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By J. G. Ross

A DESCRIPTION of the block-caving system of mining as practised at the King mine of Asbestos Corporation, Limited, Thetford Mines, Que., was presented. at the Annual Meeting of the Institute held in Quebec city, in April, 1934. The paper was published in the Transactions of the Institute for 1934. There has now been recovered, by this method, one million tons of ore, and a review of experience indicates that the method was well planned and has been executed smoothly. In approaching the problem of selecting the type of mining best adapted to this deposit, the method had to be one which would be low in cost, use no wood, and not disturb the surface immediately bounding the ore-body on two sides. Prior to 1931, block-caving had been considered but rejected, as it en-tailed disturbance of the surface area which lay within a 45° angle of the lowest contemplated workings, if the practice of such mines as Ray, Miami, Inspiration, and Morency, where this type of mining has been used extensively, was followed. At these properties there have been mined large tannages at outstanding low costs, but an extensive surface area has been disturbed in each case. In some instances, townsites in the mining area have had to be abandoned, and dwellings, not considered worth moving, have been allowed to fall into the depression. A study was made of the principles involved in the various types of block-caving, the existing information on ground movement, subsidence, etc., also being carefully analysed. Toward the end of 1931, a plan was conceived whereby the country adjoining ground being caved might be held permanently in place and undisturbed. The success of such a scheme was essential to the application of block-caving at the King mine on account of property boundaries, the Quebec Central Railway right-of-way, and expense of moving buildings. Study of existing data on caving and movement of rock, caused by sub-surface excavations of sufficient unsupported area to result in failure of the backs, indicated, in practically every instance, that such movements followed certain definite laws of mechanics.

Jan 1, 1936

By Mostafa Benzaazoua, Bruno Bussière, Jean Lelièvre

De nombreuses opérations mimères exploitent et traitent des minerais sulfurés pour concentrer des métaux precieux (Au, Ag ... ) OU des métaux de base (Cu, Pb, Zn ... ), laissant en fin de parcours des tonnages considérables de résidus plus ou moins générateurs de drainage minier acide (DMA) selon leur contenu en sulfures. De nos jours, Jes restrictions en matière de protection de l'environnement obligent Jes opérateurs miniers a trouver Jes solutions Jes plus efficaces pour préserver Jes sites environnants de la pollution due a l'oxydation des sulfures. Cette oxydation cause une acidification accrue du milieu et une mise en solution des metaux toxiques. L'utilisation des recouvrements multicouches est l'une des solutions Jes plus efficaces pour limiter la pollution liée au DMA mais entraine des coilts de construction qui sont souvent considérés par l'industrie miniere comme prohibitifs. Une façon de rendre cette technologie applicable, d'un point de vue économique, est de désulfurer Jes résidus à l'usine de traitement et d'utiliser la fraction inerte comme composante d'un recouvrernent multicouche. Cette opération de desulfuration peut etre réalisée par flottation non sélective des résidus dans le but d'obtenir d'une part un faible volume de concentré de sulfures qui devra être géré convenablement et d'autre part un rejet non générateur d'acide.

Jan 1, 1998

By E. Topuz, C. Duan

"INTRODUCTIONOperations research (OR) applications have experienced a substantial growth within the mining industry during the last three decades. The purpose of this paper is to present a summary of the results of a comprehensive survey of the application of various OR techniques to the major mining activities. It is hoped. through this sur vey , that the most widely used OR approaches, the important areas of application, and future trends have been identified.This survey included more than 500 articles published in this field in English since the late 1950s. Most of the relevant literature was found in mining publications, but, in terms of quality and originality, important applications were also found in literature not related to the mining industry. The sources constituted periodicals, proceedings research reports, and a few books. A listing of selected publications from which three or more articles reviewed in this survey appear is given at the end. Operations Research MethodologiesOperations research is concerned with optimal decision making in, and modeling of, deterministic and probabilistic systems that originate in real-life situation s. One basic feature of the OR methodologies is the attempt to optimize certain design parameters, subject to a set of constraints. This distinction has been employed in the survey as a guideline for selection of the techniques covered under the title "" OR methodologies"". The methodologies thus encountered in the literature are listed below. In a few cases, simulation has not been considered because it is not an optimization method per se."

Jan 1, 1989

By M. F. Goudge

Introduction It is only fitting on this occasion of the fiftieth anniversary of the incorporation of the Institute that we should indulge in a bit of retrospection and review the progress that has been made within this period in the various branches of the mining industry- progress that is so closely associated with the members of this Institute. Such a moment of retrospection will enable us better to appreciate the present status of the industry and to perceive more clearly the trends that should guide us in making sound plans for the future. The past half century has been a period of amazing industrial progress in Canada. In this period, the economy of our country has changed from one based chiefly on agriculture and the export of raw materials, to an economy based largely on a well integrated manufacturing industry. In all' o( these major developments, industrial minerals have played an important part and will play an increasingly, important part in the future. By ?industrial minerals? we mean the various non-metallic minerals (exclusive of fuels) as well as the rocks, sands, and clays used for industrial purposes. They are now used so widely and in such large quantities that modern industry could not function without them, and their continued availability at low cost is vital to the industrial future of Canada. The key position occupied by industrial minerals in modern Canadian industry was well illustrated two years ago when a strike occurred in the only Canadian plant producing soda-ash and calcium chloride at a time when those materials were already in short supply and unavailable from other sources. Within a short time of the shutdown of this plant, in which the two principal raw materials are limestone and salt, the great aluminium reduction plants on the Saguenay river were forced to curtail operations because of the lack of soda-ash, essential to the process of extracting aluminium from its ore. Automobile production, already harassed by a shortage of steel, was further hampered when glass for windshields and windows could not be supplied because the glass industry was slowed down almost to a standstill for want of soda-ash. Soap became almost unobtainable both to the housewife and to industrial users, because soda-ash is required in its manufacture. As a consequence of the soap shortage, the production o synthetic rubber at Sarnia was threatened because soap in large quantities is essential to the polymerization process. Motorists on gravelled highways all over Eastern Canada drove through clouds of dust because calcium chloride, used for dust laying, was not to be had. There were other cases of dislocation of industry related to the shutdown of this particular plant, but the above illustrates the wide ramifications of industrial minerals in modern industry. However, it is extremely doubtful if many Canadian citizens realized that these apparently unrelated happenings were connected in any way with limestone and salt.

Jan 1, 1948

By D. J. Xue

Four kinds of coal-rock combination were subjected to three kinds of stress waves in the SHPB numerical simulation. The wave propagation and the changes of the strain energy in the coal-rock combination during the dynamic impact process were recorded as well as the contact force. The dynamic response law of coal-rock combination was obtained. It was found that the coal had better reflectivity than the rock because of coal with larger impedance. In contrast the rock had better transmissivity. As the crest value of the incident wave increased, the increment in the crest value of the transmitted wave weakened in the coal-coal group, coal-rock group and rock-coal group, in contrast, the increment in the rock-rock group increased.

Aug 1, 2013

By T. Holmes, S. Davison

"The Special Standard Surge bin at Agrium’s Vanscoy Potash Operations (VPO) has been plagued with flow problems and wear, and corrosion issues for it’s entire working life. Investigation showed that the carbon steel construction, bin geometry, and resultant funnel-flow pattern were directly responsible for production losses and disproportionate maintenance and capital costs. Potash enters this bin at between 140°C and 165°C, but the stagnant potash outside the active flow channel was much cooler, allowing moisture to migrate toward the outer regions, which caused corrosion of the walls and reduced live capacity as the potash in this area hardened and built up on the walls over time.A 2013 inspection revealed holes and paper-thin areas in the lower cylinder wall sections and in the conical hopper. The only thing preventing major leaks and even a potentially catastrophic failure was the buildup of stagnant hardened product on the cone walls. It was concluded that the cone had reached the end of its life and required replacement. VPO’s original plan was to replace the cone in kind and repair the cylinder as necessary; however, a failure-mode and bin-performance investigation combined with a lifecycle- cost analysis indicated it would be better to redesign the hopper.For success in retrofit projects, it is essential at the design stage to consider the bulk solid flow properties and the operating environment involved. Because education in this area is not offered at a university level, engineers often do not fully appreciate the effects of the flow properties of bulk solids on bulk material handling equipment.Jenike & Johanson conducted flow properties tests on samples of potash and using the data, redesigned the bin and the feeder. After the modifications, VPO’s surge bin provides safer, more reliable operation with a much longer predicted working life. Using this retrofit as an example, we aim to provide a general understanding of bulk solids flow theory and highlight the importance of customizing the design to the appropriate flow properties in the cost effectiveness, reliability, and safety of a bulk material handling system."

Jan 1, 2016

By Robert A. Creaser, David R. Lentz

Abstract - The Moss molybdenite deposit, which was mined during both world wars, is hosted in late Grenvillian granitic pegmatite dikes. These dikes are locally aplitic, and intrude the late tectonic Onslow syenite (probably correlative with the ~1090-1070 Ma Kensington suite), which is in turn intrusive into the 1170-1155 Ma Chevreuil intrusive suite of southwestern Quebec. A Re-Os model age of 1053 ± 4 Ma (8.3 ppm Re) was obtained for molybdenite from a pegmatitic veinlet within an aplitic phase of the dike. A much younger Re-Os date of 860.9 ± 9.2 Ma (6.9 ppm Re) obtained previously from a pyrrhotiteand pyrite-rich metasomatic vein might reflect Os diffusion during slow cooling of the Grenville province, because this age is consistent with K-Ar dates reported from the region. Alternatively, the similarity between these younger dates may be fortuitous, and may instead relate to sampling issues for molybdenite. The Mo-rich granitic dikes at the Moss deposit are similar to other Mo-rich A-type pegmatite-aplite granitic dike systems that formed immediately after the peak of the Ottawan orogeny (1070-1090 Ma), and possibly are more closely related to the Kensington suite than previously thought.

Jan 1, 2005

By D. Furrer, M. Dallaire

The arrival of Image analysis in the last 20 years has changed the world of quantitative metallography. Many standard measurement techniques which were previously manual can now be done with fully automated systems. This reduces subjectivity and operator fatigue and therefore enhances the quality of the statistical results. In many laboratories, Titanium Alloy microstructures continue to be evaluated by traditional methods, where quality of results is subject to operator fatigue and level of experience. Advances in Camera technology have tremendously improved image acquisition. One can often see clearly at 500x what can not be observed at 1000x, allowing for a larger area to be analyzed, without the inconveniences associated with very high magnification objectives. Powerful and versatile Image analysis software combined with a high precision motorized stage gives access to a multitude of applications, which were extremely challenging or impossible until now. Image Analysis tools such as Multilayer Grab, which reconstructs an uneven image into one plane of focus (ex. Observation at high magnification of texture resulting from etching) and Mosaic which builds an image from a number of fields of view (ex. Reconstruction of very large grains at low magnifications) expand even further the power and flexibility of IA systems. This presentation will describe how automated methods are applied to the point count method and grain size measurement. We will show how cameras and software work together to permit quantitative measurements of primary alpha and prior beta microstructures, as well as lamellar alpha plate thickness in titanium alloys.Automated and semi automated quantitative measurements of various Titanium microstrures have been assessed, using the Clemex Vision PE. Examples of the methods and steps used are presented.

Jan 1, 2006

By Craig Faulkner

Discharge cones for large Semi Autogenous Grinding (SAG) and Autogenous Grinding (AG) mills are subjected to high wear as significant volumes of ground ore and slurry exit the mill. With the larger diameter mills of 32ft to 40ft in size becoming the norm, very high, concentrated wear is highlighting the limitations of conventional discharge cones and frequent changes are subsequently required. This paper outlines the advances made in the design of the Bullnose discharge cone. Superior wear materials to increase wear life over conventional rubber or chrome-moly steel discharge cones and the introduction of key design features to reduce reline times and improve fit and safety during installation, offer significant opportunities for the mill operator. Collated from multiple case studies, the wear data and reline history from 2004 to present clearly illustrate the way in which superior component longevity has reduced the frequency of relines over the life of the product to increase mill availability and effectively increase the tonnes milled in a period.

Jan 1, 2012

By Deepak Bhadouriya, Saurabh Singh, Aditya Raj Suman

"An experimental study of chemically enhanced filtration and dewatering of fine coal slurry with and without additives was carried out. The experiment involved determination of effect of slurry concentration, additives (cationic, anionic and nonionic), filter area, filtration velocity, particle size and cake resistance on dewatering and filtration using vacuum filtration cell. Finally, the rate of filtration and dewatering and optimum amount of additives used were determined under suitable filtration condition. Overall, it was found that the filtration and dewatering characteristics were enhanced by increased slurry concentration, larger filter area and larger particle size. In addition of additives, the kerosene was found to be best for enhancing the filtration which yielded cake moisture reductions of approximately 17% by weight. At optimum dosages, the final cake moisture contents were reduced by 3.6% and 5.8% by weight using the appropriate surfactant and flocculent, respectively.INTRODUCTIONFor India, it is estimated that coal constitute a principal source of energy for the next several decades. It is majorly used at thermal power plants to generate electricity and also to a great extent in steel and cement industry. It has been observed that its consumption is increasing so as to meet the energy requirements of the country. It has been found that in a coal preparation plant; approximately 20-25 percent coal is of the mined coal of the range below minus 0.5 mm (28 meshes). Generally, this fine fraction is discarded due to its high cost of processing and further utilisatisation is very minimal. But with ongoing research and development for advanced clean coal technology, various new techniques have been evolved to maximize the utilization of available coal. In recent time technologies such as column flotation, cleaning of fine size coal to lower the ash content and low pyretic sulfur is feasible at high recovery value. But in various researches it is found that one of the biggest hurdles in utilization of fine coal cleaning technology by the coal industry is the economic dewatering of the fine clean coal product. Thus, until an economical and practical solution to dewatering of fine clean coal is achieved, the efforts devoted to developing fine clean coal technology will be wasted. In this paper an effort toward enhancing and developing the optimum technique of dewatering and filtration of fine coal slurry has been made."

Jan 1, 2016

By H. W. McGerrigle

The St. Lawrence Valley of Quebec lies in an earthquake danger zone, the main centers of which appear to be Murray Bay, Montreal and Quebec City. This paper compares conditions in this "earthquake zone" with those of other, currently more active, earthquake zones of the Earth, deals briefly with the mechanics of earth movements and outlines the means by which earthquakes are re-corded. An account is then given of the earthquakes which have occurred in the Province of Quebec -from that of 1534-35 to the earthquake of 1925. A 50-year frequency cycle is implied. The general conclusion is that the 11robability of future earthquakes should be given more consideration in the construction of buildings in the St. Lawrence Valley region.

Jan 1, 1966

By C. Kuehmann, B. Tufts

QuesTek Innovations has applied its Materials by Design® methodology to computationally design a new ultra high-strength corrosion resistant steel. Ferriurn® S53 eliminates the need for toxic cadmium coatings currently used on conventional steels in landing gear systems. S53 has the strength of 300M steel, and corrosion resistance similar to 15-5PH stainless steel. S53's corrosion resistance improves stress corrosion cracking resistance and reduces susceptibility to hydrogen embrittlement, improving component reliability and providing an opportunity for extended overhaul and repair intervals. Ultimate tensile stress is 1965 to 2000MPa. S53 was designed to be mechanically equivalent to 300M, with the key addition of intrinsic corrosion resistance. Alloy design, microstructural characterization, and mechanical properties are discussed herein.

Jan 1, 2006

By J. G. MacGregor

At this, the opening meeting of the Western Quebec Branch of the Institute, it seems fitting that the first paper presented should embrace a survey of the known mineral deposits occurring in the area, and also a review of ?the exploration methods that have brought about their discovery. And since the study of geological structures must always be the guiding principle of an intelligent exploration campaign, it also seems to be the appropriate occasion to review the geological situation from the economic angle, in an attempt to arrive at a re-statement of the known facts governing the deposition of the mineral bodies . . It is not my intention to confine my remarks entirely to the geological problems involved, but rather to pass under review the exploratory methods that have been employed in the past and that are presently being used, and to offer a forecast of the type of exploration campaign that will be largely adopted in the future search for ore.

Jan 1, 1929

By L. A. Mells

"A laboratory test program was initiated by the Department of Energy, Mines and Resources as part of the National Uranium Tailings Program to investigate the applicability of a radium selective ion exchange complexer for removing radium from Canadian uranium mining effluents. The test program was carried out by Melis Consulting Engineers Ltd. under contract to the Department of Supply and Services using the Saskatchewan Research Council facilities located in Saskatoon, Saskatchewan.The results of this work showed the ion exchange complexer, Dowex XFS 43230.00, to be efficient in removing radium from contaminated water of uranium mining operations with the ultimate loading capacity of the resin on one type of water treated being determined as approximately 1,600 Bq/cm3 of new resin. Although this resin has potential application for treatment of effluent streams in uranium operations it has been identified that the resin efficiency and capacity is directly related to the chemistry of the water being treated and site-specific testwork is required in order to establish reliable design data for full-scale operations.IntroductionThe possible applicability of a radium-selective ion exchange complexer for removing radium from Canadian uranium mining effluents had been identified and discussed as a possible alternative to present radium removal methods during a review of disposal technology options for the National Uranium Tailings Program of the Department of Energy, Mines and Resources(1). Work by other workers(2.3) had shown the complexer to be very efficient in removing radium from contaminated water. Also, plant trials on contaminated minewater at the Mt. Taylor uranium mine in New Mexico is reported to have shown the resin complexer to be efficient under plant operating conditions.As a result, a laboratory test program was initiated by the Department of Energy, Mines and Resources as part of the National Uranium Tailings Program to investigate the suitability of this resin for Canadian uranium mining effluents. The test program was carried out by Melis Consulting Engineers Ltd. (MCEL) under contract to the Department of Supply and Services using the Saskatchewan Research Council (SRC) facilities located in Saskatoon, Saskatchewan."

Jan 1, 1985

By Wei Wang

The SMCO copper plant is located in DR Congo, and was designed by China NERIN Engineering Co., Ltd. The process is a typical hydrometallurgical plant with Leach-SX-EW, with the project treating the oxide minerals with agitation leaching, followed with three stage of solvent extraction and two stages of stripping, and using permanent SS cathodes to produce LME grade copper. Because of the special characteristic of the ore, what contains 2 different type of oxides (one high carbonate oxide and the other low carbonate), there are several new technical measures that have been developed and adopted for the plant. For example, different grinding, leaching, and filtering are used to treat different oxides. This paper, presents the project process, engineering design, construction and commissioning. The paper also describes some of the problems encountered during plant commissioning, such as the agitation leaching tank issues, and corrosion in the settler-mixer. This paper discusses some NERIN solutions to these problems, and explains the use of the CN filter, which is used to filter PLS to treat high level suspend solids, instead of the traditional sand filter. Finally, this paper also proposes steps / measures for further improvement for future plant operation.

Jan 1, 2014

By B. Caldwell

"The CompanyCardinal River Coals is jointly owned by Luscar Ltd. and the Consolidated Coal Company of Canada (Consol). The Luscar mine is operated by Luscar Ltd. and is located 40 km south of Hinton near Cadomin, Alberta (Fig. 1). The plant sits on the old townsite of Luscar, Alberta, which was founded in order to develop the coal in 1912 (Fig. 2). Initially, the coal was mined by Luscar Ltd. for heating and steam generation and used quite heavily by the railways for their steam locomotives. In 1955, the mine was decommissioned as the demand for coal for tl1ese purposes had dropped off. In 1969, the mine was re-established by Cardinal River to provide metallurgical coking coal for its customers in Japan. The coal is mined from the 13m thick Jewel Seam by open pit methods at a 10 to 1 stripping ratio. The run-of-mine coal is then cleaned to meet customer demands.The PlantThe clean coal preparation facilities at Cardinal River were extended in 1980 in order to increase the feed rate from 450 t/h to 800 t/h. The extension is a separate plant which can be operated on its own or in parallel with the old plant. In addition, modifications have been made to the fine coal circuit (hydrocyclones added), the coarse refuse circuit, (refuse bucks replaced by a refuse conveyor which backfills a pit), and the fine refuse circuit (solid bowl refuse centrifuges, refuse classifying cyclones, and hydra-rake thickener no longer utilized) since the plant was built in 1969. The plant production of 3 M t per year with a yield of 78% is achieved by first screening and breaking the run-of-mine material to a top size of 1 ½ in. The feed is then slurried, sized, and processed in three different washing circuits. The washed coal is mechanically dewatered, thermally dried, and then stored in a 14 500 t capacity silo or on a 300 000 t stockpile. The fine refuse is thickened and pumped to the same pit to which the coarse refuse is being conveyed"

Jan 1, 2000

By Dean Gerhardt

Why the need for proactive loose detection? ?? Past history of ground falls in Saskatchewan mines prompted research into new techniques for ground control. ?? Traditional tools for ground assessment (i.e. visual inspection, sounding with scaling bars) are not proactive and can often be time consuming. ?? Need existed for a system that was non-evasive, time efficient, and could be managed by a single operator. Ground Penetrating Radar (GPR) immerged showing the greatest potential.

May 1, 2008

By J. W. Meier, J. O. Edwards, R. C. Bell

"IntroductionTHE DIE CASTING industry .as we know it today is the direct result of the invention and development of die casting machines during the nineteenth century and of reliable alloys in the twentieth. The early machines were designed to cast low melting point metals such as lead .and tin, and their alloys.It was inevitable that, as these die castings were put into service, the demand should arise for stronger materials. Zinc alloys, often containing lead, tin, copper, and aluminum as major constituents, were relatively easy to cast and stronger than the lead and tin alloys. However, it became apparent after a number of years that these zinc alloys tended to become brittle, distort, and corrode, particularly if kept in warm, humid atmospheres. Thus, considerable quantities of zinc-base .alloys were in use before the trouble was realized and effective measures could .be taken to determine the cause of the instability.The deleterious effect of certain metallic impurities on the properties of zinc •die casting .alloys has now been known for about thirty years. Brauer .and Peirce, and, later, other research workers of the New Jersey Zinc Company such as Anderson and Werley, discovered the pronouned effect of lead, cadmium, and tin on the stability of zinc-alloys."

Jan 1, 1952

By J. Dilbeck, J. K. Ratliff, T. Petrov, Z. Brown

"In efforts to improve dust control during deep cut continuous mining a supplemental atomizing spray system, mounted on 14CM15 continuous miner, has been designed and successfully implemented in a U.S. coal mine. The mine is 2.1 m (7-ft) high and uses a blowing curtain face ventilation system with 1.1 m (3.5-ft) curtain offset from the rib. The face ventilation design parameters were set to 9.4 m3/s (20,000-cfm); 4.2 m3/s (9,000-cfm) line curtain flow rate, and 3.8 m3/s (8,000-cfm) scrubber capacity. The performed in-mine measurements, before and after the implementation of the atomizing spray system, showed a significant decrease in the respirable dust levels at the operator place as well as at the return. The paper describes the supplemental water spray system design and performance supported by three-dimensional computational fluid dynamics (CFD) simulations and in-mine test data.INTRODUCTIONThe work on this project have started in 2015 with a study of the conventionally applied face ventilation layouts. The specific behaviour of the face ventilation system have been analyzed trough in-mine measurements and computer modeling of typical cut scenarios. An computer modeling methodology have been developed for estimation the respirable dust concentration (RDC) using tracer gas to RDC contour mapping, calibrated by a single point value, provided by in-mine measurement. Utilizing the results of this study the engineering staff of the mine designed and implemented a supplemental atomizing spray system to improve the dust control during the deep cut continuous mining. Today the atomized spray system is successfully applied demonstrating steady performance and a significant decrease in respirable dust concentration on the working places of the continuous miner (CM) and coal transporters (CT) operators as well as at the return air stream. Information about the applied type of spray nozzles provided by other researchers (Cheng, 1973; Dick et al., 1996; Organiscak & Page, 1998; Pollock & Organiscak, 2007) and spray system manufacturers (Spraying System Co, 2011–2018; Steinen Mfg., 2016) have been used in this project. CFD code and simulation approach validated in a study conducted in 2000-2014 have been applied (Turner et al., 2002; Wala et al., 2004, 2007; Petrov, 2014)."

Jan 1, 2019

By Joseph Carlston

With environmental regulations continuing to restrict the discharge of phosphorus from wastewater treatment facilities, traditional methods of phosphorus removal are proving inadequate. To achieve the phosphorus control necessary, a new coagulant used for phosphorus removal, cerium chloride, has been studied in several municipal and industrial wastewater treatment facilities that must meet a phosphorus discharge limit of 0.5 mg/L or lower. These studies demonstrated the high phosphorus removal capabilities of cerium chloride, with the results illustrating the ability for cerium chloride to reduce phosphorus to low concentrations in the effluent using a lower volume of product as compared to traditional coagulants, such as ferric chloride. This reduction is due to the unique ability of cerium chloride to remove phosphorus as cerium phosphate, whereas iron- and aluminum-based coagulants rely on adsorption and co-precipitation.

Jan 1, 2014