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By Gao K, Wu C, Langley J. M, Waugh B, Farrell K

The dissolution of carbon from carbonaceous materials into molten iron is a key step in various ironmaking operations. For example, in new direct smelting processes, carbon in the form of coal is injected into the molten iron bath, which leads to the dissolution of carbon. In foundry operations, typical recarburizer materials can range from high purity graphite to chars. The dissolution performance of these" materials is critical to the operation and could dictate the efficiency and economics of the process.Dissolution kinetics has been studied by various investigators to explain the influence of melt conditions and carbon type (Sahajwalla et al, 1994; Shigeno, Tokuda, and Ohtani, 1985; Orsten and Oeters; 1988; Ganguly and Reid, 1992; Wright and Taylor, 1993). The influence of melt sulphur content on the dissolution kinetics has been characterised (Sahajwalla et al, 1994), with sulphur retarding the rate of carbon dissolution. The carbon dissolution from different sources is seen to vary significantly even under similar melt conditions. This observation has been explained by investigators on the basis of the varying ash content present in the carbonaceous materials. However, ash content alone cannot account for the variability in dissolution kinetics reported in other studies. One such study is presented below.In a recent study (Sahajwalla et al, 1994), pulverised carbonaceous materials were injected into the molten iron bath and the" dissolution kinetics was established. The dissolution of graphite and glassy carbon, which contain almost 100 per cent carbon, was seen to be significantly different when the molten iron contained sulphur. The influence of melt sulphur content was explained on the basis of different wetting behaviour observed.Importantly, the study showed that even pure carbon sources dissolved at significantly different rates. Hence, their performance could not be explained on the basis of ash content.The key difference between graphite and glassy carbon is in their atomic structure. Graphite is highly ordered whereas glassy carbon has relatively poor ordering in its atomic structure. This study showed that the atomic structure in carbonaceous materials can have a significant effect on their dissolution performance.The focus of the present investigation which stems from the past study described above (Sahajwalla et al, 1994), is to investigate the influence of atomic structure of carbonaceous materials on their dissolution into Fe-C-S melts.The specific objective of this study is to determine the relationship between dissolution kinetics and crystallographic character of carbon sources. In order to accomplish this goal, a range of different materials representing a spectrum of carbon sources have been chosen for the investigation. These materials include brown coal char, two types of Auscarb (A and B), and commercial graphite. Auscarb is prepared by calcining Auscoal at 1000°C. Auscoal is made from chemically cleaned Australian coals (Bowling, Chandler and Waugh, 1990). Part 1 of this paper details the dissolution performance of the materials studied, while Part 11 describes the X-ray diffraction study. The relationship between the atomic structural dimension and dissolution rate constant is discussed in light of the results obtained.

Jan 1, 1996

The Olympic Dam copper-uranium-gold-silver deposit, located approximately 520 km north-northwest of Adelaide, South Australia (Figure 1) was discovered in 1975 by Western Mining Corporation. A joint venture to facilitate development of the deposit was formed in mid-1979 between WMC (51 per cent) and the British Petroleum Group (BP, 49 per cent). Production commenced in 1988, and current annual output from the mining and treatment of 2.2 Mt of ore is approximately 65 000 t of refined copper and 1400 t of uranium oxide. Significant amounts of refined gold and silver are also produced.

Jan 1, 1993

By Palmer DJ, Bain JH, Pullen JB

Over the last ten years at Risdon, zinc production capacity has almost doubled. This has resulted in modifications, many of which have affected zinc deposition operating conditions in the cells. Some of these changes appeared to have affected average current efficiency to such an extent that a special investigation was initiated, using multiple regression analysis to assess historic cell unit operating para- meters. The study highlighted the importance of certain parameters in maintaining maximum current efficiency for zinc deposition from !Risdon purified solutions under conditions of !changing current density, acidity and zinc con- centrations. Maximum current efficiency was obtained only within a zinc to acid ratio in cell electrolyte of 0.45 - 0.55 and a residual zinc concentration greater than 48 g.1-1, irrespective of actual zinc concentration or The investigation also established: ieters giving minimum power consumption at termined current density; the effect of ntration changes in common impurities on nt efficiency; the existence of high s of some impurities in solids precipit- in the cells and pure solution tanks.

Jan 1, 1975

By Tilyard P. A

Recent exploration has established depos its of nickel sulphide in several areas of Western Australia. To assist in their develop- ment Amdel has investigated the beneficiation of many samples from these deposits and has estab- lished flowsheets for the recovery of nickel values by flotation. Metallurgical data are presented for the samples according to four factors which were encountered in their respective treatments.

Jan 1, 1973

By J C. Furness, F S. Cannon

Metal casting operations are a significant source of hazardous air pollutants. In particular, high production iron foundries emit significant quantities of volatile organic compounds (VOCs) during pouring, cooling and shakeout of iron castings made in green sand molds. End-of-the-pipeline capture and destruction methods to reduce VOC emissions add crippling costs to foundries. Alternately, the incorporation of advanced oxidants (AO) into metal casting green sand systems has been shown to reduce emissions from high production iron foundries in the US, and at the same time reduce operating costs. Cost savings are driven by the benefits of AO in clay recovery systems. Emissions reductions are the direct result of cascading AO-based reactions taking place in green sand molds. This sustainable greening of the metal casting process is a prototype for the development of other AO and non-AO process-based solutions for sustainable high temperature processing of materials. Fundamentals of AO technologies will be discussed along with the performance characteristics of AO processing systems in the metal casting industry and the breadth of other processing and remediation applications for which AO technologies have the potential to be successfully employed.

Jan 1, 2002

A report is given of the problems of finance and physical resources that currently affect The University of New South Wales, and of some of the measures adopted to alleviate them. Partly as' a result of review procedures, a School of Mines was formed to amalgamate Applied Geology and Mining Engineering, and to add the skills of extractive metallurgy to produce a group to match the needs of the minerals industry. A review of courses within the School indicated a need for enhanced computer teaching, which is partially negated by a lack of resources. It also shows an overcrowded course whose structure could possibly benefit from a split into managerial and specialist streams.

Jan 1, 1986

Modern mining and coal cleaning techniques lead to the generation of large quantities of fines which give rise to problems in their storage, handling, transportation and further processing. Pelletisation, a method of particle agglomeration, can alleviate such problems. This paper provides a brief overview of the principles of pelletisation and a survey of the coal pelletisation literature. Then it reports results from an experimental investigation of the effect of surface active reagents on coal pelletisation. Finally the paper is concluded with a few remarks on applying the results from the experimental study to practical coal agglomeration.

Jan 1, 2000

By Mowat BA, Leach TM

The Morobe Goldfield in Papua New Guinea has produced in excess of 120 tonnes of gold from predominantly alluvial sources. Hardrock gold has been mined historically at Wau (23t) and Edie Creek (40 and geological resources have been established at Hidden Valley (780, Kerimenge (360 and Hamata (30t). Numerous prospects have also been identified within the goldfield. Primary gold mineralisation is related to intrusion of dacitic to andesitic Edie Porphyry (2.4 to 3.8 Ma), often with associated diatremes, which have intruded along major regional structures. A full spectrum of deposit styles from proximal (mesothermal) to distal (epithermal) to the porphyry source is recognised. The transition between the proximal and distal styles is recognised both between deposits and within an individual deposit. The deposit styles should be termed porphyry related gold mineralisation rather than given the generic epithermal and mesothermal labels.

Jan 1, 1995

Utah's Blackwater mine began operations in 1967. The four CQCA mines controlled by Utah followed over the period 1971 to 1979. Project feasibility studies for all these were based on open cut mining to overburden depths of 60 metres, with typical project lives of 12 to 16 years, depending on reserves Further studies, initiated after the mines had started, showed that continuation of open cut mining beyond the 60 metre highwall was viable. In 1973, the Deep Stripping Project (DSP) was launched to define the scope for stripping deeper, to determine what the additional equipment needs might be, and to pu forward proposals for a full scale trial system. The project commenced at grass roots with a literature survey, proceeded through a sequence of equipment evaluation, specification, design and manufacture to the commissioning of the Goonyella BWE system. Studies are continuing to assess the future deep stripping requirements for all Utah's Bowen Basin mines.

Jan 1, 1983

Any engineering firm hoping to do business in the modern world must understand-and take into account-the social and economic realities of client, country, culture, and community. If these considerations are ignored, any large-scale international development project is doomed to failure even before it begins. In this changing world, the distinctions between `developed', `developing', and `less developed' nations are more and more blurred. The so-called `less-developed' and `developing' nations are rapidly acquiring technology, an educated man- agerial and technical class, manufacturing capa- bilities, a growing spectrum of developed financial and raw materials resources, and a broad range of labour skills. These nations are establishing themselves as an integral part of the modern world, on an equal footing with other nations and with justifiable expectations for an ever higher standard of living and an ever better quality of Life.

Jan 1, 1978

In presenting size analysis data, one has the choice of various graphical techniques; each no doubt has been developed to highlight a particular aspect of the data. A frequency size distribution plot is used quite extensively to illustrate the importance of the finer size particles in iron ore granulation. However, the basis for such a plot is often not appreciated. As a result, cases of incorrect use can be cited. The aim of this paper is to extend the work of Alien (1981) and to provide, using examples and figures, a basic understanding of the implications of the various size distributions. A simplified method of presenting sizing data on a linear scale graph paper is presented and recommended. This involves a simple construction of a histogram of mass fraction versus particle size (in geometric progression).

Jan 1, 1992

By Setterfield TN, Jones GFP, Tua P, Davis B, Antonio M

The Emperor gold deposit occurs on the western margin of a 5 Ma caldera in a large, mafic shoshonitic shield volcano on the island of Viti Levu, Fiji. Products from two major pulses of post-caldera intermediate volcanism filled the caldera. Caldera collapse-related steep and flat faults and zones of shattered rock provided per- meable conduits for vertical and lateral fluid migration and favourable sites for ore deposition. One large hydrothermal system, operating concurr- ently with extrusion of the second pulse of resurgent volcanism, may have produced porphyry- style alteration within the caldera, epithermal mineralization at Vatukoula, and weakly minera- lized, siliceous veins and breccias in an outflow zone northeast of Vatukoula.

Jan 1, 1987

By Gorken A, Mular M, Stewart A

PT Freeport Indonesia operates one of the largest copper and gold concentrator complexes in the world. Flotation is used to produce a single copper-gold concentrate. In 1995, PT Freeport Indonesia and Cytec Industries Inc established a joint p

Jan 1, 1997

Shortly after the outbreak of war in September, 1939, it became apparent that considerable quantities of certain metals and alloys which at that time were not being produced in Australia would be required in increasing amounts for the prosecution of the war effort.Australian industry had relied on overseas sources of supply for the relatively small quantities of many special metals which were needed under peacetime conditions. As the war progressed so great became the demand for mooy of these alloys in Great Britain and other allied countries that it was necessary for them to place an embargo on the export of these materials, and thus it soon became evident that if Australia's production of munitions was to expand and develop it would be necessary for her to become independent of overseas sources for many of these essential 'items. The shipping position also became very acute, and this, accentuated the difficulties of obtaining these alloys. Because of the conditions outlined aqove, the manufacture of over thirty different metals and alloys .was undertaken at Newcastle during the past decade. It is with two of these that this paper proposes to deal. They are tungsten powder and ferro-silicon.TUNGSTEN POWDERTungsten is a rare and comparatively new metal. It is used extensively in the production of high speed tool steel, some grades of which contain up to 22% tungsten. Such articles as twist drills, reamers, milling cutters, and lathe tools are made from tool steel, and the demand for these during the war years was greater than ever before. The use of tungsten in the manufacture of high speed steel was first developed in 1914 by the Germans, and when it was discovered that they were using tungsten bearing steel for the production of munitions there began a world-wide search for ores of this rare metal.

Jan 1, 1947

By Guarascio M, Massacci P

In process simulation, more reliable prediction of industrial results and evaluation of data for design purposes and process optimisation may be attained by the combined use of: the modelling and simulation of ore characteristics, and 2. the modelling and simulation of the process. It is well known that geostatistical methods allow the defining of models of orebodies in which the variables considered are the grades of the valuable components. These models are proper for reserve estimation, geostatistical contouring, design and simulation of the exploitation method, and, in addition, for evaluating the variability of the ROM which is expected to be fed to the processing plant. However, no data are normally incorporated in the orebody model in order to evaluate the ore characteristics relevant for a reliable process simulation. The procedure for process simulation aimed at predicting plant results normally used so far consists in collecting samples from different orebody sites and building up a so-called 'representative sample'. On this sample, the ore characteristics (eg liberation, washability, grindability, etc) and the processing tests are referred to as the 'average behaviour in the orebody', assumed constant. A more reliable methodology consists in collecting samples from different orebody sites, in performing tests to characterise the samples from the point of view of the process (ore patterns), and in using synthetic parameters (process features). The values of the parameters are processed using geostatistical methods in order to develop a model for simulating the feed to the process. The estimation may thus be referred to the amount of recoverable minerals instead of to the existing minerals. Furthermore, the selection of the processes, the sizing of equipment and the design of control devices, as well as the prediction of results, become more accurate and reliable.

Jan 1, 1993

By M Mee, R L. Gwyther

Accurate measurement of rock mass response during the mining of massive underground orebodies is essential, as mines become larger and deeper. These measurements enable: provision of quantitative data for optimal pit slope design and engineering; monitoring of the stability of deep pit slopes, the long-term integrity of shafts and large-scale underground infrastructure, and long-term measurements of deformation or rock mass creep following the mining process for environmental management. Strainmeters traditionally used for deformation measurement have neither the long-term stability nor the high sensitivity to perform measurements in these applications. This paper describes a new precision borehole strain monitoring system (GTS) currently deployed by CSIRO Exploration and Mining, which has the potential to solve these new issues in rock mass deformation monitoring. This technology was originally developed for use in hard rock mines (Gladwin, 1977) and refined considerably for earthquake research (Gladwin et al, 1994; Gwyther et al, 1992). A case study of the use of the GTS in monitoring longwall coal mining over the period 1993 - 1998 is presented.

Jan 1, 2000

Commercial explosives range from pure emulsions to pure ANFO, with blends of these providing interesting alternatives: energy is often adjusted through addition of aluminium, or the control of density. The energy rating of explosives is derived chiefly from detonation codes, which are used to derive expressions for the internal energy change of the detonation products as they do work under expansion. While all codes used for this purpose work on the basis of Ideal detonation, it is common knowledge that commercial explosives operate in the Non-Ideal domain, which affects the mode of energy delivery to the environment. However, since Ideality represents the foundation from which actual performance evolves, it is valuable to examine the intrinsic energy release of a formulation before attempting to understand the influence of Non-Ideality. In examining the Ideal pressure profile of fundamental formulations, remarkable correlation has been found with field performance, and this increases understanding of the influence of various formulation modifications, especially in regard to the stage at which energy is released, and the effect on rockbreaking. This work has emphasised the value of attempting to understand and define better the non-ideal detonation process.

Jan 1, 2001

By S Kodate, Ö Aydan, Y Suda, J Tomiyama

Fracture zones are commonly found in the Earth’s crust. These zones may cause very severe engineering problems. Therefore, the formation and the assessment of the mechanical characteristics of these zones is of great concern for rock engineers. A new double shearing jig was used to study the formation of shear zones in rock under static and impact loading conditions using the device developed by the authors. A series of experiments were undertaken to investigate formation on the formation and characteristics of fracture zones in laboratory. Although actual fracture zones are more complicated, various tests give some insight view of the formation of fracture zones as well as some information on their mechanical behaviour under both dynamic conditions and static conditions. The authors report the outcomes of these experiments and discuss their implications in practice.

Nov 29, 2022

The efficiency with which it is expected that a particular coal may be burnt in a power station boiler significantly affects the value of the coal. Consequently many laboratory tests have been developed to provide data on the combustibility of coal. Computer modelling of coal combustion has also provided insight into limits on coal burn- out. Such modelling suggests that burnout of bituminous coal in a power station boiler will be strongly influenced by physical limits on the diffusion of oxygen to the individual coal particles. Coal chemical reactivity appears to be relatively less important. As a consequence of the diffusional limits, significant improvement in burnout is achieved either by producing less large p.f. particles or by providing sufficient furnace residence time to burn the large particles. Field data from a variety of power stations supports these cn.clusions. Burnout was also found to correlate well with volatile content for a number of coals from widely different sources. This is expected as the high vola- tile coals produce less residual char to be burned by the relatively slow heterogeneous Combustion.

Jan 1, 1987

By Chapman RL

A new process has been developed to remove the impurities copper, cadmium, cobalt and nickel from a zinc plant electrolyte by cementation on zinc dust. The process has been tested in the laboratory and in a continuously operated pilot plant. It has been found that cadmium, in the presence of small amounts of antimony in solution, assists the removal of cobalt. Cementation is conducted in two stages: the first stage for removal of copper with a small excess of zinc dust to produce a relatively high grade product, the second stage for removal of cadmium, cobalt and nickel by addition of zinc dust in the presence of anti- mony. The excess zinc and the cadmium present in the second stage cementate can be selective- ly recovered by slow leaching in spent electrolyte. Zinc dust processes in use elsewhere are described and compared with the present system for use in the Risdon circuit.

Jan 1, 1984