Search Documents

By C. Heckman, M. S. Moats, A. Luyima, W. Cui

"Nucleation and growth of copper on 316L stainless steel from synthetic acidified copper sulfate was studied in the absence and presence of chloride ions and/or organic additives – HydroStar® 4208, DXG-F7® and Cyquest® N-900 – using a potentiostatic technique. The current–time data obtained at 0.16V versus the SHE were analyzed using nucleation and growth models. Scanning electron microscope (SEM) images of deposits produced at 300 A/m2 show that the addition of 20 mg/L chloride ions increased the size and reduced the number of copper nuclei. Potentiostatic current–time data from the electrolyte without organic additives, and confirmed by SEM images, indicate progressive nucleation with two-dimensional growth under diffusion control. None of the organic additives studied at a concentration of 2.5 mg/L with 20 mg/L chloride changed the nucleation and growth mechanism, but the additives increased the number and reduced the size of copper nuclei, leading to more uniform coverage of the stainless steel substrate.IntroductionElectrowinning of copper is an important process in the manufacture of high-purity copper metal. Approximately 20 percent of the world’s refined copper is produced from acidified copper sulfate solutions by electrowinning (Schlesinger, Sole and Davenport, 2011). In many plants, copper is electrodeposited on AISI 316L stainless steel substrates for a period of 6-7 days, after which the copper is stripped from the blanks. Even though the deposition time for a commercial copper electrowinning circuit is around one week, it is critically important to control the nucleation, growth and nature of the initial deposit (Sun and O’Keefe, 1992).Deposit morphology and structure are influenced by the real current density at the electrode surface. The real current density across the cathode surface is made uniform by proper design of the electrowinning cell and electrodes and careful operational practice. Even with good design and control, some current maldistribution occurs. The outcome of severe current maldistribution is poor deposits that affect product quality and/or increase energy consumption. To combat current maldistribution and create a larger operating window in terms of current density, temperature and copper concentration, small amounts of organic smoothing agents – traditionally, guar products – are added to copper electrowinning electrolytes. Moreover, these additives inhibit the growth of copper nodules and lead to improved deposit quality by producing bright, smooth and dense cathodes.Recently, the use of polysaccharides, such as HydroStar 4208 and DXG-F7, and polyacrylamides, such as Cyquest N-900, has been reported in commercial electrowinning tankhouses as replacements for guar (Ashford, Clayton and Sandoval, 2012; Robinson et al., 2013; Sandoval, Morales and Bernu, 2010). However, little information has been published on the effect of these new organic additives, especially regarding the nucleation and growth mechanisms of copper electrodeposits in their presence."

Jan 1, 2016

By R. J. Watters

Many rock sass classification systems exist' to assist the engineer in assessing the rock support requirements for underground design. Our ongoing research in this area is directed at attempting to utilize the fractal dimension and the acoustic emission' response of the tuffs at Yucca Mountain, Nevada to further aid in rock mass classification. The Topopah Spring' member, the proposed nuclear waste horizon, is characterized by welded and partly welded tuffs, exhibiting a wide range in moduli, strength, porosity and degree of fracturing. Differentiating between the different' types of porosity can be extremely difficult if not impossible. An attempt was made to correlate the acoustic emission response with the porosity of the sample. Events and the peak amplitude may offer a means-to distinguish between, fracture porosity and pore porosity. In addition-, fractal dimension were calculated for several fractures in densely welded tuffs. Two techniques for calculating fractal dimension were-applied' to describe-fracture geometry and roughness. Fractures in-welded-tuff were-found to be relatively smooth.

Jan 1, 1989

By D. G., Bosse&apos

Equipment choices for ultrafine grinding encompass several different types of dry and wet size-reduction devices. These need to be put into functional perspective for systematic analysis of capabilities and limitations versus processing requirements of the materials to be satisfactorily ground. Particle strengths plus maximum and average sizes are the primary variables controlling grinding action requirements and equipment options for efficient processing. These are fairly well understood and provide the starting point for decisions. Particle space requirements under dynamic processing conditions vary with particle shapes and size-distributions by as much as 30X. This additional major variable is not widely appreciated and does need adequate description to provide a firm basis for selecting processing compositions and procedures.

Jan 1, 1983

By M. L. Maniocha

Most magnesia, MgO, whether of natural or synthetic origin, is utilized in its dead burned or periclase form as refractory linings for the production of steel. Continued research in refractory science combined with good refractory maintenance and improvements in steel making practice have resulted in decreased use of magnesia. To make up for this loss of business producers of synthetic magnesia have started to manufacture a variety of magnesium based chemicals that are utilized in many diverse industries and applications.

Jan 1, 1997

By Clement K. Chase

Although flotation is the generally accepted process employed to recover gold and silver as well as copper, lead, and zinc from primary sulfide ores, the metallurgical requirements for the treatment of massive sulfide ore deposits differ markedly in many respects from those employed for the more common disseminated porphyry deposits. In Arizona, some properties classified as other then massive sulfide deposits because of mining and geological characteristics have produced mill-feeds similar to those from massive deposits. Several such occurrences are noted. The process requirements for massive sulfide deposits and unique mill-design implications are discussed in the perspective of world-wide economic considerations and the individual regional metallurgical and economic constraints in the United States.

Jan 1, 1986

By L. Gutierrez, S. Gering, C. Calderon-Arteaga

"INTRODUCTION Drill and blast (DnB) represents the most important, and sometimes the most costly processes in a mine.. The cost of drilling and blasting operations greatly contributes to the “high cost trends of the overall mining operations” (Afum B. O. and Temeng V. A. 2015). The use of available information to improve the DnB processes can be the difference between a highly expensive process and an optimized one. Mining operations have access to several types of data sets and key information from a wide variety of different systems. This information is normally used to improve, evaluate and apply processes for drilling and blasting. This may include different types of data from the different stages of the process (before, during, and after the drilling and blasting operations), such as hole locations (planned and actual), penetration rates, drill operators, fragmentation (expected and resulting), explosive (design and usage), geology, vibration, and others. This information can be used on its own or combined for further analysis to reduce costs, improve safety, and evaluate results. Fortunately, due to advances in mining software, drill and blast engineers can exploit this data and create reports to evaluate results and improve the DnB process. However, as users start combining information from multiple datasets and establishing standard operating procedures for reporting this data across multiple sites, it becomes valuable to create auditable, automated, and sustainable processes for handling the information. In many cases the task of aggregating and standardizing the data formats has already been completed and is available to consumers via the Enterprise Data Warehouse (EDW). A data warehouse team extracts data from the source systems and transforms it so that it is meaningful for decision support (Barbara H. Wixom, Hugh J. Watson, 2007). Our initial implementation plan for the DnB solution included using data stored at the sites; however we learned early on in the process that much of the work for aggregating and supplying the required data was already completed. The goal for this case study is two-fold: to show how information can be used to make decisions and improve processes, highlighting the value of using an EDW for managing Drill&Blast information; and to discuss how technical challenges encountered during the implementations were resolved. This paper is targeted at users that want to better manage their DnB data or try to set up standardized workflows for using this information. This case study will discuss the process of implementing a DnB workflow at multiple sites within Freeport McMoRan Inc (FMI) using both data at the sites and information available using the EDW. The paper will begin with an overview of the project. The discussion will then describe how DnB processes were used to set up daily workflows in order to provide information for evaluating process and making decisions. The final section will discuss some of the technical challenges and how they were solved, as well as possible next steps for further improving the workflow."

Jan 1, 2017

By B. N. Everett

The growing role of Colombia as a major supplier of internationally traded steam coal has been widely discussed in the industry. Although Colombian coal has been produced and exported in small quantities for a number of years, Colombia's position as a major coal exporter began in earnest in 1985 with the first commercial exports from the Cerrejon North Block Project. By way of background: ? The mine is located on the Guajira peninsula in Northeast Colombia, about 90 miles from the coast, as shown in Figure 1. ? In addition to the mine itself, the project involves construction of a dedicated railroad and port, which form a modern, efficient and integrated system. ? The Project is embodied in a 50/50 Association Contract between International Colombia Resources (Intercor), a wholly owned subsidiary of Exxon, and Carbocol, the Colombian state coal company. Intercor and Carbocol share investment and operating expenses equally and Intercor has the additional responsibility of managing operations on behalf of both partners. Each partner is entitled to 50% of the coal produced, and each markets its share separately. ? The project is a multi-seam, truck and shovel operation, based on large reserves (2-3 billion tonnes') of high quality bituminous coal. ? Exports began in the first quarter of 1985 at modest levels through what we call Early Coal Facilities, designed and constructed apart from the permanent coal handling system. ? Production will increase rapidly in each of the next few years, reaching the design capacity of 15 Mt per year in 1939. Based on available resources, however, the resource will support expansion, and continued growth n production into the 1990s appears feasible.

Jan 1, 1986

By M. Niec

Lignite deposits in Poland occur within clastic Tertiary series at the depth suitable for opencast mining. Aboundant aquifers with the good quality waters that should be protected against contamination or depletion often accompany them. Landscape and underground water protection are the main regional environ-mental factors that limit the possibility of exploration and mining; presented on map of lignite bearing series distribution allow to delimit areas "free" for exploration and mining and areas where some limitations can be met up to no admittance of any industrial activity.

Jan 1, 1994

By C. E. Jordan

The fundamental characteristics of ultrafine chalcopyrite flotation were investigated by the Bureau of Mines to establish techniques to improve recovery of ultrafine chalcopyrite. Intense agitation during conditioning was found to improve flotation recovery of the ultrafine chalcopyrite. A split-circuit flotation design, treating the plus 38-µm-size ore by the conventional method and treating the minus 38-µm-size ore with intense agitation conditioning followed by flotation, recovered 95.6 pct of the copper in a 28.3-pct-copper concentrate, This was a 5-pct increase in copper recovery over the conventional chalcopyrite flotation method.

Jan 1, 1986

By K. S. Olson

My reaction when first asked to present this paper was; "What could I possibly say that would hold the audience?s attention for 15 minutes? What could I offer that anyone familiar with the Nevada Barite Industry wouldn't already know?" Well, quite frankly I can't. The industry has certainly been anything but exciting for the past 10 years and, in fact, quite depressing. The challenge, for those few of us left in it, has been to keep it alive. At times it has felt like a doctor must feel with a terminally ill patient. All I can do is recap the past ten years, review the present state of the industry, and offer a few personal opinions and observations as to where I think we are headed.

Jan 1, 1993

By T. Cantwell

Techniques useful in operations, analysis are applied to the problem of planning an exploration program. The model used treats mineral exploration as a Markov process, and maximization of gain is the criteria determining the optimum program. The mathematical description of the model and the optimization are first worked out. Application of the mathematics to several simple examples is given. Finally, comparison of the data necessary to use this operations analysis with the available data shows that the method can only be a guide to planning an exploration program.

Jan 1, 1962

By W. W. Hartley

Following a Major underground coal mine incident there followed a review of the role of mines rescue ? the Queensland Mines Rescue Brigade. It wasn?t until 2002 that the real change started to happen. The issue of geographical distance was addressed by mines rescue sub stations being located on the mines sites with parent rescue stations in a central location. The funding was by means of a levy on the mining industry with legislative standards and performance included. The previous Rescue Brigades were not well organised (central districts) and the application of recognised quality management practices within local management was lacking. The structure was based on other nations models and miners managing miners was an issue for the organisation. The reform was some what painful and the QMRS organisation will still evolve with continuous improvement. Queensland has the National Champion mines rescue team for the eighth year. QMRS is participating at the level in the industry of influencing emergency systems and training senior mine management in ?Emergency Mine Management? coaching the industry in emergency response systems. We have come a long way. We have had some success and there is always the challenge of setting the standards, those we should aspire to and the courage to influence the industry to higher goals of a safer future.

Jan 1, 2010

By V. R. Bovino

You have afforded me the challenge of saying something profound in 20 minutes that will stay with you for 20 years. My hope is that from this presentation you will extract ideas that will move you? out of your offices, into the mine to seize upon the concepts that we will discuss. Your challenge is to transform those concepts into action and give life to the ideas discussed here. The notion of achieving limitless productivity produces peak levels of enthusiasm in today's mining leaders. Highly-productive mines do not happen by chance --they are created by progressive leaders. The quest for productivity improvement, exclusively through capital investment and technological advances, is an incomplete process. Improvement, through capital and technology, is often not achieved because we fail to energize the true potential and commitment in our employees.

Jan 1, 1991

By C. Patrick

Annually, the U.S. coal industry generates and must dispose of over 200 million tons of coal refuse, expanding a major environmental problem. The purpose of this research was to investigate the feasibility of utilizing coal refuse as an aggregate in concrete. This paper reports on findings of the initial phases of a project to determine the viability of replacing traditional concrete blocks, used for under-ground ventilation stoppings, with refuse blocks. Refuse was collected from three active preparation plants in Eastern Kentucky and used as the primary aggregate for concrete cylinders. The refuse fell within ranges normally observed for size consist, moisture, and ash. Stress-strain analyses yielded compressive strengths of the refuse cylinders from 59% to 77% of the control group strengths. Low variability within groups while significant differences between groups were found. On-going determination of effects of weathering on the refuse cylinders is being conducted and will be completed in early 1995. The research results are favorable for the future direction of the overall project objectives.

Jan 1, 1995

By Thomas F. Torries

It does not take sophisticated economic analysis to determine the current status of nickel production and demand (Figure 1). One only needs a quick glance at the balance sheets of the major nickel producers to learn that prices are down and profits are supressed to the point where they are major losses. Operations have been closed, and those remaining in production have reduced output. What Is now of interest Is, when will the nickel market improve and to what degree? The purpose of this paper is to attempt to answer these questions. This will be done by the normal method of projecting nickel demand, chosing a production scenario, and analyzing the results.

Jan 1, 1982

By Fred C. Wrobbel

Two counties in Illinois, Ope and Hardin, and three counties in Kentucky, Crittenden, Livingston and Caldwell comprise the entire Kentucky-Illinois fluorspar district. The output from these five counties, however, makes up over 60 percent of our domestic fluorspar production, amounting to some 175,000 tons of finished product in 1956, The area is rough and hilly. It is bisected by the Ohio River, and has numerous smaller rivers and creeks. Add to this a generous average annual rainfall, in excess of forty inches, and it is understandable that the-area-can boast of an ample water supply. An abundance of water, however, is unfortunately not always conducive to ideal mining conditions. The faulted structure of the area and the soluble Mississippian limestones make the subsurface sediments' willing hosts to the surface water. Limestone cavers and sinkhole topography also compound the occurrence of underground water. It is little wonder, then, that water frequently presents an economic problem in the area, particularly in vein-type mining.

Jan 1, 1958

"HISTORY Tube bundle systems have been used in the coal mining industry for gas detection since the 1960’s. At the time there were developments were underway for improved gas monitoring systems. The primary gas detection systems in use were the flame safety lamp, colorimetric stain tubes and the taking of samples for analysis by gas chromatography. The MSA D6 hand held methanometer was approved in the UK for statutory methane measurements in 1972 and became very popular due to its smallness and simplicity of use. In 1973 Sieger Limited also developed a BM1 methanometer which could be installed underground and relay methane concentrations to the surface. Similar developments were underway for carbon monoxide detection and one was developed in 1982 by the Yorkshire Regional Laboratory of the NCB commercial development was undertaken by Sieger Limited who named it the ‘SCO1’. The UNOR 1 carbon monoxide and methane analyzers were approved for underground use in the United Kingdom in the late 1960’s.5 The technique was developed by Dr Luft of Bergbau-Forschung Essen and the equipment was manufactured by Maihak in Germany. The apparatus was flame proof and provided an intrinsically safe output which allowed the result to be telemetered to the surface through colliery communication systems. Both analyzers work on the same principal and each of the gases adsorb a certain wavelengths of infrared radiation. The detector measures the residual transmitted radiation and determines the percentage of gas present in the sample. These flameproof versions had proven to be robust and reliable. The UNOR 1 had been used in the Saar region of Germany and Scotland in the UK. The development of tube bundles for hydraulic controls enabled the development of the tube bundle gas monitoring systems we know today. A bundle of tubes are taken underground through a shaft, a borehole or drift then distributed to the required monitoring points. This enabled the ongoing monitoring of the underground environment when the power was isolated at 1.25% CH4. In 1972 the United Kingdom (UK) National Coal Board (NCB) produced a hand book for tube bundle systems which was subsequently updated in 1974. This is a useful guideline into the operational aspects of tube bundles systems at coal mines6. Many of the processes identified are being followed today. The United State Bureau of Mines (USBM) prepared a circular similar to the NCB handbook on tube bundle systems.7 The circular was prepared by Litton C and it was targeted at the design criteria for tube bundle the systems. The circular also states that “pneumatic monitoring systems can be used to monitor for hazards that develop quite quickly”."

Jan 1, 2016

By K. W. Deter

The gold ores in the Jerritt Canyon district have been recognized as refractory since they were first encountered by FMC geologists in 1976. Upon obtaining managing rights as joint venture partner, Freeport McMoRan Inc. developed an operating plan featuring carbon-in-leach gold recovery techniques for the oxide portion of the ores and a patented sulphide oxidation step followed by chlorination for treating the organic carbon constituents of the refractory ores prior to CIL gold recovery. The plant was successfully started up in 1981 with the first gold poured on July 4, 1981. Initial plant throughput was designed to be 2495 MTPD (2750 STPD) total through the dual processing trains.

Jan 1, 1991

By T. J. Fronapfel

Impacts to ground water from mining are being comprehensively regulated in Nevada through specific requirements for design, construction, operation, permitting and closure. This program is the nation's most comprehensive for control of activities at mining operations which have the potential to cause groundwater degradation. It encompasses virtually all types of facilities, including placer, physical separation, flotation, testing, leaching and milling. Minimum design requirements are established by regulation, and must be met by each facility. Site-specific monitoring requirements are established for each facility, and are heavily emphasized. Regulatory and technical requirements and relevant permit conditions are presented and discussed.

Jan 1, 1992

By Jurgen Hahn

The paper reports on both, the design and decision making for the filters in a backfill plant in Europe as well as more then 10 years of operation and maintenance experience of the vacuum disc filters installed. It begins with the first step, the filter sizing based on a sample provided by the customer, followed by the commissioning of the filter units and reports on the development of the filter performance during the following 10 years of operation. Based on the physical properties of the sample and the process targets of the client for the backfill plant, the paper shows the logic steps taken in the laboratory to ensure the target moisture, determine the required filtration area and filter size as well as the selection of the ancillary units and the formulation of the performance guarantee. The paper discusses some issues with filter operation during the commissioning phase and the actions taken. Finally, the paper concludes by highlighting the gradual change over the more than 10 years of operation and how this change affected filter performance and operating costs.

Feb 1, 2024