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By Kremena Dedelyanova

The paper presents research of mechanism for the creation of air bubbles in vibratory a column flotation machine. Factors are discussed that influence the increase in the duration of the bubble in the area of contact with the mineral particles. Formulas are derived for the parameter effect of vibrations, applicable to the design of flotation machine. The collision efficiency of the bubbles in a vibratory column flotation machine is determined.

Aug 1, 2013

By Jaana Romppanen, Satu Jyrkönen, Tiina Ranki, Peter Björklund, Markku Lahtinen, Kaj Eklund, Päivi Suikkanen

Outotec is continuously developing our existing process equipment and new equipment solutions to enhance the Flash Smelting process. Thanks to the long operating history of the Outotec Flash Smelting process feedback from the numerous operating references are available and is utilized. The general goals for development work are to improve equipment performance, thus realizing savings in Smelter plant operation costs by increasing the process efficiency and online availability. Digitalization also opens new possibilities for the feeding equipment and furnace operation monitoring. These solutions will improve the safety and performance of the smelter, and provide process and equipment related information which has not been available earlier. INTRODUCTION The year 2019 marks the 70th anniversary of Flash Smelting. The technology was operated on industrial scale for the first time at the Outokumpu Harjavalta copper smelter in Finland in 1949. The Flash Smelting technology, is now owned and developed by Outotec Oyj and the first plant, is now owned by Boliden Harjavalta Oy. The two companies have been evolving throughout history by optimizing the process for various feeds and raw-materials, as well as through developing the equipment and operating practices. Even though sustainability was not a hot theme/topic during the first days of Flash Smelting, it has nevertheless been the key principle in guiding the development. This is well proven by the wide adoption of Flash Smelting for the processing of copper and nickel concentrates, mostly due to its ability to fulfil the economic and resource efficiency criteria demanded by its operators. Along with the process technology development, also development of the equipment has taken place over time. Outotec is continuously working on developing our equipment to better suit the changing need of our customers in the continuously changing operational environment. Orebodies are getting more challenging with lower ore grades and more impurities. Achieving high recoveries for all valuable elements becomes more difficult with high slag quantities and with the need to tackle the high impurity concentrations. There is a need for higher capacities in greenfield and brownfield smelters. The role of the Loss-in-Weight Feeder, the Air Slide and Concentrate Burner is to ensure even feed into the reaction shaft of the Flash Smelting Furnace, and to enable controlling the process well, thereby enabling the best performance for the customers smelter. The design of the Flash Smelting Furnace aims for high availability, long campaign and safe operation.

Jan 1, 2019

By EJ. Reichhardf

The Molopo Farms Complex is a major, layered ultramafic/mafic, early Proterowic intrusion which is totally covered by sediments of the Karoo and Kalahari Fonnations and situated in southern Botswana and northeastern South Africa. The approximately 3000 m thick, generally fine- to medium-grained ultramafic and mafic cumulates are intrusive into equivalents of Thmsvaal Supergroup sediments and lavas. Multiphase defonnation resulted in tilting and segmentation of the Complex into individual tectonic blocks. Sr isotopes document at least two chemically distinct parental liquids which interacted in a complex manner to form an approximately 1000 m thick rhythmically layered succession which straddles the ultramafic/mafic boundary. Repeated mixing resulted in a complex cryptic layering pattern and numerous sulfide-enriched layers which contain significant PGE+Au concentrations.

Jan 1, 1994

Abstract-This paper discusses the fundamental question, "what is an adequate sample size?" in the light of recent developments regarding parameters of Gy’s well-known formula for predicting sampling variance. New understanding of the granulometric factor, g, and the liberation factor, l, had significant impact on the results of calculations involving Gy’s equation. For the granulometric factor, justifications are given as to why nominal comminution size should always be reported as P95 (i.e., the screen size rejecting 95% of the mass). A small but important change in the model to estimate the liberation factor makes the difference between a predictive formula that works or does not. Other parameters and considerations regarding their practical implementation are commented upon in light of the author’s experience.

Jan 1, 1998

By D. Royston

In SAG mills fed with a variety of ore types, hard packing between the shell lifters can come and go depending on rock type and rock size distribution and the presence of a binder. Packing can appear in all sizes of SAG mills, and can be tenacious. High ball impact forces (depending on ball size) in larger mills may compact and encourage packing. Packing can have a negative impact on milling performance and a change in shell liner design may be required to remove it. However shell liner design changes need to be managed with care to ensure liner reliability. In smaller mills control of packing can extend shell plate wear-life and may help to maintain milling performance in fixed-speed mills through the liner wear-cycle.

Jan 1, 2012

By David F. Machuca-Mory

Modelling the geometry of a vein is a crucial step in resources estimation. The resulting models are used as mineralization domain boundaries and have a direct impact on the tonnage of estimated resources. Deterministic models are often built using time consuming wireframing techniques usually based on hand interpretation of the drillhole intercepts. Another approach consists in coding the drillhole samples by a function of their distance to the veins contacts. The coding is subsequently used for modelling the vein contacts away from drillholes. This is a more efficient approach and is able to provide a measure of tonnage uncertainty. The use of location-dependent variograms improves the modelling by incorporating local changes in the anisotropy of the vein structure. This combined approach results in more realistic vein models, particularly when the geometry of the vein has been are altered by folding, shearing and other structural processes. The approach is illustrated on a realistic case study.

Oct 1, 2009

By Patricia Dillon

EHS Management Standards Communication and Reporting (8) ! Establish processes for internal and external communications ! Designate responsibilities for communication with COI ! Report as defined by senior management ! Report annually to employees, shareholders, COI on EHS and social performance Community Rights and Public Consultation (9) !Identify COI?s and establish process to hear concerns !Acknowledge and respond to complaints !Support local communities !Plan for closure and conduct public consultation !New projects include identification of COI?s, concerns to be considered in design

May 1, 2004

By Ron Doucet

Industry today is now more than ever dependent on its assets and on the standard of maintenance. Changes in technology, environmental regulations, a continually improving focus on safety and global competitiveness has made maintenance a key activity in sustaining safe, financially viable and environmentally integral operations. Maintenance used to be looked upon as a cost centre with a sole focus of fixing equipment to attain high availability. Maintenance today affects all aspects of the business: safety, environmental integrity, energy efficiency, productivity, costs, and product quality. These new demands on the function of maintenance requires us to think vastly differently about what maintenance is all about, even to the point of contradicting old beliefs. In the following paragraphs we will examine some of the changed thinking that has evolved over the last 50 years. These new concepts will lay the foundation for the implementation of 21st century best practice maintenance.

May 1, 2003

Introduction ?MT involves the measurement of naturally occurring magnetic and electric field oscillations. ?The ratio of E/H (wave impedance) is measured as a function of frequency to give resistivitydepth information. ?The ratio of vertical and horizontal magnetic fields (tipper) gives information about the location of (channeled) current systems.

May 1, 2008

By J. W. G. Hannon

FOLLOWING the experimental work of Denny, Robson, and Irwin, and the clinical investigation by Crombie and Blaisdell, an investigation of aluminium therapy was begun at Washington, Pa., which is situated in a very large industrial section of the State. Some of the men to be studied were from plants manufacturing silica brick, refractories used in steel and glass manufacturing, and semi-porcelain table-ware; others were workers in foundries, sand blasters, and men engaged in the quarrying of ganister rock. This group of workmen gave an opportunity to study the effects of aluminium on various types of silicosis which differed somewhat from that found in hard-rock miners. EXPOSURE In their occupations, the men studied were exposed to silica dust concentrations ranging from 17 to 97 per cent free silica. In the silica brick industries, the unfired product averages 96 per cent silica in the form of quartz, whereas the fired brick contains 50 to 62 per cent cristobalite plus 17 to 30 per cent tridymite, forms of silica that, on account of their higher solubility, are more toxic than quartz. The operational dust counts in the plants varied from 15 to 9,500 particles per c.c., and the median particle size from the aerial samples was 1.0 micron for the green product and 2.0 microns for the fired product. The length of exposure varied with the occupation as well as with the individual plant, but disabling silicosis could be produced in less than four years in certain exposures. The average time needed to produce radiological silicosis in those susceptible to this disease was eight years. Some of the men in our series of cases have been treated as long as fifteen years after exposure had ceased, and have improved under treatment.

Jan 1, 1944

By Paul E. Mather, Matthew J. M. Krane

Anode or fire refining is the final pyrometallurgical step in the production of copper anode. Part of this process purifies liquid copper by reducing its dissolved oxygen with a natural gas-steam mixture. Until now there have been no transient models of this process coupling the injected gas jet mass transport with its chemical reactions. A transient, 1D flow, chemical reaction model was made to estimate the time-dependent behavior of anode copper composition, soot formation, and the transient gas jet composition along its height. Model estimates were made for reduction rate, soot emission rate, and exergy loss and destruction distributions for two melt temperatures and a range of steam addition rates. It was found that increases to melt temperature and steam addition rate increased reduction rate and decreased soot emission, while having little effect on exergetic performance. Estimates for reduction histories were compared to industrial data. INTRODUCTION Anode/fire refining is the final pyrometallurgical step in the production of copper anodes; it is essential for removing dissolved gases which cause porosity in cast anodes. Despite its significance, the open literature appears devoid of any transient models of the entire process; furthermore, there are very little published process data with which to validate any models made. This dual dearth of modelling work and process data inhibits studies of the tradeoffs between process and performance changes, desirable for decreasing reduction time and soot formation as well as quantifying changes in the exergy losses and destructions of the process. This work introduces a reduced-order, transient model of reduction during fire refining, examines performance trends with operating conditions, and compares model estimates with industrial data. Overview of anode refining The purpose of anode refining is to produce liquid copper which can be cast with minimal gas porosity, which disrupts the downstream electrorefining process. Dissolved sulfur is removed first, then oxygen, by reactions with different injected gases. The removal of oxygen (the reduction step) is the subject of this proceeding and is effected by the bubbling of natural gas, typically mixed with steam, through the melt from tuyeres. A typical refining run reduces dissolved oxygen from 3000 ppm to 300 ppm in 2–3 hours (Schlesinger, King, Sole, & Davenport, 2011). The refined copper is then cast as anodes. Figure 1 shows a schematic of the furnace vessel.

Jan 1, 2019

By Osvaldo A. Bascur

Industrial complexes rely on measurements of flow rates, qualities, and concentrations for monitoring and optimizing their operation. Corporations use the data from the various sensors and measurements to make business decisions, which affect the profitability of the operation. However, gross errors, due to a variety of reasons like faulty sensors, bad instrument calibration, or incorrect process models may corrupt the actionable information supplied to operations, quality managers, and maintenance personnel. The solution is to use the sophisticated new tools to model the process, sift through the available data to locate the gross errors, and use statistical data reconciliation to validate the sensors and instruments. In this way the data are unified to give the most accurate plant information for use by the monitoring and decision making processes. Most mining and metallurgical plants use predictive maintenance policies based on statistical analysis and special techniques, like vibration analysis, and oil and lube analysis for critical equipment. Process control strategies are installed in several metallurgical sites. All of these depend on reliable and accurate data. The data unification methods validate the individual measurements by using the concept of balances and statistical techniques where each instrument is no longer independent of the other measurements in the facility. This paper refers to the data unification and analysis methods required for profitable plant operations. Continuous improvement and monitoring of the measurement system at the plant and analysis of the reconciled data provide the best information for the decision-making process. On-line gross error detection and elimination methods are required to ensure efficient evaluation of process performance and process optimization. An open discussion of the new methods for gross error detection and data unification will be presented.

May 1, 2001

By A. Ghahreman

Activated carbon is proven to be able to catalyze arsenic oxidation in aqueous solution under acidic conditions. A commercially available granular coconut shell based activated carbon (AC) has been evaluated for catalysis of arsenic oxidation in this study. The rapid small-scale column test (RSSCT) has been developed to simulate and predict the performance of a carbon-based arsenic treatment system in a pilot scale reactor. Effects of residence time, aeration rate, and initial arsenic concentration in the influent solution on the AC catalysis of arsenic oxidation under dynamic and continuous conditions were studied by manipulating these parameters during RSSCTs. The effectiveness of the AC on arsenic oxidation was examined over the course of constant diffusivity based RSSCT operation. Residence time and initial arsenite concentration are proven to be the most effective impacting parameters on the arsenic oxidation process. For the 218 min residence time, the highest steady-state arsenic oxidation efficiency achieved was 98% with 1 g/L As(III) being treated at pH=1 under 0.05 L/min oxygen aeration. In a long-running RSSCT, the oxidation efficiency did not seem to deteriorate over a course of 666 hours operation, corresponding to 13986 mL total influent throughput volume. INTRODUCTION Arsenic is toxic to both animals and plants and inorganic arsenicals are proven carcinogens in humans. The increased extraction of low grade and complex mineral resources has introduced high ratios of arsenic into metallurgical processes. Discharge of arsenic by acid mine drainage resulting from mining activities has added intensive pressure on the need for proper treatment (Lawrence & Higgs, 1999). Since trivalent arsenite is more toxic and has lower affinity to solid surfaces for adsorption, many treatment systems initiate with an oxidation step to convert arsenite to arsenate and reach the ultimate immobilization of arsenic by the following precipitation of arsenate (Nazari, Radzinski, & Ghahreman, 2016). Scorodite precipitation has been studied extensively as a means of arsenic immobilization due to its high stability and negligible potential of releasing arsenic (Filippou & Demopoulos, 1997). As a stable ferric arsenate mineral, crystalline scorodite can contain up to 30 wt% arsenic (Paktunc, Dutrizac, & Gertsman, 2008). Arsenic must be in its pentavalent oxidation state in order for scorodite to be precipitated via oxidizing ferrous ions (Clancy, Hayes, & Raskin, 2013).

Jan 1, 2019

"Since the publication of a literature review on this topic (McIvor and Finch. 1986), the author has been involved in more than thirty rod milling efficiency tests at seven different milling operations. There have also been several interesting additional articles on rod milling found in the literature. This update describes the most important findings from investigations carried out since the previous review, as well as developments in the techniques used to evaluate the grinding efficiency of rod mills.Rod Mill Power DrawA series of power draw versus charge level measurements were taken on the rod mills at Leg Mines Selbaie and Kidd Creek Mines Limited (McIvor. 1989). These revealed a significant (about 10070) loss in power draw with the installation of new liners, a common observation among rod mill operators. This loss in power draw depends on the liner design, particularly the average thickness and lifting face profile of the new liner. The theoretical power usage of both mills was approximately 5070 lower than that given by the Allis-Chalmers power draw formula (Rowland. 1982).The shape of the power draw versus charge level curve suggested an opportunity for reducing media consumption. By increasing mill speed, power draw could be maintained with a smaller mill load, most significantly for mills operating with high charge levels. Analysis of data from 62 installations confirmed this (McIvor, 1989). On average, a 10 percentage point increase in critical speed results in a 15070 in specific media consumption (Le. kg of steel consumed per kWh of energy consumed). Table 1 lists a number of relatively high speed rod milling installations. No negative effects on the drive train, liner life, or the tendency for rods to tangle have been reported. A reduced lifting angle of the new liner leading face (e.g. 45 versus 90 degrees from the mill perimeter) is recommended for higher speed rod mills (Leclerq, 1990)."

Jan 1, 1995

By A. Probst, N. Moores, J. A. Finch

"In 1994 McGill and INCO (Sudbury operation) initiated transfer of technology originally developed to detect level in flotation columns to thickeners. A conductivity probe was installed in a concentrate thickener to monitor the mud-line and solids load. The probe consisted in a vertical tube with 32 equally-spaced electrode rings connected in pairs to give 31 conductivity cells. Conductivity was measured as a function of depth (so-called conductivity profile) from which the mud line and % solids could be inferred. The probe was installed in October 1994 and has been successfully detecting profiles since then. This communication includes a description of incidents and experiences during this technology transfer process including: probe installation and start-up; software modifications to accommodate operating conditions and operators' needs; calibration procedures to adjust to changes in performance as a consequence of long term use; and preliminary observations on the last stage, still in progress, signal interpretation and use to facilitate operation, particularly by providing early reaction to upstream disturbances.IntroductionThickening is one of the basic unit operations in mineral processing and hydrometallurgy used to separate suspended solid particles from a solid-liquid dispersion by gravity settling. As the dispersion enters the thickener, the solids settle and clarified water overflows the top. A thickener, which may be continuous or batch, is basically a large vertical cylindrical tank provided with devices to feed the dispersion and to remove the settled solids. The tank provides residence time for the particles to settle. The dispersion enters the thickener through the feedwell whose function is to dissipate the momentum of the feed stream and to create relatively quiescent conditions around the entering point. Rotating rake arms move the settled solids towards the discharge point located at the bottom centre of the tank.There are normally three distinct zones in a thickener: a top layer of clear water, a middle layer called a sedimenting zone in which particles are settling, and a bottom layer called a compression zone in which particles are pressed together as a consequence of the weight of accumulated particles. Proper operation of a thickener requires two simultaneous conditions: no solids in the water overflowing the top and the target solids content in the underflow pulp. To achieve these conditions is difficult because sensors for detecting the sediment line (interface between clear water and sedimenting zone) and the solids content in the compression zone are not commercially available."

Jan 1, 1998

By S. M. Bulatovic, D. M. Wyslouzil, K. R. Rawlings

"The suitability of a new organic reagent DS20 as a depressant for oxidized and carbonaceous pyritic lead-zinc ore from Nanisivik Mines Ltd. has been evaluated in the laboratory and in the plant.The depressant DS20 is a mixture of Lignosulphonate-Dextrin-Quebracho and was developed specifically for depression of highly oxidized and carbonaceous pyrite.The laboratory test work indicated that the poor metallurgy resulting from the oxidized ore could be improved to normal plant performance by the addition of the DS20 depressant with the existing plant reagents. The laboratory data suggested that lime consumption could be reduced when using DS20.In this paper, the development work and the plant trials with DS20 are described.INTRODUCTIONNanisivik Mines Ltd. treats approximately 2000 tonnes per day of lead-zinc massive sulphide ore, containing currently 1% Pb and 9% Zn. The concentrator operations have been described previously (1,2) and typical metallurgical performance is detailed in Table I.The concentrator flowsheet (Figure No. 1) and the standard reagent scheme (Table No. 2) demonstrate the relative simplicity of treatment of this coarse grained ore.A recently discovered satellite orebody - Area 14 - containing 2% Pb and 12% Zn was brought into production in October 1983. This ore had been oxidized to varying degrees by ground water; the pyrite mineralization was found to be very fast floating and a carbonaceous constituent present in higher than normal proportion also affected flotation. The simple high lime addition could not control the pyrite, and very low grade lead concentrates resulted; zinc metallurgy was also affected by this oxidized condition (Table 3)."

Jan 1, 1986

By W. Andrew Falls

Although we have yet to reach the midway point in the decade, the copper concentrate market has already witnessed some of the most volatile swings in history, moving from record high treatment and refining charges in 1991-92 to historic lows, in real terms, during the past year. What has been the cause for such volatility? By and large the swings can be attributed to factors of supply and demand in the "custom" copper concentrate market. For example, two relatively recent events which had a major impact on the supply-demand balance were the shutdown of the Bougainville copper mine in Papua New Guinea in 1989 due to rebel insurgency and the startup of the La Escondida mine in Chile in 1992. The first event, threw a balanced to slightly surplus concentrate market into a substantial deficit, forcing treatment terms down as smelters, caught short by the loss of concentrate supplies scrambled to cover their positions. The second event, brought over 300,000 mt per year of new copper in concentrate to the market, more than reversing the losses from the Bougainville shutdown. In combination with other additions to mine capacity via new mines or expansions, the custom concentrate market moved into a huge oversupply in 1991-92 and many mines found themselves unable to place uncommitted tonnage. But even this event was quickly overcome by the use of underutilized capacity at non-traditional buyers, such as those in the C.I.S., Zambia, or those which were not traditionally buyers of custom materials. All of this has happened in the space of five short years, a mere snapshot in the history of the market. I'll return to these points a little further on, but first I would like to review the fundamentals which govern the copper concentrate market.

Jan 1, 1995

By T. Sugawara, H. Sekimoto

Electrorefining of low-grade copper alloys containing various amounts of nickel, lead, antimony, bismuth, arsenic, selenium, silver, and gold in sulfamic acid media was demonstrated. The copper concentration of the alloys used as an anode was 70–90 wt%. The electrolyte contained 100 g L-1 of free sulfamic acid and 40 g L-1 of cupric ion. Galvanostatic electrolysis was conducted at 200–300 A m-2 in the electrolyte using a low-grade copper alloy anode and a stainless steel cathode at 25C. The terminal voltage was approximately 0.8 V at the start of the electrolysis, although it increased periodically to approximately 2.0 V and then shortly returned to its initial value. Nickel, lead, and arsenic from the anode dissolved in the electrolyte and were removed. Antimony, bismuth, selenium, and silver were removed as solids. Consequently, a dense copper cathode was obtained, and the concentration of copper was evaluated by inductively coupled plasma – optical emission spectrometry to be 99.82–99.99 wt%. INTRODUCTION Electrorefining of copper is conventionally carried out in a sulfuric acid electrolyte using crude copper assaying at 99.5 wt% Cu as the anode (Biswas & Davenport, 1994). Elements more noble than copper do not react anodically, and consequently, they are distributed in anode slimes. Elements less noble than copper dissolve from the anode. Nickel and arsenic are stabilized as aqueous species. Lead, antimony, and bismuth react with water, sulfuric acid, or arsenic acid to form barely soluble compounds; thus, they are distributed in anode slimes. An emerging issue in the electrolytic refining of copper is an increase of impurities in crude copper used as the anode (Moats et al., 2013). This is due to an increase in the content of impurities in copper concentrates as well as an increase in the types of secondary copper feedstocks (e.g., E-Scraps, automotive shredder residues, and smelting residues) treated in the copper pyrometallurgical process. An extreme case is a copper smelter that does not use copper concentrates as feedstocks. In such a process, copper-bearing feedstocks are smelted in a top submerged lance furnace to prepare low-grade copper alloys assaying at 80– 90 wt% Cu (Sekimoto et al., 2013). Such low-grade copper is not acceptable as an anode in the conventional copper electrolytic refining process because it is easily passivated during electrolysis. Consequently, electrolytic copper is produced by leaching the atomized low-grade copper in a sulfuric acid solution with oxygen, followed by electrowinning. However, electrowinning should be avoided whenever possible because the electrical energy consumed in electrowinning is 5–10 times higher than that consumed in electrorefining. Therefore, the development of technologies for electrorefining of low-grade copper alloys is desirabl.

Jan 1, 2019

By David J. Forrester

Light metals, most commonly aluminum, magnesium and titanium, and alloys containing them, are used in many industrial applications where lightness, hardness, ductility and resistance to corrosion are needed. However, these metals and their alloys can be potential ignition sources in underground coal mines. There have been documented cases in the past where coal mine explosions have been attributed to firedamp/coal dust ignitions involving light metals or their alloys. When light metals and their alloys are brought into contact with oxygen bearing material, such as iron oxide (rust) in the presence of heat, then a "thermite" reaction can occur. This source of heat can be generated from frictional contact or from merely a glancing blow. This paper outlines the hazards associated with light alloys, how to address the hazard and regulatory aspects.

May 1, 2001

By A. S. MacNeil

In the operation of any colliery, a factor of prime importance is power, of which there are three sources available--man, horse, and mechanical. It is obvious that man-power is by far the most expensive, .and that animal-power, also, is more costly than mechanical. In recognition of this fact, mine owners must, for economical ?reasons, reduce the use of man-and horse-power to the minimum by the increased use of machinery. In other words, they must aim at as complete mechanization as conditions will permit, taking advantage of existing physical factors that are favourable and making the necessary adjustments and modifications to meet the less favourable conditions. Intensive coal-mining, or the concentrated production of coal, has two distinct objectives: First, the maximum production from a limited area, in a given time, thereby reducing the pit-room to be maintained; and second, reduction in cost. To this end the coal should be mined, loaded and delivered to the surface by mechanical means wherever possible. To do this, however, requires the solution of many problems arising out of the varying conditions that obtain underground. The system of longwall mining lends itself to a more efficient scheme of mechanization than does pillar-and-room, as, in the former, the first step has already been taken by the removal of all the coal in one operation, and the opening-out of one face, the equivalent in mining area of fifteen or more rooms. Much has been clone of late towards mechanization in the longwall mines of the Sydney coal-field, and with gratifying results, but not without great difficulties and frequent disappointments. In 1923, an attempt was made with shaker conveyors. The introduction of conveying was a step to bridge the gap between the face, where the coal is produced, and the main transportation arteries leading to the slope or shaft. The receiving of the coal at the faces and its delivery to main loading points on main haulage-ways was the part allotted to the conveyors.

Jan 1, 1932