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By Afshin Sadri

One of the main reasons for blast furnace reline is the loss of refractory lining, particularly in the hearth and taphole regions. Intense operation of the blast furnace can result in extensive refractory wear and deterioration. This can then affect the continuity of the operation and the furnace campaign life. Novo-Lipetsk (NLMK) and Hatch developed a systematic approach to monitor the condition of blast furnace hearth linings using Acousto Ultrasonic-Echo (AU-E), a non-destructive testing system developed by Hatch. Continuous and periodic inspections of blast furnaces revealed areas with accelerated refractory deterioration, formation of elephant foot, extent and speed of refractory wear, as well as cracks and other anomalies. Improvement in coke quality, stave washing, the addition of titania, and other changes were recommended and implemented to prolong furnace life while maintaining the intensity of furnace operation. This paper demonstrates how the coordinated efforts between NLMK and Hatch resulted in prolonging the blast furnace campaign life.

Aug 17, 2017

By Andressa Alves da Silva

Nowadays, population growth and the interest of food industry, makes the research and applications of biodegradable polymers increase, because under favorable conditions its degradations may occur within weeks or in a few months, reducing the environmental impact. This work presents the processing and characterization of flexible films by the incorporation of 3 % (% wt) of modified bentonite light green clay in the Copolyester/PLA biodegradable blend. The clay incorporation was carried out by melt-mixing processing, using a twin screw extruder machine. The films were obtained by cast extrusion tape. The films obtained were submitted to tensile tests, SEM and XRD analysis, and the correlation between their properties was discussed. The XRD results of clay showed that the quaternary salt and sodium carbonate addition increased the interlayer distance of clay making it easier to intercalation of blend in the nanoclay. The XRD results of PBAT/PLA/Clay nanocomposite show no characteristic organoclay peaks. This result suggests intercalation between nanoclay and matrix (blend). The tensile test results showed an increase of around 30% in tensile strength at break of nanocomposite film when compared with blend film.

Aug 8, 2018

By Breno Totti Maia

In the present paper, a new energy balance equation was developed, considering the slag phase, in order to define the effects of jet penetration and determine a new value for the factor K. The factor K measure the resistance to momentum transference between exit nozzle and metallic bath. The experiments were performed based on the same conditions of the article used as a comparison. The results showed the same behavior between the experiments and it was possible to determine a new value for the factor K, which changed from the unit order for the metal phase system to hundredths order for the metal and slag phase systems. These results are considered unprecedented.

Aug 17, 2017

By Patrick Tassot

Increased worldwide highly competition in steel market imposes innovative measure for the steelmaker targeting cost reduction and climate-friendly steelmaking process in order to have the ability to withstand the pressure of the market. At the same time the demand for high purity and highest quality steels continues to grow from year to year, especially in the sector automotive in transportation of oil and gas, in the construction Industry and in the manufacture of heavy plate. As they allow producers to be up to the requirements while allowing expanding their product mix, new secondary metallurgical treatments have become a must additionally to standard equipment elements of steel plants modern. Most of these treatments occurs in the steel ladle increasing the pressure to ensure a reliable and as possible neutral reactor. Intelligent solutions for refractory lining ladles should integrate better adaptation to the operational process parameters and the high reliability/availability at the best cost/performance. This challenge has conducted Refratechnik to develop new concepts to overcome the frontier between shaped and unshaped materials and that’s what will be covered in this paper.

Aug 17, 2017

By Ronaldo Santos Sampaio

This paper call attention to increasing ratio of oxygen depletion from atmosphere besides the global worries about CO2 concentration increase in the atmosphere. It highlights the big mistake in considering Carbon Capture and Storage, CCS, as a way to reduce the increasing concentration of CO2 in the atmosphere. As a hypothetical example it presents an existing pseudo-ecosystem of manufacturing that has real windows of opportunity to increase its share in the global materials production industry, even in highly industrialized countries. As a suggestion and example the author point out possibilities to almost fulfill the proposed simple rules to be considered inside an ecosystem of manufacturing utilizing the production of steel via biomass versus fossil coal. A relevant and difficult rule to be attained in a quasi-ecosystem of manufacture is to be a near zero atmosphere oxygen depletion integrated process. The industrial alternatives that utilizes the actual photosynthesis are the ones that can reach a higher ecosystem of manufacture’s index. It is presented an ideal integrated steelmaking process where the gaseous, liquids and solid residues generated in one part of the system are or can be utilized in the other parts of the same system. A potential ecosystem of manufacture to produce primary iron is illustrated in the paper.

Aug 17, 2017

By Henrique Silva Furtado

This paper presents the results obtained on the exchange of an original old blow charge model for a new up-to-date state of art global model, employing optimization techniques and process modelling, and, the results obtained in terms of fluxes consumption reduction and the introduction of user friendly tools and practices.

Aug 17, 2017

By Douglas Glenn Stalheim

Production of structural hot strip coils in yield strengths up to 700 MPa and higher is increasing worldwide. In addition to requiring higher strengths, structural designs require good formability, toughness and weldability. Toughness and formability come from optimization of ductility properties while weldability comes from lower carbon equivalent alloy designs. The key to the production of optimized cost effective hot strip produced structural coils is to create the correct balance of a proper alloy/processing design to create as fine and uniformly distributed cross sectional grain size as possible. In addition to the creation of the fine/uniformly distributed cross sectional grain size, the correct microstructure needs to be created. In the higher yield strength grades, not only does the grain size/distribution play a role but a proper understanding and control of microalloying precipitation kinetics is required. This paper will present various examples of hot strip alloy designs to produce cost effective hot strip structural coil in yield strengths up to 700 MPa with good ductility and weldability. In addition, steelmaking/casting parameters will be discussed to assure successful production. Optimized reheating, rolling and cooling parameters of these alloy designs will be introduced in an accompanying paper.

Aug 17, 2017

By Nishit Patel

Development work on the use of plasma torches in blast furnace ironmaking was completed in the 1980s. The technology developers planned to reduce blast furnace coke consumption using electrical energy and large scale coal injection through the tuyeres. Since this time, Westinghouse Plasma Corporation has improved torch reliability with industrial experience in solid-waste-to-energy facilities, as well as metallurgical applications. As coke makes up one-third of the hot metal cost, savings efforts frequently seek to lower coke consumption by increasing process efficiency or replacing coke with cheaper fuels. Alter NRG and Hatch assessed the merits of using plasma torch technology to superheat the hot blast. Coke rate savings, electrical purchase requirements, and a financial analysis to implement the torches are presented.

Aug 17, 2017

By Mário César Mantovani

The steel for gas turbine compressor discs (26NiCrMoV14.5) requires some mechanical properties like strength, impact, toughness, fatigue, and creep resistance in order to be used in such application. To achieve the properties required for the gas turbine compressor discs, the material should have very low contents of sulfur, phosphorus, antimony, tin and arsenic. The level of cleanliness should also be very high and this is possible by achieving low oxygen content keeping the deoxidation elements like silicon, manganese and even the aluminum in very low percentages. The main problem in refining such steel is to adjust a sufficiently low oxygen content to have a good desulfurization and at same time a good cleanliness without using silicon, manganese or aluminum as deoxidizers. Combination of initial selection material, steelmaking process control, forging sequence and heat treatment cycles can provide uniform mechanical properties throughout the gas turbine compressor discs. Villares Metals SA as a big player on special steels with complex process has been developing this kind of material for several years. The objective of this work is to show the process technology evolution involved in the production of this kind of steel under the discussed preconditions.

Aug 17, 2017

By Wagner Viana Bielefeldt, Felipe Buboltz Ferreira, Antônio Cezar Faria Vilela

The continuous casting machine is one of the most important steel production steps in a melt shop. The tundish, a reservoir between the steelmaking ladle and the mold, has great influence over the steel cleanliness, along with the productivity bid. It must takes into account the quality of the metal and operational safety. Several different variables are related to the tundish process, of inclusionary cleanliness. Some of them are discussed in this paper: the free opening of ladle, tundish inertization, steel temperature in the reservoir and clogging formation, besides a brief topic about castability. Therefore, a critical analysis, with a review from some papers available in literature, is proposed in this study, with its focus on tundish.

Oct 1, 2019

By Ryoma Fujiyoshi

In this article, the technologies of highly durable MgO-C bricks for the scrap impact zone and bottom blowing tuyere of converters are demonstrated. On the bases of our recent investigations, wear of scrap impact zone and bottom tuyere are explainable in terms of crack initiation and propagation. Theoretically, crack propagation in brittle material is regarded as generation of new crack surface area. It occurs when the elastic strain energy stored in the material exceeds the energy required to generate a new crack surface area. Since the overall energy consumed for crack propagation until fracture is evaluated by fracture energy, materials exhibiting high fracture energy can be regarded as materials with high fracture resistance. Therefore, two fracture energy-improving technologies for MgO-C bricks were developed. One is matrix reinforcement and the other is carbon bond enhancement. These technologies were applied to bricks for the scrap impact zone and bottom tuyere. As a result of commercial applications, notable decreases in wear rates were recognized for high fracture energy materials for the scrap impact zone and bottom blowing tuyere of converters.

Oct 30, 2017

By Maciej Korecki

Pyrowear®Alloy 53 steel is an excellent material for the construction of drive transmission components (gears, shafts, etc.) which have to operate in difficult conditions primarily in the aviation industry (Fig. 1.). Among the properties of such items is a high case hardness and abrasion-resistance, while the core remains flexible and is capable of carrying large impact loads. They can work at elevated temperatures with limited lubrication. The thermal treatment of such materials is based on case hardening by means of carburizing. This paper presents the technology of vacuum carburizing of Pyrowear® Alloy 53 steel. It discusses the methods of establishing different profiles of carbon concentration in a layer and their influence on the hardness profile. The effects of sub-zero treatment and tempering on the properties of the hardened case are also considered. It also presents a SimVaC® simulator of vacuum carburizing, designed especially for Pyrowear® Alloy 53 steel, which provides highly accurate predictions of the outcome of the process as the profile of carbon concentration in the layer, or vice versa: establishes the process parameters which will guarantee the required profile.

Aug 16, 2017

By Adrian Villanueva

In this study, we compare the influence of two water soluble polymer-based organic binders added to bentonite, to form a hybrid-binder system for Iron Ore Pelletization. The kinetics of the agglomeration process and resulting properties of green pellets were analyzed, and examined in detail through Scanning Electron Microscopy (SEM) and Confocal Laser Scanning Microscopy (CLSM) analytical techniques. It was encountered that the differences in the mechanical properties of the pellets produced by each binder system could potentially be explained by the ability of the polymer to interact with bentonite at a macromolecular level.

Oct 30, 2017

By Aline Lima da Silva

The present work is focused on the thermodynamic study of the methane or biogas mixtures conversion on Cu-ceria catalysts. Several experimental studies reported in literature have demonstrated the ability of these materials to operate as SOFC anodes for direct methane oxidation, with the evidence of enhanced tolerance towards sulfur poisoning and carbon deposition. More recently, experimental investigations have shown the feasibility of Cu-ceria anodes to directly operate with simulated biogas feeds at intermediate temperature (1023K). In this way, the effect of the ceria redox properties on the equilibrium composition is investigated, considering methane or biogas mixtures as the fuel. Conditions under which carbon deposition and sulfur poisoning can be prevented are determined. Our study combines results from the classical thermodynamics, obtained with the help of FactSage software, with the new Cu-S and Ni-S diagrams proposed in literature, which were calculated based on the Density Functional Theory (DFT). These diagrams are able to predict a region where sulfur interacts with the metal surface through chemisorption. A comparison between the performances of Ni-YSZ and Cu-CeO2 catalysts is established from a thermodynamic viewpoint. Theoretical results are in agreement with the experimental trends from literature.

Aug 8, 2018

By Flavia de Paula Vitoretti

Pelletizing of iron ore fines is an important process used to produce high quality of raw materials for the subsequent reduction processes in the ironmaking industries. The process involves the production of green pellets and subsequent induration on a traveling grate furnace to promote inner partial melt and agglomeration which confer physical and metallurgical proprieties appropriated to the subsequent reduction processes. The pellets are produced with addition of charcoal to improve efficiency in the reduction processes. The lignin coal from sugarcane straw is an alternative source to replace the charcoal or coke in the self reduction of pellets. This work focused on the influence of biomass on the chemical kinetics parameters inner agglomerate pellet structure under industrial process conditions of the travelling grate furnace due hot gas flows within the pellets.

Aug 1, 2018

By Raúl Daniel López

Ternium-Siderar steelmaking has been focused in permanent improvements and process optimization. At present the Slab Continuous Caster N°1 has been totally transformed after 20 years of uninterrupted work. The authors of this paper summarize and comment on aspects which were the main changes and place emphasis largely on those technological developments in which they have been active during that period. Productivity and quality have been our goals during the last 20 years; it has led us to improve process and to achieve better control tools. In the development of this presentation, the authors will put special emphasis on the explanation of those works that were made following their own experiences through the technical personnel who belong to the staff of the company.

Jul 30, 2018

By Samuel Filgueiras Rodrigues

An austenitic stainless steel ISO 5832-9 was deformed in a torsion test machine over the temperature range of 1,000°C – 1,200°C and strain rates of 0.05, 0.1, 1.0 and 5.0s-1. The Steel plastic behavior was studied by analyzing the flow curves shapes and using the constitutive equations under the conditions of thermomechanical treatment. The curves initially presented an increase in stress characterized by hardening work, followed by a drop in stress to an intermediate level that reached or not, for certain conditions, the steady state softening. The plastic flow curves of ISO 5832-9 steel displayed in three different ways: (i) Curves with continuous softening presenting plastic instability for low temperatures and high strain rates; (ii) curves type flat, here after the peak there is little variation of stress with strain presenting softening mechanism by higher contribution of dynamic recovery at low temperatures and low and intermediate strain rates; (iii) curves with softening after the critical deformation favored by high temperatures and low strain rates. These behaviors indicate the influence of the stacking fault energy (SFE) and precipitated particles on the softening kinetics of this steel.

Aug 8, 2018

By Andreas Volkert

Energy efficiency, equipment reliability and cost reduction are of the key factors in any efficient plant. Badische Stahlwerke (BSW) started using its own burner technology in 2001, this was developed by Badische Stahl-Engineering (BSE). Over the past 15 years, Badische improved all aspects of its Virtual Lance Burner (VLB), to perfectly fit all steelmaking requirements. This tiltable VLB was first tested at BSW’s electric arc furnace no. 2 in 2012. Promising results like reduction of refractory wear, energy efficiency, reliability, etc., were obtained. At the same time the existing VLB system was further improved with regards to the design of the water-cooled copper box. Today in 2016 both EAFs at BSW are equipped with the new patented tiltable system and the new copper box design. The paper will describe the results of the past years at Badische, but will also show the performance at other installations.

Aug 17, 2017

By Christiano Gianesi Bastos Andrade

Clays with high content of smectite are denominated bentonites, and are widely used in industry as, for example, agents for bleaching of vegetable oils, animals and minerals. For this use, the smectite clays are treated with inorganic acid of high concentration at temperatures under boiling point, which provide the bentonite´s bleaching power. In the present study, a sample of smectite from Cubati, Paraiba, Brazil, was submitted to treatment under moderate conditions (90°C, reaction times of 1, 6, 12, 18 and 24hours in close reactor, concentration of the aqueous solution of hydrochloric acid 1.5 M, acid solution/clay ratio of 1g/10mL), aiming to reduce impurities, responsible for the color of the clay, without causing significant changes in their structure. Thus, clay can be used in the cosmetics industry and other products with high added value. The treated clay was characterized by scanning electron microscopy (SEM), stereomicroscopy, energy dispersive X-ray detector (EDS) and X-ray diffraction (XRD). It was observed a bleaching in samples with time of 12h to 18h. With the DRX was possible to monitor the peak intensity of the clay structure and the sample with 12 hours of treatment was not significantly altered its crystalline structure, maintaining the peak clay at d001. The most pronounced changes in the bleaching occurred within the first 12 hours of acid treatment.

Aug 8, 2018

By Milan Terčelj, Matej Drobne, Urška Klančnik, Peter Fajfar

The study of oxidation behavior of High Chromium Steel material used for surface layer of work rolls was carried out. Specimens taken directly from the roll were subjected to thermal fatigue in the temperature range between room temperature and 500 °C up to 700 °C by using thermo-mechanical simulator Gleeble 1500D. Our observation was focused on the impact of oxidation as a principal mechanism of degradation of the roll’s surface layer - mainly on the characteristics of oxidation propagation in relation to the test temperature and microstructure constituents characteristics of the material. Oxidation is considerably accelerated by certain characteristics of eutectic and primary carbides, i.e. their size (area), composition, morphology, orientation regarding to the water-cooled surface, etc. In the presented paper selected cases where emphasized oxidation takes place are investigated, analyzed and explained. Obtained results thus represent a contribution to explanation of conditions which lead to acceleration of oxidation behavior that in turn can lead to chipping or even early spalling of material from the roll surface layer.

Oct 1, 2019