explore a new flow sheet for the iron ore containing carbonates. The results of single mineral flotation experiment reveal that the combination regulators, starch and CaCl2, in different pH extent, can make these minerals taking on obvious flotation difference, which make it possible to process the iron ore containing carbonates. A new flow sheet, step-flotation, to process iron ore containing carbonates is explored, that is, first step, direct-flotation processing, is to eliminate the bad effect that the carbonates bring in flotation system by collecting carbonates under neutral condition; the second step, reverse?flotation processing, is to get qualified iron concentrate by collecting quartz under alkaline condition. Manual mixed ore sample were processed successfully through this new flowsheet under proper reagent system, which has absolute advantage compared with routine flowsheet. Actual ore sample of compound magnetic separation concentrate were processed successfully both open and closed circuit experiment through this new flowsheet. SEM and EDS were used to probe the reason why carbonates affect the regular processing. It is analyzed that moderate floatability of siderite and its coating on the surface of hematite and quartz make the phenomenon ?concentrate and tailing no separated?. This research provides a reasonable processing scheme for iron ores containing carbonates and can be used for reference in processing other complicated, refractory iron ore.

Jan 1, 2014

By M. Kargar Razi

According to the unique properties and many applications of nano silver powder, it was prepared from acid leaching tail solution. The low value residual gold and silver ions were occurred with fellow heavy metals as pollutants (Fe2+, Cu 2+and Zn2+) in acid leaching tail solution in Mouteh gold mine in Iran. Preparation of nano silver particles was achieved in two steps: first, by addition of ammonia as separation step and second by using different reagents as precipitation and extraction steps. Different controlled parameters were including pH, residence time and temperature, mixing time, and reducing reagents to metals molar ratio. Acid leaching process was carried out with sulphuric and nitric acid via suitable reductants. In order to remove copper, zinc, and silver ions from solution, all of the conditions were controlled. The optimum conditions for preparation of nano silver powder with less than 90 nm were pH 10.5, hydrazine/methanol to silver molar ratio of 3 to 4, and reduction time of 5 min in 45 °C. The results were evaluated via SEM, A.A and UV- Vis spectroscopy analytical methods.

Jan 1, 2014

By A. A. Rogozhin, E. G. Likhnikevich, S. I. Anufrieva, A. V. Kurkov

"Russia is among the nations holding the world's largest lithium ore reserves. Lithium is of key importance for the global economy. Therefore, it is important to review the current state of technology research aimed at finding the most effective solutions for the recovery of lithium from promising reserves in Russia. In Russia, a number of process solutions for the flotation of spodumene into salable concentrate (5% Li2O) have been implemented at the earlier existing complex low-grade ore concentration project. By applying these solutions, a sample of high-grade spodumene ore (4.7% Li2O) of the Greenbushes deposit was processed into a spodumene concentrate (7.5% Li2O) at a high recovery (~93%) of lithium. In Australia and Canada, new processes have been developed for the recovery of high-grade spodumene concentrates from high-grade ores using dense medium separation and flotation. For the recovery of mica lithium concentrates from low-grade ore, a flotation process was developed in Russia using the cationic collector ANP-2 and Oxifos-B as an additional collector. Low-grade ore containing 0.14% of lithium oxide was processed into a 2.7% Li2O concentrate. New hydrometallurgical lithium concentrate and ore processes are developed to avoid high-temperature (>1000 °C) roasting. The Sileach process (Australia) includes leaching of lithium ore with sulfuric acid in the presence of a halogen-containing component at a temperature of 95-115 °C. In the Russian process, lithium is recovered into an alkaline solution from low-grade spodumene ore in a pressure alkaline leaching environment (250 °C, NaOH concentration > 300 g/l). The developed concentration and hydrometallurgical methods will allow to design on their basis efficient processes for recovering salable products for hi-tech industries from lithium ores.INTRODUCTION Lithium has many unique and important properties. It is the least dense hard metal. Its alloys have some of the highest strength-to-weight ratios. Lithium has the lowest melting point of all known solid elements and is used as a highly-effective heat transfer medium. The high demand for lithium is due primarily to its unique electrochemical potential and low thermal expansion coefficient. It is used in the production of glass and ceramics, in petrochemicals, metals, medical and other industries. Since the late 20th century, the electronics industry has been the largest consumer of lithium. In recent years, lithium has attracted much attention also as an important component of ultra-lightweight electronic devices. It is also the preferred metal for electric batteries used in mobile electronic devices, vehicles, household power generators, making it an important resource for the development of environmentally friendly technology. Leading automotive brands have ambitious plans for the production of electric cars — Tesla Motors, VW, Toyota, GM, BYD Auto. It is expected that the production of electric vehicles alone will triple the demand for lithium by 2025. A sharp increase in the production of lithium is expected. Lithium has all the prerequisites to become a strategic resource of the 21st century. (Deutsche Bank, 2016; Bradley et al, 2017)"

Jan 1, 2018

By L. C. Zhou

The floatability of andalusite and associated minerals are studied and their action mechanisms of andalusite and associated minerals with collector alkyl benzene sulphonate are also studied. Through the mensuration of electrical potential and the infrared spectroscopy, as well as desorption tests, it is confirmed that the interaction of andalusite with sodium dodecyl benzene sulphonate (SDBS), is in addition to physical adsorption, but also is chemical adsorption. The study results of the pure minerals are used for the flotation of actual andalusite mineral. By flotation from contain-ing 45.68% andalusite ore, the fine andalusite concentrate is gained which Andalusite grade is 85.88%, containing Al2O355.29% and Fe2O3 less than 1.5%.

Jan 1, 2014

By Sushanta Majumder

The physico-chemical characteristics of raw materials used for the production of iron ore pellets have a strong influence on the productivity of pelletization operations and on the quality of pellets. Since iron ores from different sources are used for making iron ore pellets and since the quality of the ores varies with time, there is a need to optimize and control pellet plant operations on a regular basis to achieve optimum productivity while maintaining pellet quality within the desirable specifications. In order to achieve this objective, a model-based on-line optimization system was implemented on two industrial scale induration furnaces. The optimization system consists of a rigorous mathematical model of the induration process, a model for the permeability of the bed of pellets, a statistical model for the quality of iron ore pellets and an optimization module based on sequential quadratic programming. The rigorous model is tested on-line using the wind-box temperature available real-time. The process was optimized to enhance induration furnace productivity for the given constraints on pellet quality parameters such as the cold compressive strength (CCS) and Tumble Index (TI), and other equipment design parameters. Process variables such as induration machine speed, cold air flow rate and hood temperature profile were used as the optimization variables. The on-line optimization system was successfully implemented in two industrial induration furnaces and lead to enhanced productivity. Details of the on-line optimization system and results of process optimization will be presented.

Sep 1, 2012

By P. Radziszewski

In comminution research, ore breakage and wear are usually studied independently of one another. Much of this is due to the fact that wear is usually a slow process compared to ore kage. However, the abrasion wheel test used to determine the abrasive wear contribution to total steel media wear provides the opportunity to study not only abrasive wear and friction but also ore breakage. In this paper, we will explore the use of the abrasion wheel wear test device to study abrasive wear, friction and ore breakage using standard Ottawa foundry sand. We will look into the feasibility of applying the work index as well as t10methodologies to this test set-up. We will also look at how the work index results evolve with abrasive wear and friction. We will then discuss the merits of pursuing the use of this abrasion wheel test for not only wear characterization but also breakage characterization.

Jan 1, 2014

By T. Tumidajski

The purpose of the separation processes in coal processing is obtaining products of certain ash contents. In the most of cases it is assumed that the separation process is described by one, selected parameter, which usually is grain size or material density. The separation may be described by means of statistical distributions of random variables, what allows forecasting the separation results of certain enrichment method. There are very well known the applications of approximations of Tromp separation curves or distribution functions of Erasmus, Meloy or Weibull. It is necessary to say that if the fitness of the approximation more suitable, then the characteristics of the process itself is also better. In purpose of obtaining more appropriate results, these methods were modified by application the mathematical functions, as i.e. hyperbolic tangens function. Furthermore, on the basis of empirical data, so-called interpolations may be performed in purpose of getting more appropriate results of approximation. One of the most known techniques of interpolation is Hughes method. This method for interpolating standard data involves breaking down each interval into a number of smaller sub-intervals. The results of such one-dimensional approach not always contain the full in-formation of the searched distribution. It happens because such interpretation of the problem is not completely correct. In practice, the separation process depends not only on the one parameter (i.e. grain size), but also on many other features characterizing certain material (i.e. its density). It seems then that in some cases the application of multidimensional grain characteristics distributions will be more appropriate. In this paper, the technique of joining the distributions of grain size and density by means of so-called Morgenstern distributions is shown. The general form of these distributions is as following:

Jan 1, 2014

By R. Lestari

Newmont Batu Hijau operates with an accelerated mining rate to optimize life of mine (LOM) project economics. This results in a portion of ore mined being stockpiled for reclaim and processing throughout, and at the end of mine life. LOM economics can be further enhanced by preserving stockpiled ore value by mitigating oxidation effects. A detailed stockpile ore oxidation study was conducted to: ?? Develop a practical understanding of how oxidation affects ore value; ?? Determine how oxidation rate can be controlled, and; ?? Determine how oxidation effects can be mitigated to preserve ore value. The result of the study is a stockpile management strategy that significantly reduces oxidation related losses and, implementation of that strategy within practical constraints. Implementation includes installation of Controlled Potential Sulfidisation (CPS) flotation to facilitate oxidised sulfide copper recovery and, recovery of dissolved copper from stockpile drainage solution into saleable product. This paper describes the study results including managing and predicting stockpile oxidation with time, monitoring performance of implemented CPS flotation and recovery of dissolved copper from stockpile drainage. These are essential elements of successful long term mine operation in Batu Hijau.

Jan 1, 2014

By Daniel Saramak

"Issues concerning effectiveness of the high-pressure comminution process in technological circuits of copper ore treatment were presented in the paper. Crushing processes taking place in high-pressure grinding rolls devices (HPGR) are currently one of the most efficient methods of hard ore size reduction in terms of the energy consumption. The HPGR products are characterized by a fine particle size and the micro-cracks formation in individual particles, which appear in downstream grinding processes, decreasing their energy consumption. The purpose of this paper was to analyse the effectiveness of a ball mill grinding process depending on the changeable conditions of run for the HPGR crushing process. The research programme carried out included crushing tests in the laboratory scale HPGR device at various settings of the operating pressure volume and selected qualitative properties of the feed material (i.e. particle size distribution). Particle size distribution analyses of all HPGR products were performed and in the next stage the material was a feed to the ball mill grinding process. Grinding process kinetics were investigated through the determination of mass recoveries of individual particle size fractions after defined grinding time intervals. The models, defining the grinding process effectiveness as a function of changeable conditions of HPGR process run, were determined on the basis of obtained results. Based on these models the optimal grinding time in a ball mill was specified which is, in turn, the basis for optimization of operation of the technological comminution circuits for a given material type. The obtained results proved that the application of HPGR devices in a given copper ore comminution circuit may improve the effectiveness of the downstream grinding process which leads to improvement of the entire circuit work efficiency through decreasing the process energy consumption and enhancing product size reduction."

Jan 1, 2014

By S. Koca

Vast amount of fly ash, bottom ash and slags, are produced each year due to coal combustion in thermal power plants. These products consist of mainly unburned carbon and inorganic compound (such as: silica, alumina, iron oxides, magnesium oxide, phosphorus oxide etc.). These are valuable minerals and can be recycled or recovered if properly processed. One third of the material find application as an ingredient in cement and other construction products, the rest is held in dams or similar dumps, which results in a hazardous impact on the environment, polluting soil and ground water. The unproductive use of land, the associated long term financial burden maintenance and negative environmental impacts have led to realization that alternative uses for combustion by-products as a value added product beyond incorporation in construction materials are needed. At present, there is an intensive search to increase their uses. Other uses of coal combustion residues include as raw material in brick and ceramic tile fabrication, as filler in plastics and paints, extraction of valuable mineral materials, production of zeolites and soil and mine waste treatments. Separation of unburned carbon from bottom ashes by means of flotation was conducted in order to increase the possibility of the recycling of coal combustion wastes. In the flotation experiments collector, dispersant and frother amount, pulp density and pH were tested as variables. After first stage flotation experiments, at optimum conditions, the carbon content was reduced down to 5.58 % in the tailings fraction. This fraction meets the industrial specifications and can be utilized as a cement additive. At the same conditions the carbon content of the concentrate increased to 44.72 % at a carbon recovery of 65.81 %. After the cleaner stage flotation experiment the carbon content of the product is enhanced to 62.53 %. This fraction can be blended back into the coal feed to the power plant boilers.

Jan 1, 2014

By Massimiliano Zanin, William Skinner, Owusu Clement, Jonas Addai-Mensah, Daniel Fornasiero

This paper highlights the importance of pulp aeration in the selective separation of chalcopyrite from chalcopyrite/pyrite mixtures of varying pyrite content (20-80 wt.%). Laboratory batch flotation studies and oxygen demand tests were performed to predict the optimum amount of air required for the selective separation of chalcopyrite from pyrite. The pulp oxygen demand was shown to increase with increasing pyrite content but decrease with time as more air is introduced into the system. Complementary batch flotation tests showed significant improvement in chalcopyrite flotation under moderate pre-aeration of the pulp. However, a continuous decrease of chalcopyrite flotation was observed under highly aerated conditions. The amount of air required to achieve maximum chalcopyrite flotation recovery correlated positively with the mass fraction of pyrite in the pulps. The greater the wt.% of pyrite in the chalcopyrite/pyrite pulp, the longer the aeration time required. The optimum aeration time was established as the time before which the oxygen consumption rate constant reaches a bottom plateau. Surface analysis (XPS) indicated that the continuous decrease in pyrite recovery observed with increasing aeration time was due to the formation of more iron oxy/hydroxide on its surfaces, the same species accounting for the decrease in Cp recovery after prolonged aeration.

Jan 1, 2014

By S. Jeon, N. Hiroyoshi, N. Kitajima, S. Tanaka, M. Ito, R. Pongsumrankul, C. B. Tabelin

"Gold (Au) extraction is inefficient when crushed waste mobile phones (WMPs) are directly leached by ammonium thiosulfate likely because of the cementation/precipitation of dissolved Au in the presence of base metals like copper (Cu), iron (Fe) and/or aluminum (Al). This study applied physical separation techniques to remove base metals as well as plastics and concentrate the Au containing fractions from WMPs prior to leaching. Coarse fraction of crushed WMP (+2-5.6 mm) was pretreated by jig and magnetic separation to remove plastics and base metals like Fe, Cu, and Al, while the fine fraction (-2 mm) was pretreated by flotation, and float and sink separation. The leaching results showed that Au extraction increased in both of the size fractions. In the coarse fraction, Au extraction increased by as much as 2-fold after pretreated (from 4 to 7%). Improvement of Au extraction in the fine fractions after pretreatments were even more dramatic. Au extraction increased from 4 to 61%. These results indicate that physical pretreatment to remove co-existing common metals and plastics is effective to improve Au extraction from WMPs. INTRODUCTION Global sales of mobile phones are expected to increase steadily in the foreseeable future because a lot of people buy newer phones with upgraded and more advanced functions almost every two years, which leads to the higher generation of waste mobile phones (WMPs). WMPs contain a wide variety of materials including plastics, glasses, base metals and precious metals such as gold (Au). Among all the valuable materials in WMPs, Au accounts for over 80% of its total metal price (Park et al., 2017), so recovery of Au from WMPs is needed."

Jan 1, 2018

By Zhangm Zeqiang, Manman Lu, Hanquan Zhang, Hong Yu, Jintao Fu

"Pelletizing is an important technique in the ironmaking industry. Artificial and natural magnetites are materials that are widely utilized in the iron ore pelletizing process. In this work, the pelletizing characteristics of these two types of magnetite have been investigated in detail. The obtained results shown that in contrast to natural magnetite, the artificial magnetite concentrate exhibits stronger hydrophilicity, lower electronegativity, larger specific surface area, and rougher surface. In addition, the green pellets produced from the artificial magnetite concentrate are characterized by a higher compressive strength as compared to that of the pellets obtained from the natural magnetite concentrate. However, the shock temperature of the artificial magnetite pellets around 255 C is significantly lower than the threshold specified by the industry. The balling characteristics of the material obtained by mixing 20% of the artificial magnetite concentrate with 80% of the natural magnetite concentrate are considerably improved with respect to those of the individual components.INTRODUCTION Pelletization is an essential process of the ironmaking industry in China. Since the pellets produced from iron ore exhibit high mechanical strength, good particle granularity, and uniform shapes, pelletizing high-grade iron ores with good metallurgical reducibility can lower the coke ratio, improve their technico-economic index, and reduce the cost of processing pig iron in blast furnaces[1, 2]. Presently, high-grade magnetite is a material utilized for pelletizing various iron ores across the globe. However, its natural deposits have been depleting rapidly in recent years; as a result[3], China’s dependence on the foreign high-grade iron ores exceeded 70% in 2009 and reached the level of 87% in 2016. Hence, possible methods for the efficient cultivation of limonite, siderite, hematite, and other refractory minerals that correspond to low-grade, finely sized, inhomogeneous, and scattered iron ores have attracted significant attention [4, 5]. In particular, magnetization reduction roasting and magnetic separation techniques, which are widely utilized for obtaining high-grade artificial magnetite, represent effective ways of processing iron ores that can alleviate the scarcity of natural magnetite resources [6, 7]. The artificial magnetite produced by magnetization reduction roasting exhibits different characteristics as compared with those of natural magnetite (including the degree of hydrophilicity, surface potential, specific surface area, and other surface physicochemical properties[8-11], which significantly affect its pelletizing behavior. In this work, the surface characteristics of artificial and natural magnetites are investigated in detail, and their effect on their pelletizing properties (such as green ball strength, heat stability, and pelletization rate) are examined."

Jan 1, 2018

By Z. H. Zhang

Shizhuyuan is a world-class WO3, Mo, Bi and CaF2 poly-metallic deposit; it has rich reservation, but great difficulty in ore?s processing; thereby, for many years, it has been the target problem of beneficiation technologies. This paper, while briefly reviews its main scientific and technological advancement, pays special attention to the complete set of new technology and technical index achieved in recent years, which is characterized by using full-floatation flow-sheet as the backbone flow-sheet, explores some key factors influencing tungsten floatation, and presents a brief introduction to such new equipment as flotation column and comprehensive utilization of fluorite.

Jan 1, 2014

By E. Scheepers

Within a phosphorus producing submerged arc furnace it was found that the continuous fluctuation of the furnace between a flowrate-driven state (high throughput) and a thermodynamic-driven state (low throughput) caused both techniques to have similar overall, predictive abilities and resulted in a linear, ARX-type, adaptive prediction model as the model of choice. Secondly, this pre-diction model was developed, tested and then shown to have a reasonable, 8-hour-ahead predictive accuracy (R2, coefficient of determination) of 30% (±6%) on future Pslag values. This inherent relationship exists because, at the precise moment of a Pslag prediction, the furnace already contains the metallurgical memory (input variables to the linear model) needed to ensure that some predictive possibilities will always exists - all as a result of the long residence times in the furnace. Residence time, however, is not a directly adjustable variable but rather a fully dependent variable and a function of an array of interconnected and interactive variables. In fact, this applies to virtually all input variables, reemphasising the importance of innate metallurgical memory. Thirdly, predictive control possibilities were explored by simulating the set-points of two fully independent variables used by operators to control the process: the ratio of fixed carbon-to-P2O5 and the ratio of silica gravel-to-pellets. This linear, predictive control model showed only a slight improvement with an 8-hour-ahead predictive accuracy of 35% (±7%). This highlights how ineffective current adjustments are in optimally steering the process and how difficult even incremental improvements in feed-forward and predictive control can be. Finally, it is shown that fundamental design-, sampling- and process restrictions currently associated with the process will always limit the predictive and especially control accuracy or meaningfulness of any dynamic model. These restrictions include the size of the furnace resulting in long residence times, 8-hours sampling intervals, an extremely complex and interactive process and a 16% spatial analyses variation on the Pslag values ? the very value that the model is to predict. The point is made that, given the current status quo, even the perfect dynamic prediction model can not improve on an 8-hour-ahead prediction of 30% (±6%). This barrier can only be pierced with e.g. tidier and more frequent sampling regimes and other upfront capital investments, a decision that becomes a cost accounting exercise and that can only be taken by the management structure. An investment demanding ever-increasing attention is CFD software and it?s potential to shed more light on the complex interactions within the furnace.

Jan 1, 2014

By L. Y. Wang

In order to produce the iron and steel products with high quality and decrease the output of steel tailings, the quality of molten iron is a critical factor for iron and steel companies, especially the content of sulfidic in molten iron. Hot metal pre-treatment, an important and effective method to desulphur, is widely used in steel production. Millions of tons of slag from desulphurization and slag skimming are produced each year in China, and many more times this amount is stored in slag dams because of the lack of effective means to deal with it. In order to achieve the goal of sustain-able development, recycling these slag becomes necessary. The main objective of this paper is to study the composition characteristics of slag that from desulphurization and slag skimming. The sample was obtained from Anshan Iron and Steel Group Corporation, processed by hot metal pre-treatment. In this study, the chemical components and the mineral compositions of sample were tested. The results of chemical components and iron chemistry phase analysis showed that the iron and sulphide content in this sample were high, and the iron products existed mainly in the form of magnetite, metallic iron, ferrosilite. X-ray diffraction (XRD) and scanning electron microscope (SEM) results indicated that the sample included metallic iron, ferrate, wustite, metasilicate, aluminate, aluminosilicate, white lime and soon. Grading magnetic separation test work showed that magnetic separation was an effective method to recovery iron products and decrease the sulphide content in concentrate, and the tailing could be used as the raw material or padding in cement production.

Jan 1, 2014

By Susanna G. de Jager, Francis W. Petersen

"The aim of the project was to develop a methodology applicable to different South African coal types to be able to predict with a high degree of certainty what kind of reagent will be suitable for flotation of a certain coal type.The study included 5 coal samples from different collieries and included Highveld seam 3 and 4 coal (as one sample), Waterberg coal (zone 10 -11), Highveld seam 5 upper coal and Witbank seam 2 and seam 4 coal. Seam 3 and 4 (mixture) coal, Waterberg and the seam 5 upper coal were all found to be vitrinite rich coals. The coal characterisation study included petrographic analysis, proximate analysis, float-sink analysis, oxygen-containing functional groups, surface extraction, flotation release analysis and contact angle measurements.The flotation tests showed that the best reagents to float all of the coal samples studied are iso-decanol and dodecene. These reagents produced flotation products that are near to the release curve. Statistical relationship for predicting ash content and yield that can be expected for a certain coal type and selected collector was obtained. From the relationship, the accuracy of the yield is above 95% (p-value below 0.05) with a linear regression of 0.9289. The accuracy of the ash is slightly lower with a linear regression of 0.7841 but also above 95%."

Jan 1, 2003

By X. Q. Ma

The beneficiation test on low grade phosphate ore from a state of Russia is carried out. The rougher-cleaner ? re-cleaner system is used in the flotation process, The fineness of grind is 39.07% minus 200 mesh. The result indicates that concentrate containing 31.25% P2O5 can be obtained from the flotation feed assaying 6.18% P2O5, with 93.54% P2O5 recovery. The test result is also a guideline for further development of some currently operated phosphate beneficiation plants.

Jan 1, 2014

By M. L. Cao

In this study, a montmorillonite organo-intercalation compound (MOIC) was synthesized by using a Na-modified bentonite (NaB) as a matrix and hexadecyltrimethylammonium (HDTMA) bromide as an intercalating reagent under microwave irradiation. The synthesized products were characterized by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), organic carbon content measurement, and adsorption density determination. The results show that, at 10% suspension concentration and 10 minutes irradiation in a 130-W microwave oven, the basal spacing d(001) of the synthesized MOIC increases to 2.209 nm from the original 1.218 nm of NaB. The MOIC has much higher adsorptive densities to nitrobenzene and aniline from aqueous solution than the NaB. The adsorption isotherm of nitrobenzene on the MOIC is linear, and the adsorption is mainly the result of nitrobenzene?s preferred partition in MOIC over aqueous solution due to MOIC?s hydrophobicity. The adsorption isotherm of aniline on MOIC follows the Freundlich equation and the increased adsorption is not only the result of aniline?s preferred partition in MOIC over aqueous solution but also that of the MOIC?s surface adsorptions.

Jan 1, 2014

By K. C. Corin, M. S. Manono, R. M. Manenzhe, J. G. Wiese

"Environmental concerns necessitate the recycling of process water within mining operations. Given that recycled water is chemically different from fresh water, and collectors are added such that they adsorb at the liquid-particle interface, changes in the aqueous phase are expected to affect collector adsorption. A Finnish nickel-copper ore was floated in synthetic plant waters of varying ionic strengths and plant waters obtained at Boliden Kevitsa Mine, with aerophine and sodium isopropyl xanthate as collectors. Of the tested waters, the copper thickener overflow was the least conducive to xanthate adsorption and valuable mineral recovery. The nickel thickener overflow, standard process water, and raw water were the most conducive to xanthate adsorption. For the raw water and nickel thickener overflow, increased adsorption correlated with increased valuable mineral recovery. Further, recycling xanthate retained in water affected the selectivity of the collector and hence the concentrate grades.INTRODUCTIONFlotation is a separation process that exploits the differences in the surface properties of the particles being separated. The efficiency of separation is dependent on the degree of hydrophobicity achieved by the particles meant to be floated, which are, in most cases, valuable minerals. The hydrophobicity is in turn dependent on the adsorption of the chosen collector onto the surfaces of the floated particles (Fuerstenau, 1984; Taggart and Hassialis, 1946). Empirical findings suggest that species dissolved in solution strongly influence collector adsorption and overall flotation response (Fuerstenau and Chander, 1986). Due to environmental concerns, it is becoming more pertinent for mining plants to recycle process water and hence limit the usage of potable water. There is an interest to ensure minimal discharge of plant water into the environment, as this water is typically polluted with process reagents that may render it toxic (Levay et al., 2001)."

Jan 1, 2018