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By A. W. Schlechten, W. J. Kroll

As this paper is written, the only method for the commercial production of lithium metal is by the fusion electrolysis of LiC1-KC1 mixtures, as first proposed by Gunkz.2 The details of the industrial process have not been made public hut Osborg8 stated that an efficiency of more than 90 pct is obtained with a lithium metal recovery above 95 pct and that the metal is 99.5 pct pure. Pletenev9 gave a power consumption of 66 kw-hr per kilogram of lithium metal produced with a salt consumption of 9 kg of LiCl and 0.4 kg of KCI. Pletenev's figures indicate a somewhat lower recovery than that given by Osborg. In a recent report on' German lithium plants, Motock7 gives figures that are also less favorable than those reported by Osborg. At the German plants the lithium recovery in electrolysis was only 83.4 pct, with a power consumption of 140 kw-hr per kilogram of lithium. The metal averaged only 97 pct pure, with sodium and potassium as the chief impurities. The presence of SO2, SO3, SiO2, Ba, Ca, and appreciable amounts of Na and Fe2O3 were especially disturbing in the electrolysis, and it was necessary to run the cell for some time to eliminate most of these impurities and condition the bath. It may be noted here that most of these impurities do not interfere with a thermal reduction process. These facts show that the present method of producing lithium is fairly efficient and would suggest that other methods could not compete. However, fusion electrolysis has certain drawbacks, such as the necessity of supplying costly, low-voltage direct current and of collecting and processing the anodic chlorine if it is not to be wasted. An even greater disadvantage is that lithium chloride must be used for an electrolyte. It is one of the most expensive salts of lithium, since it cannot be produced in anhydrous form by precipitation from aqueous solution, as is done with LiF or Li2CO3. The reduction of lithium by a vacuum process similar to the ferrosilicon method for the production of magnesium would have certain advantages. Small units such as Pidgeon retorts, would give flexibility of production to meet demand, and a small plant would require moderate capital outlay. There is a possibility of using idle Government-owned magnesium plants for such purposes. The raw materials needed for vacuum thermal reduction would not have to be extremely pure, Director, with respect to the iron and calcium Content. This paper describes a series of experiments to determine the effectiveness of various agents for the reduction of lithium compounds. The investigation is part of a program of vacuum metallurgy con-

Jan 1, 1949

By D. Brady

When deciding to deploy rescue teams underground the decision makers need to be able to determine that there won?t be an explosion whilst the rescue teams are underground. Previously general body concentrations in areas likely to be travelled were compared to explosive limits on a one off basis with no formal process looking at trends or other areas. A new approach is being adopted that takes into account the rate of change of gas concentrations with triggers set to enable a withdrawal of personnel prior to a possible explosion and influences such a barometric pressure changes. This paper explains the rationale behind the changes made and the advantages and implications of adopting such an approach.

Jan 1, 2012

By Deshmukh A. M.

Existence of human beings and their relationship with the nature is symbiotic. The lack of perspective and negligence of nature disturbs the equilibrium of environment and causes unprecedented disasters. Geotechnical engineers are directly concerned with hazards of nature as elements of foundation and of nature are inter related. Rational design and construction of foundation can be accomplished only after properly assessing influence of environment This paper briefly delineates impacts of environment and human activities and presents salient features of management of impacts through the system of deep foundation. Limitation of negative effects and enhancement of positive developments necessitates eco-consistent planning of engineering projects based on the geotechnical aspects of environmental impact management.

Jan 1, 1996

By Irvin G. Burough

Andros Analyzers Incorporated has designed and built two prototype continuous methane monitors capable of being mounted on a mining machine'. These instruments were designed for in-mine safety use. The monitors incorporated an NDIR optical/electronic analyzer design in which the response to the sample gas (methane in air) was achieved by synchronous detection and measurement of the amplitude oscillations of the trasmitted energy from an infrared source caused by the pressure modulation of the sample gas within the optical cell. Zero and span stability were to be achieved by the amplitude modulating of the infra-red source and using detected signal to correct for optical/electronic system variation. This design effort was to simplify and reduce the cost of the major components while eliminating the need for daily calibration. This report is the final report on this effort.

Jan 1, 1981

By M. Suzuki, T. Shiomi, M. Nakada, K. Tsutsumi

Mold powder plays an important role in the continuous casting process for high quality steel production. It is well known that mold powder entrapment causes surface defects in steel sheet and the high viscosity of mold powder prevents the entrapment of mold powder in molten steel in ultra low carbon steel. This paper deals with the entrapment of mold powder caused by suction by Karman?s vortex in a laboratory experiment. At first the effect of the viscosity of oil and interfacial tension between water and oil was investigated in a water model experiment. Then hot model experiments were carried out by mold powder and molten steel. The amount of mold powder entrapment was affected by the viscosity and the interfacial tension between molten steel and mold powder. As a result, the following equation of the mold powder entrapment was obtained. m=1.06*107?-0.255?m-s-2.18 The amount of mold powder entrapment decreased when the viscosity and interfacial tension increased. But the effect of viscosity was larger than that of interfacial tension in the case of the industrial mold powder when the viscosity was under 0.5 Pa.s, interfacial tension was from 1200to 1300 mN/m.

Jan 1, 2004

By B. Krysa, J. Qiu

The zinc pressure leach plant at HBM&S's operations is now in its fifteenth year of operation. Current pressure leach operation is steady at a concentrate processing rate of around 26.5 tonnes per hour. A new cellhouse with a design capacity of 124,000 tonnes per annum and the capability of expansion of up to 154,000 tonnes per annum was commissioned in July 2001. The potential to expand the capacity of the pressure leach circuit and associated processes, as well as the purification circuit and casting plant, to meet the maximum capacity of the cellhouse has been investigated. This paper reviews current operation of the zinc plant, as well as the possibility of a capacity increase without major process modifications or major capital expenditures.

Jan 1, 2008

[Module 10. Internally Cued Operating Contingencies Prerequisite: Modules 1-7 - Estimated Instructional Time: 2.42 hrs. Module Abstract Trainees, using programmed instruction, describe the cues, consequences, operational sequences, and possible causes resulting from loss of air pressure from power fluctuations, and from a failure of the automatic lubrication system. Although some of the contingencies may be initially signaled by an alarm or from the oiler, each trainee will demonstrate proficiency in the appropriate operating techniques and procedures. This module also includes a review component for those trainees identified in the assessment exam as requiring less detailed instruction.]

Jan 1, 1976

By E. M. Spokes

Starting in 1980, a committee of the National Research Council studied the question of why some underground coal mines are safer than others and what could be done to improve the ones with poorer performance. The results indicated that safety is improved by management commitment to safety, by cooperation between labor and management on safety matters, and by quality training of employees and managers. Younger miners have higher accident frequencies, but are less likely to be killed or permanently disabled by a lost-time accident. Methods for improving safety performance are proposed.

Jan 1, 1987

This report is in fulfillment of Contract H0230031 awarded to Bituminous Coal Research, Inc., on May 23, 1973. The scope of work to be performed under this contract was divided into four phases: Phase I - Design, Phase II - Construction, Phase III - Field Demonstration, and Phase IV - Analysis and Final Report. During Phase I, an agreement was finalized with the Rochester and Pittsburgh Coal Co. for conducting field tests of the proposed shearer spray systems on a longwall panel in the company's Jane Mine in Indiana County, Pa. A drum was then designed which could be used on the Eickhoff shearer, Model EW170-L, being used on this longwall and which would utilize the following spray systems: 1. One spray nozzle located in front of each cutter bit with the jet directed at the cutting surface. 2. One spray nozzle located in back of each cutter bit with the jet directed at the back of the bit. 3. Standard Eickhoff nozzles located in a header along the drum scrolls. 4. A fixed header mounted on the shearer directly behind the drum to simulate the spray system originally used on the Eickhoff shearer.

Jan 1, 1976

By K. Wyper

"Gulf Minerals (Canada) Limited' s Rabbit Lake Uranium Operation is located in the northern portion of Saskatchewan, 198 miles southeast of Uranium City and 134 miles northwest of Lynn Lake Manitoba.This paper describes flow sheet changes to solve operating problems and briefly describes future changes to accommodate the new ""B"" Zone ore.The Rabbit Lake mill was designed to process 1600 dry tons per day of uranium ore, with an average grade of 0.370 percent u3o8. In 1981, the mill processed 2040 tons per day at a grade of 0.231 percent u3o8 . The process modifications and flow sheet changes that allowed this increase in tonnage will be discussed in relative chronological order. Mill feed was introduced on June 10, 1975, the original equipment consisted of an Ingersoll Rand hydraulic breaker mounted over a 24"" square grizzly. The - 24"" ore was fed to a 2011 X 6"" seflli autogenous grate discharge mill close circuited with 20"" cyclones, the mill discharge was screened on a tyler double deck screen with the undersize (8 rnesh) reporting to the cyclones, the screen oversize was returned by conveyor belt to the mill feed chute.The cyclone overflow (28 mesh) was thickened in a 100' diameter thickener to obtain 55 percent solids for the leach circuit.The leach circuit consisted of two slurry holding tanks and five leach tanks."

Jan 1, 1982

By G. W. Jones

One of the major activities of the Bureau of Mines is the promotion of safety in mining and other industries, In this connection, the Bureau determines the explosion hazards' of combustible gases, vapors, and solids and investigates means of controlling and preventing explosions. Many dangers are likely to confront men who must enter a building immediately after it has been damaged. Rescue workers must watch constantly for common gases and vapors that may be present in dangerous concentrations in and about demolished, buildings. Fuel gas is the most common source of danger, although refrigerants, gases from furnaces, flues, fires, sewers, and industrial processes, and gas from bomb, explosions in confined places also constitute definite hazards. To rescuers and trapped casualties, these gases offer the hazards of (1) explosion, (2) toxic effects, including asphyxiation and death, and (3) displacement of air so that the oxygen content of the atmosphere is reduced to or below the danger level.

Jan 1, 1944

Geophysical anomalies result from the passage of hydrothermal fluids through rocks. Interpretation of these anomalies, when integrated with available geological and geochemical data, assists the construction of a conceptual model of the original hydrology of the system. The original extent of a geothermal system is often indicated by the distribution of low resistivity argillic clay alteration. Quartz-adularia vein deposits, silica sinters or stockwork (often mineralised) cause local increases in resistivity. Appropriately chosen electrical techniques can therefore be used to help target such structures. Airborne magnetic surveys have also proven useful in New Zealand epithermal exploration, because hydrothermal fluids destroy magnetite causing extensive demagnetisation anomalies. Ground magnetic surveys can sometimes be useful for geological interpretation on a local scale. Positive gravity anomalies may occur as a result of mineral precipitation (silica or calcite) in high porosity host rocks, while negative gravity anomalies can result from hydrothermal fracturing and leaching of relatively dense host rocks. The relative merits of these geophysical techniques as used in the exploration of epithermal mineral prospects are discussed, with particular reference to the Hauraki Goldfield. The preferred method for defining zones of quartz veining/silicification is vector or tensor gradient resistivity. Exploration strategies and technique refinements are suggested as a means of improving the resolution of potentially mineralised target structures, in a more efficient and cost effective manner.

Jan 1, 1993

By M. Syamujulu

In 1994, Nkana smelter commissioned a multimillion US Dollar Chilean Teniente converter (CT) in its operations in order to improve its smelting technological base. The main objective was to reduce the overall smelting energy costs and increase the sulphur capture for sulphuric acid production to support the company?s leaching operations at Nchanga tailings leach plant. A decade of CT operations have since ensued following its installation and start-up. This paper provides a technical and operational audit of the performance of the CT in the first 10 years of its operations at Nkana smelter.

Jan 1, 2005

In 2004, a total of 741 nonmetal mining operations reported employment to the Mine Safety and Health Administration (MSHA). These mines (e.g., potash, gypsum, salt) comprised 5.1% of all operations.

Sep 1, 2007

With a price slowly rising above US$35 per ounce gold became a mineral worthy of prospecting and mining endeavour in the early to mid 1970s. Fortune therefore appeared to smile onNew Zealand with its favourable geological environment for gold and past record of major gold production from both hard rock and placer deposits. This was a particularly welcome development as the post war years, including both the base metal exploration boom of 1967/1971 (which produced major nickel, iron and bauxite mines in Australia) and the earlier period of uranium exploration failed to produce any mines in New Zealand with the exception of the small Tui Mine and iron sand mining. Whilst hard rock mining now appears imminent it is 15 years further along the track since the 1967/1971 exploration boom and eight years since the upsurge in prospecting for gold in 1978. New Zealand still has no hard rock base or precious metal mining. This is not for want of proven or potential gold mining situations for these clearly exist at Waihi, Monowai Reef, Golden Cross, MacRaes Flat and elsewhere.

Jan 1, 1986

By Jean-Louis Briaud

The following is a summary of a very recent report prepared at Texas A&M University for the National Cooperative Highway Research Program and entitled "Downdrag on Bitumen Coated Piles". Anytime the soil settles more than the pile, downdrag or negative skin friction will develop. The load in the pile increases with depth up to a certain point and then decreases down to the pile point. This phenomenon has been quoted as being the number one culprit for deep foundation failures. In Chapter 1, an introduction to downdrag is given. The most common criterion for downdrag is to consider it in design as soon as the settlement of the soil surface after pile driving exceeds 0.5 in. Coating piles with bitumen is an effective way of reducing downdrag forces and therefore allows to use smaller piles for the same load. This results in cost savings. Coating piles with bitumen increase the cost of piles by about 33% and therefore the decision to use bitumen is generally based on economic considerations.

Jan 1, 1989

By Emil B. Milosavljevic

Problems associated with distillation and other classical methods for analyzing operationally defined cyanide (CATC, WAD, Total and Free Cyanide) will be discussed. These methods often achieve incomplete, species dependent cyanide recoveries and suffer from serious interferences. Depending on the relative concentrations of interferents and other matrix constituents, underestimation (ultimately Type II errors probability of not detecting a constituent when it is actually present) or overestimation (ultimately Type I errors -probability of deciding a constituent is present when it is actually absent) of the cyanide levels present in a ,given sample may occur, causing in the first case false security and in the second case, excessive cyanide treatment costs. Mahy, if not all, enumerated problems can be solved by using novel flow injection (FI) gas-diffusion amperometric methods. A modification of the recently approved FI ligand exchange (FIILE) method for determination of available cyanide (USEPA Method OIA-'l677) that obviates sulfide interference will be discussed. Eight laboratory round-robin data obtained for the FI UV -digestion (FIIUV) method that determines total cyanide (Proposed Method OIA-1678) will also be presented. In addition, some methods for cyanide speciation will be presented. Finally, research needed for developing reliable methods for determination of operationally defined cyanide in solid samples will be summarized.

Jan 1, 1998

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Jan 1, 1979

By Robert S. Dewey

AS a result of drilling operations during 1943, West Texas again added sufficient new oil reserves to replace the oil produced during the year, but failed to maintain its position in currently available reserves because the deeper discoveries will require years for development. Drilling failed to provide the additional oil necessary to meet the increase in current and anticipated market demand. Although 13.3 per cent of the total footage drilled was in wildcat exploration, the ratio of oil discoveries to total wildcats was less in 1943 than in 1942, but comparable to that in 1941. Of the 732 field wells completed, 270 were at Slaughter, 55 at Wasson, 45 at Mascho and 31 at North Cowden. As of Dec. 31, 1943, there were 361 drilling wells including 71 wildcat and 290 field wells; 19.7 per cent were wildcats. It is anticipated that the percentage of wildcats of the total wells will be higher during 1944 than in either 1942 or 1943. Tables 3 and 4 present a three-year comparison of drilling activity and illustrate the downward trend of development that has been in effect during that time. Because of development lag in the deeper Ordovician fields, several years elapse before 2 sufficient number of wells is completed to give a substantial producing rate. As these new oil reserves cost more to find, and will cost more to produce on a barrel basis than the oil marketed during the year, their reserve replacement value to the industry is less in money. Costs While complete costs for deeper drilling are not yet available for analysis, it is evi- dent from the data on drilling rates to comparable depths, contract prices, and general increases in costs, that the cost of drilling has risen approximately 20 per cent during the year. One representative drilling contractor estimates that the average drilling time on a 5000-ft. field well has increased nearly one third and that out-of-pocket costs have increased a dollar per foot. Three major factors contribute to this increased cost: (I) less experienced labor, (2) deterioration in mechanical equipment and expendable material, and (3) increased contract prices. In the past, when there were more drilling rigs than wells to be drilled, some contractors would cut their drilling profit to keep their personnel and rigs working. As this practice is no longer necessary, the contract prices are adjusted upward to assure a profit. On deep and difficult drilling, contracts are let on a cost plus basis. A number of mechanical difficulties have become evident. Inferior quality of steel used in drill pipe and rock bits has added appreciably to drilling time and cost. Contractors are experiencing delay in obtaining repair work and repair parts for prime movers. As the length of drilling time required an shallow-field wells has not increased in proportion to that on deeper wells, it seems that the medium-sized drilling rig is better adapted mechanically than the heavy one to the work imposed. One of the main deficiencies in the heavy rig equipment is inadequate pump capacity. Drilling Mud The increasing amount of deep drilling has emphasized the importance and relationship of good mud to efficient and suc-

Jan 1, 1944

By Robert S. Dewey

AS a result of drilling operations during 1943, West Texas again added sufficient new oil reserves to replace the oil produced during the year, but failed to maintain its position in currently available reserves because the deeper discoveries will require years for development. Drilling failed to provide the additional oil necessary to meet the increase in current and anticipated market demand. Although 13.3 per cent of the total footage drilled was in wildcat exploration, the ratio of oil discoveries to total wildcats was less in 1943 than in 1942, but comparable to that in 1941. Of the 732 field wells completed, 270 were at Slaughter, 55 at Wasson, 45 at Mascho and 31 at North Cowden. As of Dec. 31, 1943, there were 361 drilling wells including 71 wildcat and 290 field wells; 19.7 per cent were wildcats. It is anticipated that the percentage of wildcats of the total wells will be higher during 1944 than in either 1942 or 1943. Tables 3 and 4 present a three-year comparison of drilling activity and illustrate the downward trend of development that has been in effect during that time. Because of development lag in the deeper Ordovician fields, several years elapse before 2 sufficient number of wells is completed to give a substantial producing rate. As these new oil reserves cost more to find, and will cost more to produce on a barrel basis than the oil marketed during the year, their reserve replacement value to the industry is less in money. Costs While complete costs for deeper drilling are not yet available for analysis, it is evi- dent from the data on drilling rates to comparable depths, contract prices, and general increases in costs, that the cost of drilling has risen approximately 20 per cent during the year. One representative drilling contractor estimates that the average drilling time on a 5000-ft. field well has increased nearly one third and that out-of-pocket costs have increased a dollar per foot. Three major factors contribute to this increased cost: (I) less experienced labor, (2) deterioration in mechanical equipment and expendable material, and (3) increased contract prices. In the past, when there were more drilling rigs than wells to be drilled, some contractors would cut their drilling profit to keep their personnel and rigs working. As this practice is no longer necessary, the contract prices are adjusted upward to assure a profit. On deep and difficult drilling, contracts are let on a cost plus basis. A number of mechanical difficulties have become evident. Inferior quality of steel used in drill pipe and rock bits has added appreciably to drilling time and cost. Contractors are experiencing delay in obtaining repair work and repair parts for prime movers. As the length of drilling time required an shallow-field wells has not increased in proportion to that on deeper wells, it seems that the medium-sized drilling rig is better adapted mechanically than the heavy one to the work imposed. One of the main deficiencies in the heavy rig equipment is inadequate pump capacity. Drilling Mud The increasing amount of deep drilling has emphasized the importance and relationship of good mud to efficient and suc-

Jan 1, 1944