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By A. C. Drost

The mining industry has been put under closer scrutiny in recent years, which has led to the adoption of a plethora of initiatives in countries around the world and by international organizations, some voluntary and others mandatory, governing economic, ethical, social and environmental practices of this industry. In order to plan appropriately, secure project financing, build value and manage risks, it is imperative to identify and understand the application of this new and evolving regime, which can be described under the general label of corporate social responsibility (?CSR?) law, and to incorporate compliance policies into the day-to-day operations of mining companies. Our paper and presentation will describe this new legal framework, which includes both ?soft? law and ?hard? law adopted at the international and domestic level that governs the actions of mining companies, particularly when operating in developing countries. While the notions of hard and soft law may seem abstract and grounded in legal theory, this paper shall demonstrate how these concepts concretely apply to companies in general, and to mining companies in particular. An analysis of the recent case law in this area as well as examples of corporate ?best practices? will illustrate the application of this body of law. As will be demonstrated through the case law, non-compliance of CSR law (both ?soft? law and ?hard? law) can lead to economic penalties, difficulties in accessing capital, loss of social licenses and even the withdrawal of permits and concessions. This confirms that now more than ever, ethics and sustainable practices in mining are fundamental to building a successful business model.

Aug 1, 2013

By Dennis L. Murr, James E. Wennen

"The through-put and energy efficiency of an autogenous (AG) grinding mill are adversely affected by variability in rock size and rock competency. This applies to both fully autogenous and semi-autogenous (SAG) grinding circuits. In this paper we focus on an approach to overcome the problem of inconsistent mill through-put related to variability in mill feed size and rock competency. The focus is on ores containing hard, competent rock. This approach consists of preparing feed to an autogenous mill that contains 20% coarse media rock and 80% of material crushed to pass 37 mm. Results of pilot-scale testing for two iron-ores will be presented to show that a 10% to 12% reduction in unit energy consumption is possible with prepared feed, compared with feeding the mill with conventional primary crusher discharge.INTRODUCTIONIn the past 30 years or so, autogenous grinding and semi-autogenous grinding have been the comminution technologies of choice for most mining and mineral processing operations. These technologies saved both capital and operating expenses associated with the installation and operation of multi-stage crushing and screening plants required for conventional rod mill – ball mill circuits. However, SAG and AG are inherently inefficient in terms of energy consumption, especially for very hard ores. In cases of hard ore, changing characteristics of rock fed to the mills causes wide fluctuations in mill capacity, which contributes to the inefficiency. Rising electric power costs make this the most expensive unit operation used in the extraction of valuable minerals from an ore. The objective of the concept discussed here is to reduce the energy consumption in AG grinding for hard ore and eliminate the use of large-diameter steel grinding balls that are required for SAG grinding"

Jan 1, 2012

By Guy Chevalier

QCM?s pellet plant, located in Port-Cartier, Quebec, produces up to 8.6 million tons of iron ore pellets annually. Four different types are produced: three for blast furnace operations and one for direct reduction furnaces. The paper presents the scientific approach that led to the installation of new process equipment to improve the reducibility of direct reduction pellets (DR pellet). The findings, the equipment selection and some post start-up modifications are presented. This low silica DR pellet is used in Midrex and HyL shaft furnaces. A good DR pellet has to meet strict chemical, physical and metallurgical specifications. An important metallurgical property is its ability to release oxygen when exposed to reducing gases. Considering that the market for DR pellets is expanding and being aware that reducibility is critical for our clients, a program to improve the latter was undertaken. Test work showed that one factor which has a negative effect on reducibility is the proportion of particles larger than 75 microns. Knowing that the best way to reduce the amount of coarse particles was to close our open grinding circuits, we began evaluating the most suitable classification equipment applicable to our process operations. We settled on hydro-classifiers based on their very sharp cut and their low operating costs. In light of the hydro-classifiers performance it was also decided to replace the hydro-cyclones of an already closed circuit.

May 1, 2003

By S. Sagar

In September 1996, Dofasco commissioned a 165 Mt twin shell EAF furnace and an associated ladle fleet. During and after this startup, refractory performance in the ladles was optimized on a holistic approach through several initiatives that increased ladle refractory retention times from 7000 to over 16000 mins (160 heats). This dropped the overall refractory costs by 40% while ensuring a consistent and predictable ladle performance. One initiative that drove enhancements was the proper brick selection for each particular refractory area and it's process conditions. The work concentrated on the selection of a resin bonded alumina magnesia carbon (AMC) brick in the barrel area of the ladle, upgrades to the 2 piece monolithic alumina cast ladle bottom and increasing the slagline refractory brick quality with the appropriate zoning/paneling. The adoption of a magnesia alumina carbon (MAC) brick in the transition area of the barrel/slagline has also improved performance and predictability. The design developments have lowered the overall wear rates and balanced the service life of the entire ladle. Safety was improved and breakout potential reduced by changing the safety lining from a high alumina brick to a state of art technology - monolithic shotcrete lining. This initiative decreased the overall manpower required to brick a ladle and increased shop ladle availability. The ladle bricking area environment was also improved by adopting a post combustion device to burn phenol fumes from ladle preheating practices. This has improved the overall health & safety of the reline teams. The consistent and predictable performance of the ladle on a whole has allowed the shop to decrease the number of working ladles in operation from 5 to 4. This further decreased wear rates from over-oxidation and excessive thermal cycling, saving approximately $500,000 in natural gas from pre-heater operations.

Jan 1, 2004

"The ore currently being milled at Delnite is a high pyrrhotite ore with the gold intimately associated with the pyrrhotite. To get maximum recovery of the gold with the lowest reagent cost, it is necessary to keep the pH as low as possible In the laboratory the best results were obtained with a pH of 10 but in the plant it was found that a pH of 11 was the minimum practical pH. With the n1anual control it was difficult to maintain this figure.The Mines Branch had a conductivity probe (see Fig. 1), developed by Dr. G .G. Eichholz that they wished to try out in plant operation.On June 17, 1963, the probe with all necessary control equipment was installed in the regrind circuit (see Fig. 2) at Delnite Mines. Crushed quick lime is fed at this point but it is also necessary to feed hydrated li1ne at two other points in the cyanide circuit in order to maintain the pH close to 11. 0 throughout the circuit. Only the feeding of the quick lime at the regrind mill was controlled in this test.One thing that concerned me with the operation of the probe was whether the reading on the probe chart would correspond to the pH. A look at the graph accompanying this paper will show that except for very minor variations the graphs of the chart reading and the pH reading are parallel. The upper graph shows that the pH reading and the lime titrations also correspond and that the cyanide titrations appear to have little effect on the pH reading.Table 1 gives the results obtained for the two months before and after the instal1ation of automatic control as well as the two months of control. Unfortunately there was a decided change in ore just after the automatic controls were removed. There was much less pyrrhotitc in the ore than usual thus changing the need for lime and cyanide."

Jan 1, 1964

At 14%, the representation of women working in the mining industry is the lowest among primary industry categories in Canada1. With reference to mining operations and senior leadership, the gap in the industry is even more pronounced. In an effort to narrow the gender gap, recent industry, education, and policy efforts have been made to increase the number of women entering the industry through career awareness and early career recruitment strategies. These strategies implied that by increasing the numbers of women entering the industry there would be a natural progression of women into the hierarchies of organizations. Efforts to retain women in the industry have focused around removing career barriers such as reviewing flexible work practices and programs directed at work life balance. At this time, these efforts have resulted in negligible fluctuations to the gender gap within the industry. This research investigates the under-representation of Highly Qualified Women (HQW), and the interaction of workplace culture on their career advancement and retention within the industry. HQW (women with a bachelor?s degree or higher) are the focus of the work as they represent an essential source of leadership and technical capacity for mining organizations. This paper is based on the results of a survey of 170 HQW working in the Canadian mining sector. The findings from this research suggest that HQWs careers in mining are stalled, despite a strong indication by respondents of interest in their professional career advancement. With regards to workplace culture, respondents indicated that blatant forms of gender discrimination have been reduced in mining workplaces; however, exclusion from informal networks, implicit bias and subtler forms of workplace discrimination persist. Utilizing a framework to assess the workplace culture for women in attracting and retaining their employment, respondents provided detailed information on the aspects of workplace culture that are most problematic in relation to women?s career development in mining. Women consistently identified problematic workplace culture as a significant barrier to the career advancement and retention of women within the industry. The representation of women within the labour force will likely remain stagnant until the industry addresses workplace culture within the industry, and makes strategic efforts to develop inclusive cultures throughout mining and supportive organizations.

Aug 1, 2013

By N. A. P. Kiran Kumar

The Zr-Nb alloys are reported to be showing superior resistance to corrosion and substantially lower hydrogen pickup when compared with zircaloys. In the present study zircaloy-4 and Zr-1Nb (E110) alloys were hydride using high pressure hydrogen gas furnace at a pressure of 20 MPa. Thermal cycling was done on the samples at a temperature of 3500C for 10 cycles with 5h soaking time at 3500C per each cycle. The Microstructural observations on zircaloy-4 samples show long and interlinked hydride like chain, oriented along the circumferential direction. Whereas in Zr-1Nb, short hydrides were observed with hydride platelets not showing interlinked chain like structure. The hydrides in Zr-1Nb were observed to be not showing particularly orientation along the circumferential directions. Electron backscatter diffraction was use to understand the hydride precipitation and their orientation in Zircaloy-4 and E110 alloy.

Aug 1, 2010

By D. J. Bowen

"The Great Dyke extends for 540 krn along strike, to unknown depth, and varies in width from 3 krn to 11 krn. Rb/Sr age determinations gives values of approximately 2470 Ma.The Dyke consists of a variety of mafic and ultramafic rocks, many altered to serpentinites. These include, from top to bottom, successions of gabbro/norites, pyroxenites, peridotiteslharzburgites, and dunites/picrites.The layers dip in from either margin, steepest at the edges (20°) and flattening toward the central sections. Four separate complexes are present. From north to south these are termed the Musengezi, Hartley, Selukwe and Wedza Complexes, and are described as 'boat-shaped' or 'pig-troughed'. All are similar in petrological sequences. Physiographically, the Dyke is spectacular in the north, where as a mountain range it meets the Zarnbezi Escarpment. Elsewhere in the central parts there is little surface expression and wide open treeless vleis. Dyke rocks cut through granite and schist belt terrain and are termed 'The Magnesia Belt'.Vast mineral resources exist. These include chrome, asbestos, platinoids, nickel, copper and gold. Up to eleven chrome seams numbered from top to bottom occur in the lower ultramafic sequences. Seams are narrow at 10 em to 30 em but of high grade. The platinum occurs 10 m to 40 m below the norite/pyroxenite contact.A 60 m wide zone of Light Sulfide Mineralization (LSM) of less than 1070 sulfides extends from the lower gabbronorites into the upper pyroxenites. In this LSM, four enriched zones carry up to 5% sulfides. The most widespread is termed the Main Sulfide Zone (MSZ), below which is No. 2, No.3 and No.4 Sulfide Zones. The MSZ carrying pyrite, pyrrhotite and chalcopyrite is a multielement ore with components of PGE (pt-Pd-Rh), nickel, copper and cobalt, and gold and silver.Extensive exploration programs have been carried out and the intention is to begin large-scale mining. However, with Russia supplying metals to the western markets, South Africa's cutback on production, and an end to the Cold War, delays have arisen."

Jan 1, 1994

By Scott D. Long

"Abstract-Grass roots exploration has an emphasis on good precision at low (sub-economic) concentrations of an element, in order to identify "anomalies" which may lead to drilling targets. Although it is wise to have well-defined quality controls in place during early stage sampling, the control procedures at this stage tend to be rudimentary. When a deposit warrants detailed delineation, the need for accurate geological characterization and assaying of ore-grade rock must be supported by appropriate quality control procedures.As a project returns more promising results, and the likelihood of the project warranting a prefeasibility study increases, it is time to tighten quality assurance requirements and quality control protocols. Delays in instituting adequate quality control and verification procedures may lead to costly remedial actions that can also delay completion of the prefeasibility or feasibility study. Sometimes, as a project matures, the quality control and quality assurance aspects fail to keep pace with the changing nature of the work: an increasing emphasis on precise and accurate assaying of oregrade rock.A resource model is like a house of cards. The foundation of the house is the geological observations, the sampling methods and the geological interpretations performed upon those samples. Upon the sampling, which includes all the sub-sampling steps of sample preparation, rest the assay results. The quality of the assays can be no better than the quality of the sampling. Good assaying technique will preserve all biases and imprecisions introduced during sampling and sample preparation; it cannot remove them. If the sub-samples and/or assays are bad and must be redone, all the succeeding levels of the house of cards must also be rebuilt, or at least patched up.From geological observations, a geological interpretation is built, the quality of which is critical to the construction of an acceptable resource model. Geological elements are difficult to assess, and are not discussed here; they are dependent upon the expertise of the geologists involved. Geological knowledge contributes essential quality control elements to resource/reserve determinations (Sinclair and Postolski, 1999; Postolski and Sinclair, 1999).This paper consists of five sections: (1) overview of quality control protocols, (2) maintaining quality control of databases, (3) quality control of drill sampling, (4) optimizing crushing and grinding requirements, and (5) quality control of assay data acquisition."

Jan 1, 1998

By M. Amsden

"Since the computer program is far from complete this must be only a brief progress report on the computerization of flotation metallurgy at the Ecstall concentrator at Timmins.Ecstall is currently treating about 10,000 tons per day of two different ore types. One is a low sulphide copper-zinc ore, the other is a high sulphide lead-zinc-silver ore. The concentrator is divided into three individual grinding and flotation circuits. In effect there are three mills under one roof. Normally there are two circuits on copper-zinc ore and oneone lead-zinc-silver ore. At this point in time one of the copper-zinc circuits is under computerized metallurgy control.The first step in this control is the use of an ARL on-stream x-ray analyzer, coupled with a Honeywell 21 computer which types out assays and recoveries for each individual circuit. Our approach to a computer program was to keep it simple. The program was written to coincide as closely as possible to what an operator would do in the performance of his duties based on the in-formation he was getting from the x-ray analyser read-out. Initially, computer control was put on just the copper circuit of the ""A"" Division, controlling the collector addition at three points in the circuit; primary, secondary, and scavengers. The control was based on recoveries and the grade of the copper concentrate. Targets like 95% recovery and 24% copper concentrate grades that it was felt the circuit could achieve were set to start with. It quickly became apparent that this alone was not enough because if on a certain ore the best recovery that could be made was only 94.9% the computer kept calling for more reagents until the circuit was completely out of control. On another ore it might have been quite possible to get 96% recovery but when the set point of 95% was reached the computer stopped trying for any more. To overcome this problem a very simple optimum seeking program was devised by one of the Ecstall staff and it has worked very satisfactorily since being put into use in July 1970.In the copper float only the two collectors R-208 and the xanthate R-317 are under computer control. The addition of frother and depressant is left to the operator. The flotation cells have automatic level controls which can be adjusted by the operator. pH is controlled automatically through a lime loop-sensor arrangement."

Jan 1, 1971

By Weimin Fu

Chondrite-normalized rare earth elements (REEs) profiles and high field strength elements (HFSEs) in rocks and minerals represent important tracers of geological processes. Of these the birdwing-shaped profile with negatively-sloped light REE ((La/Sm)N >1), positively-sloped heavy REE ((Tb/Yb)N <1), and strong negative Eu anomalies is commonly associated with large-scale hydrothermal systems or granitic intrusions. In a different way, severe deviation of Nb/Ta, Hf/Sm ratios from those of chondrite may also indicate hydrothermal signatures in the rocks involved as these ratios are generally stable and chondritic in normal magmatism as a result of their nearly identical ionic radii and charge. In this study, we present a typical setting where birdwing-shaped REE profiles together with Nb/Ta, Hf/Sm ratios unusually higher than those of chondrite, are systematically developed in a series of garnetite, quartzofeldspathic gneiss, Fe- or Mg-rich aluminous gneiss, and sulfides and magnetite. These units and associated Cu-Au mineralization form a VHMS-style hydrothermal system in the granulite-facies 1.4 Ga -1.35 Ga volcano-plutonic, arc-related Bondy gneiss complex (BGC), western Grenville Province, Canada. Outside the recognized hydrothermal system of the BGC, such REE profiles are not observed. Instead the surrounding felsic and mafic gneisses display primary trace element characteristics of island-arc magmas, suggesting that granulitefacies metamorphism did not modify significantly the trace element signatures of the protoliths. Although magmatic fractionation of accessory minerals can produce birdwing-shaped profiles, it cannot explain the extreme fractionation of isovalent trace elements (Nb-Ta) and the high Zr content of the hydrothermal rocks. Neither is it compatible with the lack of significant Nd depletion that would normally incur during this process. Following our study, we demonstrate that F-rich fluid and mineral phases enriched in LREEs and HREEs respectively must have been involved in the main hydrothermal alteration and REE fractionation process in the BGC. Preferential removal of REEs from the interstitial glass of the volcanic protoliths together with dissolution of plagioclase and subsequent external influx of HREEs and HFSEs can produce birdwing-shaped REE profiles. In turn, such profiles and/or unusual Nb/Ta, Hf/Sm ratios can be used as a sensitive marker of hydrothermally altered rocks in targeting mineral exploration.

May 1, 2003

By R. J. McLeod

"A new backfill plant was constructed in 1966 adjacent to the mill of Giant Yellowknife Mines. The reasons for the addition were to increase the storage capacity for sand fill, provide facilities for mixing cement with the fill for mine stope floors and provide a system for pumping fill to B -3 raise, a horizontal distance of 4700 feet from the mill. At the same time it was hoped to increase the density of the fill pumped underground.The plant consists of two only steel storage tanks of approximately 400 tons capacity of sand fill each. They are 17 feet in diameter and have conical bottoms. The cylindrical section is 28 feet high and the conical section 14 feet high. Each tank is fitted with water nozzles around the conical sections to remove solids at the required density. The water pressure on the nozzles is 150 lbs per square inch. The cyclones used to produce the sand back fill are located on top of the storage tanks. Five model Dl0B Kreb cyclones are used for this purpose. The vortex finders are 2 1/ 4 inch and the apex 1 1/4 inch. The cement silo or storage tank is located in the same building. It is a steel tank 17 feet diameter by 41 feet high with a conical bottom. The silo holds 250 tons of bulk cement, which is unloaded by air from a bulk highway carrier using 12 to 15 lbs air pressure. The cement is conveyed to the top of the silo, a distance of 70 feet from the ground by 450 lbs. of air.The mixing tank is a rubber lined steel tank 14 feet in diameter by 14 feet high. It is equipped with a Lightning Mixer supplied by Greey Mixing Equipment Ltd. The mechanism is driven by a 40 HP motor. The lower shaft is unsupported and is equipped with two 36 inch diameter axial flow turbine type rubber covered impellers. The backfill is discharged from the storage tank into the mixing tank by a 5"" x 4"" SRL-C pump powered by a 20 HP motor. A level control in the mixing tank regulates the rate of discharge of this pump through a Grinnell-Saunders automatic control valve. The cement silo is situated at such a height above the mixing tank to allow for a Rota-Lock, a small hopper and a cement feeder. The feeder is an Omega gravimetric belt type dry feeder with a Sensogram controller. The capacity of the cement feeder is 20 tons of cement per hour. The cement and backfill are mixed in the mixing tank at whatever ratio is required for the mine stope floors."

Jan 1, 1968

By J. L. Jambor, E. J. Reardon, E. C. Appleyard, J. A. Cherry

Since the 1957 initiation of deposition of mill tailings at the Heath Steele mine, New Brunswick, periodic detailed studies of the tailings geochemistry and mineralogy have been conducted, thereby providing a unique opportunity to examine the geochemical evolution of a sulfide rich mine>tailings impoundment. When deposited, the tailings contained about 85 wt% sulfide minerals, 1 wt% to 3 wt% carbonate minerals, and 12 wt% to 14 wt% alumino silicate minerals. Mineralogical examination of samples of the tailings from deep in the impoundment indicates that little oxidation occurred prior to tailings deposition. The mill process-water deposited with the tailings was neutral to slightly basic and contained low concentrations of Cu, Pb, Zn and As. Sampling of the tailings five years after deposition indicated that sulfide-oxidation reactions, occurring near the tailings surface, had decreased the tailings-water pH and increased the concentrations of Fe, S042-, Cu, Zn and Pb (up to 10 000 mglL, 25 000 mg/L, 2.5 mg/L, 200 mg/L, and 4.5 mg/L, respectively). In 1975, ten years after decommissioning, the tailings could be divided into three zones: an upper oxidation zone in which sulfide oxidation is actively occurring, a hardpan layer, 15 cm to 20 cm thick, composed of tailings cemented by secondary Fe minerals, and an underlying reduction zone in which the tailings are relatively tin oxidized (Boorman and Watson, 1976). Chemical analyses indicated the presence of low-pH waters containing very high concentrations of SOi-, Fe, and other metals (up to 63 600 mg/L SO42-, 28 600 mg/L Fe, 10 mg/L Pb, 600 mg/L Cu and 4000 mg/L Zn), suggesting that there was a period of intense sulfide oxidation between five and ten years after tailings deposition. More recent sampling, conducted some 20 years after the end of tailings deposition, indicates that relatively little change has occurred in the last ten years, thereby suggesting that the hardpan layer has provided an impediment to the downward movement of dissolved constituents. Analyses of the tailings solids show increased accumulations of many metals at or near the depth of the hardpan layer. Evaluations of the long-term evolution of the tailings can be enhanced by comparison of descriptions of the tailings with descriptions of the gossan that overlay the massivesulfide orebody prior to mining. At Heath Steele, this comparison suggests that many of the mechanisms controlling the distribution of metals in the tailings will probably persist over geologic time.

Jan 1, 1992

By Arthur Lieu

The mill effluent treatment circuit (Bulk Neutralization (BN)) in the Cameco Key Lake Operation was modified in 2008 to enhance the removal efficiency of selenium (Se) and molybdenum (Mo) from the mill process water. This modification was completed in part due to increased knowledge of the effects these elements have on biota. In addition, legacy effects from the historical operation of the Key Lake mill in regards to Se and Mo were shown to have an effect on the regional biota in the downstream receptors. This was a challenging initiative as there was no off the shelf technology available and the removal process had to be incorporated into an existing (brownfield) process. These modifications have resulted in significant reduction in the concentration of these elements in the Key Lake mill effluent. The removal efficiency for Se and Mo in the modified circuit has increased to 95% and 75%. As a result, concentrations of Se and Mo are now consistently less than 0.4 mg/l and 0.02 mg/l. In addition, the Se and Mo precipitates formed were extensively studied to ensure long-term geochemical stability in the Key Lake in-pit tailings facility. This presentation will provide additional detail on the hydrometallurgical removal mechanisms and process modifications required in the Key Lake BN circuit to remove these elements to trace levels.

Aug 1, 2010

By Michel Guillot

Gaz metal arc welding is commonly used for producing large frames and assemblies. Even for light aluminum and thin wall assemblies, the GMAW technique is increasingly preferred over the GTAW technique. This is particularly true where the welding gun motion is achieved accurately with automated or robotic systems and when using pulsed or regulated metal deposition. In this study, butt joints in floor welding position are tested at speed ranging from 1.5 to 16 m/min. Attempts are made of find parameters providing good and repeatable joint quality with minimal distortion and good appearance even at high travelling speeds. Taguchi experimental plans are proposed with different parameters tested with sheet metal samples. The parameters include typical GMAW machine settings, joint preparation geometries, wire gages, gun angles, wire feeds, and more. The robot motion speed and the proximity of the part are also considered. Direct monitoring of machine welding current and voltage is achieved. Once is found the best set of parameter settings, additional tests are carried out to verify the repeatability of weld quality. Secondly, these conditions are applied for joining and testing a floor panel made of several extrusions. Weld quality is established with Vickers micro-hardness measurements, cross section geometries of the weld pool including penetration, tensile tests and metallographic observations to establish the amount of porosity and weld microstructure in the HAZ.

Jan 1, 2011

By Aleksandar N. Nikoloski, Tendekayi Tapera, Glen P. O’Malley

Chalcopyrite (CuFeS2) and enargite (Cu3AsS4) are among the most important copper sulfides. At present, many known deposits of these minerals are uneconomic to process because they are of too low grade, insufficient size or too remote to be cost effectively treated with conventional technologies that can deal with their refractory nature. Therefore, developing an effective, low cost extraction process for recovery of copper from them is important. The research presented in this paper will deal with potentially cost effective strategies involving catalysed processing, studied under conditions relevant to recycle heap leach conditions. The present account summarises some of the main findings from the research program carried out at Murdoch University between 2014 and 2018 that has investigated the effects of the common leaching parameters, major and minor species present in the leach system and additives on the rate and extent of copper extraction from low-grade ores, in which primary copper sulfide minerals such as chalcopyrite and enargite were the dominant copper minerals. The study involved batch leaching tests, detailed structural and mineralogical characterisation and thermochemical modelling under conditions relevant to heap leaching. The results have demonstrated that silver in particular has a strong catalysing effect on the extraction of copper from ore under the leach recycle conditions and, at an adequate dosage, can effectively overcome surface passivation, enabling almost complete extraction of copper from chalcopyrite as well as enargite. The aim of this paper is to present the effect of the studied additives and to briefly elaborate on the mechanism of the silver catalysed leaching process. In addition, the presence of certain secondary agents was shown to lower the critical dosage of silver and promote extraction. The data from the study allowed the development of a theory for the silver catalysed reaction mechanism, which enables further optimisation and cost-effective application of this strategy in practice. INTRODUCTION Researching the extraction of copper from chalcopyrite is important as it is the most abundant copper mineral in the earth’s crust. The majority of ores containing this mineral are processed by flotation to produce a concentrate, followed by smelting and electrorefining. However, most reserves available nowadays are of low grade or limited in size, and therefore not suitable for this conventional approach. Hydrometallurgical processing via heap leaching with or without the aid of bacteria has been shown to be potentially economical. Chalcopyrite is refractory though and suffers from slow leaching kinetics and poor overall extraction, so understanding the mechanism of how it leaches has received significant attention by researchers working in this field over the past 50 years. The refractoriness, which is the main issue with the hydrometallurgical approach, is generally described as passivation of the chalcopyrite surface whereby a surface coating is formed that blocks the reaction interface or wetting of the chalcopyrite, limiting the copper extraction. Exactly what this layer is made of or how the issue could be overcome has been the subject of intense study and debate for many years. One of the limitations of the work to date is that much of the research focus has been on typical initial leaching conditions, while there has been relatively little research into how the leaching is affected under recycle solution conditions where certain metal ions (Fe, Mg, Al) have often accumulated in the liquor. This occurs because the leach solution exiting a heap contains many species from the dissolution of gangue minerals and typically this solution is returned to irrigate the heap, once the copper has been removed, leading to an accumulation of these species.

Jan 1, 2019

By Jocelyn Koshinsky

The uranium milling process at the Key Lake Operation of Cameco in Northern Saskatchewan, Canada results in the leaching of untargeted metal(loid)s such as arsenic, iron and nickel that are found at high concentrations in the ores. To mitigate the environmental impact of the leached As, Fe and Ni in the mill waste solution (raffinate), the pre-discharge mine tailings (rafffinate and residue) are neutralized with slaked lime, resulting in the formation of secondary As-, Fe- and Ni-bearing mineral phases which serve to control their concentrations to very low levels in the tailings porewater. As part of an ongoing investigation into the long-term evolution (10,000 year) of arsenic mineralogy in the Deilmann Tailings Management Facility (DTMF) at Cameco?s Key Lake Operation, it has become necessary to characterize secondary As-bearing mineral phases during the neutralization process prior to the discharge of the tailings and compare these to in situ As-bearing mineral phases in the tailings facility. This is primarily to determine if changes have occurred over time to As-bearing mineral phases in the tailings facility as well as to investigate whether alternate neutralization techniques may have a beneficial effect on the stability of mineral phases formed. Thus a bench-scale model was developed and preliminary testing conducted to simulate the mill neutralization process (i.e. neutralization of synthetic raffinate solutions with incremental amount of slaked lime to terminal pH values). The resulting ?tailings? (precipitates and supernatant) were then separated and analyzed. XRD analysis of the precipitates shows that the Fe occurred mostly as ferrihydrite. This was complimented with results from Raman spectroscopy which further indicated that the As appeared adsorbed onto the ferrihydrite. Results of geochemical modeling of the bench-scale test compared well with supernatant profiles from ICP-MS analysis.

Aug 1, 2010

1.Overview of the Ministry of Energy, Mines and Petroleum Resources (MEMPR) 2.First Nations Perspective 3.Revenue Sharing Framework 4.Economic and Community Development Agreements (ECDA?s ) 5.Questions? The Ministry of Energy, Mines and Petroleum Resources (MEMPR) MEMPR manages the responsible development of British Columbia?s energy, mining and petroleum resource sectors. Through the promotion of teamwork and positive working relationships with our clients, MEMPR facilitates a climate for thriving, safe, environmentally responsible and competitive energy, mining and petroleum resource sectors. Works closely with others in Government (e.g.. Integrated Land Management Bureau) to engage First Nations in consultation processes as well as revenue sharing negotiations.

May 1, 2010

THIS article describes the origin and details of a hydraulically operated switch to control the operation of an automatic underground pumping system. This system was installed in December, 1939, on the 2,350-foot level at No. 5 shaft of the Buffalo Ankerite mine. The pumping unit consists of an 8-stage centrifugal pump direct-connected to a 150 h .p., 2,200 volt motor. Pumping capacity is 200 gallons per minute under a 1,315-foot head and with a flooded suction. The control consists of a 200 amp., 2,200 volt oil-immersed starter with thermal overload protection, thermal protection on the pump, and a flow switch that is bypassed for 30 seconds after the pump starts. The 30-second time lag is operated by a relay mounted on the panel. There is a swing check valve in the discharge line of the pump which originally operated the flow switch by means of a connected outside lever which closed the switch as the check valve opened.

Jan 1, 1945

By H. C. Gunning

The Privateer is the major mine of the Zeballos mining camp; with a total production from May 1937 through the first half of 1946 of $5; 610; 423 from 139; 254 tons of ore. This includes a small production from the connected Prident mine. The entire operation was closed from October 1943 to November 1945.

Jan 1, 1954