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By Dachun Liu, Wenlong Jiang, Baoqiang Xu, Yongnian Dai, Bin Yang

"In the traditional method for refining of indium, glycerin-KI and glycerin-NH4Cl are used as electrolytes to remove Cd and Tl by electrolytic refining, which produces In with a purity of 99.995%. Large quantities of polluted industrial waste water are the result. It is calculated that the saturated vapor pressure of Cd and Tl are between 1-200 Pa, which is much larger than the vapor pressure of In. Thus, the study of removing Cd and Tl was carried out over the temperature range between 700-950 °C and pressures between 1-15 Pa. After vacuum distillation the contents of Cd and Tl in crude indium could sharply fall below 1 ppm..IntroductionIndium is a is a pale blue and silver white metal, and has high ductility [1-2]. Pure indium is generally used as a raw material to produce semiconductor compounds, fluorescent material and ITO targets [3]. Sublimation, zone melting and electrolytic refining are major methods to produce pure indium from crude indium. Electrolytic refining is the main method to product pure indium at present. High productive efficiency, simplicity of operation and short cycle of production are major advantages. However, glycerin-KI and glycerin-NH4Cl are used to remove Cd and Tl in electrolysis method. Large quantities of polluted industrial waste water are the result[4]."

Jan 1, 2012

By Jacob Bummer, Greg Roset, Dayle Flynn

"IntroductionStillwater Mining Company operates a Precious Metals Smelter (PMS) located in Columbus, Montana USA. The PMS processes iron, copper, and nickel sulfide bearing concentrates containing platinum, palladium, gold, and rhodium. The concentrates are produced from two mines in the Beartooth Mountains located in south central Montana. The PMS utilizes a 7.5 megawatt 3-in line electric furnace to smelt the concentrates, and two Top Blown Rotary Converters (TBRC's) to remove iron. In addition to the mine concentrates, the PMS also processes various forms of Platinum Group Metal (PGM) bearing recycled catalyst. The sulfide matte produced within the electric furnace and TBRC's acts as a collector for the PGMs. Throughout the operation of the PMS, there are three different forms of molten material that are processed through the Stillwater Granulation system: TBRC matte, TBRC slag, and electric furnace matte. This paper describes the operation of this granulation system.Tapping the FurnaceWhen a sufficient level of molten PGM bearing matte has been reached within the inner volume of the electric furnace, the molten material is ""Tapped"". Tapping requires drilling into the electric furnace until reaching the molten matte phase. The matte phase will drain out of the drilled hole through a graphite launder into a 5 ton refractory lined ladle. Once the ladle is full, the tap is plugged with a mud gun."

Jan 1, 2012

Plastics recycling has become an established national industry in Korea. However, it is still in its infant stage and experiences growing pains. In Korea, mixed plastic wastes generated from households after hand picking and/or mechanical sorting processes amount to 1,700,000 ton per year in 2005, and most of these waste are finally end up with landfill and/or incineration due to lacks of separation technologies and economical reasons. These plastic wastes can not be used as raw materials for chemical and/or thermal recycling because of their high content of PVC (upto 4.0 wt.%). In the present work, gravity separation system has been developed to remove PVC from the mixed plastic waste and recover the individual plastics. The separation system mainly consists of air classification, crushing, feeding system at fixed rate and wet-type gravity separation system. The gravity system based on centrifugal separation also consists of mixing, precleaning, separation, dewatering, recovery system, wastewater treatment system, etc. The main objective of this process to be developed is to achieve high separation efficiency of polyolefins (PE, PP, PS) with less than 0.3 wt.% PVC content and less than 10% moisture content in the final products. The system with a capacity of 0.5 ton per hour is developed and operational results are presented.

Jan 1, 2006

By E. Ilgar

"Deposition studies were conducted in acid copper electrolyte to determine the influence of chloride ions on cathode morphology. A statistically designed screening test was carried out in the absence and presence of 20 ppm CI- using a three factor, two level factorial design, in an electrolyte containing 36 gl'! Cu2+ and 150 gl-! H2S04, The independent variables evaluated were agitation; current density and temperature and their influence on surface roughness was determined. The copper deposited at current densities where activation was the primary control mechanism appeared similar in morphology whether stirring was used or not. The addition of 20 ppm CI- to the electrolyte gave rougher deposits under the same conditions. In the mixed control regions, considerably rougher, dendritic deposits were obtained when CI- was present. Agitation was effective in reducing the copper surface roughness both in the apparent activation and mixed control regions in the presence ofCI-. The results of this study showed that 20 ppm Cl- polarized the copper deposition at low overpotentials but caused depolarization at higher overpotentials.IntroductionChloride ion is inherently present in copper electrolyte, either as an additive or from other sources such as make up water. The behavior of the chloride ion is well documented in electrorefining operations, but its role in copper winning is less obvious. However in both cases there is evidence that cathode growth and solution chemistry are strongly influenced by its presence. The mechanism and electrochemical action of the Cl"" have been shown to be very complex, therefore a better understanding of its influence on electrocrystallization is essential for improved cathode deposit growth control. It was proposed that Cl"" polarizes the copper deposition reaction at low concentrations due to CuCI formation but depolarization occurs at higher concentrations due to the formation of a soluble CuCI2"" complex [1,2]. Franklin [3] reviewed the mechanism of additives in the electrodeposition process and proposed that the Cl"" complexed with copper, adsorbed on the cathode as an induced anion leading to an increase in the reduction rate. At cathodic overpotentials less than 100 mY, lppm NaCl had a polarizing effect, i.e. an increase in impedance of the charge transfer step. At higher Cl"" concentrations up to 100 ppm, depolarization occurred as evidenced by a decrease in impedance, which was attributed to soluble cuprous complexes [4]."

Jan 1, 1997

By Andre Thess, Oleg Zikanov

"Direct numerical simulation methods are applied to study the influence of a constant magnetic field on turbulent flows of liquid metals. The flow is assumed to be homogeneous and the problem is reduced to the classical case of the turbulent flow in a 3D box with periodic boundary conditions. The main subject of the study is the anisotropy developing in a liquid metal flow affected by constant magnetic field.To investigate the long-time evolution of initially isotropic flow the large-scale forcing is applied to maintain the flow energy at a statistically steady level. It is found that the flow evolution depend strongly on the magnetic interaction parameter (Stuart number). In the case of small Stuart number, the flow remains three-dimensional, turbulent, an approximately isotropic. At large Stuart number (strong magnetic field) the turbulence is suppressed rapidly and the flow becomes two-dimensional and laminar. Very interesting is the intermittent flow evolution at moderate Stuart number. Long periods of almost two-dimensional, laminar behavior are interrupted by strong turbulent three-dimensional bursts.The influence of a constant magnetic field on scalar transport properties of liquid metal turbulence is investigated using the simplified formulation of homogeneous flow driven by an imposed mean temperature gradient. Such a flow consists primarily of two turbulent antiparallel jets providing an effective mechanism for heat transfer. It is shown that the magnetic field parallel to the mean temperature gradient stabilizes the jets and, thus, enhances heat transfer considerably."

Jan 1, 1999

By Christian Trassy, Pierre Proulx

"Inductive plasmas are now commonly used in material processing: spraying, powder synthesis, densification or spheroidization. An inductive discharge presents, in the coil region, recirculation eddies due to the Lorentz forces, resulting in an axial backflow. If the central jet is strong enough to ""pierce"" the recirculation this axial backflow disappears on the centerline, but the external layer of the injection flow is skimmed by the remaining eddy, and particulates are rejected to the discharge periphery. To avoid this disadvantage, it is common to introduce the injection pipe inside the discharge, so that its outlet is positioned after the recirculation eddy. The powders remain confined in the axial zone, to the expense of shortened residence time.In order to increase the efficiency of the particle trajectories, a double flow injector has been designed. It enables the particles to travel closer to the axis, while the outer schrouding gas is skimmed and passes through the electromagnetic eddies. This injector is made up of two concentric tubes. The powders are injected with the carrier gas in the inner tube. A schrouding gas is injected in the annular space between the inner and the outer tubes. The powder is confined to the vicinity of the axis, resulting in a more homogeneous thermal treatment.Tungsten powders have been spheroidized with and without this device. Using the double flow injection, the spheroidization yield has been increased from 70 % up to 95 %.The design of such an injection device has. been studied and improved using numerical modelling. Another useful tool, a visualisation technique described elsewhere, has been used for the experimental study, that drastically simplifies the comparison between experimental and theoretical results: injecting yttrium oxide into the discharge results in a colorful display of the 4000 K isothenn: the ""cold"" zone, below 4000, appearing as red, and the ""hot"" zone as blue. Furthermore, it is of great industrial interest since it is a very cheap and efficient way to obtain a picture of an important isotherm."

Jan 1, 1999

By Thomas J. O'Keefe, Pu Yu, George Houlachi, Xuewen Tang

"Impedance measurements were used to investigate the electrochemical characteristics of acidic zinc sulphate electrolytes containing Sb3+, gelatin and their mixtures. The data were correlated with cyclic voltammetry curves made using synthetic as well as industrial electrolytes. The cyclic voltammetry results were similar to those obtained in previous studies in that antimony caused a depolarizing effect while gelatin gave an increase in the potential for zinc nucleation on an aluminum substrate.The electrochemical impedance spectroscopy (ElS) evaluations were conducted on electrodeposited zinc at three overpotential values. The potentials were chosen to represent various current density regions in the zinc polarization curves. The antimony and gelatin gave characteristic impedance plots which correlated with expected behavior, particularly current efficiency. Both antimony and glue appear to modify the intermediate zinc reaction sequence, but in different ways. The data strongly suggest that film formation and stability are major factors in the zinc ion reduction mechanism.IntroductionThe zinc electrodeposition process is sensitive to the presence of a variety of organic and inorganic chemical species in the electrolyte [I]. Such components can produce either beneficial or harmful effects, depending on their relative concentrations and electrochemical behavior. Extensive investigations have been made to gain a better understanding of the changes occurring during zinc deposition in the presence of such additives. Techniques employed include microscopy, x-ray diffraction, dynamic voitammetry, current imd energy efficiency studies [2-5]. Ultimately, the objectives are to identify the factors which most affect the efficiency of the process and to provide a means to effectively control them.One of the most harmful impurities is antimony, which can be detrimental when present at concentrations as low as 10 to 20 parts per billion. Dramatic changes in zinc polarization behavior, deposition structure and current efficiency have been observed with antimony in the electrolyte. Antimony appears to lower the hydrogen overpotential by hydride formation or a similar catalytic mechanism, which allows an increase in localized corrosion and zinc dissolution [6-8]."

Jan 1, 1997

By S. Kang, D. G. C. Robertson

Slag cleaning furnaces require extensive wall cooling because they involve the use of a superheated slag bath. This is in direct contrast to smelting furnaces, where the wall is usually (but not always) protected by "banks" of solid charge. In order to understand the heat transfer and flow in slag cleaning furnaces a number of model studies have been carried out using molten wax to simulate the slag. Wax is a good model fluid because, like slag, it has a high Prandtl number. Wax models cannot simulate the behavior close to the electrodes (DC arc or AC submerged), but they can and do give a good simulation of the flow and heat transfer at the wall. An understanding of these phenomena is of great importance for the design of cooling panels in the walls of the furnace. Since superheated molten slag will eventually wear away any refractory bricks over time, the wall cooling must be designed to form a frozen layer of slag, referred to as a "freeze lining". The heat flux density (Q/A) required to do this is given by Q/A = h* ?T, where h is the heat transfer coefficient in the slag phase at the wall, and Li T is the superheat (bulk slag temperature - liquidus temperature). Both Q/A and h vary greatly with position and both are usually a maximum at the slag line. In the experimental work, molten wax baths were heated by block heaters to provide similar energy densities to those encountered in commercial slag cleaning furnaces. This procedure was considered to be valid since most of the electrical energy into a furnace bath is dissipated as heat. Gas stirring was used to simulate the gas evolved at the electrode in real furnaces - the quantity of this gas could be estimated from a knowledge of electrode consumption. The similarity criterion was equal gas flow per unit area of surface, in model and prototype. Heat transfer coefficients were measured in the models as a function of power density, gas stirring, superheat, etc., and could be related to the full-scale operations by the use of dimensional analysis.

Jan 1, 1999

By M. K. Patel, K. A. Pericleous, M. Molaei

"The future trading of carbon credits and increased financial cost necessitates substantial cuts in incidental C02 emissions in the production of metals (iron, steel, aluminum, zinc, lead). Although greener methods of production are being developed, in the short term the use of point-source C02 extraction using existing technology remains attractive. Accelerated natural carbonation, in a fluidized bed is a feasible technological route investigated in this research. CFD modelling has been used to study the efficiency of C02 capture in a fluidized bed reactor containing a CaO solid sorbent. A Lagrangian/Eulerian scheme describes describe CaO particle trajectories and exchange of mass, momentum and energy with the carrier gas, with a typical off-gas composition. Different reactor geometries are considered (with uniform, stepped and gradually expanding cross-section), to maximize conversion for a given particle loading and size distribution (100-200 microns). Removal efficiencies of up to 80% are demonstrated, making this a viable process.IntroductionBased on Intergovernmental Panel on Climate Change (IPCC) reports, the major cause of climate change and global warming is due to a high level of C02 concentration in the atmosphere resulting from fossil fuel combustion, particularly in coal-fired power plants [1]. Carbon capture and storage is therefore the most important action proposed to reduce C02 from combustion flue gases. In this process, carbon dioxide is captured and may then be regenerated as pure C02 and conducted to a permanent storage, or simply stored as a solid carbonate [2]. Capture and storage of C02 has an economic penalty and the main cost of this penalty is associated with the capture plant. Capturing C02 with a lime-based solid sorbent (CaO) is a very promising technique, due to the low cost and the wide availability of the reactant. In this process, the CaO reacts with C02 based on the following reaction in a reactor called a Carbonator:"

Jan 1, 2012

By Biswadeep Saha, Meenakshisundaram Ramanathan, Chai Ren, Sivaraman Guruswamy

"Fe-Ga alloys have a large low-field magnetostriction and these alloys are attractive candidates in energy conversion and harvesting applications. Small additions of W also increase the magnetostriction of Fe. In this paper changes in magnetostriction by W substitution for Ga in various Fe-x at.% Ga alloys are presented. Fe-Ga-W single crystals were grown using vertical Bridgman Growth technique. [001]-orientated single crystal samples were prepared with faces within 1 degree off <100> orientation. The samples were annealed at 1150 °C in the alpha-phase region and water quenched. The magnetostriction coefficient (3/2)A-100 measurements were made on these Fe-Ga-W single crystals. The result on the effects of W substitution and annealing on the magnetostrictive behavior of these alloys are discussed.*Support of this work by NSF-DMR under the award DMR-0854166 is gratefully acknowledged.IntroductionMagnetostrictive materials changes their dimension exhibit reversible strains and changes in elastic properties in the presence of an applied magnetic field or the reciprocal effect of changes in the magnetic properties with the application of stress [IJ and are very important in sensor, actuator device, linear motor, magnetomechanical devices, microelectro- mechanical devices, active vibration dampening devices application areas. The discovery of an order of magnitude enhancement in the magnetostriction of Fe with Ga addition coupled with low saturation magnetic fields, and excellent mechanical properties opened up the possibility of obtaining larger magnetostriction values in other low-cost ductile a-Fe phase based alloys with alloying additives that are less expensive than rareearths such as Tb and Dy [2·4l_ The magnetostriction values observed in Fe-Ga single crystals are sensitive to thermal history and composition. The formation of second short range ordering phases and local defects inside crystal structure can also cause a dramatic change to this alloy's magnetostriction behavior [5-9l_"

Jan 1, 2012

By Alex Luyima, Jaan Kers, Lifeng Zhang

"The pyrolysis of PWBs was investigated by a TG-DTA-MS furnace at 300–1173 K. The kinetics and the control of emitted gas during the pyrolysis of PWBs with and without chemical additives were studied. Moreover, the possibility of controlling the amount of toxic exhaust gases like HBr, C6H6, Br2, Cl2, HCl gas and recovering beneficial gaseous fuels like CH4 and H2 from pyrolysis process is discussed. The MS data for each PWB sample were examined as a function of temperature and particular m/z values could be associated with the mass loss steps in the TG data. The degradation of the organic material was characterized by m/z = 2, 16, 18, 28, 36, 44, 71, 78, 81, and 160. Fe2O3 was the best inhibitor of toxic HBr and C6H6 when compared to Al2O3, CaO Y-zeolite and ZSM-5. Moreover, it had no significant effect on the valuable H2 and CH4 gas evolution. This selective inhibition of toxic gases while maintaining the valuable ones make Fe2O3 the best candidate among the investigated additives in controlling gas emissions from PWB pyrolysis process.IntroductionThe electronic and electric industry is one of the world’s largest and fastest growing manufacturing sectors. As a consequence of this growth, electrical and electronic waste (e-waste), such as computers, washing machines, printers, mobile phones, television sets, stereos, radios, etc., is generated in large quantities around the world. Printed wiring boards (PWBs) are a common component of many electronic and electric systems.[1]. The rapid development and expansion of the electronics industry over the past several decades have led to a dramatic increase in the production of PWBs and a corresponding increase in the amount of waste generated from both production and disposal. The environmental impacts of the treatment and recycling of PWBs waste have become a major concern [1-2]. PWBs are particularly problematic to recycle because of the heterogeneous mix of organic material, metals, and glass fiber [1]."

Jan 1, 2012

Many studies have been conducted over the past 3 decades on the leaching of gold in solutions containing thiosulfate, ammonia and copper. However, most of these studies have been carried out using ore samples, with very few fundamental studies of this system being attempted. The majority of the published studies have failed to acknowledge the undesirable side reaction between copper(H) and thiosulfate, let alone account for its effect. The fact that the solution chemistry is constantly changing makes it very difficult to perform a fundamental study of gold leaching. With the advent of the rotating electrochemical quartz crystal microbalance (REQCM), such fundamental studies are possible as this instrument measures mass in real time. This has allowed leach kinetics to be measured in a matter of minutes and hence at essentially constant solution conditions; The present paper highlights that a sufficient concentration of copper(II) and ammonia are required in order to achieve appreciable gold leach rates. However, the use of air (oxygen) to maintain the copper(Il) concentration catalyses the undesirable copper(II) reaction with thiosulfate. The presence of ammonium ions is shown to have an effect on this undesirable reaction as well as on the gold leaching ?reaction. Preliminary electrochemical studies into .gold electrowinning using the REQCM show that gold(I) thiosulfate cannot be readily reduced to metallic gold in the potential region at which cementation usually occurs. However, it is well known that gold cementation onto copper occurs rapidly. The current study addresses this discrepancy by studying the effect that copper and silver have on the reduction of gold thiosulfate. It has been found that the presence of both silver and copper enhance gold deposition, particularly at low over potentials. While this is beneficial in cementation, the presence of copper and silver in solution has been found to cause passivation of the cathode surface during electrowinning at &apos;higher overpotentials.

Jan 1, 1998

By Norman L. Kotraba

Zia Metallurgical Processes, Inc. has developed and patented a steelmaking process capable of converting iron bearing metallurgical wastes into high quality steel products. The process utilizes a proprietary design rotary hearth furnace to convert iron bearing wastes, pelletized with coal, or other forms of carbon, into direct reduced iron (DRI). This DRI is fed, hot, from the rotary hearth furnace into a Zia All Purpose Vessel (ZAV) where it is smelted and refined into high quality steel. A specially designed turret with three independent arms, each supporting a separate ZAV, comprises the heart of the meltshop. No overhead cranes are required to transport molten metal from the smelting/refining operation to the ladle metallurgy station to the caster to an inspection station and back to the smelting/refining point. The molten steel is contained in the ZAV throughout the operations eliminating the possibility of steel con¬tamination by non-metallic inclusions occasioned by the exposure to ambient air during metal transfer into ladles. The result is the creation of very clean steel that can be alloyed to produce virtually any desired grade from stainless steel to common structural steel.

Jan 1, 1994

By Itavahn Alves da Silva, Jose Dimas de Arruda, Amanda Aparecida Fátima Arruda, da Silva de Souza, Carlos Antonio da Silva, Varadarajan Seshadri, Samuel

The knowledge of the flow field inside a continuous casting mold is essential to improve operational efficiency of the process and also to achieve better inclusion control. Physical modeling, PIV technique and CFD have been employed to assess the velocity distribution in the metal- slag interface region in a slab mold. The analysis of results shows how higher casting velocity and lower immersion depth of submerged nozzle can lead to higher turbulence in the slag-metal interface. The effects of density difference between slag and metal and interfacial tension between the phases have been highlighted.

Jan 1, 2016

By Kikuo Okuyama, I. Wuled Lenggoro, Manabu Shimada

"Aerosol processing of materials such as (i) gas-to-particle conversion process (e.g., Chemical Vapor Deposition (CVD) method) and (ii) liquid (or droplet)-to-particle conversion process (e.g., spray pyrolysis) has become of major interest to produce novel submicron- or nanometer-sized particulate material used in electronic and chemical industries. After reviewing recent theoretical and experimental researches on the evaluation of properties and morphology of fine particles by the CVD and spray pyrolysis methods, the importance of the process engineering approach· for aerosol processing of materials and the use of advanced aerosol measurement technology have been pointed out.IntroductionMaterial synthesis via aerosol processing offers a route to producing nanometer-sized and submicrometer-sized particles of high purity with specifically tailored chemical and physical properties. Especially, single nanometer-sized particles (nanoparticle materials) are considered to play an important role in the synthesis of nanostructured materials as well as in nanotechnology in 21st century due to their quantum effect and so on.However, the transformation of gaseous or liquid precursors to the final functional particulate matters consists of various complex chemical and physical processes. In order to control the size distribution and morphology of produced particles, it is important to analyze and model various phenomena, such as gas-phase or liquid-phase chemical reaction, nucleation, condensation, agglomeration and sintering that occur simultaneously in aerosol material processing. By introducing the Aerosol Science and Materials Science, the authors have been trying to model the changes in particle properties and morphology by gas-to-particle conversion and droplet-to-particle conversion processes. The authors have also been trying to obtain the experimental data on the particles properties as accurate as possible."

Jan 1, 2000

By Shoji Taniguchi, Lifeng Zhang, Kaike Cai

"In the present paper, based on the two-phase (Eulerian-Eulerian) model, the 3D fluid flows in gas-stirred systems, i.e., air-stirred water vessel and argon-stirred liquid steel ladle, are simulated. In the Eulerian-Eulerian two-phase model, gas and liquid are considered to be two different continuous fields. The phases are assumed to share space in proportion to their volume fractions. The exchange between the phases is represented by source terms in conversation equations. Turbulence simulated by the k- e model is assumed to be the property of the liquid phase. The following effects of mathematical treatments and operational factors on the fluid flow are discussed, such as interphase drag force, turbulent model, the size of bubble, and gas injection mode.Some interesting results are derived. Except the interphase drag force, the interphase lift force should be taken into accounted in order to exactly simulate the fluid flow in gas-stirred systems. Suitable turbulent model and drag coefficient have effect on the mathematical simulation. Injecting small bubbles can realize a well mixing flow condition. The distance between the two gas-injection nozzles has effect on the fluid flow."

Jan 1, 2000

By Chang Wei, Zhigan Deng, Jiqiang Liao, Minting Li, Hongsheng Xu, Yan Song, Cunxiong Li, Xingbin Li

"Abstract: Direct ?otation of oxidized zinc-lead ore is characterized by recovery of zinc and lead only around 55% and 50%, respectively. Mineralogical analysis shows that the sample used in the present study is a carbonate hosted zinc-lead ore, with a zinc and lead carbonate content that accounts for 80.14% and 75.63% of the total minerals, respectively. The carbonate hosted zinc-lead ore was hydrothermally sulfidized with elemental sufur and the experimental data indicated that under the conditions employed up to 75% zinc and 82% lead sulfidation extent were achieved. As a result of pre-sulfidation followed by flotation, the recoveries of zinc and lead into flotation concentrate were over 90%. A flotation concentrate was obtained with 52% Zn and 37% Pb from the materials which was treated by sulfidation.IntroductionSulfide ores are the primary source of zinc and lead, and they are becoming depleted; thus, metallurgical investigators are interested in using abundant oxidized zinc-lead ore reserves. The high-grade zinc-lead oxidized ore, which normally has a zinc content higher than 15%, can be disposed of by acid leaching and electrolysis. However, the low-grade ore, which has a zinc content lower than 10%, is difficult to smelt with pyrometallurgy and hydrometallurgy, and the processes are very complicated and expensive in terms of production flow and energy consumption. Therefore, making the low-grade oxidized zinc-lead ore more beneficial has become more important in recent years. Flotation is the most common process, and the primary method of recovering zinc and lead from sulfide or oxide minerals. It is well known that there is a difference between sulfurized and oxidized minerals regarding their separation by flotation. Flotation of zinc and lead oxidized minerals is extremely complex because of the similarities in the physicochemical and surface chemistry of the constituent minerals. There are no known direct-acting collectors capable of producing single metal concentrates [1-3]."

Jan 1, 2012

By Marcelo B. Mourão

An experimental investigation was carried out to -study the rates of reduction of pellets containing iron oxides by carbon dissolved in liquid iron, at temperatures ranging from 1720 K to 1973 K. Several different pellet types were employed; the materials used in the pellet&apos;s manufacture were pure hematite, two kinds of commercial iron ores, and mixtures hematite/silica and hematite/lime: Reaction times were determined employing the constant volume pressure increase technique (CVPI). It has been observed that the reaction rate increases as the temperature and the pellet&apos;s specific surface area increases. The reaction rate is also affected by the oxide type: pellets made from commercial ores or from mixtures hematite/silica or hematite/lime show reaction rates lower than those made from pure hematite.

Jan 1, 1996

By J. McKelliget, J. Szekely, Oreper. G. M.

"1. INTRODUCTIONThis paper is concerned with heat and fluid flow phenomena in arc welding operations. Fig. 1 shows a schematic sketch of a typical arc welding arrangement. It is seen that an arc is being struck between an inert electrode and a metal surface and that the resultant current and energy flow will case the formation of a molten weldpool.It is clearly appreciated that the weldpool shape and the nature of circulation in the weldpool may play an important part in determining the ultimate weld quality. It is known, furthermore,· that the weldpool behavior in turn will be affected by the spatial distribution of the current and the heat flux it receives from the arc. Indeed, the inherent coupling between the arc and the weldpool is a key feature of welding operations.Up to the present useful work has been done on the modelling of heat transfer and melt circulation in weldpools (1,2,3,4) and also on the description of arcs, including welding arcs (5,6,7,8). However, the coupling between these two sets of phenomena is relatively unexplored in a qualitative sense. The purpose of the present paper is to examine the interaction between welding arcs and weldpools. The actual material will be presented under the following headings:"

Jan 1, 1986

By K. Asokan, K. Subramanian

"Electrowinning of copper by monopolar cells require common anode and cathode busbar and crossbars to connect each electrode to the respective common busbar. On the other hand, the bipolar configuration warrants the end electrodes only to be connected to busbars; there is substantial reduction in copper requirement. In the present work, an electrowinning cell with bipolar electrodes and end electrodes, each having an area of 1000 cm2 was designed and operated. The bipolar electrode is made of mixed metal oxide coated titanium mesh welded to plain titanium sheet. Coated titanium mesh acts as anode and the plain titanium sheet acts as cathode. Environmentally unacceptable lead anode and the recurring loss of lead are done away with. Closer spacing of the electrodes, paves way for the application of higher current density leading to mass transfer enhancement. Performance of bipolar copper electrowinning cell is reported.1. IntroductionThe normally adopted practice in electrowinning of copper is the conventional monopolar configuration. In this practice, the individual electrodes act either as anode or cathode. Hence there is a need to connect every one of the electrodes to the common anode or cathode busbar and crossbars running across the top of the cell are necessary. The common busbar carries very high current which is divided among the individual crossbars and hence has to be thicker in relation to the current load of the cell. The drawback of the need to use common busbars of thicker cross section and the need to have crossbars are obviated in the bipolar configuration."

Jan 1, 2009