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Compagnie Miniere Esperance (CME), a mining company based in French Guyana, operates a gold primary ore body in open pit. The ore is processed through crushing, grinding and gravity separation. Tailings are stored in a ?fine? pond. Analyses of the fine ponds proved a residual gold grade sufficient for a chemical treatment. However, direct cyanidation would require a too large installation, regarding the local conditions (accessibility, supplying and rainforest meteorological conditions). It has been then decided to test the feasibility of a pre-concentration using flotation. Lab tests have been carried out by SGS Lakefield (Canada) in March 2007, which proves the technical feasibility. Therefore, CME asked Caspeo to: ? Carry out an on-site flotation pilot campaign. ? Design an industrial flotation circuit. The tailings reprocessing will contribute to a better tailings management and a dry up of the gold resource, limiting the risk of illegal mining after remediation of the CME site. CME MINE The Esperance gold mine is located in French Guyana, in the vicinity of several gold deposits as Omaï, Rosebel or Camp Caïman, holded by Iamgold and Newmont. These main gold deposits are located on the figure 1. Esperance was put into operation in the early 90?s. The first years were devoted to the mining of alluvial gold in the gravel of the Esperance Creek. Since then, operation was led in the primary gold deposit. Annual production is on average 254kg for a total production in fifteen years of 4300kg. Geology Esperance deposit is located in the greenstone belt of the Guyana Shield. Mineralization is in tectonic contact between sedimentary basin of Maroni and a granitic massif. Clastic series, composed of conglomerate and lamina sandstone, overlie a volcano-sedimentary basement (series called "Paramaca"). The area is strongly folded by shear movements, resulting from granite deposit. Gold is in interlacing quartz veins intersecting the clastic series. Gold is present in association with pyrite. Other elements, as silver or arsenic, are in negligible quantity. Exploitation The Maroni River is the only access to the Esperance mine. Only the saprolite and a part of the transition rock are extracted in the open pit. Excavation works are done using shovels Hyundai 450 (4 units) and haulage works using articulated dumpers Terex TA35 (4 units). These two sorts of equipments are presented figure 2. Mill The mill is composed of crushing and grinding processing plants. After gravity concentration, both plants produce tailings that are stored in two ponds: the first pond contains coarse product which segregates the particles crushed to 2mm upstream and settled clays downstream; the second pond contains the fine product made of particles ground to 200µm. These two ponds, bordered by dams and diversion canals, are located on former alluvial sites of Esperance Creek (see figure 3). [ ] The CME mill is currently producing gold concentrate, with a global recovery of about 67%. The ore is crushed by one jaw crusher and two hammer crushers. The ore then passes through a Knelson KC 48 gravity concentrator, producing a first gold concentrate. The

Jan 1, 2009

By C. G. Anderson

Today, with a stringent economic and environmental climate prevailing in the copper business, there is increased interest in evaluating new processing alternatives for production. Hydrometallurgical pressure oxidation of copper concentrates is one of the more viable approaches and several technological candidates have emerged. Of these, an overlooked but, ironically the first industrially proven methodology, utilized nitrogen species catalyzation in the oxidizing pressure leach system to produce copper via SX/EW. Given its many inherent process advantages, this may prove to be a feasible process alternative for the future. In this paper, the history of the system and its application to copper concentrates and ores will be outlined. In particular, a novel methodology for effective recovery of precious metals from chalcopyrite concentrates will be discussed. Finally, the perceived economics of chalcopyrite concentrate treatment with this unique industrially proven process will be delineated.

Jan 1, 2001

By Tim Ross

Several shear failures were observed in Shaft #1 at the Mountain Coal Company, LLC, West Elk Mine, after mining longwall Panel 23, 1,100 ft to the east of Shaft #1. It was speculated that this shear damage could be related to differential ground movement caused by in situ stress relief from the ?stress shadow? of the caved zone above longwall Panel 23. A numerical study was conducted to assess the possibility of the shaft shear damage being caused by in situ stress relief and the potential for additional damage to Shaft #1 and two other nearby shafts, due to mining nearby longwall Panel 24. Three-dimensional (3D) models were built in FLAC3D to simulate past and future mining near shafts, the estimated local anisotropic and directional horizontal stresses, and the overlying variable surface topography. The numerical analyses indicated that stress relief due to mining Panel 23 caused the shear damage to Shaft #1and that additional damage to Shaft #1 and the other two shafts, would likely result from mining longwall Panel 24. Additional shear damage was documented in Shaft #1 when longwall Panel 24 was mined, confirming the results of the numerical analyses.

Jan 1, 2006

By Wilbert J. Huff

The organization of the Explosives Division has been outlined in two preceding publications.3/ The activities of the various units for the fiscal year 1939 are described hereafter: I. INFLAMMABILITY OF GASES AND VAPORS DETERMINATION OF EXPLOSION HAZARDS OF COMBUSTIBLE GASES AND VAPORS IN MINES AND INDUSTRIES (a) Determination of Limits of Inflammability of Gases and Vapors The following hitherto unpublished limits of inflammability were determined during the past fiscal year.

Jan 1, 1939

By P. Dennis, T. Pieters, A. De Kievit, S. Ganguly

TEMCO has been producing manganese ferroalloys in submerged arc electric furnaces for over 40 years. The furnace linings all along have been of conventional insulation type until 2001 when a freeze lining of UCAR concept was installed for a 20 MW Furnace. Continuous improvement of furnace lining performance has been a key component in improving the business competitiveness of TEMCO. The expected minimum campaign life of the freeze lining is fifteen years as compared to the ten years of the conventional linings. The success of the freeze lining is very critical to the quanta and direction of heat flow through the lining that control the freeze protection. Under freeze protection can lead to reduced lining life and over freeze protection, on the other hand, can lead to operating difficulties and loss of smelting efficiency. It was, therefore, necessary to develop a computer based system to monitor and control the freeze protection. The computer based monitoring and control system uses the basic principles of heat transfer, activeX object and heat flux from dual thermocouples and that is reviewed.

Jan 1, 2004

By Alexander Garcia

Roof and rib falls are the basic ground control hazards associated with underground roadways during development, stand up and, if applicable, retreat. Falls of ground can happen following the deterioration of supports or rock conditions over time, and particularly as a consequence of continuing rock deformation and/ or failure to install adequate support. Once developed, the risk of a failure is increased due to the effects of time as well as to front abutment stresses through retreat mining. The measurement of strata displacement using monitoring equipment is a form of ground control risk assessment. These monitoring systems are active, or ?live?, in a sense that risk is assessed real-time. However, there are circumstances in which falls of ground can occur without the prior recording of excessive movement. In addition, monitoring equipment is typically placed at set intervals, and strata conditions could vary between these points. Consequently, a visual assessment of other factors contributing to the risk of a fall should be made in order to complete a ground control risk assessment. Such surveys are usually one-off, thus capturing roadway conditions at one particular point in time. Ongoing deterioration is not documented through such one-time surveys, and there is a requirement for real-time or live assessment where a system is in place so that observation data can be updated on an ongoing basis, and a useful summary of prevailing roadway states produced on demand. To address the shortfalls of one-time assessments, a ?live? computerbased quantitative ground control risk assessment process has been developed. It combines visual observations processed in a quantitative manner with existing monitoring data into an interpretable output which indicates zones of roadway where there is an increased risk of a fall of ground from the roof or sides, so that remedial action can be carried out to mitigate that risk. Through improved procedures, it is now possible to generate a ground control risk assessment for each roadway, and one which can be updated frequently. This paper aims to outline and describe the assessment process.

Jan 1, 2012

By C. M. F. Vieira

In the county of Campos dos Goytacazes, north of the State of Rio de Janeiro, Brazil, there is a large production of red ceramic, mainly perforated bricks. A percentage of these bricks are damaged during the firing processing and become a red ceramic waste. This work investigates a possible solution to this environmental problem through the mixture of fired brick wastes, up to 20 wt.%, with clay bodies to produce red ceramics. Cylindrical pressed bodies were fired at temperatures varying from 500 to 1100ºC. After firing, samples were then tested for linear shrinkage, water absorption and mechanical strength. The results showed that brick waste addition did not changed the workability of the clay and that up to 5 wt.% of waste no detrimental effect occurred on the fired properties at all temperatures.

Jan 1, 2010

By R. H. Hiltz

The Coal Mine Health and Safety Act of 1969 legislated maximum dust levels for the working place. As the law was implemented, extensive efforts were undertaken to provide the technology necessary to control dust generation. One approach to dust control was the use of high expansion foam in place of the usual water sprays on coal cutting equipment. At the time of the act, high expansion foam had already seen considerable testing for the suppression of dust in underground coal mines. Work by MSA, several coal companies and the Bureau of Mines itself had provided data which showed foam to have some merit as a dust control mechanism. It suffered in a few areas, however, which limited its practical application. Its principal difficulty was persistence which hampered operations due to foam buildup, but problems were also encountered due to equipment size and form.

Jan 1, 1975

By D. R. Dolinar

Geogrids can be used as surface control on both the roof and rib in underground mines to prevent the fall of small pieces of rock and material from between the primary supports. The use of screen material such as geogrid can significantly reduce the number of ground fall injuries caused by these small rock falls. Because of the potential for reducing injuries through the use of screen, the National Institute for Occupational Safety and Health (NIOSH) has conducted tests on screen materials including geogrid to determine their support characteristics and identify parameters that can affect their performance with respect to maintaining broken or failed rock. A specially designed test frame installed in the NIOSH Mine Roof Simulator (MRS) has been used to evaluate the load and stiffness characteristics of the screen material. Two types of geogrids with various designs have been tested-a polyester yarn and a polypropylene grid. The load-displacement characteristics of these grids were determined and the load capacity and stiffness were calculated through 20in of displacement. The load capacity and stiffness of the geogrid in general are shown to be related to the ultimate tensile strength of the screen material.

Feb 27, 2013

By : D. Lawrence

Certain blasting applications are more prone to the generation of significant levels of nitrogen dioxide post blast fumes, more commonly referred to as after blast smoke, generally ranging in color from dark yellow to bright red. This paper reviews basic background chemistry defining the observed fumes and attempts to correlate geology, blast design, and explosive composition effects on the level of nitrogen dioxide that can be observed in various blasting conditions. Additionally, a test setting for evaluating the generation of post blast fumes is presented with pertinent test data detailing generic explosive formulation modifications which effect the overall level of post detonation generation of nitrogen dioxide.

Jan 1, 1996

By Tamara F. Kondrateva, Evgenia E. Savari, Galina V. Sedelnikova, Rauf Y. Aslanukov, RAS (INMI), Grigori I. Karavaiko

"The investigation is dedicated to study of biohydrometallurgical processing of refractory gold-arsenic concentrate with the large content of pyrrhotite. Sulfide concentrate of chemical constituents: 75g/t Au, 4,7g/t Ag, 6,3% As, 29,3% S, 2,3% Sb, 0,5% ? (organic) and of mineral composition, %: 11,8 arsenopyrite, 39 pyrrhotite, 12 pyrite, 2,9 antimonite and the rest – aluminosilicates, carbonates and quartz, was studied. The recovery of gold from concentrate by cyanidation is 51,2%. The rest of gold is embedded as finegraded segregation in sulfides.Sulfide oxidation process study is described. Bacterial oxidation was executed on a pilot laboratory unit using combined autotrophic bacterium: A. thiooxidans , A. ferrooxidans, Leptospirillum ferrooxidans and sulfobacillus thermosulfidooxidation, pH=1,5-2,2, t=28-32?C, oxidation time 120 hours. Pyrrhotite is the least stable sulfide mineral with electrode potential 0,45V versus arsenopyrite (0,55 V) and pyrite (0,55-0,6 V) and is oxidated primarily. Pyrrhotite oxidation is followed by large amount of elemental sulphur, which has a bad influence on cyanidation.It’s established that the rate of arsenopyrite (for the first 48 hours) from concentrate containing 39% pyrrhotite is 2-3 times as less as the rate of arsenopyrite bio-oxidation from concentrate without pyrrhotite. The arsenopyrite bio-oxidation is accelerated only after the elemental sulfur was oxidized by bacterium A. thiooxidans and elemental sulfur percentage was reduced from 6,8 to 3,9%. The bacterium concentration is increased from 2,5x107 to 2,5x109 cells/ml. Almost full oxidation of arsenopyrite (98%) and pyrrhotite (98- 99%) is finished in 120 hours. We have studied two pretreatment methods for elimination sulfur content influence on cyanidation: aeration in lime and electrochemical treatment. Such an operation enables to have supplemental oxidation of elemental sulfur and other oxygen and cyanide absorbants before cyanidation. After treatment the content of elemental sulfur was decreased from 3,9 to 2,2%, gold recovery from 90 to 96% and cyanide consumption from 16,2 to 7,2 kg/t decreases. The content of toxical rhodonite-ions in liquid phase of pulp and disinfection reagents consumption were decreased as result of elemental sulfur content in bio-oxidated product reduction."

Jan 1, 2003

By Dominic Fragomeni, Tony DiFeo, Martyn P. Hay

"As part of an investigation into flotation modelling of industrial scale operations, Falconbridge Ltd organised a “blind” test of the SUPASIM flotation model developed by Eurus Mineral Consultants (EMC). Two sets of rougher rate data, a flowsheet and the number and size of cells in the rougher bank were supplied from a plant that had been previously surveyed in November 2003. The name of the plant, cleaner circuit details and circuit mass balance were, at the time, unknown to EMC. With only these data, flotation performance was simulated and the cleaner circuit sizedFalconbridge then compared predicted and actual float performance and mass balance and found that final concentrate recovery and mass and circuit cell volume matched closely. Simulated recoveries relative to actual were +0.4% Cu, +0.1% Ni and -0.7% Co. However, prediction of metal distribution in the internal streams making up the various circulating loads showed some sizeable errors. On this initial success, the trial was extended and additional float test data for rougher feed, cleaner feed and cleaner scavenger feed was generated on site in April 2005. Further simulations significantly improved prediction accuracy for metal distribution in the internal streams. The average difference between predicted and actual recovery for all streams was reduced from 10.5% to 0.4%. This updated simulation was then used to ascertain the impact on final recovery, grade and plant circulating loads of increasing feed tonnage from 114 to 150t/hr. A number of scenarios were simulated in order to understand the contribution that (a) the fast and slow floating fractions and (b) regrinding of cleaner tailings are making to overall plant recovery.Simulation was then used to determine how much the flotation kinetics of both rougher feed and cleaner scavenger feed have to increase in order to deliver a 1.5% improvement in overall plant recovery. These improved kinetic values provide a target for laboratory testwork and operating conditions can be varied to determine how best to achieve these new values of fraction and rate."

Jan 1, 2006

By Fred N. Kissell

In This Chapter [The explosibility of methane gas mixtures Effect of pressure and temperature on explosibility Less common sources of methane ignitions The amount of methane stored in coal Forecasting the methane emission rate Layering of methane at the mine roof When the recirculation of mine air is hazardous The importance of higher air velocity in preventing methane explosions and Mine explosions, barometric pressure, and the seasonal trend in explosions] Dealing with methane in mines and tunnels requires knowledge of the circumstances under which dangerous accumulations of methane are likely to occur. This knowledge involves the properties of the gas itself, an awareness of where these accumulations are likely to occur, and facts on how methane mixes safely into the mine air. The other chapters in this handbook address the handling of methane under a variety of specific circumstances, such as at continuous miner faces or coal storage silos. This chapter addresses some broad concepts that serve as a foundation for the suggestions provided in other chapters. THE EXPLOSIBILITY OF METHANE GAS MIXTURES Methane entering a mine or tunnel often enters as a localized source at high concentration. Figure 1–1 depicts a cloud of methane being diluted into a moving air stream. In this illustration, methane enters the mine from a crack in the roof. As the methane emerges from the crack, it progressively mixes with the ventilation air and is diluted. In the event that this progressive dilution reduces the concentration from 100% to 1%,2 as shown in Figure 1–1, the methane passes through a concentration range of 15% to 5%, known as the explosive range. In the explosive range, the mixture may be ignited. Above 15%, called the upper explosive limit (UEL), methane-air mixtures are not explosive, but will become explosive when mixed with more air.

Jan 6, 2006

By Ahmad F. Souri, Murad Abu-Farsakh

"In this study, the static lateral resistance of vertical and battered pile groups was analyzed using 3D finite element analysis. The battered pile group finite element model was verified using the results from a case study performed on the M19 pier foundation of the I-10 twin span bridge in Louisiana. The vertical pile group model was created by adjusting pile inclinations of the verified battered pile group model. The finite element models utilized nonlinear constitutive models for materials behavior and a soil-pile interface model. The results showed that the battered pile group had greater lateral resistance than the vertical pile group with 60-70% lower pile cap displacement. The largest lateral load share was found in the middle rows in the battered pile group, while it was in the leading row for the vertical. The soil resistance profiles showed that the vertical pile group mobilized greater soil resistance compared to the battered pile group.INTRODUCTIONThe lateral resistance of a pile-soil system depends on both pile stiffness and soil reaction. The soil reaction is a nonlinear function of deflection, depth, pile stiffness, and soil stiffness and strength. The lateral capacity of single piles is evaluated at the maximum deflection limit, and can be predicted using established methods such as the p-y curve method (e.g., Matlock 1970, Reese et al. 1974), elastic solution by Poulos and Davis (1980), the strain wedge model (Ashour et al. 2004), and the finite element method (e.g., Yang and Jeremic 2002, Comodromos and Pitilakis 2005, Isenhower et al. 2014). For pile groups, the lateral capacity of a pile-in-group is less than the isolated single pile case because the soil in front of the pile-in-group is weakened by the overlap of stress zones from surrounding piles. The latter is referred to as the shadowing or group effect (Fig. 1). Prediction of the lateral capacity for pile groups is based on the p-y curve method for single piles with the use of empirical factors called “p-multipliers”. The p-multipliers accounts for the shadowing effect, and are a function of pile-pile spacing and soil type (e.g., Brown et al. 1987, 1988, McVay et al. 1995). Moreover, the lateral capacity of pile groups is also influenced by vertical load, piles arrangement, and slenderness ratio (e.g., Rao et al. 1998, Patra and Pise 2001, Ilyas et al. 2004, Hussien et al. 2012).Battered piles refer to piles installed at an angle with respect to the vertical to increase their lateral capacity. The greater lateral resistance is achieved by the additional axial reaction in the pile. Battered piles are called “negative battered” when inclined in the load direction, and “positive battered” when inclined opposite to the load direction (Fig. 1). Previous studies concluded that the lateral resistance is highest in positive battered piles followed by negative battered and vertical piles, respectively (Murthy 1964, Meyerhof and Yalcin 1993, Zhang et al. 1999)."

Jan 1, 2017

By J. D. Doll

MSHA has promulgated a rule to limit the exposure of underground metal/nonmetal miners to diesel particulate matter (DPM). In May 2008, the final personal exposure limit will be lowered to 160 µg/m3 total carbon. To comply with this rule, mine operators are implementing a variety of control technologies. In this study two types of control technologies (ventilation and cabs) which are being implemented in limestone mines were investigated. Two stone mines in this study use large diameter propeller fans for main mine ventilation and direct the air to the faces using auxiliary fans, stoppings, and long pillars while bypassing the old mine workings. NIOSH measured for sub-micrometer elemental carbon (EC) using SKC DPM cassettes (analyzed using NIOSH 5040) and a near real time instrument. With the present ventilation and the number and type of vehicles used, the concentration of EC from DPM at the working areas was at or below 400 µg/m3 for both mines and about 166 µg/m3 and 251 µg/m3 at the returns. The real time data showed that the ventilation was reaching the working areas and effectively diluting the DPM. Environmental cabs were also used to reduce DPM exposures in three underground limestone mines. Using NIOSH method 5040 and near real time EC instrumentation, NIOSH sampled inside and outside of a loader cab at one of these limestone mines to determine the effectiveness of the cab. The cab was found to be over 90% effective in removing DPM as long as the cab system was properly maintained, and doors and windows were closed.

Jan 1, 2009

By S. J. Broderick

[Xuge d-mp heap co:lt:.ini9: tilcu?:na3s of tons of cad ~eP~se 2r3 a failiar sight in coal-mininc regior@:. T5ey reprecei~t considergole economic 1083, are very l.u.,si~hC,ly, ?:ld t?ke un m-lch vaL-x3le qace. Cor.sequentl;r thelr remcval i~ geatlyr dezir36, ax2 my ret-sn t?-at c,m be obtained would be er;pecic.llj .a~elconre&apos; t.7 the cod ir.S..r; kry. T?.e vaste rk.t~ri..tl conpl-ises large pieces of slr.t.e, hi~h-2s&apos;. bore c~al., luqs cf cle:., ,ad finer refuse conin,= fro3 the vrtskery, Tilt 1:zshcr:r refilsn contnins sone yood coal. Rig coal and the &apos;better p~lcs of bore ere the zat~rla2.s ~15:;~itiered in this in- vest ig:?.tion. 7% Il~avter frnctions of the w~~sherjr ref;lw aizd tts large 2ieces of slcte ?,".:I rgck contilin 1it:lei ccai-i-bcna.c~o~s caterial ad are vir- tu<dly worthiess nc, rz:. ::atcrin!. for .*=irin,= zct,iv?*teb cCvb~n. 13 the 3irniingh.m district, i13br.12, a-c.ju",P p?rcccn",f the c3sl r?.ir?ed is washed, ,md in tkis c?i.;trict nlz:~c rcfilce ecc;:?:lletcs ~t the r%tg of 1 to 2 million .! tons 2 yew.]

Jan 1, 1941

By A. M. Elmahdy

An amphoteric collector was tested for dolomite removal from phosphate ore. The effects of some operating parameters and their significance on the flotation of dolomite were studied using statistically designed experiments. The parameters studied were impeller speed, pH and collector dosage. Analysis of the results showed that pH is the most significant parameter. Moreover, a concentrate containing 0.53% MgO and ~31.1% P2O5 with a recovery of ~ 90% can be achieved at optimum values of studied parameters, i.e., a pH of 12, an impeller speed of 1,000 rpm and a collector dosage of 2.5 kg/t.

Jan 1, 2007

By G. Belardi, N. Shehu, L. Passeri

"This paper illustrates the possibilities of applying what is essentially a physical soil-washing technique for treatment of soil contaminated by semi-volatile hydrocarbons in order to reduce the level of pollution to that permitted by Italian regulations.The ground around a factory producing lubricating-oil additives consists of silty-sandy soils which have long been contaminated by heavy hydrocarbons, especially branched alkyl benzenes and naphthalene derivatives. Pollution is particularly marked in some zones (hot-spots) where Total Petroleum Hydrocarbon (TPH) values are as high as 7000 ppm. The hydrogeological characterization showed the presence of a gravely soil in a sandy/silty matrix, with big stones making preferential paths to the water circulation. The permeability is 10-5 m/s and the water-table occurs at about 3 m below ground level.After laboratory and pilot-scale studies on representative samples of in-situ soils with TPH between 2700 and 7000 ppm a flow-sheet is proposed for reducing TPH values below the acceptable limits in Italy, namely 700 ppm for hydrocarbons with more than 12 carbon atoms and less than 250 ppm for those with fewer.On the basis of indications provided by laboratory tests a mainly physical treatment process of soil washing has been developed. This is used to clean-up soil from a site polluted by non-volatile hydrocarbons with a high TPH value. The process involves a high-density attrition stage followed by wet screening at 0.5 mm and then wet-gravity separation of the minus 0.5 mm fraction in the centrifugal field.The gravity separation products consist of a light fraction with particle size finer than 15 micron which contains most of the pollutants, and a heavy coarse fraction with TPH values conforming to the limits set by Italian regulations (less than 700 ppm hydrocarbons whose structure contains more than 12 C atoms, and less than 250 ppm of hydrocarbons with less than 12 C atoms)."

Jan 1, 2003

By Arnold Hammons

Automated temporary roof support (ATRS) systems have been incorporated into roof bolters since the 1970?s. During roof bolting, many injuries have occurred from large pieces of draw rock falling inby the ATRS beam and tipping back into the operator?s area. Other injuries have occurred due to smaller, sharp rocks falling onto the operator?s hand and arm during initiation of roof bolt drilling. These injuries are attributed to weak immediate roof, sometimes called roof skin failure. Even though ATRS systems support the roof and provide a measure of protection against roof skin failure, additional hazards sometimes do exist immediately inby and outby the supported roof. Design innovations such as the ATRS mounted rocker pad deflector systems have been designed to improve the roof bolter operator safety. This paper will inform the reader of the hazards, machine evolution through different design solutions, and the current state of the art in preventing roof skin failure injuries when roof bolting.

Jan 1, 2009

By Selda Ozkan

In this study, a combination of cathodic arc physical vapor deposition (PVD) and molten salt electrolysis methods were used to obtain ZrB2 layers on AISI 304 grade stainless steel surface. Prior to boriding, steel surface was coated with metallic zirconium via cathodic arc PVD method and then the zirconium coated steel was borided by molten salt electrolysis. Well adherent, dense, ZrB2 layers are formed on the substrates. The thickness of the ZrB2 layer showed dependence on the thickness of the metallic Zr coating layer and the time of boriding. During the boriding process the alloying elements of the substrate also took part in the coating structure depending on their diffusion characteristics.

Jan 1, 2010