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By C. D. Anderson, C. G. Anderson, P. R. Taylor

"Rare Earths have become critical for our energy and materials driven society. While primary production must ramp up to fill growing demands, the recycle of these strategic elements must also be initiated. This paper will outline the potentials of and metallurgical technologies employed for Rare Earths recycle from various secondary sources.INTRODUCTIONWhen investigating the recovery of rare earths from secondary sources it is necessary to understand the nature of the sources to be processed. As of 2009, the USGS reports the distribution of rare earths by end use, in decreasing order, was: chemical catalysts 22%, metallurgical applications and alloys 21%, petroleum refining catalysts 14%, automotive catalytic converters 13%, glass polishing and ceramics 9%, rare earth phosphors for computer monitors, lighting, televisions 8%, permanent magnets 7%, electronics 3%, and others 3% (USGS, 2011). Additionally, it is reported that the amount of recycling was quite small and consisted primarily of rare earth magnet scrap, although with the sharp increase in the price of rare earths, and the potential shortage in supply, focus in this area is continually growing. Thus, the opportunities, whether realistic or not, are extremely vast in the recycling of rare earth containing materials. The following subsections will present methods proposed for the recycling of rare earths based on the feed material type.RECYCLING OF RARE EARTH MAGNETSCurrently, investigations are ongoing in the area of recycling production scrap and end-of-life materials in the rare earth magnet industry. The following techniques illustrate potential methods for the recovery of rare earths from secondary RE magnet sources.Recycling of Rare Earth Magnet Sludge by Selective ChlorinationDuring the production of neodymium magnets, a by-product of production is the so called “magnetic sludge”. This by-product contains high amounts of neodymium, thus a process for the recovery of Nd has been proposed. In this process the Nd present is selectively chlorinated/distilled by the addition FeCl2 via the following reactions."

Jan 1, 2012

By Lin-fang Shen, Shao-jun Li, Zhi-liang Wang

"The meso-structure of real soil consists of numerous particles with different sizes, while the traditional reconstruction method of quartet structure generation set (QSGS) produce relatively uniform soil particles resulting in significant discrepancy between the actual structure and reconfiguration model. In order to remedy the deficiency, the QSGS is improved by considering the influence of porosity and autocorrelative function of soil, which make the models closer to the real soil. Based on the reconfiguration model, Lattice Boltzmann method is combined in the algorithm to conduct further simulation of fluid flow in soil pores. The D2Q9 model is applied to construct the two dimensional model for simulating mesoscopic seepage field of saturated soil by setting the non-equilibrium extrapolation scheme at the inlet and outlet boundary, and the bounce-back scheme at the soil particles boundary as well as the left and right boundary. According to the case study, the proposed program is realized to simulate mesoscopic seepage field of reconstructed soil with constant inlet seepage velocity. The results show that the seepage direction of soil is along the passage with good connectivity, therefore the permeability is controlled by these passages. The seepage velocity in such channels is faster than in bad connectivity channels. Even if the channel has larger pores, the seepage velocity is still small. INTRODUCTIONUnderstanding the seepage mechanism in porous materials is significant in both theoretical and engineering problems. As a typical porous media, soil consists of solid particles and voids, which form connected channels allowing water to flow through. Such seepage in soil exists widely among geotechnical project of slope, foundation pit, and tunnel, etc. Meanwhile, a number of engineering accidents are caused by limited knowledge of seepage characters in soil (Huang, 2006; Liu, 2013). The conventional method in describing seepage features mostly based on the parameter of permeability, which is a macro statistic mean evaluating the whole connectivity of soil. Obviously, this parameter cannot exactly reflect the details of how water flows through the inner soil structure, especially the flow velocity in local mesoscopic area, hence is unable to represent the actual seepage properties. Therefore, it is necessary to develop mesoscopic approaches to fully study the seepage mechanisms."

Jan 1, 2015

By Donald F. MacDonald

THE cement plant nearest to Nova Scotia is not far from Montreal. Cement is a heavy product which, because of its relatively low value, cannot stand a high freight charge without unduly enhancing its cost. This is one reason why cement costs are high in Nova Scotia. The regular retail price per bag (8772 lb.) in Antigonish is 85 cents, which would be $3.40 per Canadian barrel of 350 pounds, or $3.65 per American barrel of 376 pounds.It is said that the lowest wholesale price in Halifax is 65 cents per sack, which would be $2.60 per Canadian barrel or about $2.80 per American barrel. According to U.S. Bureau of Mines statistics, the average factory price for cement in 1937 was $1.48 per American barrel, which is practically the same as the value per barrel indicated in Dominion statistics for the Canadian output during that year. The difference between $3.40 and $1.48 is $1.92. It is evident that the average user of cement in the Mari-times pays a stiff premium because Maritime cement raw materials have not been developed. Rock-wool, the manufacture of which is rapidly increasing in Ontario and the United States, is much needed for building insulation in the cold climate of Nova Scotia.

Jan 1, 1939

By A. Hayatdavoudi, D. Chitila, F. Boukadi

"Shale oil and gas have provided a tremendous boost to energy production in the United States even though the characteristics and behavior of shale are yet to be fully understood. Hydraulic fracturing is often applied to horizontal shale wells to stimulate production. This experiment seeks to determine effects of cyclic variable temperature, water vapor and exposure time on shale micro fracture propagation. We used 22 small Pierre shale specimens and subjected them to aforementioned conditions. Fractures developed in 19 specimens. Combination of high temperature and high water vapor generated the largest number of micro fractures on the specimen surfaces.INTRODUCTIONShale oil and gas have contributed immensely to energy independence in the United States. Most if not all shales depending on their total organic content (TOC) and their clay content bear the promise of being a source rock. For example, the Eagle Ford shale play, located in south Texas, is one of the key contributors to the recent rise in oil and gas production in the United States. Data from the U.S. Energy Information Administration (EIA), published in 2014, states that monthly oil production from Eagle Ford wells increased from 340 barrels per day (bbl/d) in January 2009 to nearly 1 million bbl/d in June 2013. Natural gas production has also increased at a similar rate over the same period, from 5.8 million cubic feet per day (MMcf/d) to nearly 4,000 MMcf/d (EIA, 2014).According to the railroad commission of Texas (RRC) 2014 published information, the Eagle Ford shale play is an important play because it produces gas and more oil than other shale plays in the United States. It is an organic-rich play with carbonate shale percentage in the 70% range in south Texas and the shale content increases moving to the northwest. High carbonate proportion renders this play brittle and suitable for hydraulic fracturing treatments."

Jan 1, 2015

By R. M. T. Raja Ismail

Shipping and stevedoring industry is going to witness a massive increase in the amount of containers to be handled while land constraints become more critical. Offshore transfer operations hence offer a preferable solution to deal with the surge in cargos rather than to expand the port outwards. Recently, there has been increasing research interests on offshore crane automation. Suspended cargos in a ship-mounted crane system are caused to swing due to the vibratory motion of the ship induced by ocean waves, which can lead to collision between cargos and deck. Therefore, it is vital for offshore crane systems to satisfy rigorous requirements in terms of safety and efficiency. This paper presents the modelling and control development for offshore boom crane systems. A second-order sliding mode control law is proposed for trajectory tracking and sway suppression control, making use of its capability of actuator chattering alleviation while achieving high tracking performance and preserving strong robustness. The asymptotic stability of the closed-loop system is guaranteed in the Lyapunov sense. Simulation results indicate that the proposed controller can significantly reduce the effect of disturbances coming from gusty waves and other dynamic loadings.

Aug 1, 2013

By Minghao Hu, Hongbo Zhao, Jun Wang, Wenqing Qin, Rui Liao, Central South University

"In the present work, X-ray diffraction (XRD) analysis, X-ray photoelectron spectroscopy (XPS) analysis and electrochemical analysis were carried out to investigate the intermediate species and electrochemical dissolution process of chalcopyrite in the presence of sulfur and iron oxidizing microorganisms. For bioleaching of chalcopyrite by the sulfur oxidizing microorganism Acidithiobacillus caldus, the redox potential was always lower than the appropriate value and chalcopyrite was mainly directly oxidized to polysulfide (Sn 2-), thus resulting in low copper extraction. As for bioleaching of chalcopyrite by the iron oxidizing microorganism Leptospirillum ferriphilum, chalcopyrite was mainly directly oxidized to polysulfide at the initial stage where redox potential was lower than the appropriate value and resulted in low dissolution rate. At the middle stage where redox potential was appropriate (about 350–480 mV vs. Ag/AgCl), chalcopyrite was mainly transformed to intermediate species of Cu2S rather than polysulfide, thus resulting in high dissolution rate. At the later stage where redox potential was higher than the appropriate value, chalcopyrite was mainly directly oxidized to polysulfide which caused the later passivation of chalcopyrite. Finally, a model of electrochemical dissolution process of chalcopyrite in the presence of sulfur and iron oxidizing microorganisms was provided.INTRODUCTIONBiohydrometallurgy is considered as one promising mineral processing technique in processing low grade ores due to the advantages of simplicity, low cost and eco-friendly. Chalcopyrite (CuFeS2) is the most abundant copper-bearing resource, accounting for appropriately 70% of the known reserves in the world, while is recalcitrant to bio-hydrometallurgy mainly due to the coated passivation layer (Klauber, 2008; Li, Kawashima, Li, Chandra, & Gerson, 2013). However, the detailed dissolution and passivation mechanisms of chalcopyrite bioleaching are still uncertain. The microorganisms assisting chalcopyrite dissolution can be mainly classified into three types, including mesophilic microorganisms (e.g., Acidithiobacillus ferrooxidans, Acidithiobacillus thiooxidans and Leptospirillum ferrooxidans), moderately thermophilic microorganisms (e.g., Acidithiobacillus caldus, Sulfobacillus thermosulfidooxidans and Leptospirillum ferriphilum), and extremely thermophilic microorganisms (e.g., Metallosphaera sedula, Sulfolobus sp., Acidianus sp., and Sulfurcoccus mirabilis). Moderately thermophilic microorganisms have a better prospect in the future industrial application of chalcopyrite bio-hydrometallurgy (Olson, Brierley, & Brierley, 2003; Rohwerder, Gehrke, Kinzler, & Sand, 2003). Hence, investigating the detailed dissolution and passivation mechanisms of chalcopyrite bioleaching by moderately thermophilic microorganisms is of important significance, which will provide essential information for promoting chalcopyrite bioleaching by moderately thermophilic microorganisms in laboratory or industrial plant."

Jan 1, 2016

By Richard R. Klimpel

"This paper discusses the effect of water chemistry, reagent type, and other environmental factors on the performance of sulfide mineral size reduction and froth flotation processes. Two specific problems will be discussed: l.) the importance of appropriately utilizing the electrochemical window that is created in the grinding process to enhance sulfide mineral recovery by froth flotation; and 2) the impact of steel grinding media versus autogenous grinding on the efficiency of sulfide mineral flotation with varying thiol collectors and water sources.IntroductionThe mutual dependency between size reduction and mineral froth flotation is well recognized from the viewpoint of particle size and mineral liberation characteristics. The purpose of this paper is to discuss two less obvious industrial interactions between size reduction and froth flotation that have come up in the various plant optimization studies conducted by this author. These interactions are complex but appear to be important at the industrial level as plant throughput is directly affected, either positively or negatively by such interactions. Examples v.ill be given on how the method of grinding influences flotation and how different water sources influence the flotation behavior of electrochemically sensitive minerals. With each of these interactions, a number of fundamental research studies have shown previously that some effects can be measured under idealized and very small scale experiments. Such research studies will not be cataloged or exhaustingly reviewed in this paper. Whether these same types of effects can be measured in an industrial environment and are economically important is much less certain. This paper will present some rather unique experiences gained from larger scale test experiences which clearly indicate findings that plant operators should be aware of."

Jan 1, 1996

By Mory Ghomshei

Pebble Creek Geothermal Power project is associated with a massive recent volcanic eruption in Southwestern British Columbia Canada. Slim holes drilled to depths 1100 m in the prospect area, show very high temperature gradients around 80?100?C/km. The temperature and chemistry of the Pebble Creek hot springs indicate the possibility of a steam reservoir in the prospect area. In addition to high temperature gradients, presence of host rocks with high permeability, along with abundance of recharge waters (from the Lillooet River) provides clear signature of a high-grade geothermal power reservoir at depth 2000 to 3000 m. Data show that over five hundred Megawatt of green power can be generated from the prospect area in a commercially viable manner. The generated power will be base-load, which in comparison with large hydro has the advantage of lower capital costs and a significantly smaller footprint. The final hurdle to overcome, before starting the development phase, is deep exploratory drilling for resource confirmation. This paper is a summary of the data available on the Pebble Creek geothermal power prospect, presented in the context of viability of the resource for large-scale commercial power generation.

Aug 1, 2013

By I. Lackey

In 2004, Zinifex Budel Zink commenced testing with the objective to increase the precipitation of aluminium in the iron purification stage of its hydrometallurgical zinc circuit, without the use of expensive reagents. Findings from the literature applied to the leach circuit at Zinifex Budel Zink demonstrated that aluminium removal from the leach circuit could be increased by lowering the ferric concentration and acidity in the vessels where jarosite precipitation occurs. An associated increase in copper precipitation was mitigated by limiting the extent to which the ferric concentration was lowered in the vessels where jarosite forms and lowering the ratio of copper to aluminium in the solutions entering these vessels.

Jan 1, 2006

The AG/SAG circuit discharge P80 is now increasingly referred to as the ?Transfer Size? or T80 for short. From the literature it is apparent that in circuit design some approaches to the sizing of AG/SAG mills as well as the ball mills that they feed use this parameter. This paper reviews whether the use of the T80 is appropriate in this context. In the course of the review examples of AG/SAG discharge size distributions measured from range of operating circuits are used to illustrate the arguments made.

Jan 1, 2012

By C. J. Edmonds, R. Bland, W. C. Ferguson, R. Whitehead

"In 1969, the Environmental Science Division of James F. MacLaren Limited received authorization from The International Nickel Company of Canada, Limited to carry out a water quality monitoring program in the Lake Shebandowan region of Ontario, where a new base metal mining and milling complex was expected to go into operation in 1972. The objective of the program is to establish base-line water quality characteristics. Fully realizing their corporate responsibility to minimize the effects of the proposed activities on the environment, Inco decided that it would be desirable to establish a program by which any change in the quality of environmental waters will be detected before detrimental conditions ensue, permitting prompt corrective measures to be taken. The program has been in progress for over two years. The waters are sampled and analyzed four to six times per year. Sampling stations are located in Lake Shebandowan and on the adjacent Gold Creek - Matawin River system. On-site analyses and measurements are made of flow, dissolved oxygen, temperature and pH. Samples also are collected for later analysis in the laboratory. These samples are analyzed for a wide range of chemical and biological characteristics. The paper discusses the extent of the sampling program, the techniques utilized and the value of such programs in maintaining the quality of the environment."

Jan 1, 1973

By J. Aiello

"Introduction Byron Creek Collieries Limited Corbin mine is located in southeastern British Columbia approximately 180 air kilometres southwest of Calgary (Fig. I), twenty four kilometres south of Highway No. 3 via a newly constructed provincial road (Fig. 2). The development of the area began July 30, 1905, when D.C. Corbin, a prominent businessman from the northwestern U.S., and his associate E.J. Roberts first visited the site of Coal Mountain on horseback. Coal was in great demand by railways and other industrial users, so the Corbin Coal and Coke Co., after acquiring 6,000 hectares of land in the area, began to develop a mine. Mr. Roberts was responsible for the construction of the 22-kilometre rail spur, the Eastern British Columbia Railway, which joined the mine to the CPR main line at the McGillivray Loop. Rail access to the mine and its developing community, Corbin, B.C., was completed in September 1908, the same year that the first underground mine began production. The Corbin Coal and Coke Co. operated six mines on Coal Mountain (Fig. 3) and production from 1908 to 1930 inclusive totalled 2,120,800 tonnes. This production was allocated to the mines as follows:"

Jan 1, 1985

By H. Zniber El Mouhabbis

Ore dilution or stope overbreak increases the cost of production and ultimately reduces the profitability of a mining operation. The adverse economic impact of ore dilution is due to the added costs associated with the mucking, haulage, crushing, hoisting, milling, and treatment of waste rock or low grade ore in the hangingwall and footwall. One factor that could have a significant influence on stope overbreak is the undercutting of the stope into the walls. Undercutting stope walls is often necessary, in particular in narrow vein mines. Moreover, equipment size has a role in drift sizing where stope undercutting may become a must in order to fit the mobile equipment while respecting legal clearances.

May 1, 2009

By Tyson C. Birkett

Initial indicator mineral sampling covering 425,000 square km of northern Quebec and subsequent follow-up of positive results convinced the Ashton ? SOQUEM joint venture to acquire mineral rights to 380,000 hectares prospective for diamond in late summer, 2000. Drilling in 2001 and 2002 identified eight kimberlitic bodies, all significantly diamondiferous. Commercial size stones (retained on a square mesh sieve with openings 0.85 mm) and encouraging grades have been returned by several bodies tested to date: The Renard bodies are formed by steep-sided breccia pipes with kimberlitic matrix surrounded by irregular outboard breccia zones within country rock. These bodies were emplaced in high-grade metamorphic rocks of the Superior Province of Archean age. Orthogneiss with lesser tonalite hosts the breccias, although regionally paragneiss is also present. Diatreme facies portions and nearby country rock are intruded by minor to major (Renard 1) amounts of hypabyssal-facies kimberlitic rock. Renard bodies are macrocrystic, with large olivine crystals set in a groundmass of olivine, phlogopite, monticellite, spinel, carbonate, apatite and serpentine. Proximity of various Renard bodies, with most in a core area of 0.5 square km will allow planning of an efficient mining operation. Geophysics, especially magnetic surveying, has contributed to identifying bodies of kimberlitic rock.

May 1, 2003

By N. E. Izatt

Molecular recognition technology (MRT) has a wide range of applications in the hydrometallurgical and chemical processing industries for the selective removal of iron as well as various other impurities from a variety of streams, including aqueous solutions through a wide pH range, as well as organic solutions. An example of a commercial application is provided for the removal of iron from an aluminum chlorohydrate stream. In this example, MRT has a selectivity for iron relative to aluminum which is significantly higher than that of ion exchange resins. A discussion of MRT capabilities for other impurities and streams is also provided.

Jan 1, 2006

By Andrew Bamber

A fast and objective spreadsheet-based model for the financial evaluation of innovative mining and processing strategies such as pre-concentration vs. a conventional base case is presented. The size and grade of the deposit must be chosen, from which a mining rate is selected. Expected operational data for the deposit as well as any mill testwork and results from the pre-concentration testwork are entered as input variables on the sheet, and cost and revenue impacts are calculated in the ?Output? sheet. A capital sum and operating costs for the initial mine and mill development as well as the pre-concentration facility are calculated. The net changes in capital and operating costs are calculated, and impacts on revenue through changes in metal recovery are also calculated. These outputs are used to calculate the overall impact on the cutoff grade and thus the size of the mineral reserve using a generic grade-tonnage model. The NPV and NPV profile of the two scenarios is calculated, with variations in basic parameters such as operating cost, capital requirements, metal price or grade as well as discount rate. Cost and revenue impacts are evaluated and compared to the baseline to establish a positive or negative impact overall. Different scenarios of grade, tonnage, mining rate, process performance, capital and operating cost structure can be explored using the model. Outcomes projected by the model for case studies conducted thus far have been calibrated against internal estimates by the sponsoring organizations and found to be accurate to within 30%, confirming the utility of the model in practice.

Oct 1, 2009

By Alok Porwal, E. J. M. Carranza, M. Hale

Abstract- Approaches to mineral potential mapping based on weights of evidence generally use binary maps, whereas, real-world geospatial data are mostly multi-class in nature. The consequent reclassification of multi-class maps into binary maps is a simplification that might result in a loss of information. This paper describes results of using multi-class evidential maps in an extended weights-of-evidence model vis-à-vis results of using binary evidential maps in a simple-weights-ofevidence model. The study area in the south-central part of Aravalli province (western India) hosts a number of SEDEX-type base metal deposits in Proterozoic supracrustal rocks. Recognition criteria for base metal deposits were represented as both multi-class and binary evidential maps. The known mineral deposits were divided into two subsets, viz., the training and the validation subsets. The training subset was used to calculate, for the evidential maps, the weights, contrasts, and posterior probabilities and their variances. The distributions of expected frequencies of base metal deposits estimated from the posterior probabilities and the observed frequencies were compared using standard goodness-of-fit tests to verify conditional independence of the input evidential maps. The posterior probabilities from both the models were mapped and interpreted to classify the study area into zones favorable, permissive, and non-permissive for base metal deposit occurrence. As compared to the simple weights-of-evidence model, the extended weights-of-evidence model results in more robust and finely differentiated posterior probabilities in favorable and permissive zones and has a better prediction rate. The results also reveal that the statistical properties of the weights of evidence, the contrasts, and the posterior probabilities are not significantly degenerated by using multi-class evidential maps in weights-of-evidence modelling.

Jan 1, 2001

By F. Hashiuchi

In 1996, the Saganoseki custom smelter & refinery successfully shifted to a single flash smelting furnace operation and increased the copper production capacity to 450,000mtpy in 1998. As the next step, Saganoseki planned to further increase the productivity, especially in the area of P.S. converters and acid plant. As the results of modifications and operational improvements, the gas washing & cooling sections of the Saganoseki acid plant were consolidated from 3 to 2 lines, and increased the gas treatment capacity. The S02 converters in the acid plant were also modified to increase the acid production. By increasing the matte grade from 65 to 68%, six PS converters have been successfully integrated into four, while maintaining the production capacity and reducing the environmental burden in 2005. This paper discusses recent operational conditions and the results of implementation of technological improvements.

Jan 1, 2007

By L. Zhu, S. Kaierle, M. Dahmen, C. Zimmermann, T. Haubold, I. Kelbassa, C. Mattern

Application of integrally bladed disks (blisks) is of increasing interest in compressors of aero engines. Blisks are preferred due to their potential for size and weight reduction, for increased performance and for reduced manufacturing costs compared to conventionally bladed disks. In case of a damage the blisk aerofoils cannot be simply replaced. If the damage is beyond acceptance or blending limits refurbishment is possible only by scrapping the whole blisk assembly, or more cost effective by the application of advanced weld repair methods. Weld repair of blisk aerofoils is challenging as it affects a critical part with specific requirements regarding its mechanical integrity, and as the accessibility is usually limited. The paper describes the ongoing development of advanced weld repair processes as part of a comprehensive repair strategy which have been developed for small-sized blisk assembly to give competitive maintenance cost.

Jan 1, 2006

By L. Bichler

Utilizing thermal analysis techniques, pioneering research into the solidification mechanism of a popular magnesium alloy AZ91E cast by the Lost Foam Casting (LFC) process was carried out, Foam characteristics, section thickness and application of vacuum were seen to have profound effect on the cooling rate, thermal gradients and casting temperature profiles.

Jan 1, 2005