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By G. M. Proudfoot

IN June, 1940, a .Longyear 3420 blast-hole drill rig was purchased by the Hudson Bay Mining and Smelting Company for the purpose of experimental blast-hole drilling. The early work showed that the diamond drill could compete successfully with the Leyners then in use and by January 1st, 1941, the diamond drills were placed on contract. They may be considered to have gone into production at that date. Prior to the introduction of the diamond drill, our bench drilling was clone with Ingersoll-Rand S-70 and S-83 Leyner drills. Holes up to 40 feet were drilled, using coupled 1 1/4-inch round steel. Bits with a gauge of 3 inches were used in starting these holes, with a drop of 1/8-inch gauge for each 2-foot run. The holes normally ended with 1 1/2 or 1 5/8-inch gauge, though bits down to 1 1/8 inches were available for holes longer than normal or for holes drilled in abnormally abrasive ground. This method of drilling was very satisfactory and was a distinct improvement on the three-bench method of drilling used previously (1). During 1937 and 1938, when experienced miners were available, Leyner long-hole drilling was carried on with great efficiency. However, in 1939 and 1940, labour turnover in-creased and experienced long-hole drillers became scarcer. This resulted in a marked decline in the efficiency of the drilling operations, with increased costs and less tonnage drilled per shift. EXPERIMENTAL WORK The initial diamond drilling test work was carried on with a Longyear 3420 air-driven blast-hole drill rig, drilling a 1 3/16-inch hole. Tests indicated that diamond drilling could be successfully adapted to local conditions and that overall costs compared favourably with costs obtained with the Leyner long-hole method. Leyner long holes on stope benches usually bottomed at a larger diameter than the 1 3/16 -inch diamond-drill holes. More powder could therefore be introduced into the Leyner holes than could be placed in the diamond-drill holes. To achieve the same fragmentation, additional footage was required when diamond drilling. Diamond-drill holes of larger diameter were indicated.

Jan 1, 1943

By F. Q. Barnes

"Uranium, thorium and yttrium have been recovered, since the 1950s, from pyritic quartz-pebble conglomerates occurring in the basal sediments of the Quirke syncline at Elliot Lake. Gold, an element of interest in similar type deposits occurring worldwide, is a very minor constituent of the Elliot Lake conglomerates because the provenance area of the sediments had few gold-bearing rocks.Uranium, thorium and rare elements are found in resistate and diagenetic minerals occurring in the matrix of the conglomerates. The valuable elements are recovered from the acid soluble minerals during the milling process.Large uranium reserves occur in mines found on both limbs of the Quirke syncline. Major reserves are being developed on the South Limb of the syncline, where the Stanleigh Mine, among four past-producers, has been reactivated.IntroductionUranium and thorium commonly occur in anomalous amounts in coarse basal sediments. Radioactivity in basal conglomeratic sediments is generally attributable to resistate minerals, that rarely occur in concentrations high enough to be of economic significance. One type of basal conglomerate found worldwide, in Precambrian cratonic basins, has uranium or uranium and gold concentrations large enough to be of economic interest. Principal among the occurrences are the pyritic quartz-pebble conglomerates of the Huronian in Canada, of the Witwatersrand in South Africa and at Jacobina in Brazil.The uranium and gold mineralization of these conglomerates was derived from provenance areas where both elements occurred and were later concentrated through source degradation and deposition in placers in a reducing environment. Only the Huronian conglomerates, generally much richer in uranium but with negligible gold, have been exploited solely for their uranium content.The uraniferous conglomerates of the Huronian at Elliot Lake, 500 km north of Toronto, continue to represent a major world source and supply of uranium concentrate."

Jan 1, 1986

By M. Mahdi, L. So, A. MacMillan, D. Metcalfe, J. Woloshyn, D. Sauter, N. Uys, JP. Janse van Rensburg

For city smelters, with limited real estate, efficient slag cleaning furnaces followed by water granulation to produce an iron silicate product is the preferred process approach. Water granulation, however, consumes large volumes of water and requires high maintenance due to abrasive slag/water slurries. Air granulation offers an alternative to water granulation, which eliminates water use and has low maintenance requirements. Although full-scale operation has not been implemented for copper slags, full-scale operation for platinum group metal (PGM) converter slag has been implemented. A review of full-scale air granulation performance for PGM converter slag is provided. Based on PGM converter slag granulation performance, parallels to copper slag granulation are drawn and full-scale operation for copper slag is modelled using computational fluid dynamics (CFD). INTRODUCTION Typical slag management practices in the copper industry include dumping, slow air cooling, and water granulation, as shown in Figure 1. Dumping is the most commonly used slag handling method for most metal production plants, but presents challenges including the requirement for a large slag pit, requirement for expensive/high-maintenance “hot” mobile equipment, risks associated with transportation of molten slag, and no value recovery from slag as a sellable by-product or from slag as a source of heat.

Jan 1, 2019

By R. S. Adhikari

This paper presents an innovative computer vision method for condition assessments of bridges with multiple defects in bridge elements using digital images. This work utilizes 3D model of existing bridges and overlays digital images on 3D model to simulate on-site visual inspection. The analysis of element condition index (ECI) of bridges requires information about the severity and extent of defects in elements. In general, ECI is evaluated manually during routine bridge inspection considering the severity of dominant defects. The evaluation of ECI with multiple defects needs to be addressed with consideration of dominant defect as well as the interaction among defects. However, Image-based quantification techniques largely depend on geometry of objects (i.e. shapes). Shape vectors of a given object change as they are translated, rotated, and scaled with different magnitudes. This work considers shape preserving algorithms such as, affine and projective transformation for proper image alignment. Semi-automated approach for detection and quantification of concrete distress such as cracks and spalling are considered for the defects analysis. The proposed methodology ensures the consistency in reporting ECI and eliminates the shortcoming of traditional approaches.

Aug 1, 2013

By T. Yalcin, S. Brunet

The flocculant-assisted hydrocyclone involves the addition of a flocculant to the cyclone feed for the purpose of obtaining a clear cyclone overflow, and thereby eliminating or reducing thickener requirements in tailings disposal operations. This paper describes the testing of this concept on the iron ore tailings of Quebec Cartier Mining Company's Mount Wright Concentrator. The current practice at Mount Wright makes use of conventional hydrocyclones and thickeners for the disposal of their tailings, which are generated in a spiral gravity separation circuit. The test work was conducted primarily on their cyclone overflow product which becomes the feed to the thickeners. A detailed study was carried out to determine the sedimentation properties of these tailings in terms of their response to a variety of flocculating reagents, and to varying conditions of pH, pulp density and flocculant dosage. The tailings were then processed in a laboratory hydrocyclone with the aid of flocculants. The use of a shear resistant flocculant, in particular, was found to yield cyclone overflows with low solids contents. Based on the test results obtained, a conceptual flow sheet has been proposed for the treatment of the iron ore tailings at the Mount Wright Concentrator.

Jan 1, 2004

By A. L. Hinde, H. Dong, J. T. Kalala

"The High Pressure Grinding Roll (HPGR) is gaining acceptance in the mineral processing industry and has become a competitive technology in reducing the specific energy consumption in Mineral processing plants. The amount of samples required for HPGR amenability testwork and HPGR wear tests is usually high and often cannot be available at early stage of projects were only a few drill cores are available.Although HPGR was initiated from small scale piston die compression tests, the development of small scale piston die test to predict the performance of HPGR has been slow.The objectives of this paper was to present the designs, operating procedure of piston-die press and operating conditions which have resulted in similar particle size distribution obtained from a piston die test and HPGR Labwal unit starting from the same feed size distribution. Testwork were conducted using a 2 MN piston-die press and a Labwal HPGR unit on major South African ore types, viz, gold, platinum and iron ores. The results obtained show that piston-die test can generate data to predict energy consumption, product size distribution, and even to evaluate the edge effect."

Jan 1, 2012

By M. E. Stutt, R. H. Rehder

"The mining industry is taking advantage of the increased performance resulting from the use of variable speed A C drives for large motors. This technology provides increased efficiency under the variable speed and torque requirements of such drives as mine hoists, conveyors, and air moving equipment. The technology does introduce voltage spikes on the voltage wave form that stress the insulation system to a greater degree than would occur with a constant voltage source. These voltage spikes must be considered in the design of the insulation system used for these motors.BackgroundHistorically the insulation systems for large AC motors were designed to withstand with reasonable life the voltage stresses of a 60 Hz constant sinusoidal voltage. One of the design tests is a voltage endurance test that requires the application of a 60 Hz voltage from conductor to ground equal to four to five times normal and establishing a time to failure. These higher than normal voltages accelerate the normal aging process by causing extensive partial discharge activity (corona) within the insulation system and the time to failure is a relative indication of insulation life.In addition to the voltage endurance test at 60 Hz, the individual coils are subjected to a surge voltage test to establish the withstand capability of the turn to turn insulation under switching surge conditions. The surge voltage is a fast rise time, 0.2 microsecond to crest value, voltage spike that can be caused by a circuit breaker or contactor closing operation. These voltage spikes can have a crest value of greater than 3.5 times the normal line to ground crest voltage of the normal 60 Hz power supply. The standard withstand test value is thus 3.5 times normal line to ground voltage. Because the voltage surges or spikes occur mainly during start and stop switching conditions, voltage endurance under these conditions has not been a major factor in insulation system design."

Jan 1, 1995

Flotation of a mineral bearing particle is the result of successful completion of a chain of events, such as, producing particles with sufficient exposure of the valuable mineral on the surface, reagent adsorption, suspension of the particle in the pulp, collision of particle with air bubbles and subsequent attachment, ascending to the froth column and transport to the concentrate stream, among others. These sub-processes in turn are affected by the feed properties such as size and density, and process variables such as size of air bubbles, degree of turbulence in the cell, particle/particle interactions etc.. Thus, inefficiencies occurring in any one or more of the above processes will result in inefficient flotation performance. In spite of its dependency on a wide variety of sub-processes, flotation performance is commonly modelled based on first order kinetics using two or three parameter models. As the model parameters may be affected by several of the sub-processes mentioned above, interpretation of their variations and identifying the specific causes is extremely difficult. Of the many factors that influence the flotation performance, liberation information of the particles such as the grade distribution and surface exposure are considered vitally important. In this paper, it has been demonstrated a) how a predictive liberation model may be derived and used in quantifying the liberation information of the particles produced at various grind sizes and b) how the flotation process may be modelled by explicitly incorporating the liberation information, thereby improving the accuracy of the model. Comparisons of the observed data with the proposed model and those of published liberation/flotation models have also been made.

Jan 1, 2016

By C. A. Young

"The stabilization of tailings has been a matter of concern to the Mining Industry for many years. In earlier times, when mines were small and only high grade ore deposits were mined, the problem was not a great one. But, more recently - during the last 30 to 40 years - the increased world demand for various metals, combined with the vast strides that have been made in the improvement of metallurgical extraction processes, have resulted in the development of lower grade ore bodies.About 30 years ago The International Nickel Company started experiments to stabilize the surface of the tailings and prevent them from becoming a dust source under certain weather conditions. The use of chemicals to form seals, covering with crushed stone, mulching with straw and some early seedings were some of the stabilizing methods tried. Results were either unsuccessful or impractical economically.In 1954 a series of experiments to establish vegetation on the tailings began. Varying degrees of success were achieved but however unsuccessful a particular scheme turned out, the attempt to find a solution was never written off. As we look back, we realize that the first significant break-through came as the result of three test plots planted in the spring of 1957. Each plot covered an area of approximately one-third of an acre. One plot was successful and persisted until it was covered up by the expansion of the tailings area in 1961.In 1960 a review of all our test plots to that date was carried out to assess the factors which effect the chance of grass being established."

Jan 1, 1969

By C. Paulo, W. N. Wheeler, M. Kalin, M. P. Sudbury

Many researchers have tested the addition of various phosphatic materials, including Natural Phosphate Rock (NPR), to mining wastes. It was assumed that iron in the waste would form FePO4 precipitates, restricting oxygen access to pyrite surfaces and reducing oxidation. Phosphate additions were based on stoichiometry (phosphate mass to sulphide content of waste). Although some interesting, positive results were obtained with low dosages, these were considered accidental, not having followed the expected stoichiometry. In 1991, we began experimenting on tailings and waste rock with NPR, postulating that if chemo-lithotrophic microbes on the mineral surface accelerate oxidation, then heterotrophic (oxygen-consuming) microbes would reduce oxidation. All wastes with NPR produced effluents with elevated pH and low metal acidity. Later, microscopic investigations of the rocks found an organic layer on the mineral surface, which was confirmed by independent research organizations repeating experiments with very low NPR mass additions to sulphidic wastes. In 2013, heterotrophs were identified and quantified as they grew on German lignite with NPR. These data conclusively showed that the development of heterotrophic biofilms is a consequence of adding waste NPR leading to a reduction of sulphide oxidation and improved effluent from sulphidic mining wastes. We document our gradual understanding of the effects of NPR on the reduction of sulphide oxidation, covering 23 years of research.

Jan 1, 2014

By X. J. Luo, F. Zhang

"Metallurgical slag (MS) such as steel slag, copper slag is a renewable resource and its compressive strength exceeds 200MPa in general. Because pure metal slug can easily be mixed into MS, complex recycle system is necessary in order to realize MS’s recycling. Meanwhile, there is high equipment failure rate in conventional crushing system. New crushing systems with inertial cone crusher could solve this problem very well. Recovery rate of MS tailings requires that crushing product can’t contain too much oversize product, so the essential equipment include two crushers and one sieve in the traditional crushing system. The new crushing system which only includes two crushers can meet the requirement and simplify the crush process. Investment of crushing equipment and infrastructure can be cut down. Operating and maintenance costs can be obviously reduced due to the simple process, which also could achieve high energy saving and excellent economic efficiency.INTRODUCTIONMetallurgical Slag (MS) such as steel slag, copper slag is a typical industrial solid waste and it threatens our environment’s safe. Metallurgical enterprises must take action to settle these wastes in order to protect our environment. Because pure metal slug can easily be mixed into MS, its uniaxial compressive strength (UCS) will exceed 200Mpa. If crushing station employs traditional crushing equipment, equipment failure will be easily caused because of these pure metal slugs. Coarse crushing equipment usually adapts jaw crusher in traditional Crushing technology and rod mill will be utilized to finish the secondary and fine crushing works. And the same time screening machinery should be used to ensure the suitable particle size (Figure 1)."

Jan 1, 2016

By M. Coleman, M. E. Reed

The control of feed delivery quality to the flash furnace remains an unsolved problem. Many operations around the world still have limited control of feed quality to their flash furnace. Schenck Process and WorleyParsons continue to work towards the ‘holy grail’ of simple quality feed delivering both radial feed distribution and pulseless feed delivery. Ten years ago they joined forces to offer a system based on then Clyde Process RotoFeed system which could deliver ground level installation, online mixing of materials, pulseless feeding direct to the burner, with good radial distribution. Unfortunately, this proved to be too large a step for the Flash Smelting community and met with resistance from the process owners. Since then the community has developed a range of options some of which have been implemented over this period. Despite these improvements there are still areas of concern including safety issues associated with concentrate leaks and spills, uncontrolled variations in feed rate including massive flooding events, intermittent distribution improvement and set up of the burner continues to be trial and error and hard to repeat the success in each burner campaign. These continue to impact flash furnace performance globally on a daily basis. Following the community reticence to pursue the complete solution a number of interim steps are now available to pave the way to the ultimate feed system. The mixing of material has been installed and is delivering line blended materials on a daily basis. This paper will investigate the developments over the last 10 years and discuss the pros and cons of this incremental step process for overall furnace control. INTRODUCTION Schenck Process and WorleyParsons have continued to interact and observe changes in the flash smelting industry and to consider application of the Clyde RotoFeed now incorporated in the Schenck Process ProStreamTM range for delivery of feed directly to the concentrate or matte burner. Schenck Process pneumatic injection from the Clyde Process range, ProStreamTM, utilises two types of volumetric feeders to accurately control the feed of material into an injection pipeline. These are referred to as the RotoFeed and RotoScrew technologies and the choice of feeder type is dependent on the characteristics of the material to be handled. The RotoFeed is generally used for finer, granular and powdered materials which cannot be accurately handled with a screw such as pulverised coal and copper concentrate, whilst the RotoScrew is particularly suited to coarser lump materials, particularly abrasive of cohesive materials like zinc powder, electronic scrap and metal ashes. Both units can operate at high pressures and many systems work at 3 to 10 bar with the occasional system working at 20 or 30bar for carbon to gasifiers. For the Flash furnace the ProStreamTM units can be used to deliver each of the furnace feed materials into a single line, mixing the materials homogeneously and live to the burner.

Jan 1, 2019

By Robert B. Parsons

"New Brunswick Finance Minister John Baxter pulled something out of a hat for the mining industry in April, but there is a general concensus in the industry that he should put II back where it came from.The industry has never been in the mood f or progressive rate structures, but that is exactly what New Brunswick 's 1984 budget offers to this depressed sector of the economy.IntroductionThe Province of New Brunswick stunned the Canadian mining community in April with the announcement that the province' s 16% mining tax rate would be replaced with a progressive rate structure effective January 1, 1984 (Table I). The proposed change, contained in the bud get papers tabled by Finance Minister John Baxter on April 17, caught the industry totally by surprise. The move to a progressive rate structure was completely unexpected for a variety of reasons:• Generally speaking, relations between the province and the industry have been relatively good, yet the industry was apparently not consulted with respect to the proposed measure and had no indication that a change of th is nature was coming. This is in stark contrast to the mood which prevailed during the major revamping of the province' s mining tax regime in 1977: at that time, the industry was invited to contribute in advance to the province's plan for a new tax structure.• The new structure would appear to make th e province less competitive in terms of mining tax rates with Ontario , Quebec, and other provinces, despite indications in the past that New Brunswick is very cognizant of this competitive factor in formulating mineral policy.• A joint report in November 1978 by federal and provincial officials to federal and provincial finance and resource ministers, which was careful not to directly criticize Ontario and Quebec's progressive mining tax rate structures, recommended that provincial "" tax regimes be examined to ensure the inclusion of appropriate mechanisms to avoid the excessive taxation of cyclical type profit "" , and that ""the federal and provincial governments consider the concern over progressive tax regimes expressed by the industry and examine mining and royalty tax regimes and the income tax regime with a view to alleviating the effect of such regime on the aggregate marginal tax rate"". In this context, any move to a progressive rate structure would be viewed by many observers as retrograde."

Jan 1, 1984

By K. Purazrang, P. Sh. Naseri, P. Abachi

In present work, the comparative measurement of aluminum alloys' resistance to the unstable fracture was provided. Besides, the rupture mechanisms of high strength 7075 and 7050 aluminum alloys were investigated. The specimens were used as solution treated, quenched and aged condition. The elastic-plastic behavior of specimens was determined by carrying out tensile test on cylindrical specimens. The small sized specimen with 6.35 mm thickness and V-notched radius less than 60 µm was used for evaluation of damage properties, in accordance with ASTM B871-96 standard test method. All tear specimens were machined in L-T orientation. The mechanical tests were conducted at RT on an universal Instron machine under cross head speed of 0.1 mm/min. The results of mechanical tests made the evaluation of tear strength to 0.2 % tensile yield strength ratio, as a measure of notch toughness, available. The comparison of specimens' resistance to crack propagation and unstable fracture due to the presence of crack-like strain concentrator was provided using tear test data. The microstructure of specimens was studied under optical microscopy. The rupture micro-mechanisms were analyzed by examination of specimens fracture surfaces using SEM. The microstructure examination indicated almost equiaxed grains on the transverse directions and elongated grains on rolling direction. Moreover, intermetallic particles were evident at microstructure. Considering the SEM fractographs, it seems that the intermetallic particles act as void nucleation and damage initiation sites. However, the damage mechanism of tensile specimens and severely notched specimens, especially near the notched root differs due to stress and strain states.

Jan 1, 2006

By E. Burdukova

Long-chain primary amines are utilized as collectors in potash ore flotation. Krafft temperature of long-chain amines in brine is about 100 °C, and this makes such amines practically insoluble in brine at room temperature. When dodecylamine, melted at 70 °C and dispersed in hydrochloric acid (or acetic acid) aqueous solution, is added to a KCl-NaCl saturated brine at room temperature, the amine precipitates. The experimental results demonstrate that the precipitating amine hydrochloride particles are selectively abstracted by KCl particles, but not by NaCl particles.

Jan 1, 2009

By K. Ohto, B. B. Acihikari, H. Kawakita, M. Gurung, S. Alam

Two kinds of adsorbents were prepared from persimmon tannin extract to investigate their adsorption behavior of metal ions from hydrochloric acid solution; one was prepared by treating with concentrated sulfuric acid while another was prepared by immobilizing functional groups of quaternary amine. The former adsorbed only gold(III) and its maximum adsorption capacities was evaluated as high as 1510 g/kg while the latter adsorbed not only gold(III) but also palladium(II) and platinum(IV), the maximum adsorption capacities of which were evaluated as 820, 89 and 101 g/kg, respectively. For both adsorbents, practical adsorption of base metals was not observed.

Jan 1, 2011

By D. L. Johnston

"Function and ApplicationsWater-only cyclones, (WOC) are a dynamic mineral separator which cause minerals to separate in a water medium by virtue of difference in specific gravity. Figure 1 shows diagramatic plan and sectional views of a water-only cyclone.A slurry of mineral matter and water is fed through the inlet opening under gravitational or pump pressure. The combined effect of centrifugal action and conical shape is to concentrate the heaviest fraction of mineral on the periphery and bottom of the cyclone. This layer of higher specific gravity particles increases in thickness and density between the cyclone inlet and apex. The action in the bed of higher gravity particles formed in the flattened portion of the cone surrounding the tip of the vortex finder deter;nines the specific gravity of separation or cut-point. Mineral particles of lower specific gravity flow with the bulk of the water, out the vortex finder. Mineral particles of higher specific gravity flow with little water out the apex. A more technically e:mct description of the functioning of the water-only cyclone can be found in previous publications noted in the references.The water-only cyclone was invented and refined by J. Vis man, formerly of the Canadian Mines Branch staff, between 1958 and 1965. The first industrial application noted in the literature was when it was introduced as a cleaner for fine coal in 1962. Since 1970 the water-only cyclone has become a common separation apparatus in many Canadian and foreign coal processing plants. The only other mineral industry application known to the author is in separation of gold bearing heavy minerals from sand<'>. The potential does exist for other applications and this area deserves to be investigated more thoroughly than it has been."

Jan 1, 1989

By Z. Zhao, B. Li

"Fractures are the key channels for fluid flow and mass transport in fractured rocks of low/negligible matrix permeability. In single rock fractures, surface roughness causes fluid flow in tortuous paths, and reduces the overall fracture conductance. A number of empirical models have been proposed to relate the reduced hydraulic aperture to the mechanical aperture due to surface roughness, which were revisited and compared. Using two of those relationships between hydraulic apertures and mechanical apertures, we studied the influences of local surface roughness of fractures on fluid flow and solute transport processes at the macroscopic scales of fracture networks. The results show that fracture roughness can affect the flow rates and residence time to varying extent, mainly depending on the empirical models between hydraulic apertures and mechanical apertures. However, fracture roughness has negligible influences on the general patterns of fluid flow (channeling) and solute migration (e.g., travel paths and shape of breakthrough curves). This is because the connectivity of a fracture network is mainly determined by other geometrical parameters (fracture positions, orientations, and lengths), rather than roughness or apertures. INTRODUCTIONIn fractured crystalline rocks of low or negligible matrix permeability, fluid flow and contaminant migration mainly occur within the connected fractures. An understanding of fluid flow and contaminant migration in fractured rocks is a crucial issue in many deep underground projects, e.g. underground repositories for radioactive waste, CO2 sequestration, enhanced geothermal systems, oil and gas production, etc. Rock fractures are typically rough-walled, and surface roughness appears to have first order control on the mechanical and hydraulic behavior of single rock fractures (Boutt et al., 2006).It is well known that the mechanical aperture of a rock fracture is usually larger than its hydraulic aperture, due to fracture surface roughness (Tsang and Witherspoon, 1983). However, for naturally fractured rocks including numerous discontinuities, the effects of this reduced hydraulic aperture in local fractures on macroscopic fluid flow and solute transport in complex fracture systems still remain unclear. Many previous studies assumed identical hydraulic and mechanical apertures in discrete fracture network models for simplicity (Min et al., 2004; Zhao et al., 2011). Therefore, the main objective of this study is to evaluate the influences of local surface roughness of fractures on fluid flow and solute transport processes at the macroscopic scales of fracture networks, by employing the empirical models that relate the hydraulic aperture to the mechanical aperture."

Jan 1, 2015

By Jaroslaw W. Drelich

Despite the success of DLVO and extended-DLVO models that have been developed for homogeneous and smooth surfaces, a vast majority of practical surfaces encountered in mineral ore beneficiation are typically rough at various scales; they are also typically heterogeneous. The interactions of gas bubbles with particles having rough and heterogeneous surfaces are much more complex than the commonly used DLVO or extended-DLVO models predict. The effects of surface roughness on flotation and colloidal interactions have been reported many times in the past, although a clear understanding of their origins has been lacking. To explain differences in colloidal interactions for spherical hydrophobic particles, a theoretical analysis of the interaction potential was carried out for a model rough particle interacting with a bubble surface in an electrolyte solution in this study. The attractive hydrophobic interaction potential was added to repulsive retarded van der Waals and repulsive electrical double layer interaction potentials. The rough microscopic particles were modeled as spheres decorated with nano-sized asperities. Parameters that reflect common flotation separation systems were selected for testing this theoretical model and computation of the energy barrier applicable to particle – flat bubble surface interactions. It was found that hydrophobic asperities with the height of only several nanometers can reduce the repulsive interaction energy by an order of magnitude. Theoretical analysis also reveals that surface coverage of microscopic particles by nano-sized asperities is important as well. The findings of this research suggest that manipulating and engineering the particle surface topography could lead to better control over flotation separation.

Jan 1, 2016

By Mei-Yan Yang, Qiu-Ying Wang, Ltd. Yunnan Yuntong Zinc Co., Guo-Mu Chen, Meng-Yang Huang, Peng Zeng, Guo-Feng Li

"Historically, alot of jarosite was found in the leaching residue when leaching indium from secondary zinc oxide materials. The reasons for the formation of indium bearing jarosite were theoretically analyzed. The influence of controlling the acidity and the addition of reagents on the indium leaching yield during secondary zinc oxide processing was investigated. In order to increase the leaching yield of indium, a measure of controlling the creation and destruction of jarosite was proposed. The production data shows that the leaching yield of indium was increased from 60 to 96%, and the content of indium in leaching residue simultaneously decreased from 900g/t to 100–200g/t when implementing such controlling measures.INTRODUCTIONIndium does not occur as independent minerals in the earth’s crust and is mainly associated with complex sulphide minerals. Specifically some sphalerites can contain as much as 900g/t of indium. Most indium is recovered from by-products of copper, lead or zinc metallurgy. Therefore, the research on the recovery of by-products in non-ferrous metallurgy is important(Sinclair et al, 2006). The main technologies used for this objective in China include: •,pre-neutralization-reduction-precipitation indium process(Yu et al, 2008), •,countercurrent oxidizing acid leaching process and sulphation roasting-water leaching process(Cao, 2005), •,oxygen pressure acid leaching of zinc concentrate-P204 extraction process(Yang et al, 2006), •,doubleacid leaching-solvent extraction process on lead dross from a reverbatory furnace flue dust(Liu, 2003),•,an acid leaching-solvent extraction process on smelting ash(Zhouet al, 2005). Although high pressure and extreme conditions can be used to improve extraction from high iron bearing indium residues(autoclave processing), mild extraction with lower cost and lower environmental impact are preferred.This paper describes both how the indium extraction using mild conditions in a secondary zinc circuit was quite low and, how through XRD and chemical analysis jarosite formation was found as the main cause. The paper then proceeds to discuss a method for improving the leaching yield and the application of this method in industrial practice."

Jan 1, 2016