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By Gábor Mucsi, Barnabás Csoke, Viktor Mádai, Zoltán Molnár, Viktor Török, Ádám Rácz

The application of the stirred media mill in dry mode came to the front only in recent years, but at the same time several questions arise, such as aggregation, agglomeration, sticking on the liners and the grinding media. During high energy milling, not only the particle size reduces, but among others, in numerous cases the crystal structure and the amorphous state of the material also change due to the mechanical activation taking place. The present paper deals with experiments carried out on the ultrafine fly ash grinding in dry mode at various grinding conditions in a stirred media mill to investigate the mechanochemical effect and the energy efficiency of the mill. During the experiments the particle size distribution, particle shape, specific surface area, amorphity and crystal structure of the products were examined. The product related stress model was used for the evaluation of the effect of milling parameters on the mechanical activation. It was found, based on the experimental results, that there is mechanochemical effect on crystal structure of fly ash in the stirred media mill, as it was revealed by X-ray diffraction and FTIR measurements. The experimental results made it possible to determine the effect of the rotor circumferential speed and so the stress intensity on the mechanical activation of fly ash could be revealed.

Jan 1, 2014

By Ljubisa Obradovic, Baisui Han, Batnasan Altansukh, Zoran Stevanovic, Atsushi Shibayama, Jonovic Radojka, Daizo Ishiyama, Kazutoshi Hag, Radmila Markovic, Ljiljana Avramovic

This paper discussed a combined froth flotation and high pressure leaching (HPL) process to recover copper from mine tailings. At first, froth flotation were carried out using the mine tailings sample under various conditions in the presence of different pH (3.5-10) and sulfurizing reagent value (0-1000 g/t), respectively. As a result, optimum condition (sulfurizing reagent of 1000 g/t, pH of 10, PAX (collector) of 100 g/t and MIBC (frother) of 200 g/t) was found for froth flotation of copper. The effects of sulphuric acid concentration, leaching temperature, total pressure (steam pressure plus oxygen pressure) on high pressure leaching (HPL) of mine tailing were investigated using sulphuric acid solution in the presence of oxygen. The best conditions for HPL were obtained to be sulphuric acid concentration: 0 mol/L (water), leaching temperature: 170 ?, total pressure: 2 MPa, leaching time: 1 hr and pulp density: 100 g/L. The leaching rate of copper reached nearly 99 % and the concentration of copper in pregnant leach solution (PLS) was 0.24 g/L. Finally, copper in the mine tailing was recovered using froth flotation followed by HPL. As a result of a combined froth flotation and HPL, the vast majority of copper (99 %) from the mine tailings was extracted.

Jan 1, 2014

By Aysan Molaei, Kristian Waters

Solvent extraction is the one of the most common techniques for recovering metal ions from aqueous systems. However, solvent extraction is generally limited to relatively high concentrations and requires a high organic/aqueous ratio. Predispersed solvent extraction (PDSE) is a modified solvent extraction technique in which organic phase pre-comminute into colloidal liquid aphrons (CLAs). In this study, the extraction of copper by the PDSE technique was investigated. The main focus of this study was on the characterization and application of CLAs under different operational conditions, and to investigate the effects of different parameters on the extraction of copper from dilute streams. The effect of phase volume ratio (PVR), initial extractant concentration and initial copper concentration was studied and optimum conditions for copper removal using CLAs generated by LIX 984N as extractant, oil soluble and water soluble surfactants were proposed. Experimental observations indicated that PVR and initial LIX 984N concentrations had a significant effect on copper extraction.

Jan 1, 2014

By Sanja Miskovic, Manjunath Basavarajappa

Numerical investigation of fluid flow characteristics and mixing efficiency of different impeller designs, based on the mixing characteristics of a passive scalar/tracer, is conducted using CFD for lab scale flotation cells of diameter D and height H equal to 300 mm. Fine computational mesh containing close to 1.6 million cells is used to obtain fully resolved steady state flow field close to the impeller. Unsteady scalar mixing simulations are performed on a relative coarse grid consisting of approximately 450,000 cells. Based on detailed numerical simulations, flows are fully characterized for four impeller designs at two off-bottom clearances C of 50 and 25 mm (D/6 and D/12). Passive scalar is injected from the cell bottom and the time required to attain uniform concentration distribution inside the cell volume is taken as the mixing time by monitoring scalar concentration at four discrete locations. The effect of varying agitation speed and off-bottom clearance on mean flow characteristics is also investigated. The scalar mixing results reveal regions of low mixing efficiency and are used to understand mixing process in greater detail. Through the previous research work, it was found that the main flow pattern undergoes transition from double-loop to single-loop configuration with decrease in off-bottom clearance below a certain critical height for stirred tanks using flotation impellers in the absence of stator. The inclusion of stator is found to alter the mean flow behaviour by preventing the jet from transitioning to axial type flow for lower clearance. Power numbers for different impeller designs are calculated based on the torque generated on impeller blades, and also from the total turbulent kinetic energy dissipation in the overall fluid volume. Power number is found to exhibit a significant dependence on off-bottom clearance based on the CFD results.

Jan 1, 2014

By Tom Leistner, Urs A. Peuker, Martin Rudolph

"It is well known, that for conventional froth flotation techniques the processing of ultrafine mineral particles is generally inefficient and results in rather low-grade concentrates and relatively high losses of valuable minerals. Therefore, the investigation of other possible methods, which can selectively separate such fine particle systems effectively, is of considerable interest. In this study, the application of two-liquid flotation, a flotation-related process using oil droplets instead of air bubbles, is investigated as a possible processing strategy for the separation of ultrafine particle systems. The investigation involves the testing of the two-liquid flotation technique as simple laboratory-scale batch trials and moreover, the up-scaling to a semi-continuous process by using a modified lab scale flotation column. Magnetite and quartz particles, with particle sizes below 10 µm respectively, as academic mineral mixture and iso-octane and water as the two immiscible liquid phases are chosen for the experiments. To manipulate the wettability of the magnetite particles as well as the interfacial tension of the oil/water interfaces, surface active reagents of fatty acid basis are introduced in the system. The selectivity of the process is characterized by determining the removal of magnetite particles from the aqueous suspension through selective accumulation at the oil/water interface or extraction into the oil phase, respectively. Operational parameters including pH of the aqueous suspension, additional electrolyte addition and surfactant type as well as dosage are varied in order to maximize the efficiency and stability of the process."

Jan 1, 2014

By T. N. Aleksandrova, A. V. Afanasova

"The research is aimed at solving the problem of enrichment of sulphide ores, counting for more than 40% of the reserves in Russia. The aim of the research is to develop and scientifically substantiate the scheme for processing this type of ores in order to extract fine-dispersed noble metal particles (FNMP). In this work samples of sulfide carbonaceous ore and flotation concentrates were analyzed using complex precision methods of analysis: electron microscopy, spectral analysis with induction plasma, complex thermogravimetric analyzes, etc. Data on the composition of the organic constituent of the samples were obtained with the usage of complex thermogravimetric analysis. The presence of various types of kerogen and bitumen has been established. Experimental studies on the coarsening of FNMP from the initial ore and flotation concentrates using electromagnetic radiation have shown the effectiveness of this coalescence method. The data on the elemental composition of the samples and the amount of FNMP were obtained. Thus, studies on the extraction of FNMP from carbon sulphide ore have shown the possibility of effective usage of combination of electromagnetic action and classical enrichment methods to extract fine particles of noble metals. INTRODUCTION Due to the depletion of free-milling raw materials the involvement of new types of deposits is the strategy of developing mining industry of Russia. The black shale raw materials show interest as a non-traditional source of precious metals since its genetic and positional gold-carbon connection. Muruntau, Sukhoi Log, Bakyrchik, Natalkinsky, Nezhdaninskoye, Olimpiadinsky, Homsen and others are the examples of well-known deposits of the black shale formation [1]. In fact the main gold-dispersed regions of Russia are composed of black-shale strata. Review of literature [2-5] shows that in recent years in almost all deposits of the black shale formation metals of the platinum group (PGM) were detected that significantly increases their practical importance."

Jan 1, 2018

By Renato Oliveira, Walter Valery, Alex Jankovic, Birol Sönmez

"The ball mill is the most common ore grinding technology today, and probably more than 50% of the total world energy consumption for ore grinding is consumed in ball mills. On the other hand, high pressure grinding roll (HPGR) technology is relatively new to the mining industry, with significant application only since the beginning of the 21st century. Both ball mills and HPGRs are typically used in closed circuit with classifiers. There is a general consensus within the industry that classification efficiency and circulating load both have a major effect on the efficiency of closed circuit ball mills. Metso Process Technology & Innovation (PTI) conducted a laboratory test program to understand the relationship between classification efficiency and circulating load, and the impact on the performance and capacity of ball mill circuits. However, the effects on HPGR performance are significantly different. Metso PTI has initiated a pilot scale test program to evaluate the size reduction performance of the HPGR under different circuit configurations. A series of pilot scale HPGR locked cycle tests were performed to simulate the following circuit configurations: including closed circuit with a screen, partial product recycle and edge recycle. This paper discusses the results from the pilot scale HPGR and laboratory scale ball mill test programs. The effect of circulating load and classification efficiency on the performance of ball mill circuits is compared to the effect on HPGR circuits. The fundamentals of grinding behavior are also discussed in order to explain the difference."

Jan 1, 2014

By V. F. Petrov

Cyanide is widely used gold lixiviant for hydrometallurgical processes. The resulting tails contain complex toxic compounds. With reference to this, the protection of the environment should be the major issue. A complete detoxification of cyanides before disposal, a partial detoxification to the allowable concentrations and a disposal of tails at a polygon followed by the detoxification of excess water into the environment are offered as an environmentally friendly way of disposal. However, a complete detoxification of the cyanidation tails does not give the required results due to the presence of toxic compounds, cyanides and thiocyanates in tailings ponds. This is due to adsorption-desorption process occurring between solid and liquid phases. A partial detoxification is used to down cyanide to the allowable concentrations, which are safe to the environment. The storage of tails without detoxification is mainly used at low concentrations of toxic compounds in the disposed tails. With reference to this, water recycling is practiced by Russian plants in order to reduce as much as possible or almost eliminate toxic effluents into the environment. Fresh water is applied if necessary and to make up for water losses, with 8-12% of total water supply. This allows for the stability of water balance and the decrease of consumption of the reagents applied. The conditioning technologies of water recycling followed by regeneration of free cyanide and metals recovery as saleable concentrates are specially developed due to adverse impact of water recycling on gold recovery processes due to high concentration of base metals (copper). These technologies are also profitable. In order to detoxify cyanide in the tails for tailings dam, effective and inexpensive technologies involving a seasonal use of detoxified reagents were developed. For example, a technology with aldehydes use which is applied by a series of operations. Effluents disposed to the environment are detoxified using chlorination followed by almost a complete destruction of toxic cyanides and thiocyanates. Before disposal, chlorinated water is settled to precipitate the resulting hydroxides of metals and complete chemical reactions such as a full decomposition of hypochlorite ions. In order to protect ground water, watertight screens from local water-resistant materials are used. The samples of these materials were previously tested and chosen according to their maximum ability to adsorb toxic compounds in the tailings pond. If local water-resistant materials are not available, whole welded impermeable polymer screens are used. The options mentioned allow the storage of cyanidation tails in accordance with national ecological standards. Keywords: cyaninides, thiocyanates, wastes, environmental safety, recycled water-supply, detoxification, storage

Sep 1, 2012

By Graeme Lane, Yuqing Feng, Kaixi Jiang, Junwu Zhou, Zhengchang Shen, Tao Song

"Airlift reactors are used in a wide range of industries, such as hydrometallurgy, biochemical processes, chemical process industry and waste water treatment. With increasing superficial gas velocity three circulation regimes can be defined: no gas bubbles in the downcomer, gas bubbles remain stationary in the downcomer and gas bubbles in the circulating regime. In this paper a numerical modelling method was presented for gas-liquid flow in airlift reactors under different bubble recirculation regimes. Gas-liquid flow was modelled using the Eulerian two-fluid equations, and extra user defined subroutines were incorporated to consider the complex physics, such as bubble induced turbulence and turbulent dispersion force. Some alternative correlations of drag coefficient were used to capture the bubble distributions in the riser and downcomer of the airlift reactor, with consideration of the interaction between bubbles. As using constant bubble size is hard to describe global characteristics of the flow in airlift reactors for three circulation regimes, a model including multiple bubble sizes was presented to get more accurate simulation results of gas holdup and water velocity. Also, the inhomogeneous MUSIG model was used, as an exploration, to compute the complex flow regimes. The MUSIG model is a population balance method to predict the bubble sizes, taking break-up and coalescence into account. The modelling method was applied to a laboratory internal loop airlift reactor, and the simulation results were compared with the experimental measurements of Simcik et al. (2011) for gas holdup and water velocity. The three bubble circulation regimes were observed from simulation figures. Reasonable agreement was obtained over a range of operating conditions, and an improvement was demonstrated using the proposed methods."

Jan 1, 2014

By Yi-jun Cao, Jin-cai Ran, Guo-sheng Li, Jiong-tian Liu, Li-jun Deng, Shu-lei Li

A fly ash sample from a power station in Guangdong province has been characterized by size separation, X-ray diffraction, contact angle measurements and X-ray Fluorescence. The ash sample had a loss-on-ignition (LOI) (%) of 15.54% and a large proportion of the unburned carbon was distributed in the +74 µm and -20 µm fractions. Contact angle measurements suggested that the removal of unburned carbon from the fly ash using flotation would present some challenges. The effects of various operating variables on the removal rate of unburned carbon (RUC) (%) and (LOI) (%) were determined using a cyclonic-static micro bubble flotation column (FCSMC). Within the range studied, the optimum diesel oil dosage was 1200 g/t, abies oil (frother) dosage was 600 g/t, pulp density was 20%, superficial gas velocity was 1.4 cm/s and circulating pressure was 0.20Mpa. Column flotation tests indicated that the FCSMC method a viable and effective separation process for removing the unburned carbon from the fly ash. Under the optimized conditions, a clean ash with 2.13% LOI and 94.21% RUC was obtained.

Jan 1, 2014

By Nani Pajunen, Kari Heiskanen

"Products filling our societal needs, like communication and transportation needs, are becoming more sophisticated and efficient. The cost has been an increased complexity of material combinations. The same trend is also seen in investment goods. As an example, different crusher types have almost doubled the power to weight ratio in a relatively short time while producing even higher crushing rations. This has been possible by high performance materials and advanced designs. Another example is new hybrid materials in prefabricated high-strength steel structures in construction with the aim to lighten the products and obtain energy savings in the use phase e.g. in transportation. This development in general has made the end of life phase obscure. Recycling is often understood as the first phase of the material cycle. This has been supported by the material centric point of view. When, say indium, has been collected and mechanically treated to a concentrated fraction, it is assumed as recycled. This is not the case. The same applies to special steel alloys where one tends to lose some of the alloying elements to slag or even into the gas phase in the melting and refining stage, not in the earlier steps of recycling. At present there is no clear understanding of recycling of hybrid materials and no clear willingness to create new functional recycling systems. As the EU directives and most of legislation worldwide are based on the material centric thinking and implemented even on total mass recovery basis there is neither legislative incentive nor very strong economic incentives to work out the problem. In our research, we focus on industrial design towards sustainability from a product centric point of view from product collection to final metallurgical steps. It is vital, in the design phase of product, to understand the effects of decisions on recyclability to a saleable raw material. Main goal of our work is to create the fortunate circumstances in supply chain - to pass the barriers and find the effective and fruitful drivers - for reasonable use of raw materials and recycling co-operation with industry. The boundary conditions in the work are extractive metallurgical performance and the economic viability of all the steps. It can be shown from our work that small design alterations may have a large impact on the recyclability. The earlier the decisions are made in the product life chain the more positive impact they will have. It can also be shown, that a strong processing and metallurgical industry is vital to any meaningful recycling of the modern EoL products. Finally, it is also question of the individuals and values: supply and demand. Are you ready to take up the gauntlet: demand recyclable products."

Jan 1, 2014

By Xiaoping Xu, Tiansong Dong, Guosheng Wang

"Jianfengpo tin ore is located in Jiangxi Province, China. The cassiterite is fine and dispersed. It is hard to separate marmatite from a variety of sulfide minerals. Because the iron-containing sulfide minerals including pyrrhotite, pyrite and chalcopyrite are detrimental to the improvement of the grade of zinc concentrate. Besides, the presence of the iron oxides and ferro-carbonate minerals results in the difficult beneficiation of tin. Therefore, Jianfengpo tin ore is a kind of refractory cassiterite polymetallic sulfide ore. According to the properties of Jianfengpo tin ore, the technology process of "Sulphide ore preflotation-Bulk flotation of sulphur and zinc-Separation of sulphur and zinc -Magnetic separation-Gravity concentration" was developed to recover the valuable materials including marmatite, pyrite, magnetite, cassiterite and indium comprehensively. For the feed ore containing 0.87% Sn and 0.70% Zn, a zinc concentrate of 44.56% Zn with a recovery of 69.10%, a high-grade tin concentrate of 54.38% Sn with a recovery of 53.03% and a low-grade tin concentrate of 6.54% Sn with a recovery of 1.25% can be achieved in the batch flotation tests. In the industrial tests, for the feeding which contains 0.55% Sn and 0.65% Zn, the tin concentrate of 49.10% Sn with a recovery of 48.52% as well as the zinc concentrate of 45.11% Zn with a recovery of 60.10% can be produced. Thus some pyrite and magnetite concentrate are recovered as well. So Zinc, tin, sulphur and iron ores are recovered effectively by the technology."

Jan 1, 2014

By Andrzej Luszczkiewicz, Tomasz Chmielewski, Jan Drzymala, Andrzej Konieczny, Rafal Kaleta

Properties of the sedimentary Polish copper ore mined from the Legnica-Glogow Copper Basin (SW Poland) by KGHM Polish Copper S.A. were presented and currently used beneficiation technologies were described. Due to a unique lithological layered structure of the polymetallic deposit and existing mining system, the ore currently processed in the three KGHM concentrators is very complex with variable content of the carbonate, sandstone and shale fractions. The mined copper ore contains from 0.8 to 1.8 % Cu and Ag, Pb, Zn, Ni, Co, V and Mo as accompanying metals. The paper presents difficulties in upgrading the LGOM ore and selected possible solutions and development concepts of its processing. The first one is a chemical treatment with controlled amount of sulfuric acid of special product of flotation such as for instance middlings. The acid treatment leads to increased liberation of copper minerals and better further processing. Another concept is atmospheric leaching in oxygenated sulfuric acid and ferric ions solution as the major unit operation applied to selected low grade final flotation concentrates or flotation by-products. The third approach, based on copper ore pre-flotation with a frother to partially remove Corg, is also considered.

Jan 1, 2014

By Leena Vesa, Antti Remes

Design of thickeners is based on laboratory test work, characterizing the material and determining the optimal reagents, dosages and settling regimes. Several methods for dimensioning plant scale equipment exist. Kynch and Talmage-Fitch design procedures has been applied widely for a long time. Nowadays, besides them, a dynamic laboratory test work is applied for design of high rate thickeners. In that the laboratory unit is operated with known solids load per area, feed and flocculation conditions and with raking of the underflow. All these test methods afford useful data for setting up and calibrating a dynamic simulation model of a plant scale thickener. This paper presents a flocculation kinetics based dynamic thickener simulation model and a procedure to calibrate the model parameters. With the model, the underflow stream composition can be simulated over time as a function of the thickener operating parameters, which are: the feed rate and composition, underflow pumping rate, flocculant dosage and dilution of the feed. In addition, the model incorporates calculation of the slurry bed level, the cone pressure, the yield stress and the rake torque. Such a dynamic modeling scheme enables setting up simulation aided operator trainings and developing and testing of advanced control strategies, for example. The unit model can be integrated as a part of concentrator-wide flow sheet simulation model as well. Here, calibration of the kinetic flocculation model based on a laboratory test case data and further the operation of a simulated plant scale thickener are presented.

Jan 1, 2014

By Thomas Mütze, Anja Hirte, Ursx Peuker, Thomas Kuhn

"The comminution behavior of two ferromanganese nodules samples of the equatorial northeast Pacific has been examined as a basis for the separation of two kinds of metal-rich layers. Those layers were finely grown together during nodule formation and are one reason that the exploration of deep-sea minerals calls for the development of new mineral processing concepts. Therefore fundamental analyses of the fracture behavior have been made under compressive and impact stress. Further experiments took focus on the crushing behavior in a jaw crusher and a small scale impact crusher as well as the milling behavior in a dry vibrating mill, a wet planetary ball mill, and a wet agitated ball mill. The comminuted products were characterized by PSD, particle shape, particle density, and porosity. The experiments show a low stress resistance of the ferromanganese nodules. Compared to compressive stress, impact stress turned out to be the more effective for crushing. Both samples showed no significant difference in the comminution behaviour which makes differing mechanical treatments unnecessary. In both cases particle sizes below 1 µm were achieved by wet grinding. This particle size is necessary to separate the two kinds of metal-rich layers which is part of continuative studies."

Jan 1, 2014

By Bert Huls

Already starting, new drivers will dictate how future mineral processing plants will be designed and operated. These drivers include requirements in water and energy conservation because of rising costs, larger demand for mineral and metal products as the result of a rising population, and the increasing demand from the population in general to have influence over what type of operations will be developed where. Mineral operating facilities will require processing of lower grades. To do this economically, design engineers will be influenced to introduce newer concepts, or return to older processing concepts once deemed not desirable. Our understanding of the fundamentals must be improved, and this may come from better measurement techniques and more process piloting, and will go in hand with a reduction of waste generated during the process, improved separation of minerals or product size. Process engineers will also be required to not just design according to the established 3D methodology for efficient plant installation. Already in other industries the design concept encompasses the entire range from source to product. Not only that, the design will be affected by public influence that must be illustrated prior to project execution. On the one hand, the added dimension in design may slow a project; on the other hand it may result in a blessing, and in a higher responsibility for engineering.

Jan 1, 2014

By Henrique Kahn, Daniel Uliana, Juliana Antoniassi, Viviane Shimizu

"Mineral exploration and geometallurgy require a large number of samples for physical, chemical and mineralogical assays. The combination of all these data and their spatial distribution define the ore variability. This is important in exploration programs and crucial in feasibility studies as well as at the production operation level. Ore mineralogical composition and its associations, characterizing the geological formation and mineralization, are the main keys to define the ore domains and its variability, which can be quickly assessed by cluster analysis and by modern automated mineralogy tools. One hundred and ten copper ore samples from Sossego mine, in Brazil were compared and classified by X-ray diffraction cluster analysis based on the position and the intensity of the diffracted peaks. Initially four ore types were categorized based on content of major minerals: quartz, feldspar, amphibole, iron oxides, mica and chlorite. Results showed a strong correlation between the grouping and the samples location in Sequeirinho and Sossego orebodies, with a straight link to types/intensities of hydrothermal alteration prevailing in each body, which reflects the mineralogical composition and thus the X-ray patterns. Samples from four recognized ore types were submitted to detailed automated mineralogical studies by electron beam image analysis and differ strongly from each other regarding their chemical and mineralogical compositions and relevant parameters for mineral processing. Chalcopyrite is essentially the only valuable mineral, occurring both as submillimetric grains included in other minerals and as larger crystals. Except for pyrite, other sulfide minerals occur as traces. Chalcopyrite liberation curves indicate that samples from Sossego have higher liberation degree than those from Sequeirinho. The proposed method proved to be very efficient and accurate to classify a large number of samples within a short time frame, allowing the distinction of the ore types regarding their mineralogical composition as well as the mineral processing parameters."

Jan 1, 2014

By Arkady Senchenko, Yuri G. Seredkin, Alexander Aksenov

"This paper describes the development of efficient technology for the treatment of complex ores containing gold and copper as major valuable components, where silver is present as well. Copper is mostly represented by oxidized minerals in these ores; however, copper sulfides are also present. Gold is present in its free form and in associations with oxidized and sulfide minerals; silver usually accompanies gold. Complex composition of the ore requires complex solutions for their treatment. The results of searching for the techniques to recover valuable components are described in this paper. Gravity methods allow for free gold recovery, flotation methods allow one to recover major part of copper and precious metals in associations; and in the result of leaching process additional amount of copper, gold and silver is reported to solution. Combining all these methods help achieving high levels of valuable components recovery. When implementing a combined technological flowsheet about 80 % of copper goes to concentrates from gravity and flotation of sulfide and oxidized copper minerals; and sulfuric acid leaching allows increasing total copper recovery up to 90 % and higher. Major part of precious metals (up to 90 % of gold and 80 % of silver) is recovered to these concentrates, and after hydrometallurgical treatment it is possible to increase gold recovery up to 96 %, silver recovery - up to 90 %. The suggested technology helps solving the problem of precious metals recovery from complex gold-copper ores, and allows treatment of the ore with different proportion of sulfide and oxidized minerals, and at different valuable components grade."

Jan 1, 2014

By Cristian Melipichun, Leopoldo Gutierrez

The effect of the presence of fine particles of kaolinite and montmorillonite on the induction time for attachment of bubbles to particles of a copper concentrate rich in chalcopyrite was evaluated in this study. The results obtained from induction time measurements were correlated with data of concentrate recovery achieved from micro-flotation experiments. The effect of the presence of fine clays on the stability of air-water foams was also studied through measurements of the foam volume generated in a glass column under different conditions of air flowrate and MIBC concentrations. The experimental results showed that induction time values increased under the presence of fine clays. These data agreed with results obtained from micro-flotation experiments that showed that copper concentrate recovery decreased when clay particles were added. Although a complete explanation for these results is not available, the fact that experimental observations indicated that fine clay particles tend to adsorb on gas bubbles, suggests that the interactions between fine phyllosilicate particles and air bubbles have to be taken into account when studying the effect of clays on froth flotation. Foamability tests showed that the presence of fine clay particles increased the foam volumes only at high additions of clays and low dosages of MIBC. The results obtained at higher dosages of MIBC showed that the foam volumes decreased with the addition of clays under all the experimental conditions tested.

Jan 1, 2014

By S. Mitra1

"This study aims to investigate coarse particle detachment mechanisms (particle diameter > 150 ?m) utilising both experimental and numerical technique. Two mechanisms were studied – (i) interactions of bubbleparticle (BP) aggregate with vortices and (ii) coalescence of bubble-particle aggregates. On the first mechanism, interaction behaviour of coherent vortex structures with a BP aggregate (bubble diameter db = 3 mm, particle diameter dp = 0.3 mm) was studied using a CFD model in the Reynolds number range of 100 to 1000. Effect of surface hydrophobicity on the BP stability was examined using a range of contact angle boundary conditions. To address the second mechanism, interactions of bubble-particle aggregate (db ~ 4 mm, dp ~ 0.4 mm) with both free gas-liquid interface and individual bubbles were investigated using high speed imaging. Both rebound and coalescence outcomes were observed to be responsible for BP instability leading to particle detachment.INTRODUCTIONIt is widely known that flotation process performs excellent mineral recovery for base metal ore particles that are typically in the range of ~ 20 to 150 µm in diameter (Jameson, 2010). More specifically, higher recoveries are usually reported for particles in the size range of ~20 to 70 µm while outside this spectrum, generally the recovery diminishes significantly. It would be highly desirable to improve the recovery of particles at the coarse end of the flotation size range spectrum which has significant economic benefit (Jameson, 2010). However, it is essential that insights to particle detachment phenomenon, the primary impediment in coarse particle flotation caused by the underlying hydrodynamic factors are first obtained at a greater depth.In an ideal quiescent liquid medium, due to inertia, coarse particles deviate substantially from the fluid streamlines and collision efficiency with bubbles decreases which can only be augmented by increasing turbulence level in the medium sufficiently to make random physical contacts with bubbles. Nonetheless, even if successful contacts are made, it is difficult for these large particles to remain attached to bubbles in a turbulent shear flow environment. There are two major mechanisms postulated for particle detachment – interaction of turbulent flow structures (eddies) with BP aggregate and coalescence among surrounding aggregates. Earlier work of Schulze (1982) theorised a vortex acceleration component to characterise turbulence effect on BP aggregate instability in flotation machines. Wang et al. (2015) investigated bubble detachment behaviour from a stationary particle in a nearly homogeneous and isotropic flow field. Using PIV (particle image velocimetry), it was shown that the local maximum energy dissipation rate for the case of bubble detachment was significantly higher than the no detachment case, and was also higher than the critical value for bubble detachment calculated using Schulze’ theory (Schulze, 1982). Later, Wang et al. (2017) also visualised the BP aggregate instability in a cavity flow leading to particle detachment which was attributed to bubble coalescence, bubble surface oscillation and particle deceleration phenomena."

Jan 1, 2018