Search Documents

By J. R. Parga T., P. J. Valenzuela G., L. S. Quiroz C., P. Guerrero G., J. L. Valenzuela G.

"Pressure oxidation is a hydrometallurgical pre-treatment process used for refractory auriferous sulfide ores. In the work reported here, a refractory pyrite ore sample from the Mulatos mine, Sonora, Mexico was characterized. The sample was subjected to atmospheric cyanidation, and simultaneous pressure oxidation and cyanidation under different conditions of temperature and pressure. The mineral characterization showed that pyrite is the main species in the sample. The gold extraction tests were carried out in an 1-litre Parr pressure vessel at a temperature range of 90-120 °C, a pressure range of 87.5–150 psi (using oxygen), and a cyanide concentration range of 0.8-1.2 %wt. The gold extraction results showed that diffusion through product layer is the rate controlling step.INTRODUCTIONIn hydrometallurgical precious metals extraction, the most commonly used process is sodium cyanide leaching, as shown in the next reactions involving gold and silver (Fleming, 1992; Marsden & House, 2006):4Au(s) + 8CN- (aq) + 2H2O(l) + O2(g) ? 4Au(CN)2 -(aq) + 4OH- (aq) (1)4Ag(s) + 8CN- (aq) + 2H2O(l) + O2(g) ? 4Ag(CN)2 (aq) + 4OH- (aq) (2)“Refractory” auriferous ores or concentrates often contain gold and silver locked inside other sulfide phases such as pyrite. This renders cyanidation ineffective, so oxidative pre-treatments are used in order to convert the sulfide minerals into porous oxide minerals and make cyanidation work more efficiently. Reaction (3) shows the oxidation of pyrite in alkaline media and the formation of the porous oxide (Koslides & Ciminelli, 1992):2FeS2 (s) + 15/2 O2 (g) + 8H- (aq) ? Fe2O3 (s) + 4SO4 2- (aq) +4H2O(l) (3)A process of simultaneous chemical pressure oxidation and cyanide leaching for a flotation concentrate produced in the mine of Bacís, Durango, in Mexico, gave good results (Parga et al., 2007). In the study presented here, it was intended to use this treatment for a refractory pyrite mineral from the Mulatos mine in Sahuaripa, Sonora, Mexico, modifying variables such as pressure, temperature and cyanide concentration to find the best conditions for oxidation and leaching."

Jan 1, 2012

By S Sokhanvaran

Electrodeposition of silicon from a cryolite based electrolyte at a relatively low temperature (1000°C) is a promising approach to generate high purity silicon. In order to obtain fundamental data pertaining to electrowinning of silicon from Cryolite?SiO2 melts, density and electrical conductivity measurements were made. A range of temperatures and SiO2 contents was studied for each property. It was found that while density has an inverse relationship with temperature, the dependence for electrical conductivity is direct. Increasing silica content up to the saturation limit (~ 5 wt%) increases the density whereas further increase in SiO2, lowers the melt density. On the other hand, the conductivity is lower for the melts with greater SiO2 content, at any temperature.

Jan 1, 2011

By John J. Barakso

A summary of geochemical dispersion processes is presented. Secondary and tertiary dispersion of uranium was examined at several uranium prospects in British Columbia. The vertical migration of uranium from bedrock (primary dispersion) through overburden into the various soil horizons, and into snow and plants, was studied, and relationships were sought to explain the dispersion patterns in the secondary and tertiary environments. Soil developments were examined to obtain information on factors affecting the dispersion of uranium in soil profiles and tertiary substances; samples were analyzed for a number of elements. Biogeochemical data indicate that plant geochemistry is a possible exploration aid in areas of heavy overburden owing to the high selectivity of certain plants for specific elements. Some new data on the geochemistry of snow are discussed as a matter of research interest in the tertiary dispersion of uranium. Analytical techniques and problems are discussed, particularly extraction techniques, which must be carefully chosen to give reliable information on uranium dispersion.

Jan 1, 1979

By W. Kunda, J P. Warner

SHERRITT GORDON Mines Limited annually produce 300,-000 pounds of pure cobalt by processing a nickel-cobalt-copper-iron sulphide ore which is mined at Lynn Lake, Manitoba. The ore (containing 0.04 per cent Co) is •concentrated to give a concentrate containing l 1-12 per cent nickel, about 2.0 per cent .copper, and 0.25-0.35 per cent cobalt, which is treated at the Refinery in Fort Saskatchewan, Alberta. The concentrate is leached in an ammoniacal solution of ammonium sulphate using compressed air as the oxidant. After filtration the leach solution contains, besides nickel and cobalt, copper ammines, sulpharnates and salts of various thionic acids. The copper is removed by precipitation as sulphide and the sulphur compounds converted to ammonium sulphate by a combined oxidation and hydrolysis treatment. The purified solution •Containing about 45 gpl of nickel and 1 gpl of cobalt is treated with gaseous hydrogen under pressure at 350°F to precipitate metallic nickel powder, the precipitation 'being terminated when the nickel content of the solution is about 0.8-1 gpl. Only about

Jan 1, 1962

By D. R. Nagaraj, Napoleon Tercero, Raymond Farinato

"Dialkyl dithiophosphinates are a unique class of collectors used in the flotation processing of Cu- Au, complex polymetallic, and precious metal ores. They are known to exhibit higher selectivity and flotation rates for Cu sulfides, galena, and precious metal values in the presence of other gangue sulfides, than the traditionally used collectors such as dialkyl dithiophosphates and xanthates. They also have an attractive HSE profile. Historically, for most reagents used in flotation, practical methods of chemical usage have preceded detailed scientific understanding of how they work; this applies also to dithiophosphinates. Recently, however, the research community has shown significant interest in this chemistry, and numerous studies have been conducted to understand the fundamentals of interactions of dithiophosphinates with several base metal sulfides and precious metals. A critical overview of fundamental studies, laboratory ore flotation, and plant practice of dithiophosphinates is given in this paper. The findings from these studies are rationalized by drawing on concepts and insights from coordination chemistry. A comparison between the interactions of dithiophosphinates and dithiophosphate analogues with various minerals and metals is also made throughout. We believe that such a critical analysis/overview will be invaluable in identifying gaps in knowledge regarding this important set of compounds, which in turn may provide a basis for the design of studies that can advance understanding of their flotation performance. INTRODUCTIONDialkyl dithiophosphinates are an important member of the class of thiophosphorus compounds that are widely used in flotation beneficiation of base metal sulfide and precious metals ores. Ore flotation studies and plant practice experience have demonstrated their unique properties compared to the traditionally used sulfide collectors such as dialkyl dithiophosphates (their closest analogues) and xanthates. The predominant dialkyl dithiophosphinate used in the industry today is sodium diisobutyl dithiophosphinate (a.k.a. DIBDTPi; AEROPHINE® 3418A1 introduced by American Cyanamid in the late 1970s; Figure 1). The widest application of AEROPHINE 3418A is found in complex polymetallic ores of Cu-Pb-Zn-Ag, Pb-Zn-Ag, and Cu-Zn where it has demonstrated improved recoveries (and flotation rates) of sulfide minerals of Cu, Pb and Ag and selectivity against sphalerite, iron sulfides, and penalty elements (Mingione, 1991). More recently, it has also been used as a collector in the processing of Cu, Cu-Ni, and Ni ores (Guitard et al., 2015) and Cu-Au ores (Dunne, 2005). In general, it is considered to possess the collecting power of xanthates together with the selectivity (against pyrite) of dithiophosphates (Hope et al., 2003a, 2003b), while requiring lower dosages than those reagents (Guitard et al., 2015). AEROPHINE® 3418A has also found an important place in several targeted formulations to improve flotation performance. Other benefits of this reagent include higher flotation rates, having a better HSE (health, safety and environmental) profile2 compared to xanthate, and exhibiting resistance to hydrolysis and oxidation (Guitard et al., 2015). Compared to diisobutyl dithiophosphate (DIBDTP), which is known to contribute significantly to frothing (often leading to over-frothing), AEROPHINE® 3418A is observed to be froth neutral (i.e. it does not alter the existing froth characteristics). As is the case for other flotation reagents, the design and application of AEROPHINE® 3418A has preceded understanding of its behavior at a fundamental level. Recently, there have been numerous fundamental and application studies designed to develop a better understanding of its interaction with sulfide minerals and precious metals. This should help in optimizing its application in flotation and provide a basis to better rationalize its unique selectivity and activity characteristics. Past studies on the interacti"

Jan 1, 2016

By G. M. Behrend

"AbstractMeasurement and control systems in minerals processing plants are usually well thought out and designed. The criteria and design parameters have been interpreted correctly.However, these systems often fail to perform satisfactorily or break down altogether as a result of in-plant conditions which are unpredictable and over which the instrument systems designer has no direct control. The foresight necessary to anticipate the problems and allow for them in the systems design can only be generated by experience.This paper lists the most common of these problems and offers practical methods for their solution. It then follows with an analysis of instrument installation practices and comments on special points that need watching.Finally, instrument maintenance is discussed with a view to achieving good maintenance at the best possible economy.Good MeasurementGeneralTHE MINES and mineral processing plants of the nineteen seventies, after decades of sensible caution, have now committed themselves to extensive automatic control. X-ray analyzers are freely specified. Sample acquisition systems are efficient and automated, computers are reliable and relatively cheap, and computer control systems in conjunction with the new analyzers are operating in a good many plants and are proving to be profitable.The sight of shift foremen and floor operators assembled in front of a TV-tube and taking a computer data display as gospel truth is quite common now, and yet was quite unthinkable only ten years ago."

Jan 1, 1977

By P. Talonen

Since the last Iron Control in Hydrometallurgy Symposium in Montreal in 1996, the Kokkola zinc plant has increased its capacity from 175,000 t/y to 280,000 t/y by installing an atmospheric concentrate leaching process, which has also affected iron control in the leaching circuit. Major changes have been made at the jarosite residue pond; a subterranean plastic wall reinforced with bentonite and cement has been built around the pond. A new water collecting system that is used for groundwater level control in the pond area was installed. With these two investments in the pond area, it is now possible to prevent any seepage flow from the pond into the surrounding environment. Water pumped from the residue pond is treated in the water treatment plant. This paper describes the behavior of iron in Kokkola's current leaching processes. The treatment of the jarosite, the improvements to the residue pond and the water treatment process are also described.

Jan 1, 2006

By A. P. Page, G. E. Alexander, L. L. Sirois, A. A. Winer

A knowledge of the electrical surface characteristics of minerals is all-important in the choice of treatments to up-grade and beneficiate them. At their solid-liquid contacts, there are transfers of ionic species, which for insoluble oxide minerals are the H+ and OH-ions. The adsorption density of these ions can be detected by carrying out potentiometric titrations, and this paper describes the automation of such an apparatus. The details are discussed fully and the validity of the method is demonstrated by flotation tests.

Jan 1, 1969

By C. R. Edwards

"Since the first commercial extraction of uranium in the early 1940s, the range of feasible process alternatives has greatly increased. This paper reviews process options to reduce extraction costs, improve efficiencies, effect safer operations, and lessen environmental impacts. Equipment and processes used in the past, in use now, and that could be considered for future use are described.BackgroundTwo billion years ago life on earth consisted solely of single celled creatures of the simplest design (Gould 1989). Incredible as it may seem, uranium fission reactors were operating then also. In what is now western Africa, a series of natural reactors were fueled by rich uranium deposits in contact with underground rivers. Water from the rivers provided the moderator necessary to sustain the nuclear fission chain reaction. These primordial reactors ran down after about 600 000 years (Ontario Hydro 1989).Because it is ubiquitous in the earth's crust, humans have always been in contact with uranium. Mining of uranium, albeit not intentional, is ancient ; uranium minerals were embedded in ore veins mined for metals such as silver and copper.Uranium was discovered in 1789 in Berlin by an apothecary, Martin Heinrich Klaproth, who named the element after the recently discovered planet Uranus. The metallic element uranium, as opposed to its compounds, was extracted in 1841 by the French chemist Eugene-Melchior Peligot. The atomic mass of uranium was calculated to be 120, but the Russian genius Dmitri Ivanovich Mendeleev (famous and welcome everywhere except in Russia, where his liberal politics were detested by the Tsar), found this did not fit into his periodic table, and submitted a value of 240. Mendeleev was close; the exact atomic mass is 238.029.Henri Becquerel's detection of the radioactivity of uranium in 1896excited scientific study of the metal, but virtually no practical use was found for uranium outside of a minimal consumption as a colouring agent for glass and ceramics. Scientific interest intensified in the 19305. In 1933 Leo Szilard patented the concept of the nuclear chain reaction. While walking to work on a fine fall London morning and mulling over the problem of how to release atomic energy, he was stopped by a red light. He stood in thought and conceived the notion of the neutron-activated chain reaction before the light turned green. The patent was filed in 1934, and Szilard assigned it to the British Admiralty in order to keep it secret, in an honourable but ultimately futile effort to prevent the misuse of science (Bronowski 1973)."

Jan 1, 1992

By B. S. W. Buffam

Introduction The development of uranium deposits is a relatively recent phase of mining in Canada. To date, the only producer of uranium ores on a commercial scale has been the Port Radium mine on Great Bear lake, N.W.T. However, with.-in the past few years intensive prospecting has been carried on throughout Canada and many occurrences of uranium-bearing minerals have been discovered. Eldorado has been active in the search for and the exploration of uranium deposits in Canada for a longer period than any other company and has, therefore, accumulated a considerable fund of information, especially about occurrences in Saskatchewan and in the Northwest Territories along the western fringe of the Precambrian Shield. The Company has also had experience in the underground operation, and in the mining, of uranium ores at Port Radium. During the past year or so many requests have been received from the prospecting and mining fraternity for information and guidance regarding the development of the many new uranium discoveries that have been made in Canada. Assistance by Eldorado is freely given whenever possible and this paper is presented to supplement the private discussions and to provide as wide a distribution as possible of the data acquired by Eldorado.

Jan 1, 1951

By A. V. Corlett

THE use of the diamond-drill hole as a means of breaking clown ore and waste is not new. Years ago, the method was adopted in mines in northern Ontario and in the western United States to reach out to bad pillars, or to remnants of ore left on walls, the winning of which by any other method might be dangerous or too expensive. The practice is still in vogue and has generally proved a success. Of the known mineral deposits in Canada and elsewhere, many are of very low grade. Some are marginal and not even worthy of being classed as 'ore' until some means is found and proved of exploiting them economically. Other conditions being favourable, if a mining method could be found that would give a large 'bulk break' with a sufficiently low cost of development and a low cast of mining per ton, mineral deposits of this latter type might be brought into the classification of ore. We know that any block-craving system whereby the ore may be undercut and allowed to crush and cave will give a very high breakage and low costs. In some cases, however, the physical characteristics of the ore do not lend themselves to this method. In such ore-bodies, the alternative system of 'bulk-breaking' might be aided by long diamond-drill blast holes. We could obtain this 'bulk breaking' by the use of long diamond-drill holes in conjunction with a sub-level system using extremely thick benches, or possibly by the adaption of modified open-pit methods to underground mining. ln fact, if conditions are favourable, the idea would be simply ta open up a slot or free face and break into it on a larger scale with longer holes. The use of deeper benches-that is, using each level as a sub-level and thereby eliminating much development footage, slashing, setting up, and mucking time-would naturally be expected to lead to cheaper mining.

Jan 1, 1940

By W. M. Brewer

Introduction This paper describes some of the mineral resources that are tributary to that portion of the Pacific Great Eastern railway included in the Western Mineral Survey District, No. 6, of British Columbia. This district extends 38 miles northerly from Squamish, the ocean terminus of the railway at the head of Howe sound, to Alta lake. Beyond Alta lake the railway continues northerly through two other mineral survey districts: the Central Mineral Survey District No. 3, and the Northeastern District No. 2. District No. 6 includes that section of the Coast Range from which the waters flow southerly towards Howe sound. The division between District No. 6 and District No. 3 is represented by an imaginary line across the summit between the headwaters of the Cheakamus river, flowing south into the Squamish, and the Green river which flows north and empties into the head of Lillooet lake near Pemberton meadows, about 20 miles from Alta lake. History: - The history of the route of the P. G. E. railway dates back to the old Cariboo days when a pack-horse trail traversed the country northerly from Squamish to the Pemberton meadows, and also south-easterly from Squamish to the head of Seymour creek, thence southerly down that creek to the north arm of Burrard inlet.

Jan 1, 1925

By M. A. Gomez, V. Yahorava, J. A. Strauss

"It is accepted widely that pressure oxidation (POX) is the most appropriate technology for processing of arsenic containing refractory gold ores. However, studies on the stability of various iron-arsenic precipitates formed during POX are limited. Since the behaviour of these phases could have significant practical implications for gold processing plants, it is important to study them in isolation. This paper compares two synthetic precipitates, basic ferric arsenate sulphate (BFAS) and basic ferric sulphate (BFS) in terms of their formation, behaviour during hot curing and cyanidation, as well as their environmental stability. BFS and BFAS were synthesised hydrothermally at 205°C and their mineralogy was confirmed using various techniques. During synthesis, the addition of H3AsO4 into an aqueous Fe2(SO4)3-H2SO4 mixture significantly decreased the iron yield to BFAS in comparison to BFS under equimolar initial iron and acid concentrations. The BFAS dissolution kinetics was slightly faster, as compared to BFS, during subsequent hot curing. Cyanidation test work on the washed synthetic precipitates indicated that the lime consumption of BFAS was three times lower in comparison to BFS, while cyanide consumptions were comparable. Fresh BFS and BFAS precipitates, as well as their cyanidation residues, were found to pass the respective environmental tests in terms of arsenic release.INTRODUCTION Pressure oxidation (POX) is generally viewed as the most appropriate technology for the processing of arsenic-containing refractory gold ores due to the stabilisation of arsenic in the leach residue (Dutrizac & Jambor, 2007; Gomez et al., 2008; Harris, 2003; Collins, Berezowsky, & Weir, 1988). Detailed laboratory studies indicated that several Fe(III)-arsenate type compounds may be formed under typical conditions of autoclave treatment of refractory gold ores (Swash & Monhemius, 1994; Dutrizac & Jambor, 2007; Gomez et al., 2008, 2010; Gomez, Becze, Cutler, & Demopoulos, 2011). The basic ferric arsenate sulphate (BFAS) phase (Gomez et al., 2008), also known as Type II ferric arsenate (Swash & Monhemius, 1994) or Phase 3 (Dutrizac & Jambor, 2007), is one of the most common arsenic-bearing products (Harris, 2003; Dutrizac & Jambor, 2007). BFAS precipitation is viewed as one of the best routes for arsenic stabilisation and performed equally well to scorodite during environmental stability tests (Harris, 2003; Swash & Monhemius, 1994; Dutrizac & Jambor, 2007; Gomez et al., 2008, 2011)."

Jan 1, 2017

By Thom Mambe, Angelo Fernando

The objective of this work was to identify key parameters related to the reduction of the sulphur content in ammonium diuranate (ADU), and the identification of solid products being formed under various operating conditions. A laboratory-scale, continuous ADU precipitation circuit was assembled using a glass reactor vessel immersed in a temperature-controlled water bath. A pre-prepared uranium feed solution was fed continuously using a peristaltic pump. Anhydrous ammonia mixed with compressed air was metered and pumped using a double-headed peristaltic pump. An over-head mixer was used to keep the solids in suspension. The precipitated ADU slurry was removed from the reactor at the same flow rate as the feed solution. The slurry was sampled to generate ADU solids for chemical and physical analysis after four hours of continuous operation to ensure steady-state conditions. The following variables were studied to determine their influence on the sulphur content in the resulting ADU. (a) sulphate:uranium molar ratio in the reactor (1:1, 1:5, 1:10 and 1:20) (b) precipitation pH ( pH 6, 6.5, 6.9, 7.5 and 9) and (c) precipitation temperature (40C and 60C) A total of 18 tests covering the above parameters were conducted, and the results indicated that the sulphur content in the resulting solids was highly dependent on the reaction pH. Out of the pH levels tested, tests completed at pH 6.9 and 7.5 generated solids containing the lowest sulphur contents, between 0.5 to 1.5% S uranium basis (UB). The sulphur content in solids was found to vary linearly with the sulphate:uranium ratio in the feed solution, showing a statistically valid correlation. The impact of temperature was minor between 40°C and 60°C, with a slight advantage at higher temperatures. Tests at a sulphate:uranium ratio of 1:1 produced solids with the lowest sulphur contents. The influence of pH or temperature on sulphur content in solids was almost non-existent at this sulphate:uranium ratio. Precipitation pH is the major factor influencing ADU sulphur content, followed by the uranium to sulphate ratio.

Jan 1, 2020

By C. A. Y. Shephard, H. L. Brusset

Pressure maintenance by water flooding in the Pembina Field made consideration of wet crude dehydration and disposal of the produced water mandatory. Crude dehydration, the treatment and disposal of produced water, as well as the sale of gas and crude oil were expected to be handled more efficiently at one central point than at several conventional batteries. This plan was effected by routing the produced fluids to the central station by way of several well testing batteries referred to as satellites. To realize the full efficiency inherent in such consolidation the entire system was made self-regulating. Programming ensures the testing and proper routing of all products to their destination. Forty producing wells have been self-operated during the winter 1959 -1960 with gratifying results.

Jan 1, 1960

By G. R. Webber, L. M. Azzaria

"The wide interest in the application of the geochemistry of mercury to mineral exploration is leading to the continued development of a variety of analytical methods for the determination of nanogram quantities of this element. The various methods have different degrees of reliability, sophistication and portability. In this investigation, two simple portable instruments were used in geochemical prospecting surveys -an ultra-violet absorption instrument and a similar one modified with gold for the removal of interfering substances. The results show the application of the method to the determination of mercury in soils of different organic content, and in rocks, sulphides and air."

Jan 1, 1969

By K. van Warmerdam, M. Pearson, C. Kember, D. McMullen, M. Thayer, C. Ugarenko

In July 2012, Hatch Ltd. and Air Products & Chemicals Inc. completed construction and commissioning of a 4000 tpd O2 cryogenic air separation unit (ASU) for Barrick Gold’s Pueblo Viejo Project located in central Dominican Republic. The ASU produces high pressure gaseous oxygen, which is used for the oxidation of refractory sulphide ore within the pressure oxidation (POX) circuit. As a result of the project’s remote location and tropical climate, many challenges were faced over the course of construction, commissioning and start-up of the ASU. These challenges included adequate preservation of equipment due to dusty and humid site conditions, final assembly and erection of the cryogenic distillation columns on site, limited spare parts inventory/availability, and an unfinished power source for plant commissioning. This paper discusses the steps taken by Hatch and Air Products to successfully design, construct, commission and start up the largest stand-alone ASU plant for a POX application in the metallurgical industry.

Jan 1, 2014

By E. Asselin

Electrochemical polarization experiments were conducted on alloy 625 in ammonia solution between 25 and 225°C and the results were compared with those of an oxygen solubility model. Results confirm that corrosion is under oxygen control, Normalized corrosion rates are determined based on the rate of oxygen diffusion to the corroding surface, and the corrosion rate at 200°C (-9.7 µA.cm-2) is roughly 24 times higher than the corrosion rate at 25°C (0.4 nA,cm-2), An oxygen-solubility model for Supercritical Water Oxidation (SCWO) conditions was generated using the Redlich¬Kwong-Soave (RKS) equation of state, Results of the model confirm many of the experimental observations from SCWO reactors which suggest that corrosion is at a maximum at temperatures just short of the critical point, The RKS/oxygen diffusion model predicts that the corrosion rate at 365° C is ?85 times higher than the corrosion rate at 25' C. Given that a normalized corrosion rate is obtained, this type of model could be useful for selection of SCWO reactor materials.

Jan 1, 2005

By R. C. Wallace

Introduction At a time when the mineral-bearing areas in Manitoba are being fi very keenly explored because of the major developments which are now taking place in that Province, it may be timely to give an analysis of the mineralization in the two major types of deposits, with a view particularly to assist in the intensive prospecting to which the mineral-bearing areas in the Province are now to be subjected. As is already well known, there are two principal types of mineral deposits in the territory- copper-zinc and gold; and attention will be confined almost exclusively in this paper to these two types, with some indication of such modifications of the main types as may be found to be of economic value. The details of the paper are drawn from what is yet a small part of the area of the Province available for prospecting. Enough is now known of the types of mineral deposits which are described in the following pages to justify the expectation that these types may serve as criteria in the search in the newer districts. Doubtless new types will also be found as investigations proceed.

Jan 1, 1928

By A. G. Matyas

Process improvements which have reduced the lead content of slag from the Brunswick lead blast furnace are described. Microscope examination and electron microprobe analyses, supported by the results of slag settling and viscosity tests, showed that typically about 70% of the lead in the lead blast-furnace slag was present in the form of entrained prills of metallic lead. The total lead content was found to increase with the magnetic susceptibility of the slag. Measurements in the furnace settler indicated the presence of a magnetite-rich layer between bullion and slag, arising from high magnetite levels in the slag. This layer was believed to inhibit the settling of entrained lead from the slag. Tracer tests showed that the average slag residence time in the settler was less than 2 minutes. Improvements in coke quality and sizing, which led to a reduction in the slag magnetite content, and the installation of a larger settler and a continuous Roy tapper, have all contributed to a significant decrease in the slag lead content.

Jan 1, 1977