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By A. M. Ramalho

In the synthesis and sintering processes to obtain superhard materials, such as diamond and cubic boron nitride, deformable ceramic capsule is used as gasket to transmit and support the required high pressures and high temperatures, HPHT. The ceramics materials for these capsules should have special physics and chemical characteristics such as refractoriness, shear strength and compressibility. In this work, Bridgman?s anvil made of hard metal or speed steel was used to characterize some ceramics materials in terms of their maximum compressible thickness. Tests were also performed with different resin polymers used as binding mixture with ceramics powder. Chemical analyses and investigations through scanning electronic microscopic (SEM), X-ray and real tests for the synthesis of diamond were also performed. The results showed that local Brazilian calcite can be successfully used in the manufacture of HPHT gaskets.

Jan 1, 2006

By Hong Yong Sohn

Keywords: Barium sulfate, Barium sulfide, Environment, Kinetics, Pollutants, Sulfur dioxide conversion, Thermodynamics Nonferrous smelters and coal gasification processes generate sulfur dioxide streams, most of which are treated to produce sulfuric acid with the accompanying problems of market shortage and transportation difficulties. While the conversion of sulfur dioxide to elemental sulfur has many environmental advantages, no processes exist that are environmentally acceptable and economically viable. A method for converting sulfur dioxide to elemental sulfur by a cyclic process involving calcium or barium sulfide and calcium or barium sulfate without generating solid wastes has been developed. In this process, the sulfate, as the starting raw material, is reduced by a suitable reducing agent such as hydrogen to produce the sulfide, which is used to reduce sulfur dioxide producing elemental sulfur vapor and regenerating the sulfate. The latter is then reduced to reproduce the sulfide. This paper describes work on the BaS/BaSO4 system. Thermodynamic analysis and experimental results indicated that the BaS-SO2 reaction produces mainly sulfur vapor and solid barium sulfate and that the gaseous product from the BaSO4-H2 reaction is mainly water vapor. The rates of the two reactions are reasonably rapid in the temperature range 700-1050°C.

Jan 1, 2005

By Liyuan Chai

In this study, spent grain was used as an adsorbent for the removal of Hg(II) from aqueous solutions, the process parameters such as contact time, solution pH, adsorbent dose, and initial Hg(II) concentration were studied in batch experiments. The initial adsorption process was fast, 91.08% of adsorption occurred within 5 min and equilibrium was reached at around 30min. Adsorption process was found to follow pseudo-second-order kinetics. The equilibrium data were better fitted to Langmuir isotherm than Freundlich isotherm with the maximum adsorption capacity 41.36 mg/g. The structure and component of spent grain before and after adsorption of Hg(II) were investigated using scanning electron microscope(SEM) and energy dispersive X-ray analysis(EDAX), these analysis also confirmed the adsorption of Hg(II) onto spent grain. The results indicated that spent grain had potential as a new inexpensive adsorbent for Hg(II) removal from aqueous solutions.

Jan 1, 2009

By Keith S. McIntosh

The fire assay process for the quantitative recovery of platinum group elements (PGE?s) prior to subsequent analysis traditionally is a time-consuming process. Samples derive from various ore types and contain PGE?s at the ppm or ppb levels, making concentration of the elements mandatory before assaying. Traditionally sample turn-around times are of the order of 24 hours. The whole sequence of sample preparation, fire assay and subsequent analysis of PGE?s have been automated by Anglo Platinum. Some of the major challenges on the road to automation will be discussed and the novel solutions that were implemented. The engineered solution included robotic automation of the whole sequence, from sample preparation, up to the final element by element assay. The final system allowed for rapid (less than one hour) and accurate analysis of PGE?s even in streams containing very low levels, such as flotation tailing streams and drill core samples.

Jan 1, 2006

By Yufeng Guo

Mineralogy and physico-chemical characteristics of a nickel hydrometallurgical residue and recovery of iron-bearing minerals by flocculation-magnetic separation were studied. The results show that the nickel residue is super-fine and fraction less than 0.045mm reaches 85.4%. Ferrous minerals are chiefly magnetite and ferruginous glass. Magnetite accounts for 31.7% and exists as free magnetite. Ferruginous glass is of multicomponent amorphous substances with low-iron grade but strong magnetism, and accounts for 39.9% of total iron minerals. Addition of flocculants increases granularity and magnetic force of fine iron-bearing particles and improves iron grade and recovery. The tests with flocculation separation show that a concentrate assaying 56.68% Fe with 81.72% recovery was obtained in a magnetic tube. A concentrate with 56.92% iron grade and 67.96% recovery was obtained by flocculation-magnetic separation with a magnetic cylinder.

Jan 1, 2006

By Wang Shulan

The synthesis process of BaTiO3 from TiO2 and BaCO3 in the molten NaOH-KOH at 350oC was studied by the A.C impedance technique. The A.C. impedance of molten NaOH-KOH (xNaOH = 0.36) and the variation of the conductivity of the salt with time during the synthesized process were measured. The synthesized reaction of the BaTiO3 and the decomposition reaction of BaCO3 are fast and were finished in 10min. The interaction between TiO2, BaO and BaTiO3 and the molten salt was confirmed by the variation of the conductivity.

Jan 1, 2005

By H. Doostmohammadi

During the tapping of liquid steel from Electric Arc Furnace (EAF), some slag is carried over into the ladle. High levels of FeO and MnO in slag carryover increase the oxygen activity in steel melt leading to oxide inclusion formation during the ladle treatment. The demand on cleaner steels requires minimization of carryover slag. In this work, the effect of EAF slag carryover on ladle slag-steel equilibrium calculations for a hot working tool steel was studied. Steel and slag sampling were done in Uddeholm Tooling AB in Sweden. XRF and OES techniques were used to determine chemical composition of samples. The quantity of slag carryover was calculated based on a mass balance followed by thermodynamic calculations on metal-slag equilibrium using Thermo-Calc software. The agreement between predictions and experimentally determined compositions was good. This leads to the development of a prediction method for optimizing the production of other tool steel grades.

Jan 1, 2009

By M. Hochenhofer

Keywords: desulfurization, mathematical model, slag reaction To produce ferroalloys like ferro-nickel for alloying purposes in a quality that meets the requirements of today?s steel industry, refining processes like desulfurization and dephosphorization are indispensable. The performance of desulfurization-treatment by slag reaction depends on various parameters, such as: sulfide capacity and viscosity of the slag, sulfur distribution between metal and slag, activity of sulfur in melt and movement of melt. Within this work, the combined influences of these parameters on the desulfurization of a ferro-nickel alloy were examined. As a basis for this examination, a mathematical model, based on data from plant trials, was created. This model demonstrates the relationship between desulfurization rate and initial values of the above mentioned parameters. With this model the relevant parameters were evaluated and assessed concerning their influence on desulfurization.

Jan 1, 2005

By Fiseha Tesfaye, Pekka Taskinen, Daniel Lindberg

Due to increasing complexities of raw materials for base metals production the conventional pyrometallurgical processes are challenged. To make the appropriate modifications, thorough evaluations of the thermal stabilities of phases and phase assemblages which are commonly encountered in these processes are essential. In this work, phase relations and thermal stabilities of equilibrium phases in the Cu-Ni-S system have been reviewed. The calculated phase diagram of Cu-Ni system has been validated. At T < 630 K, in the Ni-rich corner, large scatter in data has been observed and discussed in detail. The other binary systems, Cu-S and Ni-S, have been also critically reviewed together with the ternary Cu-Ni-S system. The reviews were focused on compiling and discussing phase relations and thermal stabilities of the selected systems in the pyrometallurgical processes of Cu and Ni productions.

Jan 1, 2016

By Sergio N. Monteiro

Jute fiber reinforced polymer composites are among the most investigated and applied natural composites. In this past decade the mechanical properties of these composites has been assessed for various types of test conditions. However, the reported results correspond mainly to short-cut jute fiber composites, which do not present the highest mechanical strength as compared to continuous fibers of the same kind. In order to complement these results, the present work evaluated the mechanical behavior, by means of flexural tests, of polyester matrix composites reinforced with continuous jute fibers. Bend tests were conducted in standard specimens with up to 40% of jute. Fracture analysis by SEM displayed the rupture mechanisms. The results showed an improvement in some flexural properties with incorporation of jute fiber. However, a low fiber/matrix interfacial stress was responsible for limitation in the values attained by some properties.

Jan 1, 2010

By Jewel A. G. Gomes

Electrocoagulation (EC) has been performed with Al-Fe electrode system with changing polarity for the removal of arsenic from water. The removal process has been studied using ICP-AES and Anodic Stripping Voltammetry with a wide range of arsenic concentration (1-1000 ppm) at various pH (4-10) and residence times (1-60 min). Electrochemically generated by-products have been analyzed using XRD, FTIR, XPS, SEM/EDS and Mössbauer Spectroscopy. Results revealed expected crystalline iron oxides (magnetite (Fe3O4), lepidocrocite (FeO(OH)), iron oxide (FeO)) and aluminum oxides (bayerite (Al(OH)3), diaspore (AlO(OH)), mansfieldite (AlAsO4?2(H2O)), as well as some interaction between the phases. The amorphous or ultra-fine particular phase was also found in the floc. The substitution of Fe3+ ions by Al3+ ions in the solid surface has been observed, indicating an alternative removal mechanism of arsenic in these metal hydroxides and oxyhydroxides by providing larger surface area for arsenic adsorption via retarding the crystalline formation of iron oxides.

Jan 1, 2006

By Sergio N. Monteiro

Wastes generated by our society and the question on how to dispose them is, nowadays, a relevant matter of concern. The objective of the present work was to characterize the technical properties of composites made of discarded jute sackcloth with its coarse wove fabric, serving as reinforcement phase, and polyethylene wastes collected from city dumps, as continuous matrix. Different amounts, up to 30 wt.% of jute plain weave, fabric were press molded at 160°Ctogether with sieved polyethylene particles. The resulting composites displayed mechanical properties that could compete with those of low-density wooden board. Both by presenting a solution to, otherwise, disposed wastes and by helping to prevent deforestation, the investigated composite may be regarded as an environmentally correct material.

Jan 1, 2006

By Daniel Bennett

There are few methods currently applied towards on-line bulk mineralogical analysis. Yet on-line knowledge of process mineralogy could potentially provide large benefits, such as increased extraction efficiency or resource optimization. The work described in this paper involves the development of radio frequency methods for bulk mineralogical analysis. Some resonances that occur in the radio frequency spectrum are mineral specific, and potentially allow quantitative estimation of mineralogy in an ore stream. Results will be presented on the specific detection of chalcopyrite. Initial quantitative measurements investigating matrix effects have indicated the feasibility of on-line mineralogical estimation using radio frequency techniques.

Jan 1, 2006

By Regina Maria Pinheiro

This work has for objectives to characterize a waste generated in the form of sludge during the treatment of the effluent of a paper making industry and to evaluate the effect of its incorporation in the amount of 10 wt.% on the properties and microstructure of a clayey body used for brick production. For the characterization of the waste the following techniques were used: X-ray diffraction, X-ray fluorescence, differential thermal analysis and termogravimetric analysis. Incorporated bricks were produced in industrial scale before firing at 750°C in a Modified Caieira type furnace. The physical and mechanical properties evaluated were water absorption and compression strength. The microstructure of the fired ceramic was evaluated by optical microscopy. The environmental evaluation was made by solution test and atmospheric emission by monitoring the release of SO2, NOx and particulate material. The results showed that, in agreement with the characteristics of the waste, its recycling into red ceramic can contribute to decrease the consumption of fuel during the firing stage. The properties of the fired ceramic attend the norms. With respect to the environmental aspect, the incorporation of the waste did not impact the environment.

Jan 1, 2009

By Han-Tao Hu

Keywords: RH refining process, flow of molten steel, two-phase flow, gas holdup, circulation rate, mathematical modeling A three-dimensional mathematical model for the flow of the molten steel in the whole degasser during the RH refining process has been proposed and developed with considering the physical characteristics of the process, particularly the behaviors of gas-liquid two-phase flow in the up-snorkel and the momentum exchange between the two phases. The fluid flow fields and the gas holdups of liquid phases and others respectively in a 90 t RH degasser and its water model unit with a 1/5 linear scale have been computed using this model. The results showed that the flow pattern of molten steel in the whole RH degasser could be well modeled by the model. The liquid can be fully mixed during the refining process except the area close to the free surface of liquid and zone between the two snorkels in the ladle, but there is a boundary layer between the descending liquid stream from the down-snorkel and its surrounding liquid, which is a typical liquid-liquid two phase flow, and the molten steel in the ladle is not in a perfect mixing state. The lifting gas blown is rising mostly near the up-snorkel wall, which is more obvious under the conditions of a practical RH degasser, and the flow pattern of the bubbles and liquid in the up-snorkel is closer to an annular flow. The calculated circulation rates for the model unit at different lifting gas rates are in good agreement with the determined values.

Jan 1, 2005

By Sergio N. Monteiro

Natural lignocellulosic fibers are successfully replacing synthetic fibers in many engineering applications. In addition to well-known conventional lignocellulosic fibers, others with promising properties are now being considered. The present work investigated the mechanical and structural characteristics of a relatively high strength fiber, curaua (Ananas erectifolius) from the Amazon region of Brazil. The results obtained from tensile tests confirmed the superior strength while scanning electron microscopy (SEM) analysis displayed features that justify the possibility of using the curaua fiber as an effective reinforcement for polymeric composites.

Jan 1, 2006

By Xiangjun Zuo

This paper firstly reviewed the state of the art in the recycling of used Printed Wiring Boards (PWB), and then presented part of the authors study on the combustion of PWB powders with and without the addition of catalyst. During the combustion of PWB powders without catalyst addition, there were two obvious exothermic reactions, one at 300-380oC, the other at 450-500oC. With the addition of catalyst during PWB combustion, there were no obvious exothermic reactions, indicating that dehalogenation reactions are not exothermic: The results showed that NaHCO3 and CaCO3 were very efficient to control the emission of Br2 and C6H6, lowering 80% compared to the case without catalyst, Na2CO3 can slightly control the emission of Br2 gas but not for C6H6 gas mission, and NaOH has no any effect of the control of both gases.

Jan 1, 2009

By Xiangwen Wang

Electrochemical measurements associated with the electrowinning of lead metal from concentrated brine (NaCI) - lead chloride (PbCI,) electrolytes at temperatures in the range 328 to 353°K (55 - 80°C) were conducted. The electrodeposition of lead metal onto a lead rotating-disk electrode may be described by the electrodic reaction: {PbCl 4 2 + 2e- = Pb° + 4Cl-} The deposition-overpotential requirements are low (approximately 41mV per decade of current density - Am+), with a corresponding high exchange current (approximately 0.018 A.cm2). The diffusion coefficient of the electroactive PbC142- species in a 3.5 NaCl electrolyte at 353°K was insensitive to the total PbCI, concentration (0.01 to 0.1M), and its value was found to be (1.21*0.1)~10-5 cm2Is with a temperature-sensitivity coefficient (E,/R) of approximately 1.98x103K-1 (328OK(T<353OK).

Jan 1, 1993

A sinter plant baghouse dust has been treated as a hazardous solid waste, and disposed at a very high price. A series of leaching tests were conducted to examine the possibility to produce high grade potassium chloride from the solid waste. It is found that around 40% of the solid wastes can dissolve into water, and a deposit with more than 90% KCl can be produced after simply drying the solution.

Jan 1, 2009

By Raj P. Singh Gaur

Due to high concentration of NaOH in the digested slurry after scheelite digestion, it is diluted to about 4N before filtration to separate sodium tungstate solution from the sludge (residue). However, in practice there may be deviations in the normality of NaOH present in the slurry. There may also be variations in the temperature of the slurry and filtration time. Slight variations in these parameters could cause tungsten losses in the sludge via the back reaction: Ca(OH)2 + Na2WO4? CaWO4 + 2NaOH This paper pertains to the effect of normality, temperature and time on the tungsten losses in the sludge that is separated from ?diluted-scheelite-slurry-in-NaOH? via filtration. Results indicated that tungsten losses in the filtered residue (sludge) were quite significant when the slurry temperature was kept at 70°C or higher. The effect of high temperature was less significant at the slurry normality of 3.6 or higher. Combination of low slurry normality (<3.6) and high temperature (>60°C) resulted into large W-losses in the sludge.

Jan 1, 2006