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By Mohamad Sabsabi, André Hamel, André Moreau, Paul Bouchard

"Laser-Induced Breakdown Spectroscopy (LIBS) is an atomic spectroscopy technique used to measure elemental concentrations. It is well-adapted to in-situ and in-line measurements during materials processing in general, and pyrometallurgy in particular. It is an optical non-contact technique and it can measure nearly all elements, including light elements. Our group has developed a mobile prototype system to measure molten metals. The system includes a tube, also called a lance, one end of which is immersed in the molten metal. An inert gas flows in the tube and bubbles out below the surface. The LIBS measurement is made through the tube and onto the bubble’s surface. This is done to avoid measuring contaminants, slag, or fluxes often found at the surface of the melt. An added benefit is that the molten surface is constantly renewed and thus, more representative of the bulk. An alternative to using our lance is to use a tuyère, such as a gas injection tuyère in a converter, as we did several years ago in a nickel matte converter. In this presentation, we will show various applications emphasizing more recent developments. This includes the simultaneous measurement of the concentrations of Cu, Ni, Fe, Co and S in molten matte at 1125 °C. The more obvious industrial applications of the technology include determining the best time to end oxygen blowing in the converter and elemental concentration measurement during alloying.INTRODUCTIONThe mining industry continually faces challenges in optimizing cost and productivity. Because of the large volumes of materials that are being processed, small improvement can have a big impact on benefits. Better real-time information can help improve this optimization."

Jan 1, 2016

By C. H. B. Leitch, T. N. MacAuley, R. L. Linnen, A. E. Williams-Jones

"The Trout Lake stockwork molybdenum deposit is temporally and spatially related to the emplacement of a late Cretaceous granodiorite-tonalite stock in southeastern British Columbia and contains an estimated 49 million tonnes grading O.I9% MoS2- No metal zonation patterns are apparent, with the exception of peripheral tungsten skarn, and exploration was guided largely by geological interpretation. It is typical of the granodiorite, or fluorine-poor type of molybdenum deposit. Molybdenite is contained within a quartz-feldspar vein stockwork and coeval dissemination in igneous (and less commonly metasedimentary) hosts. In general, molybdenite is strongly associated with alkali feldspars, but in detail it is intimately associated with incipient muscovite replacement of albite and K-feldspar; veins that lack feldspars are also typically barren of molybdenite. These textures suggest that fe/dspathic alteration (and precipitation in veins) was an important precursor to mineralization, and the occurrence of similar textures elsewhere (e.g. Henderson) suggest that early feldspathic alteration is important to the genesis of molybdenum deposits in general. Molybdenite deposition at Trout Lake was preceded by contact metamorphism, skarn and potassic alteration, and was overprinted by muscovite-ankerite (phyllic) alteration. Only moderate temperature changes are recorded by the metamorphic and alteration mineral assemblages (350°C to 450°C}; however, with time, fluids became increasingly more acidic and enriched in C02- In light of the intimate molybdenitemuscovite intergrowths, the decrease of pH probably exerted a major control on mineralization.IntroductionGranite-hosted molybdenum deposits can be classified in terms of the composition of the related intrusion, e.g., the granodiorite and granite types of Mutschler et a!. (1981), or the calc-alkaline, alkali-calcic, and alkalic types of Westra and Keith (1981). They have also been classified on the basis of their fluorine contents (Theodore and Menzie, 1984) with the fluorine-rich and -poor varieties roughly corresponding to granite- and granodiorite-type deposits, respectively. For economic reasons, most exploration and research has concentrated on the high-grade/large tonnage granite-type of deposit, exemplified by Climax. F1uorine-poor, granodiorite-type deposits are, however, the most common type in Canada and have been mined in the past (e.g., Endako). In this paper, the authors summarize the research that has been carried out on the fluorinepoor Trout Lake deposit (Boyle and Leitch, 1983; Linnen, 1985; Linnen and Williams-Jones, 1987; 1990) and use what has been learned to develop guidelines for the future exploration of fluorinepoor, granodiorite-type molybdenum deposits."

Jan 1, 1995

By A. A. Ruitenberg, S. C. Johnson, L. R. Fyffe

"Several types of stratiform and epigenetic gold deposits have been found in New Brunswick, It is the purpose of this paper to describe and classify the epigenetic deposits and demonstrate their relationship to tectonic evolution. The stratiform deposits are mostly volcanogenic massive sulphide deposits that are described elsewhere (Davies et al., 1985).The auriferous epigenetic deposits include quartz-carbonate veins and stockworks, polymetallic veins, contact metasomatic, porphyry copper and volcanic breccia (epithermal) deposits. These epigenetic deposits are concentrated in major fault zones that define or are close to the boundaries of tectonostratigraphic terranes or terranes and cover sequences. The host rocks of the deposits were subjected to extensive crustal thickening resulting from thrusting and/or high angle reverse faulting.The gold deposits north of the Avalon Terrane occur indilatent structures related to mainly dextral wrench faulting that postdated the episode of crustal thickening. The deposits along the southern margin of the Avalon Terrane occur in structures related to late phase thrusting."

Jan 1, 1990

By C. Holmes, T. Holmes

Engineered-in material handling problems are responsible for significant unrealized value in mineral processing plants. At the root, is a lack of awareness and understanding of bulk material handling science and how important it is, especially in early design stages. Mineral processes add value to mined raw feedstock through physical and chemical transformations in unit operations, but only if the material can flow through them. Essentially, each unit operation receives a unique feedstock and produces a unique product to be collected, transported, and fed into the next unit operation. Such material-handling systems can only be expected to achieve design throughput if the system equipment is designed to the materials’ characteristics, over their full range of conditions. This requires quantification of flow properties to support the necessary customized equipment designs. Too often, assumptions or “library values” of a material’s properties are used as the basis for flow modelling and conceptual, and sometimes even detailed, design. This is especially true for hazardous materials like uranium ore, for which the additional precautions, costs, and time necessary for safe handling are often used to rationalize postponing or even bypassing testing. The surprises that often transpire in the wake of insufficient material handling consideration can have acute and costly effects. Fortunately, there is a better way.

Jan 1, 2020

By J. T. Vehkala, S. S. Kerr, D. E. Robertson

"Since the late 1970s, extensive work has been carried out at Placer Dome Inc. 's Dome Mine to develop new mining methods and equipment to improve the productivity of narrow vein mining (Mining Magazine, Oct. 1986, pp. 308-317; Mar. 1988, pp. 176-/79). This work has been focused on mining veintype deposits varying from 0.9 m to 1.5 m in width using open stoping and cut-and-fill mining methods.In 1989, the Dome Mine entered into a contract with Ram Raising Ltd., a joint venture company of Angus Martin and I.S. Redpath Ltd., to develop and mine a narrow vein test stope using an Alimak Raise Climber. Early results have been favourable, indicating that Alimak methods can be used successfully to mine narrow vein are.HistoryThe Dome Mine, which has been in continuous operation since 1910, is located in South Porcupine, part of the city of Timmins, Ontario. The mine is wholly-owned and operated by Placer Dome Inc. and is part of Placer Dome Inc.'s international stable of of 19 mines."

Jan 1, 1990

By G. S. Hume

THE Plains of east-central Alberta herein described embrace an area from Viking east to the Saskatchewan boundary and from North Saskatchewan river south to Coronation and Monitor (Figure 1). By far the greater part of this area is deeply drift-covered, and .outcrops of bedrock are relatively few and often widely separated. Within the area there are large morainal hills and others of considerable extent that superficially have all the characters of morainal hills but contain a core of bedrock. These latter, then, were hills when the ice sheet traversed the country and only have been modified by glacial agencies. In many places on them, the drift is but a thin veneer, as is certainly the case in part of the Neutral hills (Figure 2) northeast of Coronation and north of Monitor. In other cases, however, as in the Blackfoot hills, southwest of Lloydminster, the drift is sufficiently thick to conceal practically all the bedrock and in many places no information is available as to whether a bedrock core, representing a pre-glacial hill, is present. There is no question, however, that the larger river valleys, as for example those of the North Saskatchewan and Battle rivers, are in part at least pre-glacial. Proof of this can be demonstrated in many places, because obviously the valleys must have been present in pre-glacial times to allow glacial deposits to have accumulated in them. It is also known that inter-glacial deposits occur. At one locality in Battle River valley, in sec. 30, tp. 45, range 2, west of the 4th mer., the following section occurs( l ): 15 feet of boulder clay with granite and other boulders. 56 feet of stratified sands, clays, and gravels containing pebbles of Precambrian rocks and fresh-water shells. From this it is apparent that the 56 feet of stratified sands, clays, and gravels must have derived their Precambrian pebbles from a previous glaciation of which the overlying boulder clay represents another ice advance in this area. Thus, although the river valleys contain glacial and interglacial deposits, they have not been filled by them to such an extent that the drainage has been diverted, and in many places, especially in the case of Battle river and some smaller streams, the size of the valley is altogether out of proportion to the size of the stream it now contains.

Jan 1, 1937

By Zhenyu Han, Dion Weatherley, Ruslan Puscasu

"This study aims to demonstrate the capacity of the Discrete Element Method (DEM) to model and simulate fracture in brittle rock, capture the crack propagation process and determine crack propagation rates for various levels of external loading. In the numerical experiments reported here, a macroscopically homogeneous body of brittle rock, containing a single pre-existing crack, was subjected to tensile stress loading. Simulations concerned with model I crack growth process in 3D were carried out. The process of fracture has been observed under various steady state and dynamic conditions. The numerical results obtained reproduce qualitatively and quantitatively a variety of observed fracture phenomena. Specifically, this study examined the onset of cracks, single dominant cracks that grow across the specimen, crack bifurcations and branching. The density of fractures that can be nucleated and grow to a significant size with and without arresting each other, crack growth speed and stress distribution, all have been consistently and systematically analyzed. Suggestions on potential future developments are made and discussed.INTRODUCTIONFracture and failure mechanics are very important in mining, manufacturing, materials processing, mineral processing, civil and mechanical engineering, and many other disciplines of science and engineering. Yet, due to the complexity of fracture phenomena, no theoretical models of broad applicability are currently available (Bieniawski 1967). The simulation of crack propagation is therefore considered an open question in numerical rock mechanics. Although, a significant body of experimental research on fracture of materials was carried out since the early days of fracture mechanics (circa 1940s) (Poncelet 1946, Mott 1948), often in parallel with the development of fracture mechanics theories as well as with the development of experimental and observational techniques themselves, the experimental results were often done on particular classes of material such as glasses and other very brittle materials. Indeed, a number of specific experimental observations on the behavior of growing cracks in brittle materials were made in the 1940s for which generally accepted explanations based on physical principles are still lacking. Likewise, quantitative numerical modeling, based on both continuum and discrete methods, as a basis for understanding dynamic crack growth is still in a preliminary stage."

Jan 1, 2015

By T. Johnson, K. Lambrych, D. Kelley

Materials for construction of equipment used in hydrometallurgical plants are selected based on a combination of their ability to perform as required in aggressive process environments as well as their cost. As a material of construction, fiber reinforced plastic (FRP) has been shown to provide equal if not improved durability relative to alternative materials such as corrosion resistant alloys at a considerably lower cost. This is particularly true in the case of equipment used in acid leaching processes for copper, cobalt, nickel and rare earth elements. The selection and extensive use of FRP over alloys in new hydromet plant construction in North and South America illustrates this advantage of FRP effectively. This paper will compare corrosion performance and cost of plant equipment fabricated with stainless steel alloys and FRP made with Epoxy Vinyl Ester thermoset resins. Real world case histories for FRP piping, storage tanks, extraction vessels, and electrowinning cells combined with laboratory based corrosion studies will be reviewed to demonstrate how FRP materials are selected for hydrometallurgical equipment.

Jan 1, 2015

By M. Lahtinen

Traditionally, there have been three main methods for iron removal in the hydrometallurgical production of zinc. These methods are atmospheric precipitation of jarosite or goethite and pressurised precipitation of hematite. Jarosite precipitation is without doubt the leading and the most commonly used technology for iron removal. However, jarosite precipitation has some drawbacks, such as a low iron content (and, thus, high residue volume), high moisture content after filtration and often a high zinc content. These features make any environmentally acceptable way of using or disposing of jarosite more expensive, as compared to hematite and goethite. The importance of environmental regulations has grown in the zinc industry during the last decade, which will have an increasing effect on new investments. Hematite has several advantages over jarosite, such as a high iron content, low moisture and low zinc content. An important advantage of hematite is that it is suited for further use in the cement industry. However, until now the need for autoclave equipment has limited the spread and implementation of hematite precipitation in the zinc industry. Outokumpu Technology Oy has recently developed an alternative method for iron removal, which is the atmospheric precipitation of hematite. A patented method for precipitating hematite at atmospheric pressure is presented and compared with conventional methods for iron removal. The process conditions, the quality of the hematite precipitate and the environmental aspects are also discussed.

Jan 1, 2006

By M. L. Jeremic

The design of the long-hole sublevel mining method was originally based on the traditional assumption that the principal load was due to the weight of the overlying rock, and that the horizontal stresses are equal to one-third of the vertical stress. However, as mining progressed, the virgin lateral stress was found to be equal to or greater than the vertical stress. The virgin stress in the rock mass is not uniform throughout the folded orebody and adjacent strata. From detailed investigations, three basic patterns of virgin stress in ore panels have been inferred: uniform, bent and twisted. Stresses induced by stoping are up to three times greater than original stresses in the rock mass; they cause heavy ground conditions and make extraction of ore difficult. In the last ten years, the original mining system has been modified several times in order to destress the ground and improve the extraction of ore.

Jan 1, 1978

By A. Alfantazi, E. Asselin

"The corrosion of commercially pure titanium (CP-Ti) was studied from room temperature up to medium temperature (~160°C) under conditions relevant to medium temperature chalcopyrite leaching processes. The corrosion rates were measured by immersion and electrochemical tests in sulfuric acid. The influences of chloride, cupric and ferric ions on the corrosion rate and behavior were also investigated. Corrosion of the CP-Ti did not account for the total current density measured by linear polarization tests. The corrosion rates of CP-Ti under medium temperature leaching conditions were surprisingly high. The corrosion rate measured in ferric containing solution at 160°C was approximately 20 mm/yr.INTRODUCTIONTitanium exhibits excellent corrosion resistance in many aggressive environments because of the formation of a very chemically stable, highly adherent, and protective oxide film on its surface (Mitsuo et al., 2002). Because titanium is the only metal available at a reasonable cost that resists the high temperature corrosive slurries in many leaching processes, it is often chosen as autoclave liner material where it is subjected to severe conditions of acidity, temperature and pressure (Grauman and Say, 2000).A number of distinctly different hydrometallurgical processes for the pressure leaching of chalcopyrite have been developed and patented by various companies and they can be classified into low, medium and high temperature regimes (McDonald and Muir, 2007). For example, chalcopyrite concentrate may be processed at medium temperatures (115-175°C) and pressures of 800-2200 kPa (Dreisinger, D., 2006; Sahu and Asselin, 2011). The lixiviant may contain 20 to 55 g/L sulfuric acid, 8 to 12 g/L chloride ions, 10-25 g/L Cu2+ (Jones, 1995, 1997, 1999), and less than 1 g/L Fe3+ (Defreyne et al., 2005). The amount of these additions is determined by the grade of the ores and details are shown in Table 1."

Jan 1, 2012

By T. Verdel, Y. Gunzburger

Rockfalls are major and essentially unpredictable sources of danger, particularly along transportation routes (roads and railways). Thus, the assessment of their probability of occurrence is a major challenge for risk management. From a qualitative perspective, it is known that rockfalls occur mainly during periods of rain, snowmelt, or freeze-thaw. Nevertheless, from a quantitative perspective, these generally assumed correlations between rockfalls and their possible meteorological triggering events are often difficult to identify because i) rockfalls are too rare for the use of classical statistical analysis techniques and ii) all intensities of triggering factors do not have the same probability. In this study, we propose a new approach to investigate the correlation of rockfalls with rain, freezing periods, and strong temperature variations. This approach is tested on three French rockfall databases, the first of which exhibits an outstandingly high frequency of rockfalls (approximately 950 events over 11 years), whereas the other two databases are more typical (approximately 140 events over 11 years). These databases come from (1) the national highway RN1 on La Réunion Island, (2) a railway in the Bourgogne-Franche Comté region, and (3) a railway in the Auvergne region. Whereas a basic correlation analysis is only able to highlight an already obvious correlation in the case of the “rich” database, the newly suggested method appears to detect correlations even in the “poor” ones. Indeed, the use of this method confirms the positive correlation between rainfalls and rockfalls on La Réunion Island database. This method highlights a correlation between cumulative rainfalls and rockfalls in the Bourgogne region, and it detects a correlation between the daily minimum temperature and rockfalls in the Auvergne region. This new approach is easy to use and also serves to determine the conditional probability of rockfall function of a given meteorological factor. This approach will help to optimize risk management in the studied areas based on their meteorological conditions. Nevertheless, even if some rockfalls are correlated to meteorological factors, other seems to occur independently of these factors, which highlights the unpredictability of rockfall hazard.

Jan 1, 2015

By Simon B. Blancher, Malo Rousseau, Renato Contessotto, Thomas Wallmach

The Manganese division of the ERAMET group extracts manganese ore in Gabon and produces manganese alloys for the steel industry. ERAMET has an economic interest to maximize the ore throughput without reducing the lifetime of its manganese mines. This can be achieved by means of research and development leading to innovative ore beneficiation processes. For this purpose, the ERAMET research center has designed and constructed a new pilot plant for ore beneficiation by physical separation processes. This pilot facility was erected within an infrastructural and synergetic framework, including competencies in hydrometallurgy, pyrometallurgy, numerical modelling, analyses and mineral characterization that provide ideal research conditions. After laboratory scale tests, a pilot operation of beneficiation of low grade Mn ore (around 35% Mn) was carried out by jigging of the 1-10 mm fraction. This gravity separation process exploits density differences between the various Mn-bearing minerals such as pyrolusite and lithiophorite as well as gangue minerals such as silicates and iron-hydroxides. Enrichment leads to the production of a marketable product associated with a high mass recovery (53% for the jigging step). However, 20% of pyrolusite and 30% of lithiophorite are lost in the waste. Mineral characterization has shown microtextural complexities, but grinding the ore to approach the liberation mesh was not an option due to commercially defined constraints given by the ferro-alloy industry. Recovery of the Mn-bearing minerals or adjustments of the feed grain size (6.3-10 mm) are two potential areas of process improvements identified by means of Qemscan® mineral characterization. This paper details the process tested on a pilot scale (0.5 t/h), which has led to a significant increase in the beneficiation of a low grade Mn ore.

Jan 1, 2016

By R. Flood

"Oil has been discovered off Newfoundland in a number of locations on the Grand Banks, the most notable and exciting being in 1979 when Hibernia was discovered. This discovery has brought new challenges to the province as well as to all of Canada. During the seven years"" since its discovery, both industry and governments have attempted to define its parameters and to find the most efficient and economical way to develop the field.A number of studies have been completed during the interval and in 1985, Mobil Canada Ltd. and partners stated that they would prefer to develop the field by using a concrete Gravity-Based Structure (GBS). IntroductionHibernia is located in an environmental climate much more severe than that of any previously developed oil field. The wind and wave conditions are similar to those of the North Sea, but unlike the North Sea, any structure on the Grand Banks would have to contend with ice floes and icebergs. Decisions had to be made on whether fixed structures could be put in place that would withstand the pressures of the ice and the impact of an iceberg, or whether structures that could be removed when such impacts were imminent would be used.Early studies in 1981, determined that it was possible to build a concrete Gravity-Based Structure which could withstand the impact of the largest icebergs that are anticipated to float in that area of the banks.Additional studies increased the knowledge of icebergs: their patterns and size, and verified the original conclusions that Concrete Gravity-Based platforms would provide a practical solution."

Jan 1, 1988

By Franc R. Joubin

"Gold has been found in many parts of the Bridge River district of British Columbia; but it is from a relatively small area in the valley of Cadwallader creek that most production has come. The ore-bearing area measures 1/2 mile in width by 3 miles in length; and for convenience it is called the Cadwallader gold belt in this paper. In this belt are found the Bralorne and Pioneer mines and in addition several prospects under development.The gold of the Cadwallader gold belt occurs in quartz veins averaging about 3 feet in width and containing about ½ oz. of gold a ton. Except for a relatively small amount of silver, no other metals are produced from these veins. The ore-bearing veins occur in a variety of rocks. They occupy reverse faults and tension fractures belonging to a distinctive fracture system. Some of these structures are ore-bearing over lengths exceeding 5,000 feet and depths exceeding 3,700 feet. The production of the Bralorne mine (1932-1945) is 996,383 oz. gold and 190,709 oz. silver; that of the Pioneer mine (1930-1945) is 777,588 oz. gold and 135,698 oz. silver. These two mines have together distributed about $25,000,000 in dividends.The Bridge River district first attracted attention in 1863* when prospectors were attracted by its small but rich placer gold deposits. Most of the important lode deposits of the Cadwallader gold belt were discovered in 1897 (11). Many years of desultory development followed and it was not until 1928 and 1932 that the Pioneer and Bralorne mines, respectivdy, entered into profitable production."

Jan 1, 1954

By P. L. Schwartz

The present method of shipping potash to the myriad of consumers is inefficient, not only because of the extreme and unpredictable nature of seasonal demand, but also because railway car turnaround times are very lengthy. The Floating Train system employs unit trains of potash operating from Saskatchewan mines to distribution warehouses located throughout the six corn-belt states of Minnesota, Iowa, Wisconsin , Illinois, Indiana and Ohio, transshipment points at Thunder Bay and the U.S. waterway network, and, where applicable , large consumers. These unit trains would "float", meaning that they would not originate at the same mine nor terminate at the same warehouse on each trip . They would " float " freely among the origins, destinations and participating railways. The potash would be shipped uniformly throughout the year and usually stored in warehouses located within the six states. It would be subsequently delivered to consumers within a 75-mile radius. Distribution warehouses and rolling stock would be provided by a new company, Potash Distribution Limited, consisting of major potash producers and the Canadian railways. Potash Distribution Limited would be responsible for the distribution of potash from the origin through the warehouses to the final consumer. The additional costs of providing warehouse space and outbound delivery will be offset by the reduction in both rail rates and "peaking" expenses.

Jan 1, 1978

By Kim H. Shikaze, John R. Hawley

"Even though acid mine drainage is an old problem, particularly in coal mining areas, its appearance in the form of a major environmental hazard in the hardrock mining districts of Ontario was unexpected. The yellow and amber coloured wastes that characterize an acid mine drainage situation were first noted by the Ontario Water Resources Commission in the uranium mining Elliot Lake district. Problems of a similar nature were also noted in the copper-lead-zinc camp at Manitouwadge, the nickel camp at Sudbury and at numerous isolated base metal properties, both in and out of the Province of Ontario.Without exception, when acid mine drainage type effluents were evident, the specific companies involved worked sulphide or sulphide-associated ores. Without exception, the ore bodies contained quantities of iron sulphide (in various mineralogical forms) and, without exception, the milling circuits serving these operations were such that the iron sulphides were rejected to the tailings areas as waste.Once in a tailings area and after a varying period of time, iron sulphides react to form water soluble salts which, when discharged in the effluents from the tailings area, can affect stream chemistry and stream ecology.It is not unusual that the minerals pyrite, marcasite and pyrrhotite (all iron sulphides) react to form a stable oxide under atmospheric conditions. The law of stability of rocks and minerals, for instance, states that rocks and minerals are stable only in the environment of their formation and, as the environment surrounding them changes, the rocks and minerals tend to change to other species which are relatively more nearly stable under the conditions of the new environment (a). Under atmospheric conditions, iron oxide exhibits a greater stability than iron sulphide."

Jan 1, 1971

By Royston Colbourne

Objectives Of Presentation - Identify specific risks - A fresh look at risk - Provide a moment reflection on risk - Open discussion on risk A route to solution and advanced thinking.

May 1, 2010

By V. T. Panayotov, M. I. Panayotova

Wastewater from mining and mineral processing activities is often polluted by anion forming metals, such as molybdenum and chromium. Low cost materials, including zeolites, are studied for removing heavy metals from wastewater. It is widely accepted that natural zeolites are not effective in removing metals in anionic form. The paper presents study on use of metal modified natural clinoptilolite to remove Mo (VI) and Cr (VI) ions from model soft wastewater. Modification with Pb, Fe(III), Zn and Ba increases clinoptilolite uptake capacity with respect to Mo(VI) at low pH values of the water subjected to treatment, the efficiency decreasing in the order Pb > Fe(III) > Zn > Ba. Only lead-modified clinoptilolite shows high uptake of Mo(VI) in acidic, neutral and slightly alkaline conditions. Modification with Pb, Ba and Fe(III) increases zeolite uptake capacity with respect to Cr(VI) from neutral water. The effectiveness of Ba-modified zeolite decreases in slightly acidic water. Over 90 % uptake of initially available Cr(VI) is achieved by lead-modified clinoptilolite both under neutral and slightly acidic conditions. Increasing the initial pollutant concentrations increases the removed amount both of Cr(VI) and Mo(VI) for Pb-modified clinoptilolite. The findings could be a basis for using the natural clinoptilolite to remove in consecutive steps: firstly Pb(II) and/or Fe(III) ions and then loaded zeolite to be used for Mo (VI) and/or Cr(VI) removal. The kinetics of Mo(VI) uptake by CL-Ba, CL-Fe(III), CL-Pb, and CL-Zn is best described by the pseudo-first order kinetic equation. The kinetics of Cr(VI) removal by CL-Ba, CL-Fe (II), CL-Fe (III) and CL-Zn is best described by the pseudo-first order kinetic equation. Kinetics of Cr(VI) removal by CL-Pb obeys the equation for the first order irreversible reactions. Finding way to remove anions-pollutants from the mineral processing wastewater will render this industry more environmentally friendly and socially acceptable.

Jan 1, 2016

By M. Reda

Because of the adverse environmental effect of Chromate, Molybdate ions had been investigated as replacement for Chromate and the results had shown not to be encouraging. Film deposited from peroxopolymolybdate (from reaction of Molybdenum meta, with excess Hydrogen Peroxide), are more robust than that deposited from molybdate solutions. This was shown to be due to higher fraction of Mo (IV) and Mo (V) that form from Mo (VI) in the peroxopolymolybdate deposited film than the film deposited from Molybdate solutions. The peroxopolymolybdate film contains 40% un-hydrated molybdic acid, tetraperoxodimolybdate and tetra peroxo tetra molybdate. The protective properties of peroxopolymolybdate were shown to be due to the effectiveness of the un-hydrated molybdic acid.

Jan 1, 2010