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By G. Dodbiba, A. Otsuki, T. Fujita, J. Ponou, A. Shibayama

"The different types of nano to submicron particles, which are well-dispersed nano particles, coagulated nano particles or settled submicron particles, have been measured by the interactive force apparatus (IFA). The information is very useful for mineral processing treatment. The IFA can measure the particle size distribution in low to high concentration of particles in liquids and non-light transparent liquids. Here, mainly the emulsion and bubble size measurements are described.Emulsion (w/o type) is prepared with oil and water mixture. The nano to micro emulsion particle size is usually measured by light scattering method. The particle size distribution of emulsion of light oil measured by IFA agreed well with the one by the dynamic light scattering (DLS) method. The water size distribution in emulsions of gasoline is difficult for the small reflection index and C heavy oil is difficult for the black color by DLS method. The IFA can measure both emulsions.There are many methods to measure fine air bubbles, however, the finer nano size measurement apparatuses are DLS method and IFA. A “ghost” peak appeared in the large particle micron meter size in DLS method. The mean diameter in IFA is similar with DLS for the nano meter size. INTRODUCTIONParticle size distribution measurement of nano to submicron particle, emulsion and bubble size distribution are very useful for ultrafine particle separation and characterization of fine particles by the necessity of recent fine minerals separation (For example, Li et al.2016, Mikhlin et al.2016, Wang et al.2013). As for the size measurement of solid particles in liquids, three different types of nano to submicron particles, that are well-dispersed nano particles, coagulated nano particles or settled submicron particles, have been measured by the interactive force apparatus (IFA). The particle size distributions are compared with the one of dried particles measured by TEM or SEM. The well-dispersed nano particle size distribution by IFA is influenced by the nano size surfactant micelles and becomes smaller, when compared with the TEM result. The size distribution of nano size of magnetite particles in water is influenced by the isoelectric point and the mean diameter of coagulation becomes larger. The particle coagulation in diluted suspension is about 2nm smaller when compared with the higher concentration. The submicron nickel particle size distribution is well agreed the result by SEM. The coagulation effect is small in the submicron size of nickel powder in water (Fujita et al., 2013). In this paper, the emulsion and bubble size measurements are mainly described."

Jan 1, 2016

By Takao Oishi, Go Ohara, Toru Kitazaki, Masahiro Tanaka

"The High Pressure Acid Leach (HPAL) plant for nickel-cobalt mixed sulphide production at Coral Bay Nickel Corporation (CBNC) in the Philippines has been in operation since 2005 with a capacity of 10,000 t/year of nickel. Subsequent to the commissioning of the second plant in 2008, the production capacity increased to 22,000 t/year of nickel (Llerin et al., 2011). CBNC’s annual nickel production reached more than 24,000 tons of nickel in 2014. The concepts to achieve this capacity are the high availability and the reciprocally flexible operation of both plants. The availability depends on some factors, such as the control of impurities in the process and the equipment condition, to mention a few. In the HPAL process, it is not only the autoclave operating conditions that affect nickel extraction but also the impurities in the ore greatly influence it. The major element in the ore is iron and most of this iron is precipitated as Fe2O3, while the rest remains as Fe2+ or Fe3+ sulphate in solution. These ions in solution reduce the availability, so it is important to control the formation of iron ions by controlling the impurities in feed ore as well as the HPAL conditions. This paper presents the general HPAL process and the behaviour of impurities, focusing on iron behaviour in the HPAL process.INTRODUCTIONCoral Bay Nickel Corporation ProfileCoral Bay Nickel Corporation (CBNC) was founded on April 2002, as a joint venture of four companies; namely, Mitsui Corporation (18%), Sojitz Corporation (18%), Nickel Asia Corporation (10%) and Sumitomo Metal Mining Corporation (SMM) with a controlling stake of 54%. Aside from its capital share, Nickel Asia Corporation also supplies the ore and limestone for the High Pressure Acid Leach (HPAL) plant located in Rio Tuba, Philippines, as shown in Figure 1 (Tsuchida, 2008). The objective of the CBNC project is to produce 22,000 t/year (original design) of nickel and 1,500 t/year of cobalt, as sulphide, by the treatment of nickel laterite ore which is a low grade nickel oxide ore in the Philippines (Mines and Geosciences Bureau, 2014). The sulphide product has been exported as a raw material to the SMM Nickel Refinery in Japan for 30 years. The product of this plant, a mixed (Ni/Co) sulphide, is shipped to the SMM’s Nickel Refinery in Niihama, Japan. SMM Corporation provides the technology and management personnel to the plant. SMM Corporation also supplies the sulphuric acid, which is the main reagent for the HPAL process."

Jan 1, 2016

By V. H. Valenzuela

Materials in process or in stocks are quite relevant items in almost every plant, particularly in mining operations, where efficiency in rate of recovering material of interest becomes a key issue when production costs are evaluated. A manager requires information to do an effective use of the resources, especially when raw materials are involved. Losses associated to leaking, efficiency in the transformation process, performance of equipment, and operating conditions are a short list of items which must be properly identified and evaluated. Operations supervisors require information in order to keep key process variables under control. Because of these information needs, it is absolutely necessary to carry on a series of activities related with installation and maintenance of measuring equipment, sampling equipment, sample preparation, chemical analysis, statistical analysis, data handling and reports generation. These pieces of data must be managed on a wise manner in order to get the most of it, keeping always on mind data reliability. Normally, information related with metallurgical balance and even more, the metallurgical balance concept, is handled under an accounting criteria which does not allow dealing with the real world. This situation happens because the criteria utilized do not consider aspects such as bias and uncertainty associated with every measurement that affect the quality of the information and therefore conclusions drawn from it. The purpose of this paper is to give a few rules, necessary to follow, in order to develop an adequate Metallurgical Balance System for an operational point of view. The Gaussian approach for error propagation is used as a basis, allowing one to know the actual uncertainty of the balance and the way how it can be improved. A few real applications of this concept are listed, detailing experiences obtained from practice.

Jan 1, 2007

By Otto Engel

"A multipurpose program for a hand-held programmable TJ-59 calculator and PC-100C printer facilitates the evaluation of various mineral processing tests and the calculation of mass and metal balances. Its application is demonstrated by some example problems. Detailed user instructions are given for each application.IntroductionThe program listed in Appendix I is written for a programmable Texas Instruments TI-591 PC-100C calculator I printer combination. The program is applicable for the evaluation of:1) screen analyses;2) flotation test s; and3) mass and metal balances.Each application is demonstrated by an example problem and corresponding detailed user instructions. The ""measured"" data in the examples are fictitious and do not represent a real operation.The steps in using the program are the same for each of the three types of application, viz.:1. Enter the number of product fractions and press ""A"".2. Enter the measured weights (0) of each fraction and press ""RIS"" each time. After the last fraction has been entered, the printer automatical1y displays the total weight.3. Press ""B"" to calculate the weight distribution (Y). Once ""B"" is pressed, the printer automatically displays the weight distribution of all fractions.4. If the accumulated weight distribution (EV) is also needed, press ""RIS"". The printer now displays these data. This step is optional and may be bypassed.5. Press ""2nd A"" to prepare for entering of the measured metal assay (M).6. Enter the measured metal assays of each fraction and press ""RIS"" each time. If analytical data exist for more than one metal, each data set has to be entered separately in one sequence.7. Press ""C"" to determine the ""calculated"" head assay (MA) of all fractions.8. Press ""RIS"" to calculate the metal distribution (R). Once ""RI S"" is pressed, the printer automatically displays the metal distribution of all fractions. This operation is optinal and may be bypassed if desired.9. Again press ""RIS"" to obtain the accumulated metal distribution (ER). This operation is optional and may be bypassed.10. Press ""D"" to calculate the gangue distribution in the concentrate (W). One ""D"" is pressed, the printer automatically displays the data for all fractions. This operation is optional and may be bypassed.11. Press ""RIS"" to obtain the accumulated gangue distribution (EW). This operation is optional and ma y be bypassed.12. For more than one metal, press ""E"" to clear the memory for storing the assays of the next. Then press ""2nd A"" and start entering the assays of the next metal as described previously (6 to 11). Steps 5 to 12 may be repeated as many times as desired."

Jan 1, 1982

By Avinash Kandalam, Markus Reuter, Jörg Kleeberg, Michael Stelter

The Top Submerged Lance (TSL) technology has obtained significant importance in the pyrometallurgy industry for nearly four decades. One of the advantages of TSL furnace is its high reaction rate, which is caused by splashing and turbulence of the melt. In contradiction, this phenomenon stands as a barrier for conducting experimental investigations to validate the simulation models. The highly turbulent and splashing environment in the TSL furnace is caused due to the immersion of the lance into the slag layer and thus the effect of the flame structure is directly related to the splashing, turbulence, reaction kinetics and life-span of the lance. Moreover, the material properties such as viscosity, density and the surface tension will also influence the flame structure. As a first step to understand the flame structure, attempts are made to generate a stable flame of the lance in an open environment. INTRODUCTION Top Submerged Lance (TSL) technology was invented during the 1970s at Commonwealth Scientific and Industrial Research Organisation (CSIRO), Australia by Floyd and Denholm. This technology was later commercialised and currently, there are about 100 TSL plants around the world commissioned by various licence holders such as AUSMELT (Outotec) and ISASMELT (Xstrata- Glencore Technology). Copper is the most produced non-ferrous metal followed by lead and zinc, see Hunt (2005). Today, a wide range of primary, secondary, and complex recycling materials are used as a feed material in the TSL, Alvear et al. (2010), Kaye et al. (2008). The working principle of TSL technology lies on inserting and submerging a lance from the top of a vertical cylindrical chamber into the slag layer. The lance is considered as the heart of the furnace, where the air and fuel are transported through two concentric tubes and are mixed in a combustion chamber, which is approximately 7 cm from the tip of the lance (considering the pilot-scale TSL furnace at the Institute for Nonferrous Metallurgy and Purest Materials - INEMET). The TSL furnace is very flexible with the type of fuel, feed material and the air input. The fuel can be natural gas/heating oil/fine coal particles and the air could be enriched with oxygen (Figure 1). The general mechanism of the TSL furnace lies on feeding the material from the top of the furnace and the material is pulled into the molten bath due to the high turbulent atmosphere, which results in high reaction rates. The thermocouples installed in the furnace (i.e. in the ceramic linings) allow the operator to know the temperature of the melt. For example, in the case of copper production the tapped material (i.e. matte/metal) can be transported to a settler for further processing or directly used.

Jan 1, 2019

By J. Oliver, B. Wilson, 10

"Red Dog is one of the world’s largest zinc producing mines and a significant producer of lead and silver. While some of the operational challenges relate to the mine’s location in a remote part of Alaska, there are also challenges in the mineral separation process. Recent processing upgrades have included the installation of two M5000 IsaMills to improve the zinc regrind circuit and of one Jameson Cell to improve the pre-flotation circuit. Relatively fine grinding is required to achieve efficient mineral separation at Red Dog, but while fine grinding aids in the production of high grade concentrates, it also creates challenges in the efficient recovery of fine minerals. Over half of the lead lost to the lead circuit tailings, as well as almost half of the zinc lost to the final tailings, is in the finer size fractions (<10 µm). The high pulp density experienced in the pre-flotation and lead rougher circuits also causes significant entrainment loss of lead and zinc to the pre-flotation concentrate and of zinc to the lead concentrate. To help improve fine mineral recovery, Red Dog has recently plant tested and installed magnetic conditioning technology in the flotation circuits. The equipment aggregates fine paramagnetic sulphides and selectively increases their flotation recovery. This paper outlines the testing and positive results at Red Dog.INTRODUCTIONRed Dog is the largest zinc mine in North America and represents approximately 29% of North American zinc concentrate production. The mine is located in northwest Alaska, approximately 100 miles north of the Arctic Circle and 50 miles inland from the Chukchi Sea. The remote location makes the mine accessible only by air or seasonally by ocean-going barges. Red Dog is a partnership between NANA Regional Corporation Inc, the land owner and Teck Alaska Incorporated, the operator of the mine. Red Dog Ore and Mineralogy The Red Dog deposit is a rich sedimentary exhalative (sedex) zinc-lead-silver deposit. The main minerals present in order of abundance are: quartz, sphalerite, pyrite, barite and galena. Production began in 1989 with mining of the Main deposit. Between 1989 and 2012, approximately 55.6 million tonnes of ore with an average grade of 20.5% Zn, 5.6% Pb, and 97 g/t Ag was mined from the Main deposit. Subsequent to the development of the Main pit reserve, two additional open pit deposits were discovered: Aqqaluk and Qanaiyaq. The first blast in Aqqaluk occurred on June 4, 2010. As of December 31, 2014, the Aqqaluk deposit reserve is an estimated 45.7 million tonnes of ore with an average grade of 15.1% Zn, 3.9% Pb and 71 g/t Ag."

Jan 1, 2016

By C. Sui, J. E. Nesset, M. Li, J. Y. Kim, S. L. Chryssoulis

"A plant study of zinc rougher flotation at Brunswick Mining was conducted using lime, soda ash and a combination of both as the pH modifiers in order to establish the effects on sphalerite and pyrite kinetics and mineral selectivity. The plant sampling and analysis was augmented by surface analysis using TOF-LIMS, SEM and XPS as well as fundamental precipitation and surface-charge studies in the sphalerite Ca/C03/S04 system.The results revealed the important role of carbonate ions in cleaning the sphalerite surface for effective activation by CuS04 to occur, and the beneficial role of combined soda ash and lime in increasing pyrite and galena depression.1.0 IntroductionThe studies reported in this paper were initiated as part of an investigation into the causes of a particularly pronounced seasonal deterioration in metallurgical performance at the Brunswick Mining concentrator during the summer of 1995. The concentrator treats a complex base metal ore having a typical feed composition of 9.0% Zn, 3.5% Pb, 0.4% Cu and 100g/t Ag at a current throughput of 9,000 TPD, although at the time of the problem in 1995, the average production rate was closer to 10,500 TPD. Zinc, lead, copper and bulk (zinc-lead) concentrates are produced with overall metal recoveries of 86% zinc, 63% lead, 60% copper and 60% silver; results which are typical of the lower recoveries associated with fine-grained, highly complex VMS and SEDEX type deposits. The main economic minerals of interest are an iron-containing (7% Fe) sphalerite, galena and chalcopyrite with the main diluent (about 60% wt) being pyrite.Figure 1 shows a simplified flowsheet of the Brunswick milling circuit while the seasonal decrease in summer metallurgy in 1995 is illustrated in Figure 2. Of significance is the rapid drop in copper and lead recovery in June while there is an apparent delay until late August-September before the zinc deterioration reaches its lowest point. A more typical seasonal effect within the experience of the authors is the reverse of the Brunswick situation, namely an improvement in summer performance thought to be associated with improved differential flotation kinetics during warmer weather leading to better mineral selectivity. The historical Brunswick experience was particularly severe during the summer of 1995 with estimated incremental losses of $10 Million for this period. The potential of the very significant economic benefits to be gained from understanding and hopefully improving the annual drop in performance led to an investigation involving the minesite metallurgical group, the Noranda Technology Centre (NTC) as well as researchers in Professor Jim Finch's group at McGill and the surface analytical services and interpretive skills of AMTEL."

Jan 1, 1998

By J. P. Messervey

As a result of my field examinations in this Province, I have been struck by the evidence of widespread mineralization in rocks, particularly the limestones of Carboniferous age. Six prospects of lead and zinc or lead alone scattered through the eastern part of the mainland, one copper prospect and three veins of siderite, all point to a period of mineralization subsequent to the forming of the Carboniferous rocks in which they occur. While none of the present prospects are of proved economic importance, still it is possible, and indeed probable, that further prospecting will find concentrations sufficiently large to make mines. It may possibly aid the prospecting for these base metals if the present scraps of information are assembled from various sources, and I will further briefly recount the information as a result of my observations. Gay?s River At Gay&apos;s river, midway between Halifax and Truro, and four miles east of the railway, numerous pits and natural exposures show galena and sphalerite in limestone of Carboniferous age, near where it lies unconformably upon slate and quartzite of the gold series. These exposures extend for a length of over one thousand feet along a curving contact. The pits show that on the contact there is a fossiliferous and somewhat porous layer of limestone, which is so impregnated with galena and small amounts of sphalerite as to be of ore grade. Wherever observed, the thickness of this layer is less than two feet.

Jan 1, 1929

By J. R. Bradfield

THOSE familiar with the development of the Horne mine can readily appreciate that more and more accommodation bas been required for underground labour as the mine has grown. A permanent fire-proof change house, 30ft. by 75 ft., was built in 1927 to accommodate 194 men. This was extended ro 30 ft. by 92 ft. in 1928 to accommodate 296 men, and to 30ft. by 110 ft. in 1930 to accommodate 398 men. By 1933 this building was again overcrowded and tentative plans for a new change house were drawn up. However, it was realized that future operations would be centred around No. 4 shaft and a proposed new shaft, and the decision as to the location of the new change house had to be deferred until the area which seemed most suitable for the new shaft had been thoroughly explored underground. In the spring of 1934, the basic idea was accepted of drying the wet clothes in open mesh compartments or baskets located between rows of standard steel street-clothes lockers and built so that the covers or lids would serve as seats or benches.

Jan 1, 1935

By Q. Shi, Q. Feng

"The influence mechanism of chlorite on the flotation of pyrrhotite was investigated through flotation tests, Zeta potential measurements, optical microscope photos, solution ion measurements and absorption measurements. It is observed that, the addition of chlorite influences the flotation of pyrrhotite seriously. The IEP (isoelectric point) of pyrrhotite and chlorite is 7.6 and 4.3 respectively, in the condition of slight alkalinity, both pyrrhotite and chlorite are negatively charged, and the hetero-aggregation will not occur. With the existence of oxygen in solution, the iron ions are dissolved from pyrrhotite surface because of the oxidation of pyrrhotite during pulp conditioning. The dissolved iron ions adsorb onto the surface of chlorite in the forms of iron hydroxyl and iron hydroxide, and the adsorption results in the opposite charge of chlorite surface. As a result, the hetero-aggregation between pyrrhotite and chlorite occurs. The adsorption of chlorite changes the surface property of pyrrhotite and restricts the adsorption of amyl xanthate onto pyrrhotite surface, and then decreases the flotability of pyrrhotite.INTRODUCTIONIn sulfide ores processing, magnesium silicate bearing gangue minerals often report to the concentrate causing downstream processing problems as well as increased smelting costs. Talc,chlorite and serpentine are gangue minerals commonly encountered in complex sulfide ores (Engel, Middlebrook, & Jameson, 1997; Pietrobon et al., 1997; Witney & Yan, 1997; Chen, Grano, Sobieraj, & Ralston, 1999a, 1999b; Bremmell, Fornasiero & Ralston, 2005; Senior & Thomas, 2005; Wang, Somasundaran, & Nagaraj, 2005; WieseHarris & Bradshaw, 2007). All of them are characterized with uniform crystal structures consisting of silicon-oxygen tetrahedron and magnesium-oxygen octahedron. The magnesium-oxygen octahedron layers are broken during the liberation of serpentine to expose the magnesium-oxygen bonds with strong ionicity and hydration, which results in natural hydrophilicity of serpentine. In water, the hydroxyl on serpentine surface ruptures and dissolves into the aqueous phase while the Mg2+ remains, resulting in surface positive charge (Tao, 2012). As serpentine has a positive potential at alkaline condition, it is therefore likely that it will attach through electrostatic attraction to the negatively charged mineral surface and reduce both the flotation rate and recovery of target minerals (Lu et al., 2011). For talc, characterized as good natural hydrophobicity, the liberation comes from the interlaminar fracture to remain molecular bonds on surface with weak hydration. Being naturally hydrophobic, talc easily reports to flotation concentrates, thus reducing concentrate grade (Shortridge, Harris, Bradshaw, & Koopal, 2000; Beattie, Huynh, Kaggwa, & Ralston, 2006). Meanwhile, both molecular bonds and magnesium-oxygen bonds are exposed on chlorite surface when liberation occurs, resulting in moderate natural hydrophobicity between serpentine and talc (Tao, 2012). And thus the mechanisms of influence of chlorite on sulfide ores are more difficult to study."

Jan 1, 2016

By Fernando Canales

In the last decade a great dealt of attention has been paid to the chemistry of polynuclear gold derivatives with a central heteroatom, not only from the experimental and structural but also from the theoretical standpoint (1). Interesting hypercoordinated species of the type [C(AuPR3)5]+, [C(AuPR3)6]2+, [N(AuPR3)5]2+, [P(AuPR3)5]2+ and [P(AuPR3)6]3+ have been described (2), apart from other complexes with more conventional stoichiometry, and all have in common the presence of gold-gold interactions of ca. 3 Å. Usually, the chemistry of the first row elements of the p-block is known to follow classical rules of bonding, and only in cases of extreme electron-deficiency has the traditional electron count to be reconsidered to account for special types of molecular or solid state structures. Many of these heteroatomcentered complexes are electron-deficient and the gold-gold interactions provide a significant contribution to their stability. The attraction between these closed-shell systems has recently captured the attention in inorganic and organometallic chemistry (1). P. Pyykkö has summarized the available theoretical and experimental evidence of intra- and inter-molecular interactions between heavy metal atoms, such as Au(I) (3). In general, when heavy metals are involved in such interaction, the closed-shell attractions are of metallophilic or van der Waals type, as has been found for d8, d10 coinage-metals, and d10s2 centers. Experimental evidence for the aurophilic Au(I)???Au(I) attraction is available from crystallography, NMR and Raman spectroscopies, and optical spectroscopic measurements of the interaction strength (4). It is manifested in molecular conformations with relatively close Au???Au interactions of ca. 3 Å, whose strength has been estimated at ca. 25-50 kJ/mol (5). These attractions are weaker than most covalent or ionic bonds, but stronger than other van der Waals bonds and comparable in strength to typical hydrogen bonds. The phenomenon cannot be satisfactorily explained by classical theories such as hybridization (3). From a theoretical point of view, the attractions close to equilibrium distances are caused by dispersive interactions together with relativistic effects (6). The attractive contributions are dominated by pair-excitations from the heavy metal, such as gold, strengthened by relativistic effects. In all the cases where there are inter- or intramolecular metal-metal attractions, the correlation effects are essential; if they are omitted, at the Hartree-Fock (HF) level, repulsive interactions are obtained (6). Hence, it is necessary to use at least second-order Møller-Plesset level (MP2) methods for the dispersive forces, which are included in the electronic correlation effects (7).

Oct 1, 2003

By W. N. Roman

This paper will examine the challenges involved in ventilating and cooling South African mines, with particular emphasis on solutions to the issues of heat (generally associated with depth), mechanization and energy efficiency. Comparisons will be made with other international mining areas. Some of the deepest mines in the world are to be found in the South African goldfields. The Mponeng mine is approaching 4,000 m below surface, with virgin rock temperatures (VRT) of between 60°C and 70°C. Mining at these depths has only been possible with the use of large refrigeration plants supplying cold air, water and ice to the workings. In the Bushveld Igneous Complex, where most of South Africa?s platinum mines are located, similar VRTs are being experienced at significantly shallower depths. This is due to the different geothermal properties of the host rock between the two areas. Existing mines are being forced to go deeper and new underground mines are being planned and constructed in other areas with widely differing thermal conditions. South African metal mining has traditionally been labour intensive for historical reasons as well as for the narrow tabular nature of many ore bodies. Due to cost pressures and labour problems, some mines have been investigating the possibility of using mechanized equipment, both diesel and electric, to increase production and to improve efficiency. Studies have been carried out to determine the effect of the additional equipment on the overall ventilation system and some of the conclusions are discussed. The use of diesel equipment adds heat and pollutants to the ventilation air but, although electrical equipment has a lesser effect on the ventilation systems, it is generally less favoured due to claims of lower flexibility/manoeuvrability. Mechanization holds the promise of more concentrated mining activities but, with higher localized ventilation and cooling needs. Systems which will control the provision of air and cooling more effectively are required and are being implemented. In the 1990s and early 2000s, the South African economy experienced significant growth which was not matched by the growth in infrastructure. Consequently, at present there is a shortage of electricity generation capacity which affects large industrial consumers, including mines. Increasing levels of heat and mechanization will require more electrical energy for ventilation and cooling. There are many initiatives underway to save power or to shift consumption to periods of national low demand and these will be described.

Aug 1, 2013

By P. Au, R. Kearsey, D. Y. Seo, Patnaik. P. C.

Three nickel based superalloys (7.5%Cr+5%Co+2%Mo+1%Ti+5%Al and Ni balance (wt%)) containing different amounts of W and Re were produced in the single crystal (SX) condition utilizing the Bridgman casting process. First, the effect of different levels of Re, and W on chemical microsegregation were investigated by EPMA quantitative analysis, and eutectic phase fraction analysis. Second, in order to investigate the effect of these refractory elements addition on oxidation behaviour, isothermal oxidation testing of the SX nickel based superalloys was conducted at 1000°C for 277 hours under 3 ppm moisture content of air in a thermogravimetric analyzer (TGA). All three SX nickel based superalloys revealed an excellent SX solidification structure with a common primary dendrite arm spacing of -250 µm and a large fraction of ?/?&apos; eutectic located between the secondary dendrite arms. From the average EPMA compositional results, with the exception of Ni, elements such as Cr, Co, Re, Mo, and W all tended to segregate towards the dendrite core during solidification, while Al, Ti, and Ta were present in greater quantity in the last liquid phase to solidify, which resulted in large eutectic ?/? &apos; phases to form within the interdendritic regions. As the nominal level of Re increased, microsegreagation of Re, W, Cr and Mo increased, indicating that Re had a much greater influence on partitioning behavior compared to W. Figure la shows the specific mass gain as a function of exposure time for each alloy. An alloy with 2wt% of W and Re (Alloy B) exhibited less weight gain compared to two other alloys with either higher content of W or Re (Alloy A and C). Microstructural and compositional analyses of oxidized samples were conducted using SEM and EDS. Figure lb shows the typical surface morphologies of the oxidized Alloys A and B. It is evident that more oxide nodules (indicated by arrows in the figure) were presented in Alloy A. It is speculated that the amount of these nodules was responsible for more mass gain in Alloy A compared to the two other alloys. From the examination of the longitudinal section of the oxidized samples as shown in Figure 2, for Alloy A, nodules actually penetrated deep into the material. For Alloy B, however, a relatively uniform and continuous oxide layer was developed and deeply attacked areas were not observed. It was also found that preferential oxidized regions were located at the area between the ?/?&apos; eutectic phase and the dendrite arms where the concentration of refractory elements was relatively high. Therefore, it is plausible that the oxidation kinetics of these alloys is related to the extent of microsegregation.

Jan 1, 2004

By H. E. T. Haultain

Research is a much over-overworked word, sometimes a much abused word; the result of this has been that many who really need the word avoid it, shy away from it just as we do from that most useful word camouflage. We have not been altogether happy in our substitutes. Some years ago I spoilt a very good proposition by using the word investigation. There were those who thought that men and methods were to be investigated instead of simply processes. They expected disruption instead of co-ordination. The bad psychology up-set the scheme. The word experiment is even worse in its psychology. To the mind of the "practical" business man experiment denotes ignorance, waste of time and money and presupposes failure. It is not so long ago that the recognized way of improving the methods about a mine was to get a new manager. Until comparatively recently the average life of a boss in a mine in the West was under, rather than over, two years. Certainly was this the case in the smaller mines. Directors did not recognize that a cock-sure new boss was a greater experiment than a certain amount of feeling-his-way on the part of the old one. We always say that no two mines are the same but we are only now realizing to what extent the fine points of the game can and must be learnt on the job itself. One of the main differences between a small property and a large one lies in this study of the fine points of the game. In the early stages operation is the main point-get her going and keep her going.

Jan 1, 1924

By R. F. Errington

"Radioactive minerals are found together with the more familiar ore minerals in veins, gossans, and pegmatites, Since they have a peculiar property, that of giving off penetrating radiation, the simplest means of field detection is by the use of some radiation detector.The two principal radioactive elements one may encounter are uranium and thorium. These may occur separately or together. At present there is very little demand for thorium and hence radioactive occurrences should be examined with some care to determine which element is present. To do this it may be necessary to have a chemical analysis made of samples from the occurrence. Uranium minerals that do not carry appreciable thorium have a conventional occurrence in quartz or carbonate veins. They are distinctive in appearance. Pitchblende, the principal ore, is hard, black, and very heavy. It weathers readily to soft, powdery minerals •brilliantly coloured orange, yellow, and sometimes green. It may be associated with familiar minerals such _as native silver, nickel-cobalt sulphides and arsenides, chalcopyrite, and hematite.It is the purpose of this paper to review very briefly the types of radiation detectors available .and to draw some general conclusions as to the types most suitable for particular applications.The highly penetrating gamma radiation is the most useful for detection of radioactive mineralization. The alpha rays have little or no penetration, and beta rays are stopped by thicknesses of a millimeter or so of material. We shall confine our remarks principally to those instruments intended to detect gamma radiation. These are of three types."

Jan 1, 1950

By D. Kovachevich, M. A. Pfeifer

"A t remote locations typical of mines and associated ore processing plants, diesel electric generators are ideally suited for power plants due to their inherent operating flexibility, efficiency and reliability. In recent years rapid escalation in fuel and related transportation costs has made extensive waste heat recovery from generating sets financially attractive to a much greater extent than previously.The paper outlines key considerations during planning and design stages for utilizing the various waste heat sources available to best advantage. Based on two /980 mining projects built in the Canadian Arctic, data is presented on potential operating and capital costs savings. A review of heat balances, engineering flow diagrams and major equipment selections for process and building heating systems utilizing waste heat is included.IntroductionResource projects increasingly occur in remote areas requiring on-site self sufficiency in electrical power generation. For such projects, the low- or medium-speed turbo-charged diesel engine is very often the preferred choice as a prime mover for the generating sets . It is inherently reliable, has good response to load changes and has comparatively high fuel efficiency over a wide load range . From a project execution standpoint, It is capital cost- competitive and procurement lead-time normally &apos; fits &apos; within tight schedule constraints. In addition, its potential for waste heat recovery is excellent , particularly in northern climates where space heating requirements are usually substantial, and also where there a re requirements for heat for process and plant services.The high cost of fuel , with add-on transportation costs , provides a major incentive to fully exploit the available waste heat recovery potential o f such installations.As a result of the rapid escalation in the price of petroleum products following major crude oil price increases in 1973 and again in 1978-79, liquid petroleum fuels, having the desirable properties of comparatively high heat content and transportability, are no longer &apos;cheap&apos; commodities and have become so valuable that industry has widely undertaken serious conservation efforts.Currently, it appears that petroleum cost trends of the 1970s may not continue, at least in the near term, and that we may see somewhat reduced energy costs for a time. In the longer term , and certainly within the life spa n of major projects, however, it is generally believed to be inevitable that these fuels will be increasingly expensive . Energy costs are today a major operating cost for remote minerals processing plants and will remain so for the foreseeable future.In order to meet the economic challenge posed by high energy costs, future projects should be thoughtfully planned from the outset with the goal of minimizing energy requirements and maximizing the use of waste heat recovery to meet such requirements. There is also considerable potential for significant energy savings by retrofitting of existing installations."

Jan 1, 1984

By Jiahao Xu, Namsoo P. Kim, Guikuan Yue

Iron (ferrous ions and ferric ions) plays an important role in the heap leaching of copper sulfide minerals and copper electrowinning. In our previous study, a novel oxidation-reduction potential (ORP) equation only based on the variables of temperature and nominal ferric/ferrous ratio was developed to predict the redox potential of the quaternary H2SO4-Fe2(SO4)3-FeSO4-H2O system, and its applicability was also extended to more complex acidic iron sulfate solutions, especially those generated during the acidic leaching and bioleaching of Printed Circuit Boards (PCBs) to recover copper. In this work, the broader range of applicability of this equation to other complicated acidic iron solutions containing copper ions has been extended and determined. Specifically, synthetic iron-containing solutions with copper ions according to the conditions of industrial electrolyte during copper electrowinning and heap leaching have been used to measure the ORP and test the developed equation. It seems that this equation can still be employed to predict the redox potential of the Fe3+/Fe2+ couple for the simulated solutions under conditions related to copper electrowinning and pregnant leaching solution generated during heap leaching over a wide range of solution concentration, nominal Fe3+/Fe2+ ratio and temperature. It has shown that the prediction and measurement of redox potential is highly useful to estimate and understand the iron chemistry of industrial leaching and electrowinning processes. INTRODUCTION It is well-known that iron (ferric or ferrous) ions are widely involved in the hydrometallurgical production of non-ferrous metals such as Cu, Au and Zn, mainly in the form of acidic iron sulfate solutions. As far as Cu is concerned, in a typical leaching-solvent extraction-electrowinning process, ferric ion plays a central role in the heap leaching process and is reduced to ferrous ions in the pregnant leaching solution. Ferric ion is the most important surrogate oxidant and the dissolved ferric/ferrous couple plays an important catalytic role in accelerating the leaching rate with oxygen as an oxidant (Peters et al., 1986; Schlesinger, King, Sole, & Davenport, 2011). In addition, during the traditional electro-winning process, oxygen is evolved at the anode, and copper is reduced at the cathode. A common idea is that iron in the electrolyte in copper electrowinning cell (with total iron of 1–4.4 g/L) plays an important role in reducing the current efficiency. According to the published results (Winand et al., 1975; Dew et al., 1985; Moats et al., 2009; Khouraibchia et al., 2010), thecurrent efficiency decreases linearly with increasing ferric ion concentration and the energy consumption increase was mainly caused by the decrease in current efficiency.

Jan 1, 2019

By Antonio Laguna

During the past few years, synthetic efforts have been addressed to the synthesis of polymeric materials with optical or semiconducting properties or even with capabilities to act as sensors for volatile organic compounds (1). The most recent studies have been concerned with the synthesis of heterometallic systems with short metal-metal interactions and the determination of their optical properties. These complexes are undoubtly interesting from a theoretical viewpoint and include an emerging class of luminescent materials, in which the observed luminescence results mainly from the interactions among the different metal centers, as well as the environments of these atoms. The understanding of the photophysics and photochemistry of these products could permit the design of complexes with appropriate metals and ligands chosen for individual applications. Following a synthetic strategy consisting on reactions between acid heterometal complexes and basic gold precursors we have succeded in synthesizing supramolecular assemblies formed via acid-base stacking, which display tunable luminescence or selective and reversible sensitivity to Vapour Organic Compounds (VOC?s) (2-5). In this sense, in accord with previous Mössbauer studies carried out in the gold precursor complex [AuR2]- (R = C6F5), the basic properties of this and related materials have been employed as building blocks of supramolecular assemblies in their reactions with complexes in wich the metallic centers act as lewis acids as, for instance, Tl(I) or Ag(I) (6). For instance, in the case of silver, by reacting equimolecular quantities of [NBu4][Au(C6F5)2] with AgClO4, in acetone, a solid of stoichiometry [Au2Ag2(C6F5)4(OCMe2)2]n is obtained. The polymeric nature of this material in solid state is confirmed through X-ray analyses (figure 1). It consists of polymeric chains formed by repetition of Au2Ag2 moieties linked through short gold-gold interactions. Nevertheless, in solution, the nature of this polymeric materials was still a matter of controversy and, in this case, the optical properties have been shown as useful tools in order to obtain information. Thus, while dilute acetone solutions of this complex give a emission coming from pentafluorphenyl localized ??* excited states, in accord with the presence of isolated tetranuclear Au2Ag2 units, when the measurements are done at different and higher concentrations, a band that does not obey the Lambert-Beer law appears. This deviation is consistent with molecular aggregation in solution of these units through gold-gold interactions, and a clear correlation between the emssion wavelength and the structure in the solid state and in solution is shown (figure 2). DFT calculations accord with the observed experimental behaviour and show the nature of the orbitals involved in each transition.

Oct 1, 2003

By Avi Nanda, Robert Brandt, Alex Piatkiewicz, David M. Jones

In 2010 the United States Environmental Protection Agency (UESPA) revised the National Ambient Air Quality Standards (NAAQS) by lowering the permissible value to a 1-hour average SO2 concentration of 75 ppb. In 2012, the USEPA designated the Miami area as non-attaining for the new SO2 NAAQS. A number of options were studied to assist in bringing the Miami smelter into attainment with the new standard. The chosen solution included: Installation of a large tertiary hooding system over the converter aisle; Hooding of the anode vessels and treatment of the anode gas in a baghouse; Installation of a large 2,325,212 Nm3/hr caustic scrubber to treat the captured converter fugitives and anode off-gases; Installation of a secondary ESP for the tapping fugitive off-gas treatment system; and the continuous scrubbing of all acid plant tail stack gases. The modifications have reduced smelter SO2 emissions by 85%, achieving a world class SO2 stack emissions rate of 0.45 kg of SO2/tonne Cu. INTRODUCTION The Freeport McMoRan Miami smelter has been previously described in literature (Steinborn, Pasca, Sallee, Binegar, Bhappu). For the sake of brevity a brief description is given here. The Miami smelter is located 129 km east of Phoenix, Arizona near the town of Miami, Arizona. The smelter was established in 1915 and has undergone a number of process upgrades and modernizations over the years. The present smelter consists of an Isasmelt furnace, an electric settling furnace, four Hoboken converters, two anode refining vessels & one casting wheel; and one double contact sulfuric acid plant. Concentrates are railed & trucked to Miami from four Freeport McMoRan mines located in Arizona & New Mexico. The wet concentrates, typically containing 10% H2O with a Cu/S ratio of 0.85, are smelted in an Isasmelt furnace to a matte grade of 58%. The entire output from the Isasmelt is laundered into an Elkem electric furnace (originally installed in 1972 as the primary smelting furnace) for separation into matte and slag. Slag containing 0.85% Cu is skimmed from the electric furnace and discarded. Molten matte, containing 60% Cu, is tapped from the electric furnace and processed in one of four Hoboken converters to produce blister copper. Two anode refining vessels further refine the blister copper before the final product is cast on a single, 30 mold, casting wheel. All of the anodes produced at Miami are shipped to the Freeport McMoRan electrolytic refinery in El Paso Texas for refining into cathode copper. Smelter off-gases from the Isasmelt, electric furnace and Hoboken converters are combined and treated in a double contact acid plant to produce sulfuric acid. Acid produced at Miami is internally consumed at Freeport McMoRan mines in the region.

Jan 1, 2019

By T. L. Tanton

"The New Helen mine is 12 miles east of Michipicoten harbour on lake Superior. It is 2 miles east of Wawa station, on the Algoma Central railway, with which it is connected by a spur line railway and a highway.The mine was discovered by Ben Boyer in 1898 during the gold rush near Wawa lake, Ontario. The original discovery was of solid hematite ore extending to a height of 100 feet on a hill rising abruptly on the east side of Boyer lake. The property was acquired by the Algoma Steel Corporation and mining was commenced in 1899. The first iron ore was shipped in 1900. The mine was operated until 1918 when the hematite became exhausted at a depth of 800 feet below Boyer Lake level.Drilling at the Helen mine, after 1910, revealed a large body of siderite both below and to the east of the hematite. By 1913, the body was known to be about 200 feet wide, 3,000 feet long, and at least 2,200 feet deep. In this there was estimated to be 100,000,000 tons of proved and probable siderite ore. An adit was driven into this body in 1917, and in 1918 work was suspended. In 1937 the Algoma Steel Corporation proceeded with the development of the New Helen mine by open-cut mining, and the beneficiation of the ore by sintering. Production commenced in 1939 and has since been maintained at the rate of approximately 500,000 tons a year.From 1900 to 1918, inclusive, the total production from the Helen mine was 2,823,369 tons of hematite ore and 51,930 tons of pyrite. From 1939 to the end of 1945 the total production from the New Helen mine was 3,921,455 gross tons of siderite ore.GEOLOGYThe Helen property is underlain by rocks of Precambrian age. For general description, and a statement on the structure of the iron deposits, the map-units are those shown in Fig. 1.The oldest rocks occur in a complex that lies north and south of an east-west trending zone, 1 ½ miles long and ¼ mile wide, in which the iron deposits occur. That part of the complex lying south of the iron deposits includes small masses of altered conglomerate and slate, and greenstones and pyroclastics. Other fairly abundant rocks are sericitic, chloritic, ottrelitic, and carbonatized schists of doubtful origin, and almost massive metamorphic rocks in which a development of carbonate, ottrelite, quartz, and other minerals has obscured a pre-existing schistose structure. Felsite and quartz porphyry are· prominently exposed south of the iron deposits."

Jan 1, 1954